Underground Storage & Disposal - The Salt Concept. Thomas Brasser - GRS

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Underground Storage & Disposal - The Salt Concept Thomas Brasser - GRS

Who is GRS ( Plant & Reactor Safety Ltd. ) Non-profit, independent expert and research organisation Assess and improve safety of technical facilities Focus on nuclear safety and waste management Customers: Ministries and authorities, European Commission Technical support of Federal Ministries conc. safety of chemicals, e.g. Hg

Background: EU Storage Obligation for Metallic Mercury Regulation allows only few storage options, e.g.: Temporary or permanently in salt mines *) or in deep underground hard rock formations **) *) adapted for the disposal of metallic mercury **) providing a level of safety and confinement equivalent to that of salt mines

Potential Host Rocks in Western Europe (PAGIS 1984) Salt formations Clay formations Crytallline

Salt Rock: Concept of Complete Inclusion Aquifer Overburden Isolating Salt Rock Disposal Mine Rock Zone

Host Rock Type - Rock Salt Properties of Rock Salt Advantages for Underground Disposal Mechanical stability Viscoplastic behavior High creeping capability Low porosity Low permeability High thermal conductivity Low water content Construction of large cavities without special lining Fast closing of cavities No connected fissures and fractures Self-healing of fractures Negligible transport of fluids and gas Fast removal of heat Rapid and complete inclusion of wastes

Host Rock Type - Rock Salt Additonal advantages of rock salt formations High persistence of rock salt deposits Salts of Zechstein-age within saltdomes since app. 250 m.y. without contact to aquifers Deposits in geological stable regions with low earthquake activity Large accumulations of host rock esp. in salt domes Long lasting experience from mining Numerous & widespread deposits (low conflict of interests) Effects of earthquakes in salt generally lower *) *) but high seismicity will be an overall exclusion criterion!

Host Rock Type - Rock Salt Disadvantages of rock salt High water solubility *) Low sorption capacity Low gas permeability Geological complex structure of salt domes *) reason for prohibition of fluids!

Why Rock Salt? Large and stable cavities

Why Rock Salt? Former drift in a salt mine Unique rock properties, esp. plastic behaviour Enables complete inclusion of waste disposed off Former drift in a salt mine

Concept of Underground Disposal in Salt Rock a. Layered Salt Disposal-Site b. Salt Dome Disposal-Site

Concept of Underground Disposal in Salt Rock Insertion: The Asse-Case

Types of Geosystems - Rock Salt Host rock Geosystem Variant Thickness of host rock body Potential disposal depth Rock salt Salt dome up to > 1,000 m 800 m Rock salt Layered salt app. 100 m 650 1,100 m

Host Rock Properties - Comparison (Detail) Properties Rock Salt Clay / Claystone Crystalline (e.g. Granite) Thermal Conductivity high low medium Hydraulic Conductivity nearly impermeable very low - low very low (without joints) - permeable (jointed) Mechanical Strength medium low - medium high Deformation Behavior viscous (creep) plastic - brittle brittle Stability of Cavities self-stability timbering necessary high (without joints) - low (intensively jointed) In-situ-Stress lithostatic isotropic anisotropic anisotropic Solubility high very low very low Sorption Capability very low very high medium - high Source: BGR

Waste Isolation Multibarrier System (1) Waste content Waste form Canister Backfill Sealing Technical Barriers Geological Barriers Host rock Overburden

Host rock Waste Isolation Multibarrier System (2) Overburden Shaft sealing Drift sealing Borehole sealing Waste & Canister Backfill

Strategy of Long-term Safety Assessment Geo-scientific long-term prognosis on site development Knowledge of site characteristics Rocks and their properties Hydrology (regional/local) Hydrogeology (Biosphere) 100 Sub-Parts of Disposal System Geology Hydrogeology Biosphere Man Potentiality for Prognosis of Alterations for Sub-Parts Design of disposal facility Running off processes 10,000 1,000,000 yrs.

Important Questions Concerning Mercury Scientific Knowledge on Mercury What is the behavior of metallic Mercury in contact with air and brines? How much is the solubility of metallic Mercury influenced by impurities? Does the conversion of metallic Mercury in Hg-sulfides hold advantages? significant in case of waste not isolated totally Demand of Regulations Which of the existing criteria are likely to be unsuitable for liquid Hg? Which specific provisions for the containment are necessary and how does it effect the system?

Citations - DE Technical Instructions on Waste (TA Abfall) - http://www.bmu.de/files/pdfs/allgemein/application/pdf/taabfall.pdf (in German) Act for Promoting Closed Substance Cycle Waste Management and Ensuring Environmentally Compatible Waste Disposal - http://www.bmu.de/files/pdfs/allgemein/application/pdf/promoting.pdf Ordinance on Landfills and Long-Term Storage Facilities (Landfill Ordinance DepV) - Annex 2: Instructions on the maintenance of long-term safety records within the context of site-related safety assessments for mines in salt rock - http://www.bmu.de/files/pdfs/allgemein/application/pdf/deponievo_engl.pdf Contact: Dr. Thomas Brasser Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) mbh Theodor-Heuss-Strasse 4 38122 Braunschweig, Germany Phone: +49-531-8012-238/270, Fax: +49-531-8012-10238, Email: thomas.brasser@grs.de