SECTION 5: THIN SECTIONS

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SECTION 5: THIN SECTIONS

142-864A-1M-01 (0-10 cm) OBSERVER: BR GRAIN : Microcrystalline. TEXTURE: Spherulitic (variolitic) to microlitic (no glass). WHERE SAMPLED: Unit 1 COMPO srnon 0.2-1 mm Euhedral, prismatic. Some slight oscillatory zoning. Skeletal overgrowths common. Occasional glomerocrysts. Plaeioclase Titanomagnetite l%-3% Tr ' l%-3% Tr <0.15 mm Skeletal, acicular bundles. Skeletal, equant. Anhedral, skeletal, equant. Often in sheaf-like, radial, or bow-tie microlites. Within and between sheaf bundles of acicular microlitic plagioclase. 2% : Flow banding shown by spherulitic and microlitic bundles. Microlites show preferred orientation parallel to banding. Sheaf spherule texture common in spherulitic zone. Rock is fresh. 142-864A-1M-02 (0-35 cm) OBSERVER: HAR GRAIN : Glassy to microcrystalline. TEXTURE: Glassy with spherulites. WHERE SAMPLED: Unit 1 0.07-0.3 mm Euhedral prisms Both zoned and unzoned crystals. Few glomerocrysts. <O.l mm <O.l mm Skeletal to acicular. Skeletal and acicular. SEE : Many of the olivine and plagioclase microlites lie at the center of spherules. Spherules are often coalesced in linear zones one spherule wide implying crystallization associated with flow shear. Some smaller crystals of same material in sheaf-like bundles with some preferred orientation parallel to linear spherule zones. Some vesicle walls are decorated with sporadic tiny sulfide globules 1 to 2 microns in diameter. 142-864A-1M-02 (35-55 cm) GRAIN : Microcrystalline. TEXTURE: Spherulitic to microlitic, no glass. OBSERVER: HAR WHERE SAMPLED: Unit 1 0.08-1.2 mm Euhedral. Euhedral, Drism prismatic. Both zoned and unzoned crystals. Some glomerocrysts. 5%-l( Titanomagnetite <0.6 mm <0.08 mm <O.Ol mm Acicular, skeletal. Skeletal, acicular, equant. Some preferred orientaton of microlites. Microlites form bow-tie and radial clusters. Some sheaf-like bundles. Some hopper crystals. <.O5 mm : Rock is fresh.

142-864A-1M-02 (100-150 cm) GRAIN : Microcrystalline. TEXTURE: Spherulitic to microlitic, no glass. OBSERVER: HAR WHERE SAMPLED: Unit 1 0.1-1.4 mm Euhedral prismati< Titanomagnetite 2%-4% <1.4 mm <0.008 mm Skeletal, equant. Anhedral skeletal. Sheaf-like bundles of acicular microlites. : Some linear zones of spherules. Some preferred orientation of microlites parallel to linear spherule zones. Spherules are turbid and felty in appearance. Rock is fresh. 142-864A-1M-03 (0-35 cm) GRAIN : Glassy to microcrystalline. TEXTURE: Glassy with spherulites. OBSERVER: BRO WHERE SAMPLED: Unit 1 0.1-0.6 mm Euhedral, prism Sheaf-like bundles. Small sheafs often at the core of spherules. <0.04 mm : Coalesced spherules form flow banding, one spherule wide. Glass contains 10% 15% to 80% spherules and crystallites. Rock is fresh. 142-864A-1M-03 (55-85 cm) OBSERVER: BRO WHERE SAMPLED: Unit 1 GRAIN : Microcrystalline. TEXTURE: Spherulitic (variolitic), no glass. 0.1-1.0 mm Euhedral to prismatic. Slight zonation in some crystals. Titanomagnetite 17c.O mm <O.OOl mm Acicular to skeletal, equant. Anhedral, skeletal Some sheaf-like bundles. Sheaf-like bundles. Interstitial to silicate minerals. l%-10% Located in zones. <1.4 mm Irregular to rounded. : Rock is fresh. 90

142-864A-1M-03 (55-85 cm) GRAIN : Microcrystalline. TEXTURE: Spherulitic (variolitic), no glass. OBSERVER: BRO WHERE SAMPLED: Unit 1 COMPOsrπoN 0.2-0.7 mm Euhedral, prism Twinned, unzoned. Skeletal overgrowths common. Titanomagnetite <0.004 mm Acicular to subhedral prismatic. Often in sheaf-like bundles. Hopper crystals common. Throughout 0.01-0.4 mm Round to irregular. : Sheaf spherules are very well developed. Spherules are coalesced and make up great majority of the rock. Two generations of vesicles. First is rounded to irregular (may represent coalescing of vesicles), 0.1-0.4 mm in size. Second is smaller, 0.001-0.10 mm in size, and round. Rock is fresh. 142-864A-1M-03 (100-150 cm) GRAIN : Fine-grained. TEXTURE: Intergranular, no glass. OBSERVER: BRO WHERE SAMPLED: Unit 1 0.25-1.0 mm Euhedral, prism Twinned, unzoned. 30%-40% Clinopyroxene 5% 15% 30%-40% <0.8 mm 5%-15% Anhedral to plagioclase. Some hopper crystals. Some in radial intergrowths. Minor amount of sub-ophitic subhedral, equant or clinopyroxene grown around acicular plumose. <10% Titanomagnetite Anhedral, equant. Interstitial to silicate minerals. : Approaching sub-ophitic texture. Slight preferred orientation of plagioclase microlites. Rest of groundmass is mesostasis. Rock is fresh. 91

142-864A-1M-04 (0-9 cm) GRAIN : Fine-grained. TEXTURE: Subophitic, intergranular, intersertal. OBSERVER: NIU WHERE SAMPLED: Unit 1 0.3-1.0 Tabular to rounc rounded. Only a few grains, some of which show resorbed features. 40 Clinopyroxene 40 2 Magnetite 1-2 40 40 2 1-2 Mesostasis 15 15 <1.5.O <O.l <O.Ol Acicular to swallow-tailed. Subhedral, anhedral, crystals. Subhedral to anhedral. Skeletal, anhedral, (mesostasis) patches. Quench growth features: skeletal and elongate. Subophitic growth around plagioclase acicular to prismatic. Occurs within glassy or spherulitic to euhedral. VOIDS 6 Random. 2 FELLING Irregular. Leached vesicles? : The rock is fresh and is crystalline. Except for a few grains which are phenocrysts, all plagioclase crystals are of quench morphology (skeletal, cicular, and swallow-tailed), though the grain/length can be as much as 1.5 mm (length). There are some sulfide globules, occurring within glassy or spherulitic (mesostasis) patches (size <0.006 mm) with variable shapes, from irregular to rounded. They seem to form by exsolution of sulfide-liquids from silcate melts. Based on the reflectivity, characteristic color, and isotropic nature, they are likely pyrite. This report is based on two thin section descriptions. One section (T.S. #29) was heated to 500 degrees C for magnetic properties studies. The mesostasis of this section has a pinkish tint reflecting the presence of hematite. Marked as Piece #1. 142-864A-1M-04 (9-20 cm) GRAIN : Microcrystalline TEXTURE: Spherulitic to microlitic. OBSERVER: NIU WHERE SAMPLED: Unit 1.O.O 0.2-0.8 Euhedral, tabular. Clinopyroxene Magnetite Sulfide Minerals 15 1-2 15 5 1-2 <0.7 <0.15 <O.l <0.05 <0.005 Skeletal and acicular. Skeletal, anhedral. Equant, anhedral to euhedral. Irregular to round. Microlites show extreme elongation or swallow-tailed shapes due to rapid growth (quench). Sector, sweep zoning..o Random. 0.1-0.15 Irregular to round. : One blue, granular crystal (about 0.08 mm) has high relief, low birefrengence, occurs within a void, and it is unidentified but is probably grinding powder(?). The sulfide drops are probably pyrite. The rock is fresh. Marked as Piece #1. 92

142-864A-1M-04 (20-30 cm) GRAIN : Mostly glassy. TEXTURE: Spherulitic to glassy. OBSERVER: NIU WHERE SAMPLED: Unit 1.O.O up to 1 Euhedral, tabular wedge-like. Twinned, clear interior (no inclusions)..o.o <0.5 long Skeletal, and acicular. Magnetite <O.OOl microlites show extreme elongation (rarely > 5-6 micron wide) due to rapid growth (quench). Dispersed around spherule rims. Voids 1-2 Between spherules. 0.01-0.5 Circular to irregular : One perfect, euhedral plagioclase grain (0.1-0.3 mm) shows excellent zoning. Large, coalesced, irregular vesicules up to 0.5 mm. Smaller vesicles are rare in glassy areas, most common in coarser spherulitic ground mass. The rock is very fesh. Marked as Piece #1. 142-864A-1M-05 (0-100 cm) GRAIN : Glass to microcrystalline. TEXTURE: Glassy to spherulitic. OBSERVER: BCH WHERE SAMPLED: Unit 1 0.2-0.6 Euhedral. Mainly tabular. <3 Sulfide globule <3 <0.2 <0.008 Concentrated in a spherulitic 1 through middle of section. Occur freelv in glass. Irregular. 0.02-0.1 Round to irregular. : Rock is fresh, showing glass sandwiching a band of spherulitic rock. Marked as Piece #1. 142-864A-1M-05 (0-100 cm) GRAIN : Glass to microcrystalline. TEXTURE: Glassy to spherulitic. OBSERVER: NIU WHERE SAMPLED: Unit 1 <0.8 Euhedral, tabular. Glomerophyric clusters, some grains show zoning. Magnetite Sulfide globules 8 8 <0.8 <0.005 <0.005 Acicular, skeletal Irregular or round. Some skeletal grains show swallow-tailed forms. Sparsely distributed. Likely pyrite, crystallized from exsolved sulfide liquid from silicate melt. PERCEN Random. <0.08 Irreeular to round. : The rock is fresh. Textural zoning is characterized by glassy margin and more sperulitic texture in the interior. Almost all the spherules have incipient microlites as cores. Marked as Piece 2. 93

142-864A-1M-05 (100-118 cm) GRAIN : Fine-grained. TEXTURE: Intergranular. OBSERVER: BCH WHERE SAMPLED: Unit 1 0.3-0.4 Subhedral to euhedral, blocky Scalloped, rounded edges look resorbed. 50-55 50-55 <0.3 Clinopyroxene 30-35 30-35 <0.3 <0.05 Magnetite 1-2 1-2 <0.12 Mesostasis 15-20 15-20 Acicular to elongate laths. Anhedral to subhedral. Anhedral to subhedral. Radial intergrowths dominate the groundmass. Some are subophitic around plagioclase lath. 2 Clustering 0.6-0. Irregular. : The rock is fresh and shows minor subophitic texture. In the groundmass small sulfide globules (<0.012 mm) of light yellowish color (probably pyrite) occur. Marked as Piece 2B. 142-864A-1M-05 (100-118 cm) GRAIN : Fine-grained. TEXTURE: Intergranular. OBSERVER: BCH WHERE SAMPLED: Unit 1 1 1 0.2-1 Tabular. Glomerophyric or single crystals, zoning in some grains. 25-30 25-30 Skeletal to acicular. Clinopyroxene 10-15 10-15 <0.2 Anhedral to Often in sheaf-like and plumose masses, subhedral or skeletal. Magnetite 1 Sulfide globules <0.5 long 1 <O.l <0.006 Anhedral to subhedral, elongate, skeletal. 1 Irregular 0.02-0.3 Round to irregular. : Matrix is mainly composed of spherulites and minor glassy patches. Rock is fresh. Marked as Piece 2A. 94

142-864A-1M-05 (100-118 cm) GRAIN : Microcrystalline. TEXTURE: Spherulitic. OBSERVER:BCH WHERE SAMPLED: Unit 1 0.2-0.4 Subhedral to eul <5 Clinopyroxene <5 Magnetite <5 1 <5 <5 1 <O.l <O.l <O.Ol <0.05 Subhedral to skeletal. Rounded. Sector, sweep zoning. Concentrated between spherulites. 1 <1.5 Round to irregular. : A kink-banded layer of microcrystalline grains crosses through the thin section. The "upper" part of the thin section shows minor portion of darkbrown cryptocrystalline mesostasis. The rock is fresh. Marked as Piece 1. 142-864A-1M-06 (0-75 cm) GRAIN : Microcrystalline TEXTURE: Glassy to spherulitic (variolitic). OBSERVER: HEK WHERE SAMPLED: Unit 1 0.1-0.6 mm Euhedral, tabula Glomerocrysts common. Most crystals have quench overgrowths. Slight compositional zonation. 5% Titanomagnetite 5% <0.03 mm <0.005 mm Acicular to skeletal. Anhedral Microlites in sheaf, radial, or bow-tie bundles. Often in small aggregates. Sometimes concentrated along margins of vesicles. CAVTΠES Localized SEE 0.002-0.4 mm Round to irregular. : Chilled glassy margin grades into spherule-rich interior with no glass. Sample is foliated with individual foliation surfaces defined by the concentration of spherules. Two generations of vesicles with large, irregular ones (0.1-0.4 mm) and small, round ones (0.02-0.03 mm). Rock is fresh.

142-864A-1M-06 (75-140 cm) GRAIN : Glass to microcrystalline. TEXTURE: Glassy to spherulitic. OBSERVER: BCH WHERE SAMPLED: Unit 1 SEE Clinopyroxene 0.2-0.6 0.4 Euhedral. Euhedral. Only one grain <O.l Very minor. 1-4 Patchy. 0.02-1.5 Round to irregular : Rock is fresh and shows coalesced sheaf and radial spherules make up bulk of the rock. Marked as Piece 1. 142-864A-1M-06 (75-140 cm) OBSERVER: BCH WHERE SAMPLED: Unit 1 GRAIN : Microcrystalline to fine-grained TEXTURE: Microlitic to intergranular 0.3-0.8 Euhedral, tabular. Scalloped, rounded edges look resorbed. 3 0 30 <0.8 Subhedral to skeletal. Mainly acicular. Clinopyroxene 10 2 10 2 <0.2 <O.l Subhedral to skeletal, plumose. Subhedral. Sector, sweep zoning. 3-4 0.02-0.4 Round to irregular. : About 20% of the rock is dark, cryptocrystalline mesostasis. The rock is fresh. Marked as Piece 2. 96

142-864A-3Z-01 (0-6 cm) OBSERVER: BRO GRAIN : Microcrystalline. TEXTURE: Spherulitic (Variolitic) to Microlitic. No glass. WHERE SAMPLED: Unit 2 <1.2 mm Euhedral, prism Slight quench overgrowths. Clinopyroxene Titanomagnetite Sulfide globules 10% 5 c /< 3% 2% 10% 5'2. 3% 2% <0.4 mm <O.l mm <0.06 mm <0.005 mm Acicular, skelet Anhedral, plumose Largely individual microlites. Some sheaf and bow-tie bundles. Intergrown with plagioclase. Individual crystals. Pale yellow. Uniaxial. Pyrite (?). SEE : Crystal clot of intergrown clinopyroxene and plagioclase. Large (up to 6 mm in length), euhedral, poikilitic clinopyroxene crystal intergrown with plagioclase. Individual plagioclase crystals are euhedral, prismatic (up to 3 mm in length), and sometimes skeletal. Rock is fresh. 142-864A-4Z-01 (Piece 3, 9-15 cm) OBSERVER: BRO GRAIN : Medium-grained. TEXTURE: Microlitic to intersertal to intergranular. No glass. WHERE SAMPLED: Unit 2 l%-2% l%-2% 0.4-3.0 mm Euhedral, elongated to prismatic. Slight compositional zonation. Significant quench overgrowths. Clinopyroxene 2%-5% l%-2% 2%-5% 0.02-1.5 mm Anhedral, skeletal, and plumose. Radial, sheaf, and bow-tie bundles. Intergrown with granular pyroxene and acicular olivine. Two varieties present. (1) equant, granular, anhedral, skeletal crystals intergrown with plagioclase and olivine, and; (2) microcrystalline, plumose variety. 4% Titanomagnetite 2%-3% <0.5 mm <O.l mm Acicular, skeletal. 0.1-0.4 mm : Large (several mm diameter) crystal clot of intergrown plagioclase and clinopyroxene. Individual clinopyroxene crystals are prismatic, up to 2 mm in length, and poikilitic with large plagioclase inclusions. Individual plagioclase crystals are euhedral to subhedral, up to 2.5 mm in length. One large crystal is skeletal with a hollow interior. There is no preferred orientation of crystals. Small (<2 microns) sulfide blebs. Rock is very fresh. Description is based on two thin sections cut from the same sample. 97

142-864A-5Z-01 (Piece 1, 0-5 cm) OBSERVER: BRO GRAIN : Microcrystalline. TEXTURE: Spherulitic (variolitic) with patches of intergranular texture. No glass. WHERE SAMPLED: Unit 2 <1.5 mm <0.25 mm Euhedral. Euhedral. Slight compositional zonation. Slight quench overgrowths. Single crystal with well-developed bi-pyramidal external form. 3% Clinopyroxene Titanomagnetite 5% v/< <0.6 mm <0.5 mm < 0.02 mm Acicular, skeletal. Anhedral, equant. Anhedral. Mostly individual microlites. Occasional radial or bow-tie bundles. Mostly individual crystals. Some skeletal. intergrown with plagioclase in radial clusters. Always present as intergrowths with plagioclase microlites in radial bundles. 3% <0.3-3.0 mm Round to slightly irregular. : Small (<2 microns) sulfide blebs. Rock is fresh. 142-864A-5Z-01 (Piece 5, 15-19 cm) GRAIN : Medium-grained. TEXTURE: Intergranular. No glass. OBSERVER: BRO WHERE SAMPLED: Unit 2 mm Euhedral to subhedral. Strong compositional zonation. Slight quench overgrowths. Some glomerocrysts. Some resorbed-looking edges? 40% 40% Clinopyroxene 40% 40% Titanomagnetite l%-3% l%-3% Mesostasis 10% 10% mm <0.15 mm Acicular, skeletal. Anhedral, equant. Anhedral. Euhedral to anhedral, skeletal. Radial, sheaf, and bow-tie bundles. Intergrown with, and surrounding plagioclase and olivine crystals. Some plumose clinopyroxene. Approaching a sub-ophitic texture. Interstitial to silicate minerals. SECONDARY REPLACING/ CAVHTES 5% 0.03-0.3 mm Round to irregular. One large (1 mm diameter) vesicle. : Sub-ophitic groundmass texture. Patchy zones with no plagioclase microlites, often surrounding vesicles. Small (<2 microns) sülfide blebs interstitial to silicate minerals. Rock is fresh. 98

142-864A-5Z-01 (Piece 7, 24-29 cm) GRAIN : Microcrystalline TEXTURE: Spherulitic OBSERVER: BCH WHERE SAMPLED: Unit 2 mm Euhedral, elongated to tabular. <0.15 mm <O.l mm Clinopyroxene Mesostasis 15-20 15-20 Magnetite <0.005 Acicular, skeletal. Elongated, skeletal. Skeletal There are patchy agglomerations of elongated plagioclase and olivine crystals. Very few grains show twinning. Dark brown to black, cryptocrystalline. Veins Fractures 4%-5% 0.02-0.8 mm <O.Ol mm <O.l mm FELLING None, Irregular to round. Fe-hydroxyoxides. Large irregular vesicles occur in the mesostasis. One small veinlet filled with reddish-yellow Fe-hydroxyoxides. : Individual spherules are outlined with a dark mesostasis, consist of very fine-grained coalesced spherules. The rock is fresh. The only evidence for a slight alteration is the subordinate occurrence of Fe-hydroxyoxides in small veinlets and in some vesicles. 142-864B-2W-01 (Piece 3) GRAIN : Fine-grained. TEXTURE: Intergranular. OBSERVER: BRO WHERE SAMPLED: Unit 1 <1.5 mm Subhedral. Most crystals show evidence for resorption. Clinopyroxene Titanomagnetite Sulfide Globules 40% l%-2% 40% 4% 40% l%-2% 40% 4% <1.2 mm <O.l mm <0.4 mm <O.Ol mm 1-2 microns Anhedral, equant Anhedral, granular" Spherical. Radial bundles common. Intergrown with plagioclase in radial bundles. Approaches a subophitic texture. Concentrated in mesostasis. <0.4 mm Round to irregular. : Mesostasis constitutes 13% 15% of the groundmass. The rock is fresh. 99