Dave and the Dead Russians. Early Contributions by Russian Organic Chemists to the Development of the Discipline

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Dave and the Dead ussians Early Contributions by ussian Organic Chemists to the Development of the Discipline

Nikolai Nikolaevich Zinin (1812-1880) kandidat Kazan' 1836 Dr. Chem. St. Petersburg 1841 Study abroad in western Europe 1838-1841 included a year with Liebig in Giessen meant to be learning technology, not "new" chemistry Kazan' University Professor of Chemical Technology 1841-1848 Medical-Surgical Academy, University of St. Petersburg Professor of Chemistry 1848-1878

N. N. Zinin (1812-1880) CHO KCN O Ann. Chem. Pharm. 1840, 34, 186-192. NO 2 NH3 /H 2 S NH 2 Bull. Sci. Acad. St. Petersburg 1842, 18. Bull. Phys.-Math. Acad. St. Petersburg 1852, 348. Ann. Chem. Pharm. 1842, 44, 283-287; 1844, 52, 361-362; 1853, 85, 328-329.

Aleksandr Mikhailovich Butlerov (1828-1886) kandidat Kazan' 1849 (entomology) M. Chem. Kazan' 1851 Dr. Chem. Moscow 1854 Study abroad in western Europe 1857-1858; 1867-1868. met Erlenmeyer and Kekulé spent six months with Wurtz in Paris not supposed to be a research trip Kazan' University Professor of Chemical Technology 1851-1858 ector twice. University of St. Petersburg Professor of Chemistry 1869-1880

A. M. Butlerov (Butlerow) (1828-1886) Structural Theory Ann. Chem. Pharm. 1859, 111, 5146. Textbook Introduction to the Study of Organic Chemistry (Kazan', 1861).Lehrbuch der organischen Chemie zur Einführung in das specielle Studien derselben (Leipzig, 1867) H 3 C C O (CH 3 ) 2 Zn/ H 3 C H 3 C C Cl H 3 C Jahresb. 1863, 475; 1864, 496. Ann. Chem. Pharm. 1867, 144, 132.

Aleksandr Mikhailovich Zaitsev (1841-1910) diplom Kazan' 1862 (economics) kandidat Kazan' 1865 Ph.D. Leipzig 1866 M. Chem. Kazan' 1868 Dr. Chem. Kazan' 1870 Study abroad in western Europe 1862-1865. studied with Kolbe at Marburg 1862-1864 studied with Wurtz in Paris 1864-1865 Kazan' University unpaid laboratory assistant 1865 Assistant in Agronomy 1866-1868 Extraordinary Professor of Chemistry 1869-1871 Professor of Chemistry 1871-1910 served two terms as President of the ussian Physical- Chemical Society

A. M. Zaitsev (Saytzeff) (1841-1910) Zaitsev's ule: Ann. Chem. Pharm. 1875, 179, 296-301. S HNO 3 /H 2 O S O Ann. Chem. Pharm. 1866, 139, 354-364; 1867, 144, 148-156. Cl C O Na/Hg/Et 2 O HOAc Z. Chem., N.F. 1869, 5, 551-552; 1870, 6, 105-108.J. prakt. Chem., N.F. 1871, 3, 76-88, 427. Cl C O 2 Zn ' ' Cl C O 'I/Zn/Et 2 O ' ' Ann. Chem. Pharm. 1875, 175, 351-374, 374-378; 1877, 185, 148-150, 151-169, 175-183. J. prakt. Chem. 1885, 31, 319-320.

Vladimir Vasil evich Markovnikov (1838-1904) kandidat Kazan' 1860 (economic science) M. Chem. Kazan' 1865 Dr. Chem. Kazan' 1869 Study abroad in Germany 1865-1867. studied with Kolbe at Leipzig studied with Erlenmeyer at Heidelberg Kazan' University Docent in Chemistry 1867 Extraordinary Professor of Chemistry 1868 Professor of Chemistry 1869-1871. Odessa University Professor of Chemistry 1871-1873 Moscow University Professor of Chemistry 1873-1893

V. V. Markovnikov (Markownikoff) (1838-1904) Markovnikov's ule Ann. Chem. Pharm. 1870, 133, 228-259. Compt. rend. 1875, 82, 668-671, 728-730, 776-779. Synthesis of HO 2 C CO 2 H Ann. Chem. Pharm. 1881, 208, 333-349. Synthesis of Compt. rend. 1892, 110, 466-468; 115, 462-464.

Sergei Nikolaevich eformatskii (1860-1934) graduated Kostroma Spiritual Seminary 1878 kandidat Kazan' 1882 M. Chem. Kazan' 1889 Dr. Chem. Warsaw 1890 Study abroad in western Europe 1889-1890. studied with Viktor Meyer at Heidelberg and Göttingen studied with Wilhelm Ostwald at Leipzig Kazan' University curator of museum 1882-1889 Kiev University (St. Vladimir) Professor of Chemistry 1891-1934 Corresponding member, USS Academy of Science 1928

S. N. eformatskii (1860-1934) Br CO 2 Et Zn/Me 2 CO CO 2 Et Br CO 2 Et Zn/Me 2 CHCHO CO 2 Et Ber. Deut. chem. Ges. 1887, 20, 1210-1211; 1895, 28, 2838-2841, 2842-2846, 3262-3265. Textbook: A Beginner's Course of Organic Chemistry (Kiev, 1891)

Egor Egorevich Vagner (1849-1903) kandidat Kazan' 1874 (juridicial science) M. Chem. St. Petersburg 1885 Dr. Chem. Warsaw 1888 St. Petersburg University Assistant in Chemistry 1876-1882 (under Menshutkin) Novo-Aleksandriya Institute of Agriculture and Forestry Professor of Chemistry 1882-1886 University of Warsaw Professor of Chemistry 1886-1903

E. E. Vagner (Wagner) (1849-1903) CHO Et 2 Zn Ann. Chem. Pharm. 1875, 175, 351-374; 1875, 179, 302-313, 313-325. KMnO 4 H 2 O HO Ber. Deut. chem. Ges. 1888, 21, 1230-1240, 3343-3346, 3347-3355, 3356-3360. H + Ber. Deut. chem. Ges. 1899, 32, 2302-2325; 1900, 33, 2121-2125.

Aleksandr Erminingel dovich Arbuzov (1877-1968) diplom Kazan' 1900 M. Chem. Kazan' 1905 Dr. Chem. Kazan' 1914 Novo-Aleksandriya Institute of Agriculture and Forestry Assistant in Chemistry 1901-1905 Professor of Chemistry 1906-1911 Kazan' University Professor of Chemistry 1911-1930 Deputy Dean, Physics-Mathematics Faculty 1922-1930 Kazan' Technical Institute, USS Academy of Sciences Professor and Director 1930

A.E. Arbuzov (1877-1968) PhO PhO P: PhO MeI PhO O P PhO Me + Ph + HI J. uss. Phys. Chem. Soc. 1910, 42, 395-420, 549-561. Chem. Zentr. 1910, 11, 453-454.

Nikolai Yakovlevich Demyanov (1861-1938) kandidat Moscow 1886 M. Chem. Moscow 1895 Dr. Chem. Moscow 1899 Petrine Forestry and Agricultural Academy, Moscow Assistant 1887-1893 Adjunct Professor 1894-1898 Professor 1898-1938 Institute of Organic Chemistry, USS Academy of Science Director 1935-1938

N. Ya. Demyanov (N. J. Demjanov) (1861-1938) NH 2 HONO + NH 2 HONO + J. uss. Phys. Chem. Soc. 1903, 35, 26; 1904 36, 186. Chem. Zentr. 1903, I, 828; 1904, I, 1214. Ber. Deut. chem. Ges. 1907, 40, 4393, 4961; 1908, 41, 43. Textbook Organic Chemistry (3rd edition printed 1944)

Nikolai Matveyevich Kizhner (1867-1935) kandidat Moscow 1890 M. Chem. St. Petersburg 1895 Dr. Chem. Moscow 1900 Tomsk Technoological Institute Professor of Chemistry 1901-1913 Shanyavskii Popular University, Moscow Professor of Chemistry 1914-1917 Aniline Trust esearch Institute Director 1918-1934 Corresponding Member, USS Academy of Sciences 1929-1934

N. M. Kizhner (Kishner) (1867-1935) O NH 2 NH 2 NNH 2 K/ H H J. uss. Phys. Chem. Soc. 1911, 43, 582. (c.f. Chem. Abstr. 1912, 6, 347).

Aleksei Evgenievich Chichibabin (1871-1945) kandidat Moscow 1892 M. Chem. Moscow 1904 Dr. Chem. St. Petersburg 1912 Moscow University Docent 1901, 1906-1908 University of Warsaw Adjunct Professor 1905-1906 Moscow Higher Technical School Professor 1908-1929 Dean, Chemistry Faculty (intermittent) 1909-1929 Left ussia 1930 worked with Tiffeneau at Hôtel Dieu worked at Collège de France Director, Scientific Department, Kuhlman Co. 1930-45 technical advisor, Schering & oosevelt Co. 1930-1945

A. E. Chichibabin (1871-1945) N NaNH 2 N NH 2 J. uss. Phys. Chem. Soc. 1914, 46, 1216. CHO NH 3 J. uss. Phys. Chem. Soc. 1906, 37, 1229. J. prakt. Chem. 1924, 107, 122. N OEt OEt MgX H EtO 3 O OEt OEt Ber. Deut. chem. Ges. 1904, 37, 186; 850. CHO

Nikolai Dmitrievich Zelinskii (1861-1953) kandidat Odessa 1884 M. Chem. Odessa 1889 Dr. Chem. Odessa 1891 Studied abroad 1885-1887 studied with Wislicenus at Leipzig and V. Meyer at Göttingen Moscow University Professor of Chemistry 1893-1953 St. Petersburg Polytechnical Institute Professor of Chemistry 1911-1917 USS Academy of Sciences Corresponding Member 1926 Academician 1929 Head, N.D. Zelinskii Institute 1934

N. D. Zelinskii (Zelinsky) (1861-1953) CHO +NH 4 Cl + KCN CN NH 2 J. uss. Phys. Chem. Soc. 1906, 38, 722; 1908, 40, 790. CO 2 H 1) Br 2 /P 2) H 2 O Br CO 2 H Ber. Deut. chem. Ges. 1887, 20, 2026.

Lev Aleksandrovich Chugaev (1873-1922) M. Chem. Moscow 1903 Dr. Chem. Moscow 1906 Moscow University Adjunct in Bacteriological Institute 1904-1908 St. Petersburg University Professor of Inorganic Chemistry 1908-1922

L A. Chugaev (Tschugaeff) (1873-1922) 1) Na/CS 2 2) MeI 3) Ber. Deut. chem. Ges. 1899, 32, 3332. Development of α-dioximes as reagents for Group VIIIB metals (e.g. dimethylglyoxime for nickel) Z. anorg. allgem. Chem. 1905, 46, 144.

Nikolai Aleksandrovich Menshutkin (1842-1907) kandidat St. Petersburg 1862 M. Chem. St. Petersburg 1866 Dr. Chem. St. Petersburg 1869 Study abroad in western Europe 1863-1866 studied with Strecker in Tübingen, Wurtz in Paris, Kolbe in Leipzig St. Petersburg University Professor of Chemical Technology 1841-1848 Medical-Surgical Academy, University of St. Petersburg Professor of Chemistry 1848-1878

N. A. Menshutkin (Menschutkin) (1842-1907) eaction rate studies in alcohols and amines: 1 1 2 N + X 2 N 4 X 3 3 Z. Phys. Chem. 1890, 5, 589; 1891, 6, 41.

Aleksandr Porfir evich Borodin (1834-1887) kandidat St. Petersburg Medical-Surgical Academy 1855 M.D. St. Petersburg Medical-Surgical Academy 1858 Study in western Europe 1859-1862 frequently travelled with Mendeleev delegate to Karlsruhe conference 1860 St. Petersburg Medical-Surgical Academy Extraordinary Professor of Organic Chemistry 1862-1864 Professor of Organic Chemistry 1864-1887

A. P. Borodin (Borodine) (1834-1887) CO2 Ag Br 2 Br Z. Chem. 1861, 4, 5; 1869, 12, 342. Ann. Chem. Pharm. 1861, 119, 121. CHO Na Ber. Deut. chem. Ges. 1873, 6, 982. CHO COCl KHF 2 COF Compt. rend. 1862, 55, 553. Z. Chem. 1862, 5, 576. Nuov. Cim. 1862, 15, 305. Ann. Chem. Pharm. 1863, 126, 58.

Aleksei Evgrafovich Favorskii (1860-1945) kandidat St. Petersburg 1883 M. Chem. St. Petersburg 1891 Dr. Chem. St. Petersburg 1895 St. Petersburg Technical Institute Professor of Chemistry 1896-1907 USS Academy of Sciences Associate Member 1921 Academician 1929

A. E. Favorskii (Favorsky) (1860-1945) CH 2 C C H C C H H C H J. uss. Phys. Chem. Soc. 1887, 19, 414. Ber. Deut. chem. Ges. 1887, 20, 781. C C CH 3 C C H + O C C J. uss Phys. Chem. Soc. 1900, 32, 652; 1905, 37, 643. Chem. Zentr. 1905, II, 1018. O Br Na J. prakt. Chem. 1913, 88, 658. CO 2 H

Vyacheslav Evgenievich Tishchenko (1861-1941) Ar CHO Al(OEt) 3 Ar O J. uss. Phys. Chem. Soc. 1906, 38, 355, 482, 540, 547. Chem. Zentr. 1906, II, 1309, 1552, 1555, 1556. c.f. Claisen, L., Ber. Deut. chem. Ges. 1887, 20, 646. O Ar

Ivan Nikolaevich Nazarov (1906-1957) acid O O Izv. Akad. Nauk SSS, Otd. Khim. Nauk 1942, 200. Sergei Semenovich Nametkin (1876-1950) H Liebigs Ann. Chem. 1923, 432, 207.