Practice Packet Unit 6: Moles & Stoichiometry

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Regents Chemistry: Mr. Palermo Practice Packet Unit 6: Moles & Stoichiometry 1

LESSON 1: Moles and Molar Mass 1. Put an M if the substance is molecular/covalent, an I if ionic under the formula listed. Then Fill in the remainder of the table Formula Moles of each atom Total moles of atoms Formula Moles of each atom Total moles of atoms a. HClO 3 f. CaCl 2 b. NH 4C 2H 3O 2 g. Mg 3(PO 4) 2 c. Mg(OH) 2 h. CH 3CH 2CH 3 2. Complete the table below. Use Table E!!! Ionic Compound Cation (+ ion) Anion (- ion) Total moles of ions Ionic Compound Cation (+ ion) Anion (- ion) Total moles of ions a. NH 4C 2H 3O 2 e. CaF 2 b. Ba(NO 3) 2 f. Al 2O 3 c. Li 2CO 3 g. KMnO 4 d. NaHCO 3 h. (NH 4) 3PO 4 2

Calculate the gram formula mass (molar mass) and don t forget the units!!! 1. CO2 9. Fe2O3 2. FeS 10. MgO 3. NaCl 11. Ca(OH)2 4. Al2(CO3)3 12. CH4 5. SiO2 13. NH3 6. H2SO4 14. H2O2 7. Al2(SO3)3 15. NaHCO3 8. C12H22O4 16. C6H12O6 3

Lesson 2: Calculating Moles Solve for the mass given the moles. (Show your work) 1. 2.00 moles of C6H12O6 5. 12.0 moles of SiO2 2. 5.00 moles of SrSO4 6. 0.330 moles of FeS 3. 0.250 moles of CH4 7. 1.50 moles of MgO 4. 0.100 moles of NH3 8. 0.500 moles of ZnCl2 4

Find the number of moles in the following measurements: (Show your work) 1. 900. grams C6H12O6 5. 22 grams of CO2 2. 24.5 grams H2SO4 6. 20. grams of Fe2O3 3. 192 grams SiO2 7. 3.40 grams of H2O2 4. 450. grams of ZnCl2 8. 840. grams of NaHCO3 Regents Practice: 5

Lesson 3: Mole to Mole Ratios Use the formula below to answer questions 1-7 3Cu + 8HNO3 3Cu(NO3)2 + 2NO + 4H2O 1. If 1.00 mole of water is produced, how many moles of HNO3 are used? 2. If 1.50 moles of copper are used, how many moles of NO are produced? 3. If 4.50 moles of HNO3 are used, how many moles of copper (II) nitrate are produced? 4. If 0.200 moles of NO are produced, what is the mass of copper (II) nitrate produced? 5. If 9.00 grams of water are produced, how many moles of copper were used? 6. If 3.00 moles of copper are mixed with 4 moles of HNO3, how many moles of NO can be formed? 7. If 16.0 moles of HNO3 react with 4.00 moles of copper, how many moles of water are produced? 6

Use the formula below to answer questions 8-13 Fe2O3 + 3CO 2Fe + 2CO2 8. If 3.00 moles of Iron (III) oxide are used, how many moles of Iron are formed? 9. If 2.50 moles of CO are used, how many moles of carbon dioxide are formed? 10. If 8.56 moles of iron were produced, how many moles of the iron ore were used? 11. If 25.68 grams of iron (III) oxide were used, how many grams of carbon dioxide are formed? 12. If 3.00 moles of iron (III) oxide react with 5.50 moles of CO, how many moles of CO2 are formed? 13. If 1.00 moles of Fe2O3 react with 4.00 moles of CO how many moles of the excess reactant are left over? 7

Regents Practice 8

Lesson 4: Balancing Reactions 1. Which equation represents conservation of mass? (1) H2 + Cl2 HCl (2) H2 + Cl2 2HCl (3) H2 + O2 H2O (4) H2 + O2 2H2O 2. A 4.86- gram sample of calcium reacted completely with oxygen to form 6.80 grams of calcium oxide. This reaction is represented by the balanced equation below. Determine the total mass of Oxygen that reacted. 2Ca(s) + O2(g) 2CaO(s) BALANCE THE FOLLOWING REACTIONS Challenge: Fe2O3 + CO Fe + CO2 9

Regents Practice 10

Types of Reactions Equation Reactant(s) Product(s) a. Cl 2 + 2NaI 2NaCl + I 2 Cl2 and NaI NaCl and I2 Type of Reaction Single replacement b. HNO 3 + LiOH H 2O + LiNO 3 c. 2NaN 3 2Na + 3N 2 d. Ba(NO 3) 2 + K 2SO 4 2KNO 3 + BaSO 4 e. BaO + SO 3 BaSO 4 f. 2Al + Fe 2O 3 Al 2O 3 + 2Fe g. P 4 + 6Cl 2 4PCl 3 Using TABLE J to predict a Single Replacement Reaction The higher up on table J the more REACTIVE the metal. If the unbonded metal is higher than bonded metal it replaces it. If the unbounded metal is lower than the bonded metal no reaction occurs. Example: Fe(s) + CuSO4(aq) Cu(s) + FeSO4(aq) Fe (unbounded metal) is higher on table J (more reactive) so it replaces the bonded metal (Cu) Example: Cu(s) + ZnSO4(aq) No Reaction (Copper cannot replace zinc because it is LOWER than ZINC on chart) 11

Find the missing substance: Identify the type of reactions from above: a. f. b. g. c. h. d. i. e. j. 12

Lesson 5: Determining empirical and molecular formulas Below is a list of formulas. Write the empirical formula (if not already empirical) and identify the type of substance & type of bonds inside the substance. Formula Empirical formula (simplest ratio) Type of Substance (ionic or covalent) Type of Bonds (ionic and/or covalent) Electrons are (shared and/or transferred) a. C 4H 10 b. C 3H 6 c. N 2O 4 d. Na 2SO 4 e. C 6H 10 f. Al 2O 3 g. NH 4NO 3 h. C 11H 22O 11 i. K 2S 2O 3 j. S 2O 4 k. CH 4 l. C6H12Cl2O2 Calculate the molecular formula from the empirical 1. What is the molecular formula of a compound that has a mass of 276 and an empirical formula of NO 2? 2. What is the molecular formula of a compound that has a mass of 56g and an empirical formula of CH2? 13

3. What is the molecular formula of a compound that has a mass of 51g and an empirical formula of HO? 4. What is the molecular formula of a compound that has a mass of 289g and an empirical formula of NH3? 5. What is the molecular formula of a compound with a mass of 760g and an empirical formula of Cr2O3? 6. What is the molecular formula of a compound that has a mass of 126g and an empirical formula of SO2? 7. What is the molecular formula of a compound that has a mass of 248g and an empirical formula of NO3? 14

Regents Practice 15

Lesson 6: Percent Composition Determine the % composition of all elements in these compounds. Show all work! 1) ammonium sulfite Formula Mass of N %N Molar mass Mass of H %H Mass of S Mass of O %S %O 2) aluminum acetate Formula Mass of Al %Al Molar mass Mass of C %C Mass of H Mass of O %H %O 3) sodium bromide Formula Mass of Na %Na Molar mass Mass of Br %Br 4) copper (II) hydroxide Formula Mass of Cu %Cu Molar mass Mass of O %O Mass of H %H 5) magnesium carbonate Formula Mass of Mg %Mg Molar mass Mass of C %C Mass of O %O 16

Percent Composition of a Hydrate 1. Determine the percent by mass of water in the following hydrates. a. Na2CO3 10H2O (GFM = 286g) c. MgSO4 7H2O (GFM = 246 g) b. Initial mass of hydrate: 9.5 g Final mass of anhydrous salt: 3.77 g d. Initial mass of hydrate: 5.3 g Final mass of anhydrous salt: 4.1 g 2. If 125 grams of BaCl2. 2H2O is completely dehydrated, how many grams of anhydrous Barium Chloride will remain? 3. What is the percent composition of water in FeCl3. 6H2O? 17