Effect of Typhoon-Driven Ocean Waves on Sea-to-Air Transfer of Dimethylsulfide (DMS)

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Effect of Typhoon-Driven Ocean Waves on Sea-to-Air Transfer of Dimethylsulfide (DMS) Peter C Chu Department of Oceanography Naval Postgraduate School Monterey, California, USA pcchu@nps.edu http://www.oc.nps.navy.mil/~chu International Workshop on Computational Hydrometeorology and Prof. H.L. Kuo s Memorial Symposium, Hsinchu, Taiwan, Oct 15-17, 2007

Following Prof. Kuo s Milestone Paper on Tropical Cyclone 504 citations

Low-level Velocity in Tropical Cyclone (Kuo 1965) Theoretical Base for Surface Wind Field Tangential Radial

What are tropical cyclone s effects on oceans and regional seas? With Prof. Kuo (1965) s milestone paper, high-resolution surface winds can be produced, and in turn to study the tropical cyclone s effect on oceans becomes feasible.

References Chu, P.C., J. M. Veneziano, and C.W. Fan, 2000: Response of the South China Sea to tropical cyclone Ernie 1996. Journal of Geophysical Research, 105, 13991-14009. Chu, P.C., Y. Qi, Y.C. Chen, P. Shi, and Q.W. Mao, 2004: South China Sea wave charcteristics. Part-1: Validation of wavewatch-iii using TOPEX/Poseidon data. Journal of Atmospheric and Oceanic Technology, 21 (11), 1718-1733. Chu, P.C., and K.F. Cheng, 2007: Effect of wave boundary layer on the sea-to-air dimethylsulfide transfer velocity during typhoon passage. Journal of Marine Systems, 66, 122-129. Chu, P.C., and K.F. Cheng, 2007: South China Sea wave characteristics during Typhoon Muifa passage in winter 2004. Journal of Oceanography, inpress.

Tropical cyclone s effects on oceans Strong near-inertial, anticyclonic turning upperocean currents to the right of the storm track Maximum sea surface temperature cooling to the right of the storm track Air-sea fluxes Ocean surface wave boundary layer

Outlines (1) DMS and Climate (2) Sea-to-air DMS transfer (3) Tropical cyclone wind profile model (4) Wave effects (Wavewatch-3 Modeling) (5) Typhoon effects on sea-to-air DMS transfer (6) Summary

1. DMS and Climate

Dimethylsulfide (DMS) Cycle Ocean and Atmosphere Exchange DMS (CH 3 SCH 3 ) changes the radiation budget in the atmosphere and in turn changes the climate.

The dominant natural source of sulfur to the atmosphere is the oceanic DMS (Bates et al., 1992; Gondwe et al., 2003).

2. Sea-to-Air DMS Flux

C a (DMS concentrations at airside) Air m a =k a (C a -C s,w /α) m a (flux in airside) C s,w (concentration at the interface) m a = m w m w =k w ( C s,w C w ) m w (flux in waterside) C w (DMS concentrations at waterside) Ocean

Ostwald Solubility Coefficient Representing ratio of C w /C a at equilibrium T in o K

Sea-to-Air DMS Flux (H) (McGillis et al., JGR 2000) Eliminating C s,w

Airside DMS Transfer Velocity k a k a = 659 u r (M H2O /M) 1/2 M molecular weight of DMS 129.075 M H2O molecular weight of H 2 O 18 u r = u(z r ) k a z r = 10 m

Waterside DMS Transfer Velocity (Jahne et al., 1987) Waterside transfer velocity (n = 0.58) Schmidt Number = 720 (DMS at 300 K) DMS Diffusion coefficient (Saltzman et al., 1993) Roughness Reynolds Number

Nondimensional Roughness Length z 0 is roughness length Nondimensional

u r k a (z 0, u * ) k w

What is the effect of tropical cyclones on the sea-to-air DMS transfer?

Tropical Cyclones Ocean Waves (z 0 u * ) k w Sea-to-Air DMS Flux

3. Tropical Cyclone Wind Profile Model

Wind Decomposition V = (1 ε )( V + V) + εv 4 c ε =, c = c V t Translation velocity 4 1+ 0.9 V c relative velocity to storm center V bg Background velocity (R 0, R m ) zero and maximum tangential velocities c t bg r R 0

Continuation of Kuo s (1965) Work Tropical Cyclone Wind Profile Model (TCWPM) (Carr and Elsberry 1997) f R a vc () r = ( ) 2 R r r 1 a u () r = tan() γ v () r c a = r R m 4 0 0 X 0 4 c γ inflow angle of air as it spirals into the typhoon center X positive parameter (~ 0.4)

Typhoon Muifa (2004) Best Track Record from the JTWC (2005) Duration 14 Nov. to 26 Nov. 20 Nov. to 25 Nov. (in the SCS) Max. Wind Speed 59.2 m/sec (115 kt) 46.3 m/sec (in the SCS) Hurricane Translation Speed (HTS): 1~10 m/sec

Comparison between NCEP and QSCAT-TCWPM (QTCWPM) Winds NCEP Wind Fields QSCAT-TCWPM Wind Fields

Comparison between QSCAT and QTCWPM Winds QuikSCAT Wind Fields QTCWPM Wind Fields

4. Wave Effects on Air-Sea Fluxes

Drag Coefficient without Ocean Waves C D = (u * /u r ) 2 z r = 10 m

Charnock (1955) Parameterization Constant z 0 = 0.0144 u *2 /g

Drag Coefficient with Ocean Waves Chalikov (1995) parameterization μ p = 0.57 (u * /C p ) 3/2 C p is the peak phase speed.

NOAA WaveWatch-3 Third Generation Wave Model (Tolman 1999), N t + 1 φn cosφ φ cosθ + λn λ + k kn + θ N θ g = S σ, S = Sin + Snl + Sds + Sbot φ = c g cosθ + U R φ λ = c g sinθ +U R cosφ φ θ g = θ c g tanφ cosθ R

South China Sea

Numerical Integration Spatial grid Latitude: 0º to 15ºN, Longitude: 105º to 122ºN Spatial Interval: 1/4 º X 1/4 º Energy spectra 25 frequencies with logarithmic increment. 24 directions (15º interval) Time step Global step = Spatial step = Spectral step = 300 sec. Source step = 100 sec.

WaveWatch-3 was evaluated using T/P (a) crossover points and (b) tracks in the SCS (Chu et al., 2003, JTECH)

TOPEX/Poseidon Altimetry T/P Satellite NASA and CNES cooperation project. August 1992 till now. 9.916 days repeat period. Dataset in use 00UTC 16 Nov. to 12UTC 25 Nov. 2 Cycles: 448, 449. 14 Passes: 001, 012, 051, 064, 077, 088, 114, 127,140, 153, 164, 216, 229. Total 25 crossover points.

Evaluation Using Significant Wave Height (H S ) Statistics 38 data pairs (T/P vs. WW3). BIAS = 0.137 m. RMSE = 0.308 m. Corr. Coeff. = 0.895. T/P observations and WW3 simulations are in a good agreement. WW3 simulation in the SCS is accurate and reasonable.

Effects of Tropical Cyclone on H S

Comparison of Max. H s and Winds Maximum Wave Field Maximum Wind Field Along the typhoon track: to the right side; expending wider to the right side.

5. Typhoon Effect on Sea-to-Air DMS Transfer

Typhoon 23W (Wukong) Sept 5-11, 2000 Maximum Sustained Wind: 38 m/s

Effect of WBL on z 0* Nondimensional Peak Wave Frequency

Effect on C D

Relative Difference of C D

Effect on k w

Relative Difference of k w

Conclusions (1) WBL increases C D and in turn enhances the momentum flux negative feedback. (2) WBL decreases k w and in turn weakens the sea-to-air DMS transfer less sulfate haze, CCN air quality and climate (3) Such opposite WBL effects are evident for typhoon Wukong (max wind ~ 38 m/s) 13% reduction in k w (4) Such opposite WBL effects under tropical cyclones on the climate should be further investigated.