GPC-/SEC-Columns. MZ-Gel SD. MZ-Gel Super FG SEC with fluorinated Eluents

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GPC-/SEC-Columns & 2 accessories2 0 18 direct from Producer packed in new generation column hardware! MZ-Gel SD MZ-Gel SD LS MZ-Super FG Development Manufacturing Distribution Consulting HPLC-Columns New + Refill Complete Range of Packings Micro Analytical Preparative PerfectChrom PerfectBond MZ-AquaPerfect PerfectSil PerfectSil Target Orbit Distributor For: GRACEVYDAC GL-SCIENCES THERMO SCIENTIFIC MERCK Eka-Nobel/KROMASIL TCI Agilent DAICEL / CHROMTECH ES-INDUSTRIES AMT/HALO ACE SEPAX TECHNOLOGIES MACHEREY-NAGEL HICHROM MZ-PAH Analytics of PAH s MZ-PBM Analytics of Pesticides MZ-Gel SD SEC-Columns hydrophobic (Styrene-Divinylbenzene) MZ-Gel Super FG SEC with fluorinated Eluents Accessories IDEX H&S Valves EXMIRE-Syringes Guard-Columns Capillaries Fingertight-Fittings etc. http://www.gpc.biz e-mail: info@gpc.biz

info@gpc.biz 30+ YEARS FOR SEPARATION MZ-Analysentechnik GmbH was founded in 1986. Ever since we are active in the field of research and development of columns and bulk media for high performance liquid chromatography (HPLC), gel permeation chromatography (GPC) and size exclusion chromatography (SEC). Our goal is to provide customers worldwide with LC-columns, packing media and accessories with the highest level of quality by reasonable pricing. Columns and packing media made by MZ- Analysentechnik serve chromatographers in obtaining reliable and reproducible separations, very often shipping as OEM-products with other brand names. The continuous refinement of the manufacturing process ISO 9001-certified improved quality and durability of the columns. This brochure is a short survey of our series of GPC-and SEC-columns highlighting the following specialties: MZ-Gel SDplus LS extra low phase bleeding for detection via light scattering techniques MZ-Gel SDplus 3 µm hydrophobic GPCcolumns with guaranteed platenumbers > 100,000 m -1 Narrow bore & Micro bore GPC-/SECcolumns (saving up to 70 % eluent) For additional information please contact us or visit our homepage: http://www.gpc.biz MZ-Gel SDplus MZ-Gel SDplus is a proprietary development of MZ-Analysentechnik GmbH based on highly cross-linked styrene / divinylbenzene high-performance copolymer MZ-Gel SDplus: durability Narrow pore size distribution and low polydispersity combined with nearly perfect spherical particle shape Ships in new High-End-hardware, fully compatible with previous columns and with guaranteed Refill-capabilities High reliability, reproducibility and durability TECHNICAL DATA MZ-Gel SDplus 3 µm 5 µm 10 µm particle shape spherical spherical spherical available porosities [Å] 50-10 3 Å 50-10 6 Å + linear 50-10 6 Å + linear plate numbers: min. guaranteed [m -1 ] 100,000 60,000 50,000 plate numbers: typical [m -1 ] 120,000 80,000 60,000 pressure stability [bar] 160 160 160 backpressure per 30 cm [bar]* 40 25 15 max. flow rate analytical 8 mm ID 1.5 ml/min 1.5 ml/min 3 ml/min max. flow rate narrow bore 4.6 mm ID 0.6 ml/min 0.6 ml/min 0.6 ml/min max. flow rate preparative 20 mm ID 10 ml/min 20 ml/min temperature range max. 100 C max. 100 C max. 140 C * based on column 300 x 8 mm, flow rate 1 ml/min, eluent THF

www.gpc.biz MZ-Gel SDplus MOLECULAR MASSRANGE & EXCLUSION LIMIT POROSITY MOLECULAR MASS RANGE EXCLUSION LIMIT 50 Å < 2,000 3,000 100 Å < 3,000 5,000 500 Å < 20,000 20,000 10e3 Å 1,000-40,000 70,000 10e4 Å 4,000-500,000 700,000 10e5 Å 10,000-2,000,000 4,000,000 10e6 Å 200,000-10,000,000 > 10,000,000 linear 1,000-1,000,000 > 2,000,000 Molecular weight [D] 10e7 10e6 10e5 10e4 10e3 10e2 4 6 8 10 Volume (ml / 30 cm) SOLVENT COMPATIBILITY CHART MZ-Gel SDplus GPC-columns are manufactured, tested and shipped by default in THF. By request we can deliver these columns filled with any other common solvent. Please follow the solvent compatibility chart below if you intend to change the solvent due to the swelling of the polymer. The swelling capacity of GPC-eluents is classified in four categories from low up to very high. This offers the following possibilities for changing the eluent: cycloheptane ethylether methylethylketone high methylenechloride ethylacetate p-xylene benzene HFIP THF TCB n-butanol methanol cyclopentane very high toluene o-dichlorobenzene iso-propanol acetonitril weak pyridin chloroform n-hexane cyclohexane m-cresol DMSO Freon 113 dioxane n-methylpyrrolidone dimethylacetamide o-chlorophenol medium aceton DMF GPC-solvents: swelling capacity and possibilities for changing the eluent

info@gpc.biz MZ-Gel SD PRICES AND ORDERING INFORMATION ANALYTICAL 8 MM ID PRICE/ LENGTH X ID PARTICLE SIZE POROSITIES NEW REFILL 300 x 8 mm 3 µm 50 Å, 100 Å, 500 Å, 10 3 Å 1,023.-- 921.-- 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 895.-- 793.-- 5 µm linear 972.-- 870.-- 10 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 665.-- 563.-- 10 µm linear 757.-- 655.-- 600 x 8 mm 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 1,279.-- 1,125.-- 5 µm linear 1,468.-- 1,315.-- 10 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 967.-- 813.-- 10 µm linear 1,095.-- 941.-- 50 x 8 mm 5 µm all porosities + linear 312.-- 271.-- 10 µm all porosities + linear 312.-- 271.-- MICRO BORE 250 x 3 mm 5 µm all porosities + linear 614.-- 512.-- 40 x 3 mm 5 µm all porosities + linear 164.-- 149.-- 250 x 2 mm 5 µm all porosities + linear 614.-- 512.-- 40 x 2 mm 5 µm all porosities + linear 164.-- 149.-- NARROW BORE 4.6 mm ID (SAVING UP TO 70 % ELUENT) 300 x 4.6 mm 3 µm 50 Å, 100 Å, 500 Å, 10 3 Å 1,023.-- 921.-- 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 767.-- 665.-- 5 µm linear 844.-- 742.-- CODES MZ-Gel SDplus Porosity 3 µm 5 µm 10 µm 50 Å 5553 5555 5530 100 Å 5013 5015 5010 500 Å 5053 5055 5050 1,000 Å 5303 5305 5300 10 4 Å - 5405 5400 10 5 Å - 5505 5500 10 6 Å - 5605 5600 Linear - 5005 5000 40 x 4.6 mm 3 µm all porosities + linear 179.-- 123.-- 5 µm all porosities + linear 179.-- 123.-- 10 µm all porosities + linear 179.-- 123.-- PREPARATIVE 20 mm ID 300 x 20 mm 10 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 1,940.-- 1,685.-- 10 µm linear 2,195.-- 1,940.-- 50 x 20 mm 10 µm all porosities + linear 473.-- 325.-- PART-NO. Analytical Narrowbore Microbore MZ four-digit Materialcode length in mm LEN IDØ ID in 1 /10 mm 8 mm 4.6 mm 3.0 mm 2.0 mm 1.6 mm Example: MZ-Gel SDplus 100 Å 5 µm (5015); SEC-Column 300 x 8,0 mm => Part-No.: MZ5015-300080 Please inquire about details of Refill-Service All prices in EUR excluding VAT. Shipping details by request.

www.gpc.biz MZ-Gel SD LS - for Detection via Light Scattering Detection via todays Laser-Lightscattering-technique enables direct aquisition of polymeric molecular size information during a GPC/SEC-run. Due to its high sensitivity, this method requires special attention upon the whole chromatographic procedure - sample preparation, purity of the solvent and the stability and quality of the GPC column. MZ-Gel SDplus LS is a propriety development of MZ-Analysentechnik based on highly-crosslinked and totally porous high-performance styrene-divinylbenzene copolymer. It is derived from th well-known MZ-Gel SDplus as base material via a special posttreatment to meet the special requirements of detection via light-scattering. Therefore MZ-Gel SDplus LS features an extremely low phase-bleeding plus the extraordinary capabilities as the HPLC-like separation efficiency of the well-known original material. MOLECULAR MASSRANGE & EXCLUSION LIMIT POROSITY MOLECULAR MASS RANGE EXCLUSION LIMIT 50 Å < 2,000 3,000 100 Å < 3,000 5,000 500 Å < 20,000 20,000 10e3 Å 1,000-40,000 70,000 10e4 Å 4,000-500,000 700,000 10e5 Å 10,000-2,000,000 4,000,000 10e6 Å 200,000-10,000,000 > 10,000,000 linear 1,000-1,000,000 > 2,000,000 Molecular weight [D] 10e7 10e6 10e5 10e4 10e3 10e2 4 6 8 10 Volume (ml / 30 cm) TECHNICAL DATA MZ-Gel SDplus 3 µm 5 µm 10 µm particle shape spherical spherical spherical available porosities [Å] 50-10 3 Å 50-10 6 Å + linear 50-10 6 Å + linear plate numbers: min. guaranteed [m -1 ] 100,000 60,000 50,000 plate numbers: typical [m -1 ] 120,000 80,000 60,000 pressure stability [bar] 160 160 160 backpressure per 30 cm [bar]* 40 25 15 max. flow rate analytical 8 mm ID 1.5 ml/min 1.5 ml/min 3 ml/min max. flow rate narrow bore 4.6 mm ID 0.6 ml/min 0.6 ml/min 0.6 ml/min max. flow rate preparative 20 mm ID 10 ml/min 20 ml/min temperature range max. 100 C max. 100 C max. 140 C * based on column 300 x 8 mm, flow rate 1 ml/min, eluent THF

info@gpc.biz MZ-Gel SD LS - PRICES AND ORDERING INFORMATION ANALYTICAL 8 MM ID Price/ LENGTH X ID PARTICLE SIZE POROSITY NEW REFILL 300 x 8 mm 3 µm 50 Å, 100 Å, 500 Å, 10 3 Å 1,122.-- 1,020.-- 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 982.-- 880.-- 5 µm linear 1,068.-- 966.-- 10 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 727.-- 625.-- 10 µm linear 829.-- 727.-- 600 x 8 mm 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 1,404.-- 1,250.-- 5 µm linear 1,613.-- 1,460.-- 10 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 1,057.-- 903.-- 10 µm linear 1,199.-- 1,045.-- 50 x 8 mm 5 µm all porosities + linear 342.-- 301.-- 10 µm all porosities + linear 342.-- 301.-- MICROBORE 250 x 3 mm 5 µm all porosities + linear 670.-- 568.-- 40 x 3 mm 5 µm all porosities + linear 177.-- 162.-- 250 x 2 mm 5 µm all porosities + linear 670.-- 568.-- 40 x 2 mm 5 µm all porosities + linear 177.-- 162.-- NARROW BORE 4.6 mm ID (SAVING UP TO 70 % ELUENT) 300 x 4.6 mm 3 µm 50 Å, 100 Å, 500 Å, 10 3 Å 1,125.-- 1.023.-- 5 µm 50 Å, 100 Å, 500 Å, 10 3 Å, 10 4 Å, 10 5 Å, 10 6 Å 840.-- 738.-- 5 µm linear 926.-- 824.-- 40 x 4.6 mm 3 µm 50 Å, 100 Å, 500 Å, 10 3 Å 192.-- 136.-- 5 µm all porosities + linear 192.-- 136.-- 10 µm all porosities + linear 192.-- 136.-- Codes MZ-Gel SDplus LS Porosity 3 µm 5 µm 10 µm 50 5554 5556 5531 100 5014 5016 5011 500 5054 5056 5051 1,000 5304 5306 5301 10 4-5406 5401 10 5-5506 5501 10 6-5606 5601 Linear - 5006 5001 PART-NO. MZ four-digit Materialcode length in mm LEN IDØ ID in 1 /10 mm Example: MZ-Gel SDplus LS linear 5 µm (5006); GPC-Column 300 x 8.0 mm => Part-No.: MZ5006-300080 Please inquire about details of Refill-Service All prices in EUR excluding VAT. Shipping details by request.

www.gpc.biz MZ Super-FG: GPC-COLUMNS FOR FLUORINATED ELUENTS MZ Super-FG GPC-columns are packed with especially modified silica. The surface chemistry offers optimum interaction between the stationary phase and analytes which require fluorine containing mobile phases like TFE or HFIP. TECHNICAL DATA MZ-GEL SUPER FG particle size 7 µm pressure stability max. 300 bar max. flow rate: analytical 8 mm ID 3 ml/min preparative 20 mm ID 20 ml/min temperature range max. 80 C ph-stability 2 9 pore volume 0.6 1.0 ml/g Molecular weight [D] Volume (ml / 30 cm) POROSITY MOLECULAR WEIGHT RANGE EXCLUSION LIMIT 100 100-30,000 100,000 300 1,000-100,000 1,000,000 1000 20,000-1,000,000 10,000,000 4000 100,000-10,000,000 20,000,000 Linear 100-1,000,000 10,000,000 MZ Super-FG columns are available as four different porosities & 1 linear mix. The table exhibits the appropriate molecular mass range and exclusion limit. Prices and Ordering Information ANALYTICAL PRICE/ NEW REFILL 300 x 8 mm 7 µm all porosities 767.-- 665.-- 7 µm linear 870.-- 767.-- 600 x 8 mm 7 µm all porosities 1,074.-- 921.-- 7 µm linear 1,222.-- 1,069.-- 50 x 8 mm 7 µm all porosities + linear 312.-- 271.-- PREPARATIVE 300 x 20 mm 7 µm all porosities 2,071.-- 1,816.-- 7 µm linear 2,301.-- 2,046.-- 50 x 20 mm 7 µm all porosities + linear 430.-- 282.-- PART-NO. MZ four-digit Materialcode length in mm LEN IDØ ID in 1 /10 mm Example: MZ Super-FG linear 7 µm (9000); SEC-Column 300 x 8,0 mm => Part-No.: MZ9000-300080 Please inquire details for Refill-Service Porosity Code 100 9010 300 9030 1,000 9100 4,000 9400 linear 9000 All prices in EUR excluding VAT. Shipping details by request.

info@gpc.biz www.gpc.biz ACCESSORIES PART-NO. PRODUCT AMOUNT PRICE/ AS0301 stainless steel tubing AD 1/16 x 0.13 mm ID 3 m 20.-- AS0325 AD 1/16 x 0.25 mm ID 3 m 18.-- AS0350 AD 1/16 x 0.50 mm ID 3 m 18.-- AS0370 AD 1/16 x 0.75 mm ID 3 m 18.-- AS0310 AD 1/16 x 1.00 mm ID 3 m 18.-- AS1001 stainless steel ferrules 1/16 10 pieces 19.-- AS1010 stainless steel ferrules 1/16 100 pieces 152.-- AR1101 stainless steel ferrules 1/16 Rheodyne 10 pieces 19.-- AS2001 fitting screws stainless steel short 10 pieces 26.-- AS2101 fitting screws stainless steel long 10 pieces 26.-- AS2201 fitting screws stainless steel large 10 pieces 39.-- AS3001 ZDV-union stainless steel 1/16 1 piece 32.50 AS3101 tee-piece stainless steel 1/16 1 piece 80.-- AS3201 cross stainless steel 1/16 1 piece 99.-- AP0313 PEEK-tubing AD 1/16 x 0.13 mm ID 3 m 24.-- AP0317 AD 1/16 x 0.17 mm ID 3 m 24.-- AP0325 AD 1/16 x 0.25 mm ID 3 m 24.-- AP0350 AD 1/16 x 0.50 mm ID 3 m 24.-- AP0375 AD 1/16 x 0.75 mm ID 3 m 24.-- AP5001 fingertight-fittings PEEK 10 pieces 50.-- AP5101 coupler PEEK universal fingertight 1 piece 19.-- AP5201 union PEEK 1/16 (incl. 2 fingertight-fittings) 1 set 18.-- AP5301 tee-piece PEEK 1/16 (incl. 3 fingertight-fittings) 1 set 60.-- AP5401 cross PEEK 1/16 (incl. 4 fingertight-fittings) 1 set 89.-- AN5501 plug Nylon 1/16 10 pieces 7.-- AN5510 100 pieces 39.-- AS6000 pliers for stainless steel tubings 1 piece 19.-- AR6100 Rheotool 1 piece 21.-- AP6200 Clean-Cut for cutting polymeric tubings 1 piece 15.-- AP6300 Guillotine-Cutter 1 piece 7.50 AC7000 EasyFlange Kit 1 set 145.-- AC7100 EasyFlange Combi-Kit 1 set 170.-- AS7500 Last-drop mobile phase-filter with 2.0 µm stainless steel frit 1 piece 20.50 AP7500 Last-drop mobile phase-filter with 2.5 µm PAT-frit 1 piece 20.50 SYRINGES EXMIRE HIGH QUALITY INJECTION SYRINGES smallest volume amount Part-No. Price/ 5 µl 0.1 µl MSR 05 48.-- 10 µl 0.2 µl MSR 10 34.-- 25 µl 0.5 µl MSR 25 34.-- 50 µl 1.0 µl MSR 50 37.-- 100 µl 2.0 µl MSR 100 41.-- 250 µl 5.0 µl MSR 250 48.-- 500 µl 10.0 µl MSR 500 61.-- All prices in EUR excluding VAT. Shipping details by request.