PELLISSIPPI STATE TECHNICAL COMMUNITY COLLEGE MASTER SYLLABUS APPLIED CHEMISTRY II W/LAB CHT 1120 Class Hours: 3.0 Credit Hours: 4.0 Laboratory Hours: 3.0 Date Revised: Fall 2001 NOTE: This course is not designed for transfer credit. Catalog Course Description: A study of the quantitative aspects of solutions, reaction kinetics, chemical equilibria, thermo chemistry, ionization of electrolytes, and coordination chemistry. Laboratory emphasis will be on individual laboratory work, and an industrial type notebook will be maintained. Course includes three hours of lecture and three hours of laboratory applications each week. Entry Level Standards: Student needs background in Algebra, including logarithms and exponents. Prerequisite: CHT 1110 Corequisite: MATH 1731 Textbook(s) and Other Reference Materials Basic to the Course: Brady, James E. and John H. Holum. General Chemistry with Qualitative Analysis. 2nd ed. John Wiley & Son, Inc. Bull, William E., William T. Smith, and Jesse H. Wood. Laboratory Manual for College Chemistry, 6th ed. San Francisco, CA: Harper and Row Publishers, 1980. I. Week/Unit/Topic Basis: Week Topic 1 Lecture: Solution Chemistry Lab: Standard solutions and titration 2 Lecture: Solution Chemistry Lab: Colligative properties 3 Lecture: Solution Chemistry Lab: Enthalpy change for a chemical reaction 4 Lecture: Chemical Thermodynamics
Lab: Enthalpy of combustion of a vegetable oil 5 Lecture: Chemical Thermodynamics Lab: Heat of neutralization and Hess's Law 6 Lecture: Reaction Kinetics Lab: Reaction rate: Iodine clock 7 Lecture: Reaction Kinetics Lab: Chemical Kinetics: Bromination of acetone 8 Lecture: Chemical Equilibrium Lab: Chemical Equilibrium 9 Lecture: Ionic Equilibrium Lab: Determination of an equilibrium constant 10 Lecture: Ionic Equilibrium Lab: Determination of an ionization constant 11 Lecture: Solubility Product Lab: Buffers 12 Lecture: Solubility Product Lab: Solubility product constant 13 Lecture: Electrochemistry Lab: Solubility product constant 14 Lecture: Electrochemistry Lab: Eectrochemistry 15 Lecture: Coordination compounds Lab: Coordination chemistry 16 Lecture: Final Exam Lab: No lab II. Course Objectives*: A. Calculate the heat of a reaction at 25 degrees. I, III, V B. Determine the reaction order and rate constant for simple reaction systems. I, II, III, V C. Make reaction equilibrium calculations. I, II, III D. Make calculations of ph and POH in simple and Buffered Solutions. I, II, III E. Calculate potentials for electrochemical cells. I, II, III F. Make solubility product constant calculations. I, II, III G. Name simple coordination compounds. III, IV H. Understand some of the important coordination chemistry principles. I, II, III, V *Roman numerals after course objectives reference goals of the Chemical/Environmental Engineering
Technology program. III. Instructional Processes*: Students will: 1. Attend lectures and discuss concepts. Communication Outcome, Problem Solving and Decision Making Outcome, Information Literacy Outcome, Active Learning Strategy 2. Solve assigned problems out of class and be prepared to discuss the problem solutions. Communication Outcome, Problem Solving and Decision Making Outcome, Numerical Literacy Outcome, Information Literacy Outcome, Active Learning Strategy 3. Attempt to apply the principles of thermodynamics and kinetics to real life examples. Problem Solving and Decision Making Outcome, Technological Literacy Outcome, Numerical Literacy Outcome, Information Literacy Outcome, Transitional Strategy 4. Participate in laboratory experiments which are direct applications of the concepts studied. Communication Outcome, Problem Solving and Decision Making Outcome, Technological Literacy Outcome, Information Literacy Outcome, Active Learning Strategy 5. Perform laboratory experiments, collect data and keep a research style lab notebook. Communication Outcome, Problem Solving and Decision Making Outcome, Technological Literacy Outcome, Information Literacy Outcome, Active Learning strategy *Strategies and outcomes listed after instructional processes reference Pellissippi State s goals for strengthening general education knowledge and skills, connecting coursework to experiences beyond the classroom, and encouraging students to take active and responsible roles in the educational process. IV. Expectations for Student Performance*: Upon successful completion of this course, the student should be able to: 1. Define and use of the thermodynamic properties enthalpy, entropy free energy, heat and work. A 2. Make calculations of the heat of reaction from standard enthalpy of formation. A 3. Determine whether a reaction is exothermic or endothermic. A 4. Estimate heat of reaction in an organic reaction using average bond energies. A 5. Describe the role of free energy in determining the spontaneity of chemical reactions. A 6. Define first and second order reactions. B 7. Calculate reaction rate constants from experimental data. B 8. Determine reaction order from experimental data. B 9. Demonstrate an understanding of the effect of temperature on reaction rate. B 10. Calculate the Arrhenius relationship for a reaction rate constant from experimental data. B 11. Describe the effect of a catalyst in terms of thermodynamics and energy relationships. B 12. Express the reaction equilibrium relationship for various reactions. C
13. Calculate reaction equilibrium constant from experimental data. C 14. Explain the implications of LeChatelier's principle. C 15. Explain the effect of temperature and pressure changes on reaction equilibrium concentrations. C 16. Give a qualitative explanation of the behavior of materials in reactions that occur in more than one phase. C 17. Explain the auto ionization of water and the effect it has on solution equilibrium. D 18. Explain the difference between strong and weak electrolytes. D 19. Define ph and poh. D 20. Calculate the ph of a solution of a weak electrolyte. D 21. Calculate the percent of ionization of a weak electrolyte solution. D 22. Define the common ion effect. D 23. Define a buffered solution. D 24. Calculate the ph of a buffered solution. D 25. Calculate solubility product constant from experimental data. E 26. Explain how the solubility product is used in analytical chemistry. E 27. Describe electrochemical reactions and equipment. E 28. Explain and use the electromotive series. E 29 Calculate cell voltages using the Nernst equation. F 30. Demonstrate an understanding of the nomenclature of complexions. G 31. Explain the meaning and the importance of ligands, chelates, polydentates and isomers. H *Letters after performance expectations reference the course objectives listed above. V. Evaluation: A. Testing Procedures: There will be 3 exams and a comprehensive final exam. B. Laboratory Expectations: Students are expected to complete the laboratory work. If a laboratory is missed, the student must take the initiative (immediately) to arrange for make-ups. Each student will maintain a laboratory notebook and the laboratory grade will be primarily determined by the lab notebook. The laboratory notebook will be graded for grammar and spelling. Homework will be assigned and collected. Any homework not turned in will not effect the grade. The course grade will be determined by the formula below.
VI. Policies: G = 3/4 [(.55t +.35f)/(.9 +.1(h/ht)) + 10( h/ht)] + 1/4 L Where t = Exam average grade f = Final exam grade h = Homework turned in ht = Total homework assigned L = Laboratory grade C. Grading Scale: 90 100 A 87 89 B+ 80 86 B 77 79 C+ 70 76 C 60 70 D below 60 F A. Attendance Policy: Pellissippi State Technical Community College expects students to attend all scheduled instructional activities. As a minimum, students in all courses must be present for at least 75 percent of their scheduled class and laboratory meetings in order to receive credit for the course (Pellissippi State Catalog). Individual departments/programs/disciplines, with the approval of the vice president of Academic and Student Affairs, may have requirements that are more stringent. Chemical/Environmental Engineering Technology Program: Regular attendance in this course is required. Students who miss the equivalent of 10% of either classroom hours or laboratory may, at the discretion of the instructor, have their course grade dropped by one letter. Students who arrive late for a class after the roll as been called have the responsibility of seeing the instructor after class the change their status from A (absent) to T (tardy). B. Academic Dishonesty: In keeping with college-wide policies, the student is expected to adhere to the general rules and regulations relevant to academic and classroom misconduct as outline in the catalog.