Dr Christopher Timperley Dr Jonathan Forman Professor Paula Vanninen VERIFIN.

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Report from the workshop on chemical forensics in Helsinki Capabilities across the field and potential applications in the CWC Implementation June 20-22, 2016 Helsinki Dr Christopher Timperley Dr Jonathan Forman Professor Paula Vanninen www.helsinki.fi/verifin 1

Workshop agenda Experiences and Perspectives on Investigations of Alleged Use, moderated by dr Christophe Curty Chemical forensics and chemical weapons: moderated by dr Daan Noort Chemical forensics in law enforcement: Crime laboratories, moderated by mr Cheng Tang Chemical forensics in law enforcement: Illegal drug attribution analysis, moderated by professor Slawomir Neffe Biomedical samples, moderated by professor Slavica Vučinić Other attribution analysis, moderated by professor David Gonzalez Reconstructing past events, moderated by professor Ponnadurai Ramasami www.helsinki.fi/verifin 2

Mr Dominique Anelli, former head of the OPCW Demilitarisation branch /Paula Vanninen 18.11. 2010 3

Mr Dominique Anelli 18.11. 2010 4

Mr Dominique Anelli 18.11. 2010 5

Mr Lennie Phillips, Team leader in the OPCW FFM OPCW Fact Finding Mission www.helsinki.fi/verifin 6

Mr Lennie Phillips, Team leader in the OPCW FFM OPCW Fact Finding Mission Use of Chlorine Use of Sulfur mustard Since 2013 almost 800 samples has been coordinated by the OPCW lab/ Hugh Gregg www.helsinki.fi/verifin 7

Mr Lennie Phillips, Team leader in the OPCW FFM OPCW Fact Finding Mission Recommendation: System for managing and collection of data should be established including Use of Chlorine collection of samples, analytical information and annotation. A searchable collection of physical Use of Sulfur mustard objects and information is valuable for retrospective review. Since 2013 almost 800 samples has been coordinated by the OPCW lab/ Hugh Gregg www.helsinki.fi/verifin 8

Dr Ralf Trapp 18.11. 2010 9

Dr Ralf Trapp Recommendation: Development of ROPs for the sampling of biomedical materials, and their handling and storage Methods for TICs like chlorine 18.11. 2010 10

Abonded chemical weapons discovered in China Dr Zhanshang Zhao Ministry of National Defence and Mr Cheng Tang (OPCW SAB) 18.11. 2010 11

Carlos Fraga, PNNL 18.11. 2010 12

Carlos Fraga, PNNL 18.11. 2010 13

Recommendation: Methods using impurity profiling and isotopic ratio distribution for purposes related to determining responsibility for use of chemical weapons, for abandoned chemical weapons, or for clandestine chemical weapons production are valuable to develop solvents, trace metals and inorganic elements Carlos Fraga, PNNL 18.11. 2010 14

Mr Jari Pukkila, National Bureau of Investigation Forensic Laboratory, Finland described the general principles of crime scene operations, evidence collection and sample handling. 18.11. 2010 15

Recommendation: Cooperative working relationships with organizations and network of experts relevant to forensics Mr Jari Pukkila, National Bureau of Investigation Forensic Laboratory, Finland described the general principles of crime scene operations, evidence collection and sample handling. 18.11. 2010 16

Dr Michael Collins, Australian Forensic Drug Laboratory, National Measurement Institute, the illicit drug profiling programme 18.11. 2010 17

Martin Söderström,, Biomedical samples in chemical weapo 18.11. 2010 18

Dr. Rudolf Johnson, CDC, Measuring Human Exposure to Nerve Agents and Marine Toxins 18.11. 2010 19

Juhani Huuskonen, University of Jyväskylä Professor Juhani Huuskonen,University of Jyväskylä and RECENART Inc., Finland), chemical forensics and art 18.11. 2010 20

Professor Juhani Huuskonen,Univer ty of Jyväskylä and RECENART Inc., Finland), chemical forensics and art 18.11. 2010 21

18.11. 2010 22

Professor Evershed 18.11. 2010 23

Professor Evershed 18.11. 2010 24

Professor Evershed 18.11. 2010 25

Professor Evershed Linking of molecular structure-to-isotopic composition increases the diagnostic value of commonly occurring preserved biomarkers, such as lipids and proteins, allowing exploitation of previously inaccessible information relating to metabolism, digestive physiology, environment, climate and absolute age, thereby enhancing provenance assignments. 18.11. 2010 26

18.11. 2010 27

Professor Patric Degryse, Centre for Archaeological Sciences at the Katholieke Universiteit Leuven, on provenance, technology, on exchange and trade of inorganic materials in an archaeological context by examining isotopic evidence 18.11. 2010 28

Professor Patric Degryse 18.11. 2010 29

Conclusions-Recommendations A Workshop or a temporary working group could be considered to develop forensic methods and capabilities for CWC verification Appropriate functions within the OPCW could benefit from cooperative working relationships with organisations and networks of experts relevant to forensics. Establishing a system for the management of data is essential for use in a forensic capacity. www.helsinki.fi/verifin 30

Conclusions-Recommendations A searchable collection of physical objects and information is valuable for retrospective review For example, existing compiled data on abandoned chemical weapons and impurity profiles for known synthetic routes to nerve and vesicant agents could serve as a resource to those working in the field of chemical weapons related investigations www.helsinki.fi/verifin 31

Conclusions-Recommendations Methods using impurity profiling and isotopic ratio distribution for purposes related to determining responsibility for use of chemical weapons, for abandoned chemical weapons, or for clandestine chemical weapons production are valuable to develop Autonomous systems to support investigations of alleged use of chemical weapons could benefit investigators Forensic training will continue to be valuable for enhancing forensic awareness and forensic investigation capabilities www.helsinki.fi/verifin 32