MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.

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Exam Name MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) Magnesium and nitrogen react in a combination reaction to produce magnesium nitride: 1) 3 Mg + N2 Mg3N2 In a particular experiment, a 9.27-g sample of N2 reacts completely. The mass of Mg consumed is g. A) 24.1 B) 8.04 C) 13.9 D) 0.92 E) 16.1 2) The combustion of ammonia in the presence of excess oxygen yields NO2 and H2O: 2) 4 NH3 (g) + 7 O2 (g) 4 NO2 (g) + 6 H2O (g) The combustion of 28.8 g of ammonia consumes g of oxygen. A) 54.1 B) 108 C) 15.3 D) 28.8 E) 94.7 3) The combustion of ammonia in the presence of excess oxygen yields NO2 and H2O: 3) 4 NH3 (g) + 7 O2 (g) 4 NO2 (g) + 6 H2O (g) The combustion of 43.9 g of ammonia produces g of NO2. A) 2.58 B) 43.9 C) 0.954 D) 178 E) 119 4) The combustion of propane (C3H8) produces CO2 and H2O: 4) C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O (g) The reaction of 2.5 mol of O2 will produce mol of H2O. A) 4.0 B) 3.0 C) 2.5 D) 2.0 E) 1.0 5) The combustion of propane (C3H8) in the presence of excess oxygen yields CO2 and H2O: 5) C3H8 (g) + 5O2 (g) 3CO2 (g) + 4H2O (g) When 2.5 mol of O2 are consumed in their reaction, mol of CO2 are produced. A) 2.5 B) 3.0 C) 6.0 D) 1.5 E) 5.0 6) Calcium carbide (CaC2) reacts with water to produce acetylene (C2H2): 6) CaC2 (s) + 2H2O (g) Ca(OH)2 (s) + C2H2 (g) Production of 13 g of C2H2 requires consumption of g of H2O. A) 4.8 102 B) 4.5 C) 4.8 10-2 D) 9.0 E) 18 1

7) Under appropriate conditions, nitrogen and hydrogen undergo a combination reaction to yield ammonia: 7) N2 (g) + 3H2 (g) 2NH3 (g) A 7.1-g sample of N2 requires g of H2 for complete reaction. A) 1.2 B) 0.51 C) 17.2 D) 0.76 E) 1.5 8) Lead (II) carbonate decomposes to give lead (II) oxide and carbon dioxide: 8) PbCO3 (s) PbO (s) + CO2 (g) How many grams of lead (II) oxide will be produced by the decomposition of 2.50 g of lead (II) carbonate? A) 2.09 B) 0.41 C) 2.61 D) 2.50 E) 0.00936 9) GeF3H is formed from GeH4 and GeF4 in the combination reaction: 9) GeH4 + 3GeF4 4GeF3H If the reaction yield is 92.6%, how many moles of GeF4 are needed to produce 8.00 mol of GeF3H? A) 2.78 B) 5.56 C) 2.16 D) 3.24 E) 6.48 10) What mass in grams of hydrogen is produced by the reaction of 4.73 g of magnesium with 1.83 g of water? 10) Mg (s) + 2H2O (l) Mg(OH)2 (s) + H2 (g) A) 0.0485 B) 0.204 C) 0.0162 D) 0.102 E) 0.219 11) Silver nitrate and aluminum chloride react with each other by exchanging anions: 11) 3AgNO3 (aq)+ AlCl3 (aq) Al(NO3)3 (aq) + 3AgCl (s) What mass in grams of AgCl is produced when 4.22 g of Ag NO3 react with 7.73 g of AlCl3? A) 4.22 B) 3.56 C) 11.9 D) 17.6 E) 24.9 12) How many moles of magnesium oxide are produced by the reaction of 3.82 g of magnesium nitride with 7.73 g of water? 12) Mg3N2 + 3H2O 2NH3 + 3MgO A) 0.114 B) 0.0378 C) 0.0756 D) 4.57 E) 0.429 2

13) A 3.82-g sample of magnesium nitride is reacted with 7.73 g of water. 13) Mg3N2 + 3H2O 2NH3 + 3MgO The yield of MgO is 3.60 g. What is the percent yield in the reaction? A) 46.6 B) 99.9 C) 78.7 D) 49.4 E) 94.5 14) Pentacarbonyliron (Fe(CO)5) reacts with phosphorous trifluoride (PF3) and hydrogen, releasing carbon monoxide: 14) Fe(CO)5 + PF3 + H2 Fe(CO)2(PF3)2(H)2 + CO (not balanced) The reaction of 5.0 mol of Fe(CO)5, 8.0 mol of PF3 and 6.0 mol of H2 will release mol of CO. A) 5.0 B) 15 C) 24 D) 6.0 E) 12 15) What is the maximum mass in grams of NH3 that can be produced by the reaction of 1.0 g of N2 with 3.0 g of H2 via the equation below? 15) N2 (g) + H2 (g) NH3 (g) (not balanced) A) 1.2 B) 2.0 C) 4.0 D) 17 E) 0.61 16) What is the maximum amount in grams of SO3 that can be produced by the reaction of 1.0 g of S with 1.0 g of O2 via the equation below? 16) S (s) + O2 (g) SO3 (g) (not balanced) A) 0.27 B) 2.5 C) 1.7 D) 2.0 E) 3.8 17) Solid aluminum and gaseous oxygen react in a combination reaction to produce aluminum oxide: 17) 4Al (s) + 3O2 (g) 2Al2O3 (s) The maximum amount of Al2O3 that can be produced from 2.5 g of Al and 2.5 g of O2 is g. A) 9.4 B) 5.3 C) 7.4 D) 5.0 E) 4.7 18) Sulfur and fluorine react in a combination reaction to produce sulfur hexafluoride: 18) S (s) + 3F2 (g) SF6(g) The maximum amount of SF6 that can be produced from the reaction of 3.5 g of sulfur with 4.5 g of fluorine is g. A) 5.8 B) 16 C) 8.0 D) 12 E) 3.2 3

19) Solid aluminum and gaseous oxygen react in a combination reaction to produce aluminum oxide: 19) 4Al (s) + 3O2 (g) 2Al2O3 (s) In a particular experiment, the reaction of 2.5 g of Al with 2.5 g of O2 produced 3.5 g of Al2O3. The % yield of the reaction is. A) 26 B) 74 C) 47 D) 66 E) 37 20) Sulfur and oxygen react in a combination reaction to produce sulfur trioxide, an environmental pollutant: 20) 2S (s) + 3O2 (g) 2SO3 (g) In a particular experiment, the reaction of 1.0 g S with 1.0 g O2 produced 0.80 g of SO3. The % yield in this experiment is. A) 29 B) 30 C) 21 D) 88 E) 48 21) Sulfur and fluorine react in a combination reaction to produce sulfur hexafluoride: 21) S (s) + 3F2 (g) SF6 (g) In a particular experiment, the percent yield is 79.0%. This means that in this experiment, a 7.90 -g sample of fluorine yields g of SF6. A) 0.110 B) 10.1 C) 7.99 D) 24.0 E) 30.3 22) How many grams of N2 are required to react with 2.30 moles of Mg in the following process? 3 Mg + N2 Mg3N2? (Mg = 24.3, N = 14.0 g/mol) A) (2.30)(3)(28.0) B) (2.30/3)(28.0) C) (2.30/3)/28.0 D) (2.30)(28.0) E) (2.30/3) 22) 23) How many moles of H3PO4 are produced when 20.0 g of HCl are produced by the reaction PCl5 + 4 H2O H3PO4 + 5 HCl? (P = 31.0, Cl = 35.5, H = 1.0, O = 16.0 g/mol) A) (20.0/36.5)/5 B) (20.0/35.5)/5 C) (20.0/36.5) D) (20.0/98.0)/5 E) (20.0/98.0) 23) 24) For the reaction 2 Al + Fe2O3 Al2O3 + 2 Fe, 2.5 g of Al (27.0 g/mol) and 7.2 g of Fe2O3 (159.8 g/mol) produce how many g of Fe (55.9 g/mol)? A) 7.2 (55.9/158.9) B) 2.5 (55.9/27.0) C) 2.5 (55.9)(2)/(27.0)(2) D) 7.2 (55.9)(2)/158.9 E) 2.5 (55.9/158.9) 24) 4

25) Which metal will produce the most hydrogen per gram of metal? A) Mg + 2 HCl MgCl2 + H2 B) Sn + 4 HCl SnCl4 + 2 H2 C) 2 Li + 2 HCl 2 LiCl + H2 D) 2 Fe + 6 HCl 2 FeCl3 + 3 H2 E) 2 Cr + 6 HCl 2 CrCl3 + 3H2 25) 26) Gases emitted during volcanic activity often contain high concentrations of hydrogen sulfide and sulfur dioxide. These gases may react to produce deposits of sulfur according to the equation: 2 H2S(g) + SO2(g) 3 S(s) + 2 H2O(g) For the complete reaction of 6.41 mol of hydrogen sulfide: A) 628 g of total reactants are consumed B) 308 g of sulfur is formed C) 320 g of total products result D) 410 g of sulfur dioxide is consumed E) 231 g of water vapor is produced 26) 27) 24.0 g of ethane (C2H6) are burned to form CO2 and H2O. How many grams of CO2 are produced? A) 70.3 g B) 32.8 g C) 43.2 g D) 14.4 g E) 35.1 g 27) 28) Given the following reaction: Na2SO4(s) + 2 C(s) Na2S(s) + 2 CO2(g) How many grams of carbon are required to produce 18.4 g Na2S(s)? A) 2.83 g B) 11.3 g C) 239 g D) 142 g E) 5.66 g 28) 29) The chemical reaction occurring during the discharge of a lead storage battery can be represented by the equation: Pb(s) + PbO2(s) + 2 H2SO4(aq) 2 PbSO4(s) + 2 H2O(l) What mass of lead sulfate would result from the complete reaction of 41.4 g of lead? A) 121 g B) 115 g C) 60.5 g D) 105 g E) 57.6 g 29) 30) A 1.900 g sample of C6H12 is burned in an excess of oxygen. What mass of CO2 and H2O should be obtained? A) 10.45 g CO2, 4.27 g G H2O B) 0.994 g CO2, 0.407 g H2O C) 2.98 g CO2, 1.22 g H2O D) 5.96 g CO2, 2.44 g H2O E) 5.23 g CO2, 2.38 g H2O 30) 31) How much Cl2, in g, is required to produce 12.0 g CCl4 according to the following reaction? CH4 + 4 Cl2 CCl4 + 4 HCl A) 11.0 g B) 5.52 g C) 12.0 g D) 1.38 g E) 22.1 g 31) 32) Given the reaction: 2KMnO4 + 10 KI + 8 H2SO4 6 K2SO4 + 2 MnSO4 + 5 I2 + 8 H2O How many moles of H2SO4 are required to produce 2.0 moles of I2, given the other reactants are in excess? A) 1.3 mol B) 1.6 mol C) 3.2 mol D) 4.0 mol E) 0.80 mol 32) 5

33) Given the reaction: 2 KMnO4 + 10 KI + 8 H2SO4 6 K2SO4 + 2 MnSO4 + 5 I2 + 8 H2O How many moles of I2 are produced by reacting 28.0 g KMnO4, 18.0 g KI and 46.0 g H2SO4? A) 0.108 mol B) 0.0542 mol C) 0.886 mol D) 0.293 mol E) 0.443 mol 33) 34) The chemical reaction during low current discharge of a simple ʺdry cellʺ involves: (unbalanced) Zn + MnO2 + NH4Cl ZnCl2 + Mn2O3 + NH3 + H2O What is the coefficient for zinc in the balanced equation, and what is the limiting reagent for a process in which equal masses of reactants are mixed? A) 1/MnO2 B) 1/Zn C) 2NH4Cl D) 2/MnO2 E) 2/Zn 34) 35) What is the percent yield if 185 grams of SiO2 are made from 328 g of Cr2O3 by the following equation? 3 Si(s) + 2 Cr2O3(s) 3 SiO2(s) + 4 Cr(l) A) 142% B) 95% C) 56% D) 105% E) 70% 35) 36) What is the percent yield if 122 grams of SiO2 are made from 246 g of Cr2O3 by the following equation? 3 Si(s) + 2 Cr2O3(s) 3 SiO2(s) + 4 Cr(l) A) 83.6% B) 59.3% C) 49.6% D) 125% E) 33.1% 36) 37) If 0.500 mol of CaCl2 is mixed with 0.200 mol Na3PO4, the maximum amount in moles of Ca3(PO4)2 that can be formed is: A) 0.10 B) 0.50 C) 0.67 D) 0.20 E) 0.17 37) 38) Consider the equation: 2 Na + 2 H2O 2 NaOH + H2. If 92.0 g of sodium is reacted with 76.0 g of water until the reaction goes to completion, which reactant will remain and in what quantity? A) 10.0 g sodium B) 43.5 g sodium C) 72.0 g water D) 10.0 g water E) 3.9 g water 38) 39) 42.6 g Cu are combined with 84.0 g of HNO3 according to the reaction: 3 Cu + 8 HNO3 3 Cu(NO3)2 + 2 NO + 4 H2O. Which reagent is limiting and how many grams of Cu(NO3)2 are produced? A) HNO3, 93.8 g B) HNO3, 125.6 g C) Cu, 125.6 g D) Cu, 93.8 g E) Cu(NO3)2, 125.6 g 39) 6

40) Consider the gaseous reaction: N2H4(g) + 3 O2(g) 2 NO2(g) + 2 H2O(g) If the above reaction has a percent yield of 98.5%, what mass in grams of oxygen is needed to produce 49.0 g of NO2(g)? A) 25.9 g B) 23.1 g C) 51.9 g D) 11.5 g E) 50.4 g 40) 41) Chromium in its +VI oxidation state is considered a hazardous, carcinogenic species, destruction of which may be accomplished by the process symbolized as: 4 Zn + K2Cr2O7 + 7 H2SO4 4 ZnSO4 + 2 CrSO4 + K2SO4 + 7 H2O If 1.0 mol of each reactant is mixed, what is the limiting reagent, and what is the theoretical yield of chromium(ii) sulfate? A) H2,1.0 mol B) Zn,0.50 mol C) H2SO4,0.29 mol D) K2Cr2O7,2.0 mol E) no limiting reagent, 1.0 mol 41) 42) Given the reaction: P4(l) + 6 Cl2(g) 4 PCl3(l) If the percent yield is 82%, what mass of P4 is required to obtain 2.30 g PCl3 (Cl2 in excess)? A) 0.16 g B) 0.43 g C) 0.52 g D) 0.63 g E) 0.95 g 42) 43) In the following reaction: 2 KClO3(s) 2 KCl(s) + 3 O2(g) 14.0 g KClO3 yielded 1.40 g KCl. What is the percent yield? A) 16.4% B) 10.0% C) 32.9% D) 6.08% E) 11.0% 43) 44) Cryolite is a compound needed for the Hall-Heroult process for producing aluminum. Cryolite is produced by the following reaction: 6 HF + Al(OH)3 + 3 NaOH Na3AlF6 + 6 H2O How many grams of cryolite are produced if the reaction has a 94.3% yield and a limiting reagent of 27.8 grams of HF? A) 15.9 B) 275 C) 48.6 D) 15.0 E) 45.8 44) 7

Answer Key Testname: CALCULO ESTEQUIOMETRICO 1) A 2) E 3) E 4) D 5) D 6) E 7) E 8) A 9) E 10) D 11) B 12) A 13) C 14) E 15) A 16) C 17) E 18) A 19) B 20) E 21) C 22) B 23) A 24) D 25) C 26) B 27) A 28) E 29) A 30) D 31) E 32) C 33) B 34) A 35) B 36) A 37) A 38) E 39) A 40) C 41) C 42) D 43) A 44) E 8