Kami L. Hull Current Position Assistant Professor Department of Chemistry University of Illinois at Urbana Champaign Office: (217) 300-0196 600 S. Mathews e-mail: kamihull@illinois.edu Champaign, IL 61821 Education Stanford University, Stanford, CA NIH Postdoctoral Scholar Adviser: Professor Barry M. Trost The University of Michigan, Ann Arbor, MI Ph.D., Chemistry, February 2009 Advisor: Professor Melanie S. Sanford Macalester College, St. Paul, MN B.A., Chemistry, cum laude, May 2003 Advisor: Professor Ronald G. Brisbois Research Experience Stanford University, Stanford, CA 2009-2012 Research Adviser: Professor Barry M. Trost University of Michigan, Ann Arbor, MI 2003-2009 Research Advisor: Professor Melanie S. Sanford Macalester College, St. Paul, MN 2001-2003 Research Advisor: Professor Ronald G. Brisbois Montana State University, Bozeman, MT summer 2001 Research Advisor: Professor Paul Grieco Awards Center for Advanced Studies Fellow 2017-18 Theme Chemistry Awardee 2017 Sloan Research Fellowship 2016 NSF CAREER Award 2016 Chemical & Engineering News Talented 12 2015 Petroleum Research Fund Young Investigator Award 2013 Kasimir Fajans Award in Chemistry 2011 NIH Postdoctoral Fellowship 2009-12 Roche Excellence in Chemistry Award 2008 Writ and Mary Cornwell Outstanding Graduate Student Research Award 2007 ACS Division of Organic Chemistry Fellowship, Eli Lilly 2006 Novartis Graduate Fellowship 2005 Chemical Sciences at the Interface of Education NSF-GAANN Fellowship 2004 Wallace Undergraduate Summer Research Fellowship, Macalester College 2002 Outstanding Student Employee Award, Macalester College 2002 1 of??
Publications [12.] Kohler, D. G; Kennemur, J. L.; Gockel, S. N.; Hull, K. L. Anti-Markovnikov Selective Pd-Catalyzed Redox-Relay Oxidative Amination, submitted. [11.] Wu, Zhao; Laffoon, S. D.; Nguyen, T. T.; McAlpin, J. D.; Hull, K. L. Rhodium- Catalyzed Enantioselective Isomerization/Oxidation of Allylic Amines for the Synthesis of β-chiral Amides, Angew. Chem. Int. Ed., 2017, early view. [10.] Nguyen, T. T.; Hull, K. L. Rhodium-Catalyzed Oxidative Amidation of Sterically Hindered Aldehydes and Alcohols, ACS Catal. 2016, 7, 8214. [9.] Kennemur, J. L.; Kortman, G. D.; Hull, K. L. Rhodium-Catalyzed Regiodivergent Hydrothiolation of Allyl Amines, J. Am. Chem. Soc. 2016, 138, 11914-11919. [8.] Nguyen, T. T.; Kortman, G. D; Hull, K. L. Synthesis, Cycloaddition and Cycloreversion Reactions of Mononuclear Titanocene oxo Complexes, Organometallics, 2016, 35, 1713-1725. [7.] Wu, Z.; Hull, K. L. Rhodium-catalyzed oxidative amidation of allylic alcohols and aldehydes: effective conversion of amines and anilines into amides, Chem. Sci. 2016, 7, 969-975. [6.] Ensign, S. C.; Vanable, E. P.; Kortman, G. D.; Weir, L. J.; Hull, K. L. Anti-Markovnikov Hydroamination of Homoallylic Amines, J. Am. Chem. Soc. 2015, 137, 13748-13752. [5.] Nguyen, T. T.; Bertke, J. A.; Gray, D. L.; Hull, K. L. Facile C H, C F, C Cl, and C C Activation by Oxatitanacyclobutene Complexes, Organometallics 2015, 34, 4190-4193. [4.] Gockel, S. N.; Hull, K. L. Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations, Org. Lett. 2015, 17, 3236-3239. [3.] Gupta, A. K.; Hull, K. L. Synthesis of 1,2-Diamines via Hydroamination Reactions, Synlett 2015, 26, 1779-1784. [2.] Kortman, G. D.; Orr, M. J.; Hull, K. L. Synthesis and Reactivity of Dioxazirconacyclohexenes: Development of a Zirconium Oxo-Mediated Alkyne Aldehyde Coupling Reaction, Organometallics 2015, 34, 1013-1016. [1.] Ickes, A. R.; Ensign, S. C.; Gupta, A. K.; Hull, K. L. Regio- and Chemoselective Intermolecular Hydroamination of Allyl Imines for the Synthesis of 1,2-Diamines, J. Am. Chem. Soc. 2014, 136, 11256-11259. Prior Publications [10.] Trost, B. M.; Stilvala, C. E.; Fandrick, D. R.; Hull, K. L.; Huang, A.; Poock, C.; Kalkofen, R. Total Synthesis of ( )-Lasonolide A, J. Am. Chem. Soc. 2016, 138, 11690-11701. [9.] Trost, B. M.; Stilvala, C. E.; Hull, K. L.; Huang, A.l Fandrick, D. R. A Concise Synthesis of ( )-Lasonolide A, J. Am. Chem. Soc. 2014, 136, 88-91. [8.] Lyons, T. W.; Hull, K. L.; Sanford, M. S. Controlling Site Selectivity in Pd- Catalyzed Oxidative Cross-Coupling Reactions, J. Am. Chem. Soc. 2011, 133, 4455-4464. [7.] Hull, K. L.; Sanford, M. S. Mechanism of Benzoquinone-Promoted Palladium- Catalyzed Oxidative Cross-Coupling Reactions, J. Am. Chem. Soc. 2009, 131, 9651-9653. 2 of??
[6.] Hull, K. L.; Sanford, M. S. Catalytic and Highly Regioselective Cross-Coupling of Aromatic C H Substrates, J. Am. Chem. Soc. 2007, 129, 11904-11905. [5.] Hull, K. L.; Lanni, E. L.; Sanford, M. S. Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations, J. Am. Chem. Soc. 2006, 128, 14047-14049. [4.] Hull, K. L.; Anani, W. Q.; Sanford, M. S. Palladium-Catalyzed Flourination of Carbon Hydrogen Bonds, J. Am. Chem. Soc. 2006, 128, 7134-7135. [3.] Desai, L. V.; Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxygenation of Unactivated sp 3 C H Bonds, J. Am. Chem. Soc. 2004, 126, 9542-9543. [2.] Dick, A. R.; Hull, K. L.; Sanford, M. S. A Highly Selective Catalytic Method for the Oxidative Funtionalization of C H Bonds, J. Am. Chem. Soc. 2004, 126, 2300-2301. [1.] Mio, M. J.; Kopel, L. C.; Braun, J. B.; Gadzikwa, T. L.; Hull, K. L.; Brisbois, R. G.; Markworth, C. J.; Grieco, P. A. One-Pot Synthesis of Symmetrical and Unsymmetrical Bisarylethynes by a Modification of the Sonogashira Coupling Reaction, Org. Lett. 2002, 4, 3199-3202. Invited Presentations [18.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Iowa State University Ames, IA Nov. 2016. [17.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Iowa Iowa City, IA Nov. 2016. [16.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Duke University Durham, NC Oct. 2016. [15.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, North Carolina State University Raleigh, NC Oct. 2016. [14.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Chicago Organic Symposium Chicago, IL Oct. 2016. [13.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Organometallics Distinguished Lectureship Symposium, ACS National Meeting Philadelphia, PA Aug. 2016. [12.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Organic Reactions and Processes Gordon Research Conference Easton, MA July 2016. [11.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, TrostCon 75, a symposium in honor of Prof. Barry M. Trost s 75 th Birthday, Stanford, CA, May 2016. [10.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, ISACS19: Challenges in Organic Chemistry, Irvine, CA, March 2016. [9.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Andrews University, Barrien Springs, MI, Feb. 2016. [8.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Abbvie, North Chicago, IL, November 2015. [7.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, 250 th National ACS Meeting, Boston, MA, August 2015. 3 of??
[6.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Merck, Raway, NJ, May 2015. [5.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Frontiers Symposium, University of Illinois, Urbana-Champaign, IL, Oct. 2014. (Invited Lecture) [4.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, St. Olaf College, Northfield, MN, Oct. 2014. [3.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Kalamazoo College, Kalamazoo, MI, Oct. 2014. [2.] Hull, K. L. Selective Pd-Catalyzed Oxidative Cross Coupling Reactions and The Total Synthesis of ( )-Lasonolide A, University of Michigan, Ann Arbor, MI, Nov. 2012. (Invited Lecture) [1.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, Roche Excellence in Chemistry Symposium, Palo Alto, CA, May 2008. (Invited Lecture) Other Presentations [19.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June 2015. (Poster [18.] Hull, K. L. Regio- and Chemoselective Hydroamination Reactions, Organic Reactions and Processes Gordon Research Conference, Bryant, RI, July 2014. (Poster [17.] Hull, K. L. Regio- and Chemoselective Hydroamination Reactions, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June 2014. (Poster [16.] Hull, K. L. Regioselective Hydro- and Oxidative Amination Reactions, Organic Reactions and Processes Gordon Research Conference, Bryant, RI, July 2013. (Poster [15.] Hull, K. L. Regioselective Hydro- and Oxidative Amination Reactions, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June 2013. (Poster [14.] Trost, B. M.; Hull, K. L. Development of a Pd-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Lactams, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June 2010. (Poster [13.] Trost, B. M; Hull, K. L.; Huang, A.; Kalkofen, R.; Fandrick, D. Progress Towards the Total Synthesis of ( )-Lasonolide A, 239 th ACS National Meeting, San Francisco, CA, March 2010. (Poster [12.] Hull, K. L.; Sanford, M. S. Determining the Mechanism of Palladium-Catalyzed Oxidative Coupling Reactions, 239 th ACS National Meeting, San Francisco, CA, March 2010. (Oral [11.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, 236 th ACS National Meeting, Philadelphia, PA, August 2008. (Oral 4 of??
[10.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, DOE Catalysis Meeting, Annapolis, MD, May 2008. (Poster [9.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Coupling Reactions, Heterocycles Gordon Research Conference, Newport, RI, June 2007. (Poster [8.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Coupling Reactions, National Organic Symposium, Durham, NC, June 2007. (Poster [7.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Functionalization of C H Bonds, Macalester College, February 7, 2007. (Invited Lecture) [6.] Hull, K. L.; Lanni, E. L.; Anani, W. Q.; Sanford, M. S. Directed Palladium- Catalyzed Fluorination and Oxidative Coupling International Conference on Organometallic Chemistry, Zaragoza, Spain, July, 2006. (Poster presentation) [5.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Fluorination of C H Bonds, Perspectives on Chemistry Research at the University of Michigan, Ann Arbor, MI, June, 2006. (Invited lecture) [4.] Hull, K. L.; Anani, W. Q.; Sanford, M. S. Selective Oxidative Functionalization of C H Bonds, Novartis Science Day, Cambridge, MA, October, 2005. (Poster presentation) [3.] Hull, K. L.; Anani, W. Q.; Desai, L. V.; Sanford, M. S. Pyridine Directing Groups for Selective sp 3 C H Activation and Oxidation, National Organic Symposium, Salt Lake City, UT, June, 2005. (Poster presentation) [2.] Hull, K. L.; Brisbois, R. G. Design and Synthesis of Building Blocks for Pd- and Pt-Mediated Supramolecular Self-Assembly Pew Undergraduate Research Symposium, St. Louis, MO, November, 2002. (Oral presentation) [1.] Hull, K. L.; Markworth, C. J.; Grieco, P. A. Synthesis of Self-Assembled Half Barrel, Pew Undergraduate Research Symposium, Chicago, IL, November, 2001. (Poster presentation) 5 of??