October 26, Dear Mr. White: - PDF Free Download

ExxonMobil Environmental Services Company 38 Varick Street Brooklyn, New York 11222 October 26, 2011 New York State Department of Environmental Conservation Division of Environmental Remediation Remedial Bureau D 625 Broadway 12th Floor Albany, New York 12233-7013 Attention: Mr. A. Joseph White Re: Discharge Monitoring Report September 2011 SPDES Permit No. NY-0267724 ExxonMobil Greenpoint Petroleum Remediation Project Greenpoint, Brooklyn, New York Dear Mr. White: ExxonMobil Oil Corporation is submitting this Discharge Monitoring Report (DMR) for the On-Site Free-Product Recovery System (RCS) and the Off-Site Free-Product Recovery System (ORS) for the month of September 2011. The RCS was sampled on September 12, 2011 for the monthly DMR (Outfalls 001 and 01A), with the RCS operating at a flow rate of approximately 391 gallons per minute (gpm). The average operational flow rate for the period of September 1, 2011 through September 30, 2011 was approximately 405 gpm. The total amount of flow treated and discharged by the RCS during this reporting period was approximately 16,809,648 gallons, of which, approximately 2,606,159 gallons were conveyed from the BP remedial system and approximately 10,737,994 gallons were conveyed from the OU-7 recovery wells (formerly known as the Off-Site wells). The RCS sample results indicate no exceedances of either the discharge quality or flow limits for the parameters specified in the monthly DMR (Outfalls 001 and 01A). A summary of the RCS DMR analytical results is provided in Tables 1 and 2. A summary of the analytical results for additional parameters detected is provided in Table 3. The RCS laboratory analytical data are provided in Attachment 1. RCS photographs of the discharge point and receiving water taken in September 2011 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by RCS operations personnel on a periodic basis, the RCS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfalls 001 and 01A are provided in Attachment 3. The ORS was sampled on September 8, 2011 for the monthly DMR (Outfall 002), with the ORS operating at a flow rate of approximately 389 gpm. The average operational flow rate for the period of September 1, 2011 through September 30, 2011 was approximately 397 gpm. The total MC0172.0030Y027.1817/ML

Mr. A. Joseph White October 26, 2011 Page 2 amount of flow treated and discharged by the ORS during this reporting period was approximately 16,145,130 gallons. The ORS sample results indicate no exceedances of either the discharge quality or flow limits for the parameters specified in the monthly DMR (Outfalls 002). A summary of the ORS DMR analytical results is provided in Table 4. A summary of the analytical results of additional parameters detected is provided in Table 5. The laboratory analytical data are provided in Attachment 1. Photographs of the discharge point and receiving water taken in September 2011 are enclosed in Attachment 2. Based on visual inspections of the discharge location performed by ORS operations personnel at the time of the sample collection, the ORS discharge is in compliance with the narrative water quality standard for turbidity (NYCRR Title 6, Chapter X, Part 703.2). The DMR forms for Outfall 002 are provided in Attachment 3. Should there be any questions or comments on this submission, please do not hesitate to contact me at 718.404.0652. Sincerely, Attachments Steve P. Trifiletti Project Manager cc: Regional Water Engineer (NYSDEC Region 2) Long Island City, NY NYSDEC (Division of Water, Bureau of Water Compliance Programs) Albany, NY [Attachment 3 Only] Justin Kennedy, Roux Associates, Inc. MC0172.0030Y027.1817/ML

Table 1. September 2011 Outfall 01A Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 01A Discharge Limitations Results Discharge Loading (lbs / Day) Estimated Parameter Daily Max Units Type RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent Percent Removal Flow 0.932 MGD DL -- -- 0.56 NA -- ph 7 6.5-8.5 S.U. DL 7.84 7.32 7.23 NA -- Oil & Grease 15 mg/l DL 7.5 <5.2 <5.1 <23.96386 -- Total Suspended Solids 40 mg/l DL 17.0 28.0 4.0 18.79519 76.5% Settleable Solids 0.1 ml/l DL <0.10 <0.10 <0.10 <0.46988 -- 1,1-Dichloroethane 10 µg/l DL 1.6 0.30 <1.0 <0.00470 >37.5% 1,2-Dichloroethane 10 µg/l DL <1.0 <1.0 <1.0 <0.00470 -- Benzene 10 µg/l DL 215 68.1 4.0 0.01880 98.1% Copper 95 µg/l DL <10 <10 <10 <0.04699 -- Ethylbenzene 5 µg/l DL 8.5 5.2 0.56 <0.00263 >93.4% Mercury Monitor µg/l -- <0.20 <0.20 <0.20 <0.00094 -- Methyl-tert-butyl ether 50 µg/l AL-I 20.0 27.2 7.2 0.03383 64.0% Naphthalene 20 µg/l AL-I 4.8 3.0 3.4 <0.01598 >29.2% Phenols Monitor µg/l -- <200 <200 <200 <0.93976 -- Tetrachloroethylene 10 µg/l DL 70.5 0.31 3.5 0.01645 95.0% Toluene 5 µg/l DL 15.9 3.1 0.36 0.00169 97.7% Trichloroethylene 10 µg/l DL 91.7 2.2 1.40 0.00658 98.5% Vinyl chloride 10 µg/l DL 5.4 0.74 <1.0 <0.00470 >81.5% Xylenes (Total) 10 µg/l DL 40.0 14.0 2.40 0.01128 94.0% Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. The ph was measured in the field at the time of sampling 8. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BPAmoco's treatment system 9. "RCS - BP Influent" includes the untreated process water from the BPAmoco treatment system 10. "RCS - Effluent" includes the process water that has been treated and discharged by the air strippers 11. DL - Discharge Limit 12. AL-1 - Action Limit Type I 13. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 14. The maximum daily flow is reported as the flow at the time of sampling. 15. Outfall 01A was sampled on September 12, 2011. SPDES Number: NY-0267724 Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 MTBE EPA Method 8260 SVOCs (Naphthalene): EPA Method 625 Oil & Grease EPA Method 1664A Metals (Copper, Iron, etc.): EPA Method 200.7 Mercury EPA Method 245.1 *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y027.1817/WKB

Table 2. September 2011 Outfall 001 Discharge Monitoring Results Summary, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 001 Discharge Limitations Parameter Daily Max Units Type Results RCS-Inground OWS Effluent Discharge Loading (lbs / Day) RCS-Inground OWS Effluent Flow Monitor MGD -- 0.49 NA ph 7 6.5-8.5 S.U. DL 7.25 NA Oil & Grease 15 mg/l DL <5.3 <21.71902 Total Suspended Solids 40 mg/l DL <4.0 <16.39171 System Turbidity 7 (Influent / Discharge Pipe) Turbidity 7 (Receiving Water Background) Monitor NTU -- 1.2 NA Monitor NTU -- 4.0 NA Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. ph and Turbidity were measured in the field. 8. "RCS-Inground OWS Effluent" includes the treated effluent to be discharged at Outfall 001. 9. DL - Discharge Limit 10. AL-1 - Action Limit Type I 11. The maximum daily flow is reported as the flow at the time of sampling. 12. Outfall 001 was sampled on September 12, 2011. SPDES Number: NY-0267724 Laboratory Analytical Method Summary Constituent Method Oil & Grease EPA Method 1664A * Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y027.1817/WKB

Table 3. September 2011 Outfall 01A Summary of Additional Detections, Former ExxonMobil Brooklyn Terminal ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 01A Results Discharge Loading (lbs / Day) Estimated Parameter Units RCS - Influent RCS - BP Influent RCS - Effluent RCS - AS Effluent Percent Removal Flow MGD -- -- 0.56 NA -- 1,2-Dichloroethene µg/l 44.6 4.52 1.0 0.00470 97.8% Acenaphthene µg/l 6.2 0.86 7.3 0.03430 -- Anthracene µg/l 1.1 <1.1 1.9 0.00893 -- Benzo(a)anthracene µg/l 0.84 <1.1 1.5 0.00705 -- Benzo(a)pyrene µg/l <1.0 <1.1 0.98 0.00460 -- Benzo(g.h.i)perylene µg/l <1.0 <1.1 0.63 0.00296 -- Chrysene µg/l 0.81 <1.1 1.5 0.00705 -- Fluoranthene µg/l 0.53 <1.1 0.68 0.00320 -- Fluorene µg/l 9.3 0.96 15.0 0.07048 -- Phenanthrene µg/l 16.9 1.3 29.6 0.13908 -- Pyrene µg/l 1.2 <1.1 2.1 0.00987 -- Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Sample not analyzed for this parameter; analysis not required by permit 7. "RCS - Influent" includes the untreated process water from the ExxonMobil recovery wells and BPAmoco's treatment system 8. "RCS - BP Influent" includes the untreated process water from the BPAmoco treatment system 9. "RCS Effluent" includes the process water that has been treated and discharged by the air strippers 10. "RCS-BP Influent" was not measured due to inaccessibility at the time of sampling. 11. DL - Discharge Limit 12. AL-1 - Action Limit Type I 13. "RCS - Effluent" concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 14. The maximum daily flow is reported as the flow at the time of sampling. 15. Outfall 01A was sampled on September 12, 2011. SPDES Number: NY-0267724 Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, ect.): EPA Method 624 SVOCs: EPA Method 625 *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y027.1817/WKB

Table 4. September 2011 Outfall 002 Discharge Monitoring Results Summary, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 002 Discharge Limitations Results Discharge Loading (lbs / Day) Estimated Parameter Daily Max Units Type OSS - Influent OSS - Effluent Effluent Percent Removal Flow 0.62 MGD DL -- 0.56 NA -- ph 6.5-8.5 S.U. DL 7.12 7.53 NA -- Oil & Grease 15 mg/l DL <5.1 <5.1 <23.84128 -- Total Suspended Solids 40 mg/l DL 21.0 11.0 51.42238 47.6% System Turbidity (Influent / Discharge Pipe) Monitor NTU -- 9.4 24.2 NA -- Turbidity (Receiving Water) Monitor NTU -- -- 2.14 NA -- Settleable Solids 0.1 ml/l DL <0.10 <0.10 <0.46748 -- 1,1-Dichloroethane 10 µg/l DL 10.4 <1.0 <0.00467 >90.4% 1,2-Dichloroethane 10 µg/l DL <5.0 <1.0 <0.00467 -- Benzene 40 µg/l DL 771 <1.0 <0.00467 >99.9% Copper 95 µg/l DL <10 <10 <0.04675 -- Ethylbenzene 5 µg/l DL 51.4 <1.0 <0.00467 >98.1% Mercury Monitor µg/l -- <0.20 <0.20 <0.00093 -- Methyl-tert-butyl ether 90 µg/l AL-I 59.9 11.1 0.05189 81.5% Naphthalene 40 µg/l AL-I 20.2 <1.0 <0.00467 >95.0% Phenols Monitor µg/l -- <200 <200 <0.93495 -- Tetrachloroethylene 10 µg/l DL 351 0.46 0.00215 99.9% Toluene 10 µg/l DL 55.1 <1.0 <0.00467 >98.2% Trichloroethylene 20 µg/l DL 245 0.48 0.00224 99.8% Vinyl chloride 10 µg/l DL 39.9 <1.0 <0.00467 >97.5% Xylenes 20 µg/l DL 209 0.26 0.00122 99.9% Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. ph and Turbidity were measured in the field at the time of sampling. 8. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall 002. 9. "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System. 10. DL-Discharge Limit 11. AL-1 - Action Limit Type I 12. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 13. The maximum daily flow is reported as the flow at the time of sampling. 14. Outfall 002 was sampled on September 8, 2011. SPDES Number: NY-0267724 Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 MTBE EPA Method 8260 SVOCs (Naphthalene): EPA Method 625 Oil & Grease EPA Method 1664A Metals (Copper, Iron, etc.): EPA Method 200.7 Mercury EPA Method 245.1 *Copies of all laboratory chain of custody reports are maintained in files at the Roux Associates, Inc. office, located at 209 Shafter Street, Islandia, New York ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y027.1817/WKB

Table 5. September 2011 Outfall 002 Summary of Additional Detections, Off-Site Free-Product Recovery System ExxonMobil Greenpoint Petroleum Remediation Project, Greenpoint, Brooklyn, New York Outfall 002 Results Discharge Loading (lbs / Day) Estimated Parameter Units OSS - Influent OSS - Effluent Effluent Percent Removal Flow MGD -- 0.56 NA -- 1,2-Dichloroethene µg/l 658.8 3.40 0.01589 99.5% Notes: 1. mg/l - milligrams per Liter, µg/l - micrograms per Liter, ml/l - milliliters per Liter, MGD - million gallons per Day 2. NTU - Nephelometric Turbidity Unit 3. NA - Not Applicable 4. NM - Not Measured 5. S.U. - Standard Unit 6. NS - Not Sampled 7. "OSS - Effluent" includes the treated Off-Site System effluent to be discharged at Outfall 002. 8. "OSS - Influent" includes the untreated process water from the recovery wells to be treated by the Off-Site System. 9. AL-1 - Action Limit Type I 10. Effluent concentrations (highlighted column) are those that are used for comparison with the effluent discharge limits and action limits. 11. The maximum daily flow is reported as the flow at the time of sampling. 12. Outfall 002 was sampled on September 8, 2011. SPDES Number: NY-0267724 Laboratory Analytical Method Summary Constituent Method VOCs (BTEX, TCE, etc.): EPA Method 624 SVOCs: EPA Method 625 ROUX ASSOCIATES, INC. 1 of 1 MC0172.0030Y027.1817/WKB

ATTACHMENT 1 Laboratory Analytical Data ROUX ASSOCIATES, INC. MC0172.0030Y027.1817/AT-CV

e-hardcopy 2.0 Automated Report New Jersey 09/27/11 09/27/11 Technical Report for Roux Associates ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY PO#4513473199 WBS#08 Accutest Job Number: JA85914 Sampling Date: 09/12/11 Report to: Roux Associates rpatel@rouxinc.com ATTN: Ritu Patel Total number of pages in report: 35 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova 732-329-0200 Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ 08810 tel: 732-329-0200 fax: 732-329-3499 http://www.accutest.com Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA85914 1 of 35

Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results... 4 2.1: JA85914-1: RCS-INFLUENT... 5 2.2: JA85914-1A: RCS-INFLUENT... 11 2.3: JA85914-2: RCS-BP INFLUENT... 12 2.4: JA85914-2A: RCS-BP INFLUENT... 18 2.5: JA85914-3: RCS-INGROUND OWS EFFLUENT... 19 2.6: JA85914-4: QAQC_TB... 20 2.7: JA85914-5: RCS-EFFLUENT... 22 2.8: JA85914-6: QAQC TRIP BLANK... 29 Section 3: Misc. Forms... 31 3.1: Chain of Custody... 32-1- Sections: 1 2 3 2 of 35 JA85914

1 Accutest LabLink@635844 13:57 27-Sep-2011 Sample Summary Roux Associates Job No: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Project No: PO#4513473199 WBS#08 JA85914 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA85914-1 09/12/11 10:15 MS 09/12/11 AQ Influent RCS-INFLUENT JA85914-1A 09/12/11 10:15 MS 09/12/11 AQ Influent RCS-INFLUENT JA85914-2 09/12/11 11:15 MS 09/12/11 AQ Influent RCS-BP INFLUENT JA85914-2A 09/12/11 11:15 MS 09/12/11 AQ Influent RCS-BP INFLUENT JA85914-3 09/12/11 10:50 MS 09/12/11 AQ Effluent RCS-INGROUND OWS EFFLUENT JA85914-4 09/12/11 11:15 MS 09/12/11 AQ Trip Blank Water QAQC_TB JA85914-5 09/12/11 10:00 MS 09/13/11 AQ Ground Water RCS-EFFLUENT JA85914-6 09/12/11 10:00 MS 09/13/11 AQ Trip Blank Water QAQC TRIP BLANK 3 of 35 JA85914

2 Section 2 New Jersey Accutest LabLink@635844 13:57 27-Sep-2011 Sample Results Report of Analysis 4 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69198.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 2E69213.D 5 09/16/11 MAH n/a n/a V2E3103 Run #1 Run #2 Purge Volume 5.0 ml 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene 215 a 5.0 1.4 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene 0.35 1.0 0.19 ug/l J 75-00-3 Chloroethane 0.75 1.0 0.40 ug/l J 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane 1.6 1.0 0.14 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene 2.3 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene 42.1 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene 2.5 1.0 0.27 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene 8.5 1.0 0.18 ug/l 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene 70.5 1.0 0.19 ug/l 108-88-3 Toluene 15.9 1.0 0.12 ug/l 71-55-6 1,1,1-Trichloroethane 0.32 1.0 0.16 ug/l J 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 5 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89972.D 1 09/21/11 LP 09/13/11 OP51844 ER3461 Run #2 Initial Volume Final Volume Run #1 955 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.2 1.0 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.2 1.2 ug/l 120-83-2 2,4-Dichlorophenol ND 5.2 1.6 ug/l 105-67-9 2,4-Dimethylphenol ND 5.2 1.7 ug/l 51-28-5 2,4-Dinitrophenol ND 21 0.93 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 10 0.75 ug/l 88-75-5 2-Nitrophenol ND 2.1 1.9 ug/l 100-02-7 4-Nitrophenol ND 21 0.88 ug/l 87-86-5 Pentachlorophenol ND 10 2.0 ug/l 108-95-2 Phenol ND 2.1 0.52 ug/l 88-06-2 2,4,6-Trichlorophenol ND 2.1 1.3 ug/l 83-32-9 Acenaphthene 6.2 1.0 0.37 ug/l 208-96-8 Acenaphthylene ND 1.0 0.40 ug/l 120-12-7 Anthracene 1.1 1.0 0.42 ug/l 92-87-5 Benzidine ND 21 0.29 ug/l 56-55-3 Benzo(a)anthracene 0.84 1.0 0.37 ug/l J 50-32-8 Benzo(a)pyrene ND 1.0 0.38 ug/l 205-99-2 Benzo(b)fluoranthene ND 1.0 0.62 ug/l 191-24-2 Benzo(g,h,i)perylene ND 1.0 0.44 ug/l 207-08-9 Benzo(k)fluoranthene ND 1.0 0.44 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.1 0.31 ug/l 85-68-7 Butyl benzyl phthalate ND 2.1 0.62 ug/l 91-58-7 2-Chloronaphthalene ND 2.1 1.0 ug/l 106-47-8 4-Chloroaniline ND 2.1 0.42 ug/l 218-01-9 Chrysene 0.81 1.0 0.26 ug/l J 111-91-1 bis(2-chloroethoxy)methane ND 2.1 0.68 ug/l 111-44-4 bis(2-chloroethyl)ether ND 2.1 0.55 ug/l 108-60-1 bis(2-chloroisopropyl)ether ND 2.1 0.77 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.1 0.45 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.1 0.22 ug/l 122-66-7 1,2-Diphenylhydrazine ND 2.1 0.47 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.1 0.17 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 2 of 2 2.1 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q 106-46-7 1,4-Dichlorobenzene ND 2.1 0.19 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.1 0.90 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.1 0.59 ug/l 91-94-1 3,3'-Dichlorobenzidine ND 2.1 1.3 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 1.0 0.57 ug/l 84-74-2 Di-n-butyl phthalate ND 2.1 0.62 ug/l 117-84-0 Di-n-octyl phthalate ND 2.1 0.60 ug/l 84-66-2 Diethyl phthalate ND 2.1 0.41 ug/l 131-11-3 Dimethyl phthalate ND 2.1 0.34 ug/l 117-81-7 bis(2-ethylhexyl)phthalate ND 2.1 0.69 ug/l 206-44-0 Fluoranthene 0.53 1.0 0.26 ug/l J 86-73-7 Fluorene 9.3 1.0 0.47 ug/l 118-74-1 Hexachlorobenzene ND 1.0 0.56 ug/l 87-68-3 Hexachlorobutadiene ND 1.0 0.18 ug/l 77-47-4 Hexachlorocyclopentadiene ND 10 0.43 ug/l 67-72-1 Hexachloroethane ND 5.2 0.30 ug/l 193-39-5 Indeno(1,2,3-cd)pyrene ND 1.0 0.32 ug/l 78-59-1 Isophorone ND 2.1 0.62 ug/l 91-20-3 Naphthalene 4.8 1.0 0.34 ug/l 98-95-3 Nitrobenzene ND 2.1 0.44 ug/l 62-75-9 n-nitrosodimethylamine ND 2.1 0.48 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.1 0.49 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.2 0.54 ug/l 85-01-8 Phenanthrene 16.9 1.0 0.38 ug/l 129-00-0 Pyrene 1.2 1.0 0.35 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.36 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 33% 10-111% 4165-62-2 Phenol-d5 22% 10-117% 118-79-6 2,4,6-Tribromophenol 92% 25-151% 4165-60-0 Nitrobenzene-d5 93% 40-131% 321-60-8 2-Fluorobiphenyl 90% 48-117% 1718-51-0 Terphenyl-d14 92% 20-141% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.1 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium 228000 5000 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Iron 8020 100 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Manganese 3620 15 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Mercury <0.20 0.20 ug/l 1 09/21/11 09/21/11 JW EPA 245.1 1 EPA 245.1 4 (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 9 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.1 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1080 20 mg/l 10 09/22/11 05:18 AE EPA 300/SW846 9056A HEM Oil and Grease 7.5 5.2 mg/l 1 09/23/11 MP EPA 1664A Phenols <0.20 0.20 mg/l 1 09/20/11 10:37 MG EPA 420.4/LACHAT Solids, Settleable <0.10 0.10 ml/l 1 09/12/11 21:30 ML SM20 2540F Solids, Total Suspended 17.0 4.0 mg/l 1 09/15/11 JF SM20 2540D Turbidity 76.5 1.5 NTU 5 09/12/11 23:23 LS EPA 180.1 ph a 6.72 su 1 09/12/11 17:05 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85914 10 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.2 2 Client Sample ID: RCS-INFLUENT Lab Sample ID: JA85914-1A Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: SW846 8260B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U149681.D 1 09/22/11 SS n/a n/a VU6075 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q 64-17-5 Ethanol ND 100 51 ug/l 1634-04-4 Methyl Tert Butyl Ether 20.0 1.0 0.18 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 94% 77-120% 17060-07-0 1,2-Dichloroethane-D4 105% 70-127% 2037-26-5 Toluene-D8 95% 79-120% 460-00-4 4-Bromofluorobenzene 87% 76-118% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 11 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.3 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69199.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene 68.1 1.0 0.28 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene ND 1.0 0.19 ug/l 75-00-3 Chloroethane ND 1.0 0.40 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane 0.30 1.0 0.14 ug/l J 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene 4.0 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene 0.52 1.0 0.27 ug/l J 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene 5.2 1.0 0.18 ug/l 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene 0.31 1.0 0.19 ug/l J 108-88-3 Toluene 3.1 1.0 0.12 ug/l 71-55-6 1,1,1-Trichloroethane ND 1.0 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 12 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.3 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R90010.D 1 09/22/11 LP 09/13/11 OP51844 ER3463 Run #2 Initial Volume Final Volume Run #1 930 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.4 1.0 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.4 1.3 ug/l 120-83-2 2,4-Dichlorophenol ND 5.4 1.7 ug/l 105-67-9 2,4-Dimethylphenol 3.7 5.4 1.8 ug/l J 51-28-5 2,4-Dinitrophenol ND 22 0.96 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 11 0.78 ug/l 88-75-5 2-Nitrophenol ND 2.2 1.9 ug/l 100-02-7 4-Nitrophenol ND 22 0.91 ug/l 87-86-5 Pentachlorophenol ND 11 2.0 ug/l 108-95-2 Phenol 2.0 2.2 0.53 ug/l J 88-06-2 2,4,6-Trichlorophenol ND 2.2 1.4 ug/l 83-32-9 Acenaphthene 0.86 1.1 0.38 ug/l J 208-96-8 Acenaphthylene ND 1.1 0.41 ug/l 120-12-7 Anthracene ND 1.1 0.43 ug/l 92-87-5 Benzidine ND 22 0.30 ug/l 56-55-3 Benzo(a)anthracene ND 1.1 0.38 ug/l 50-32-8 Benzo(a)pyrene ND 1.1 0.39 ug/l 205-99-2 Benzo(b)fluoranthene ND 1.1 0.64 ug/l 191-24-2 Benzo(g,h,i)perylene ND 1.1 0.45 ug/l 207-08-9 Benzo(k)fluoranthene ND 1.1 0.45 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.2 0.32 ug/l 85-68-7 Butyl benzyl phthalate ND 2.2 0.64 ug/l 91-58-7 2-Chloronaphthalene ND 2.2 1.1 ug/l 106-47-8 4-Chloroaniline ND 2.2 0.43 ug/l 218-01-9 Chrysene ND 1.1 0.27 ug/l 111-91-1 bis(2-chloroethoxy)methane ND 2.2 0.70 ug/l 111-44-4 bis(2-chloroethyl)ether ND 2.2 0.57 ug/l 108-60-1 bis(2-chloroisopropyl)ether ND 2.2 0.79 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.2 0.46 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.2 0.22 ug/l 122-66-7 1,2-Diphenylhydrazine ND 2.2 0.49 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.2 0.17 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 14 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 2 of 2 2.3 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q 106-46-7 1,4-Dichlorobenzene ND 2.2 0.19 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.2 0.92 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.2 0.60 ug/l 91-94-1 3,3'-Dichlorobenzidine ND 2.2 1.3 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 1.1 0.58 ug/l 84-74-2 Di-n-butyl phthalate ND 2.2 0.64 ug/l 117-84-0 Di-n-octyl phthalate ND 2.2 0.61 ug/l 84-66-2 Diethyl phthalate ND 2.2 0.42 ug/l 131-11-3 Dimethyl phthalate ND 2.2 0.35 ug/l 117-81-7 bis(2-ethylhexyl)phthalate ND 2.2 0.71 ug/l 206-44-0 Fluoranthene ND 1.1 0.27 ug/l 86-73-7 Fluorene 0.96 1.1 0.48 ug/l J 118-74-1 Hexachlorobenzene ND 1.1 0.58 ug/l 87-68-3 Hexachlorobutadiene ND 1.1 0.19 ug/l 77-47-4 Hexachlorocyclopentadiene ND 11 0.44 ug/l 67-72-1 Hexachloroethane ND 5.4 0.30 ug/l 193-39-5 Indeno(1,2,3-cd)pyrene ND 1.1 0.33 ug/l 78-59-1 Isophorone ND 2.2 0.63 ug/l 91-20-3 Naphthalene 3.0 1.1 0.35 ug/l 98-95-3 Nitrobenzene ND 2.2 0.45 ug/l 62-75-9 n-nitrosodimethylamine ND 2.2 0.49 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.2 0.50 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.4 0.55 ug/l 85-01-8 Phenanthrene 1.3 1.1 0.39 ug/l 129-00-0 Pyrene ND 1.1 0.36 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 1.1 0.37 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 34% 10-111% 4165-62-2 Phenol-d5 25% 10-117% 118-79-6 2,4,6-Tribromophenol 88% 25-151% 4165-60-0 Nitrobenzene-d5 105% 40-131% 321-60-8 2-Fluorobiphenyl 96% 48-117% 1718-51-0 Terphenyl-d14 95% 20-141% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 15 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.3 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium 200000 5000 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Iron 15100 100 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Manganese 2200 15 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Mercury <0.20 0.20 ug/l 1 09/21/11 09/21/11 JW EPA 245.1 1 EPA 245.1 4 (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 16 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.3 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2 Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1180 20 mg/l 10 09/22/11 05:42 AE EPA 300/SW846 9056A HEM Oil and Grease <5.2 5.2 mg/l 1 09/21/11 JOO EPA 1664A Phenols <0.20 0.20 mg/l 1 09/20/11 10:38 MG EPA 420.4/LACHAT Solids, Settleable <0.10 0.10 ml/l 1 09/12/11 21:30 ML SM20 2540F Solids, Total Suspended 28.0 4.0 mg/l 1 09/15/11 JF SM20 2540D Turbidity 149 3.0 NTU 10 09/12/11 23:23 LS EPA 180.1 ph a 6.75 su 1 09/12/11 17:10 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85914 17 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.4 2 Client Sample ID: RCS-BP INFLUENT Lab Sample ID: JA85914-2A Date Sampled: 09/12/11 Matrix: AQ - Influent Date Received: 09/12/11 Method: SW846 8260B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U149491.D 1 09/17/11 SS n/a n/a VU6067 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q 64-17-5 Ethanol ND 100 51 ug/l 1634-04-4 Methyl Tert Butyl Ether 27.2 1.0 0.18 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 91% 77-120% 17060-07-0 1,2-Dichloroethane-D4 98% 70-127% 2037-26-5 Toluene-D8 93% 79-120% 460-00-4 4-Bromofluorobenzene 88% 76-118% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 18 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.5 2 Client Sample ID: RCS-INGROUND OWS EFFLUENT Lab Sample ID: JA85914-3 Date Sampled: 09/12/11 Matrix: AQ - Effluent Date Received: 09/12/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1000 20 mg/l 10 09/22/11 06:06 AE EPA 300/SW846 9056A HEM Oil and Grease <5.3 5.3 mg/l 1 09/23/11 MP EPA 1664A Solids, Total Suspended <4.0 4.0 mg/l 1 09/15/11 JF SM20 2540D Turbidity 7.8 0.30 NTU 1 09/12/11 23:23 LS EPA 180.1 ph a 7.65 su 1 09/12/11 17:14 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85914 19 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.6 2 Client Sample ID: QAQC_TB Lab Sample ID: JA85914-4 Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69202.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene ND 1.0 0.28 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene ND 1.0 0.19 ug/l 75-00-3 Chloroethane ND 1.0 0.40 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.14 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene ND 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene ND 1.0 0.27 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene ND 1.0 0.18 ug/l 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene ND 1.0 0.19 ug/l 108-88-3 Toluene ND 1.0 0.12 ug/l 71-55-6 1,1,1-Trichloroethane ND 1.0 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 20 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 2 of 2 2.6 2 Client Sample ID: QAQC_TB Lab Sample ID: JA85914-4 Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/12/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q 79-01-6 Trichloroethene ND 1.0 0.17 ug/l 75-69-4 Trichlorofluoromethane ND 2.0 0.60 ug/l 75-01-4 Vinyl chloride ND 1.0 0.18 ug/l 1330-20-7 Xylenes (total) ND 1.0 0.17 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 (SUR) 94% 68-134% 2037-26-5 Toluene-D8 (SUR) 98% 87-112% 460-00-4 4-Bromofluorobenzene (SUR) 100% 83-116% 1868-53-7 Dibromofluoromethane (S) 99% 85-117% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 21 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69214.D 1 09/16/11 MAH n/a n/a V2E3103 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene 4.0 1.0 0.28 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene ND 1.0 0.19 ug/l 75-00-3 Chloroethane ND 1.0 0.40 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.14 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene 1.0 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene ND 1.0 0.27 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene 0.56 1.0 0.18 ug/l J 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene 3.5 1.0 0.19 ug/l 108-88-3 Toluene 0.36 1.0 0.12 ug/l J 71-55-6 1,1,1-Trichloroethane ND 1.0 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 22 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: SW846 8260B Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 U149694.D 1 09/22/11 SS n/a n/a VU6075 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q 1634-04-4 Methyl Tert Butyl Ether 7.2 1.0 0.18 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 93% 77-120% 17060-07-0 1,2-Dichloroethane-D4 99% 70-127% 2037-26-5 Toluene-D8 89% 79-120% 460-00-4 4-Bromofluorobenzene 85% 76-118% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 24 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R90008.D 1 09/22/11 LP 09/13/11 OP51844 ER3463 Run #2 Initial Volume Final Volume Run #1 1000 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 0.95 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 1.2 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 1.6 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.6 ug/l 51-28-5 2,4-Dinitrophenol ND 20 0.89 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 10 0.72 ug/l 88-75-5 2-Nitrophenol ND 2.0 1.8 ug/l 100-02-7 4-Nitrophenol ND 20 0.84 ug/l 87-86-5 Pentachlorophenol ND 10 1.9 ug/l 108-95-2 Phenol ND 2.0 0.50 ug/l 88-06-2 2,4,6-Trichlorophenol ND 2.0 1.3 ug/l 83-32-9 Acenaphthene 7.3 1.0 0.35 ug/l 208-96-8 Acenaphthylene ND 1.0 0.38 ug/l 120-12-7 Anthracene 1.9 1.0 0.40 ug/l 92-87-5 Benzidine ND 20 0.28 ug/l 56-55-3 Benzo(a)anthracene 1.5 1.0 0.36 ug/l 50-32-8 Benzo(a)pyrene 0.98 1.0 0.37 ug/l J 205-99-2 Benzo(b)fluoranthene ND 1.0 0.59 ug/l 191-24-2 Benzo(g,h,i)perylene 0.63 1.0 0.42 ug/l J 207-08-9 Benzo(k)fluoranthene ND 1.0 0.42 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.30 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.59 ug/l 91-58-7 2-Chloronaphthalene ND 2.0 0.98 ug/l 106-47-8 4-Chloroaniline ND 2.0 0.40 ug/l 218-01-9 Chrysene 1.5 1.0 0.25 ug/l 111-91-1 bis(2-chloroethoxy)methane ND 2.0 0.65 ug/l 111-44-4 bis(2-chloroethyl)ether ND 2.0 0.53 ug/l 108-60-1 bis(2-chloroisopropyl)ether ND 2.0 0.74 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 0.43 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.0 0.21 ug/l 122-66-7 1,2-Diphenylhydrazine ND 2.0 0.45 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.0 0.16 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 25 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 2 of 2 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q 106-46-7 1,4-Dichlorobenzene ND 2.0 0.18 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.0 0.86 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.0 0.56 ug/l 91-94-1 3,3'-Dichlorobenzidine ND 2.0 1.2 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 1.0 0.54 ug/l 84-74-2 Di-n-butyl phthalate ND 2.0 0.59 ug/l 117-84-0 Di-n-octyl phthalate ND 2.0 0.57 ug/l 84-66-2 Diethyl phthalate ND 2.0 0.39 ug/l 131-11-3 Dimethyl phthalate ND 2.0 0.33 ug/l 117-81-7 bis(2-ethylhexyl)phthalate ND 2.0 0.66 ug/l 206-44-0 Fluoranthene 0.68 1.0 0.25 ug/l J 86-73-7 Fluorene 15.0 1.0 0.45 ug/l 118-74-1 Hexachlorobenzene ND 1.0 0.54 ug/l 87-68-3 Hexachlorobutadiene ND 1.0 0.18 ug/l 77-47-4 Hexachlorocyclopentadiene ND 10 0.41 ug/l 67-72-1 Hexachloroethane ND 5.0 0.28 ug/l 193-39-5 Indeno(1,2,3-cd)pyrene ND 1.0 0.30 ug/l 78-59-1 Isophorone ND 2.0 0.59 ug/l 91-20-3 Naphthalene 3.4 1.0 0.32 ug/l 98-95-3 Nitrobenzene ND 2.0 0.42 ug/l 62-75-9 n-nitrosodimethylamine ND 2.0 0.46 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.0 0.47 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.0 0.52 ug/l 85-01-8 Phenanthrene 29.6 1.0 0.36 ug/l 129-00-0 Pyrene 2.1 1.0 0.34 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.34 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 25% 10-111% 4165-62-2 Phenol-d5 22% 10-117% 118-79-6 2,4,6-Tribromophenol 52% 25-151% 4165-60-0 Nitrobenzene-d5 106% 40-131% 321-60-8 2-Fluorobiphenyl 94% 48-117% 1718-51-0 Terphenyl-d14 104% 20-141% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 26 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium 227000 5000 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Copper <10 10 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Iron 6930 100 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Manganese 3640 15 ug/l 1 09/21/11 09/22/11 BL EPA 200.7 2 EPA 200.7 3 Mercury <0.20 0.20 ug/l 1 09/21/11 09/21/11 JW EPA 245.1 1 EPA 245.1 4 (1) Instrument QC Batch: MA27130 (2) Instrument QC Batch: MA27135 (3) Prep QC Batch: MP60326 (4) Prep QC Batch: MP60330 RL = Reporting Limit 27 of 35 JA85914

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 1 2.7 2 Client Sample ID: RCS-EFFLUENT Lab Sample ID: JA85914-5 Date Sampled: 09/12/11 Matrix: AQ - Ground Water Date Received: 09/13/11 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1180 20 mg/l 10 09/22/11 04:54 AE EPA 300/SW846 9056A HEM Oil and Grease <5.1 5.1 mg/l 1 09/23/11 MP EPA 1664A Phenols <0.20 0.20 mg/l 1 09/20/11 10:39 MG EPA 420.4/LACHAT Solids, Settleable <0.10 0.10 ml/l 1 09/13/11 17:00 CW SM20 2540F Solids, Total Suspended 4.0 4.0 mg/l 1 09/15/11 JF SM20 2540D Turbidity 29.9 0.30 NTU 1 09/13/11 21:23 LS EPA 180.1 ph a 7.69 su 1 09/13/11 13:43 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85914 28 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 1 of 2 2.8 2 Client Sample ID: QAQC TRIP BLANK Lab Sample ID: JA85914-6 Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69203.D 1 09/16/11 MAH n/a n/a V2E3102 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene ND 1.0 0.28 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene ND 1.0 0.19 ug/l 75-00-3 Chloroethane ND 1.0 0.40 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.14 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene ND 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene ND 1.0 0.27 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene ND 1.0 0.18 ug/l 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene ND 1.0 0.19 ug/l 108-88-3 Toluene ND 1.0 0.12 ug/l 71-55-6 1,1,1-Trichloroethane ND 1.0 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85914 29 of 35

Accutest LabLink@635844 13:57 27-Sep-2011 Report of Analysis Page 2 of 2 2.8 2 Client Sample ID: QAQC TRIP BLANK Lab Sample ID: JA85914-6 Date Sampled: 09/12/11 Matrix: AQ - Trip Blank Water Date Received: 09/13/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY VOA PPL List CAS No. Compound Result RL MDL Units Q 79-01-6 Trichloroethene ND 1.0 0.17 ug/l 75-69-4 Trichlorofluoromethane ND 2.0 0.60 ug/l 75-01-4 Vinyl chloride ND 1.0 0.18 ug/l 1330-20-7 Xylenes (total) ND 1.0 0.17 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 (SUR) 94% 68-134% 2037-26-5 Toluene-D8 (SUR) 100% 87-112% 460-00-4 4-Bromofluorobenzene (SUR) 100% 83-116% 1868-53-7 Dibromofluoromethane (S) 99% 85-117% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 30 of 35 JA85914

3 Section 3 New Jersey Accutest LabLink@635844 13:57 27-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody 31 of 35 JA85914

3 3.1 JA85914: Chain of Custody Page 1 of 4 32 of 35 JA85914

3 3.1 JA85914: Chain of Custody Page 2 of 4 33 of 35 JA85914

Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85914 Date / Time Received: 9/12/2011 15:50 Client: ROUX Project: GREENPOINT, BK 3.1 No. Coolers: 1 Airbill #'s: 1634 9107 Delivery Method: PRIORITY 3 Cooler Security Y or N 1. Custody Seals Present: 2. Custody Seals Intact: 3. COC Present: 4. Smpl Dates/Time OK Cooler Temperature Y or N 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: IR Gun Ice (Bag) Quality Control Preservatio Y or N N/A 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: 3. Samples preserved properly: 4. VOCs headspace free: Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Y or N N/A Comments DID NOT RECEIVE "RCS-EFFLUENT" DID NOT RECEIVE "QAQC-TB" Accutest Laboratories V:732.329.0200 2235 US Highway 130 F: 732.329.3499 Dayton, NJ 08810 www/accutest.com JA85914: Chain of Custody Page 3 of 4 34 of 35 JA85914

Problem Resolution Page 2 of 2 Accutest Job Number: JA85914 CSR: Response Date 3.1 Response: 3 JA85914: Chain of Custody Page 4 of 4 JA85914 35 of 35

e-hardcopy 2.0 Automated Report New Jersey 09/23/11 09/23/11 Technical Report for Roux Associates ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY PO#4513473199 WBS#08 Accutest Job Number: JA85910 Sampling Date: 09/12/11 Report to: Roux Associates rpatel@rouxinc.com ATTN: Ritu Patel Total number of pages in report: 15 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova 732-329-0200 Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ 08810 tel: 732-329-0200 fax: 732-329-3499 http://www.accutest.com Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA85910 1 of 15

Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results... 4 2.1: JA85910-1: RCS-BEFORE CARBON... 5 2.2: JA85910-2: RCS-LEAD-1 CARBON EFFLUENT... 7 2.3: JA85910-3: RCS-LAG-1 CARBON EFFLUENT... 10 Section 3: Misc. Forms... 12 3.1: Chain of Custody... 13 3.2: Summa Canister and Flow Controller Log... 15-1- Sections: 1 2 3 2 of 15 JA85910

1 Accutest LabLink@635393 14:08 23-Sep-2011 Sample Summary Roux Associates Job No: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Project No: PO#4513473199 WBS#08 JA85910 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA85910-1 09/12/11 10:35 MS 09/12/11 AIR Air RCS-BEFORE CARBON JA85910-2 09/12/11 10:38 MS 09/12/11 AIR Air RCS-LEAD-1 CARBON EFFLUENT JA85910-3 09/12/11 10:40 MS 09/12/11 AIR Air RCS-LAG-1 CARBON EFFLUENT 3 of 15 JA85910

2 Section 2 New Jersey Accutest LabLink@635393 14:08 23-Sep-2011 Sample Results Report of Analysis 4 of 15 JA85910

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: RCS-BEFORE CARBON Lab Sample ID: JA85910-1 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A634,A599 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23961.D 25 09/13/11 YXC n/a n/a V3W948 Run #2 Run #1 Run #2 Initial Volume 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units 67-64-1 58.08 Acetone ND 10 1.8 ppbv ND 24 ug/m3 106-99-0 54.09 1,3-Butadiene ND 10 1.2 ppbv ND 22 ug/m3 71-43-2 78.11 Benzene 1520 10 2.3 ppbv 4860 32 ug/m3 75-27-4 163.8 Bromodichloromethane ND 10 1.5 ppbv ND 67 ug/m3 75-25-2 252.8 Bromoform ND 10 1.9 ppbv ND 100 ug/m3 74-83-9 94.94 Bromomethane ND 10 1.8 ppbv ND 39 ug/m3 593-60-2 106.9 Bromoethene ND 10 1.8 ppbv ND 44 ug/m3 100-44-7 126 Benzyl Chloride ND 10 2.0 ppbv ND 52 ug/m3 75-15-0 76.14 Carbon disulfide ND 10 1.6 ppbv ND 31 ug/m3 108-90-7 112.6 Chlorobenzene ND 10 1.3 ppbv ND 46 ug/m3 75-00-3 64.52 Chloroethane ND 10 2.0 ppbv ND 26 ug/m3 67-66-3 119.4 Chloroform ND 10 1.4 ppbv ND 49 ug/m3 74-87-3 50.49 Chloromethane ND 10 1.8 ppbv ND 21 ug/m3 107-05-1 76.53 3-Chloropropene ND 10 2.1 ppbv ND 31 ug/m3 95-49-8 126.6 2-Chlorotoluene ND 10 1.6 ppbv ND 52 ug/m3 56-23-5 153.8 Carbon tetrachloride ND 10 2.0 ppbv ND 63 ug/m3 110-82-7 84.16 Cyclohexane 431 10 1.7 ppbv 1480 34 ug/m3 75-34-3 98.96 1,1-Dichloroethane 11.2 10 1.4 ppbv 45.3 40 ug/m3 75-35-4 96.94 1,1-Dichloroethylene 10.3 10 2.3 ppbv 40.8 40 ug/m3 106-93-4 187.9 1,2-Dibromoethane ND 10 1.4 ppbv ND 77 ug/m3 107-06-2 98.96 1,2-Dichloroethane ND 10 2.2 ppbv ND 40 ug/m3 78-87-5 113 1,2-Dichloropropane ND 10 1.9 ppbv ND 46 ug/m3 123-91-1 88.12 1,4-Dioxane ND 10 2.8 ppbv ND 36 ug/m3 75-71-8 120.9 Dichlorodifluoromethane ND 10 1.9 ppbv ND 49 ug/m3 124-48-1 208.3 Dibromochloromethane ND 10 1.3 ppbv ND 85 ug/m3 156-60-5 96.94 trans-1,2-dichloroethylene 13.7 10 1.6 ppbv 54.3 40 ug/m3 156-59-2 96.94 cis-1,2-dichloroethylene 239 10 1.9 ppbv 948 40 ug/m3 10061-01-5 111 cis-1,3-dichloropropene ND 10 2.1 ppbv ND 45 ug/m3 541-73-1 147 m-dichlorobenzene ND 10 1.9 ppbv ND 60 ug/m3 95-50-1 147 o-dichlorobenzene ND 10 1.3 ppbv ND 60 ug/m3 106-46-7 147 p-dichlorobenzene ND 10 1.2 ppbv ND 60 ug/m3 10061-02-6 111 trans-1,3-dichloropropene ND 10 2.0 ppbv ND 45 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 5 of 15

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 2 of 2 2.1 2 Client Sample ID: RCS-BEFORE CARBON Lab Sample ID: JA85910-1 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A634,A599 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units 64-17-5 46.07 Ethanol 20.9 25 4.7 ppbv J 39.4 47 ug/m3 100-41-4 106.2 Ethylbenzene 36.8 10 1.5 ppbv 160 43 ug/m3 141-78-6 88 Ethyl Acetate ND 10 3.1 ppbv ND 36 ug/m3 622-96-8 120.2 4-Ethyltoluene 16.8 10 1.2 ppbv 82.6 49 ug/m3 76-13-1 187.4 Freon 113 ND 10 1.7 ppbv ND 77 ug/m3 76-14-2 170.9 Freon 114 ND 10 1.5 ppbv ND 70 ug/m3 142-82-5 100.2 Heptane 18.6 10 1.7 ppbv 76.2 41 ug/m3 87-68-3 260.8 Hexachlorobutadiene ND 10 2.3 ppbv ND 110 ug/m3 110-54-3 86.17 Hexane 64.7 10 2.2 ppbv 228 35 ug/m3 591-78-6 100 2-Hexanone ND 10 2.1 ppbv ND 41 ug/m3 67-63-0 60.1 Isopropyl Alcohol ND 10 2.9 ppbv ND 25 ug/m3 75-09-2 84.94 Methylene chloride ND 10 1.4 ppbv ND 35 ug/m3 78-93-3 72.11 Methyl ethyl ketone ND 10 2.4 ppbv ND 29 ug/m3 108-10-1 100.2 Methyl Isobutyl Ketone ND 10 1.8 ppbv ND 41 ug/m3 1634-04-4 88.15 Methyl Tert Butyl Ether 73.1 10 1.4 ppbv 264 36 ug/m3 80-62-6 100.12 Methylmethacrylate ND 10 2.1 ppbv ND 41 ug/m3 115-07-1 42 Propylene ND 25 3.5 ppbv ND 43 ug/m3 100-42-5 104.1 Styrene ND 10 1.4 ppbv ND 43 ug/m3 71-55-6 133.4 1,1,1-Trichloroethane ND 10 1.1 ppbv ND 55 ug/m3 79-34-5 167.9 1,1,2,2-Tetrachloroethane ND 10 1.5 ppbv ND 69 ug/m3 79-00-5 133.4 1,1,2-Trichloroethane ND 10 1.5 ppbv ND 55 ug/m3 120-82-1 181.5 1,2,4-Trichlorobenzene ND 10 2.6 ppbv ND 74 ug/m3 95-63-6 120.2 1,2,4-Trimethylbenzene 41.8 10 1.2 ppbv 205 49 ug/m3 108-67-8 120.2 1,3,5-Trimethylbenzene 30.5 10 1.4 ppbv 150 49 ug/m3 540-84-1 114.2 2,2,4-Trimethylpentane 101 10 1.4 ppbv 472 47 ug/m3 75-65-0 74.12 Tertiary Butyl Alcohol 9.9 10 1.6 ppbv J 30 30 ug/m3 127-18-4 165.8 Tetrachloroethylene 206 2.0 1.4 ppbv 1400 14 ug/m3 109-99-9 72.11 Tetrahydrofuran ND 10 2.3 ppbv ND 29 ug/m3 108-88-3 92.14 Toluene 82.6 10 2.0 ppbv 311 38 ug/m3 79-01-6 131.4 Trichloroethylene 339 2.0 1.6 ppbv 1820 11 ug/m3 75-69-4 137.4 Trichlorofluoromethane ND 10 2.1 ppbv ND 56 ug/m3 75-01-4 62.5 Vinyl chloride 44.2 10 1.6 ppbv 113 26 ug/m3 108-05-4 86 Vinyl Acetate ND 10 2.8 ppbv ND 35 ug/m3 106.2 m,p-xylene 136 10 1.6 ppbv 591 43 ug/m3 95-47-6 106.2 o-xylene 35.5 10 1.6 ppbv 154 43 ug/m3 1330-20-7 106.2 Xylenes (total) 172 10 1.6 ppbv 747 43 ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 93% 65-128% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 6 of 15

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 1 of 3 2.2 2 Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA85910-2 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23962.D 1 09/13/11 YXC n/a n/a V3W948 Run #2 3W23979.D 1 09/14/11 YXC n/a n/a V3W949 Run #1 Run #2 Initial Volume 400 ml 100 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units 67-64-1 58.08 Acetone ND 0.20 0.036 ppbv ND 0.48 ug/m3 106-99-0 54.09 1,3-Butadiene ND 0.20 0.024 ppbv ND 0.44 ug/m3 71-43-2 78.11 Benzene 41.5 a 0.80 0.18 ppbv 133 a 2.6 ug/m3 75-27-4 163.8 Bromodichloromethane ND 0.20 0.030 ppbv ND 1.3 ug/m3 75-25-2 252.8 Bromoform ND 0.20 0.037 ppbv ND 2.1 ug/m3 74-83-9 94.94 Bromomethane ND 0.20 0.037 ppbv ND 0.78 ug/m3 593-60-2 106.9 Bromoethene ND 0.20 0.037 ppbv ND 0.87 ug/m3 100-44-7 126 Benzyl Chloride ND 0.20 0.041 ppbv ND 1.0 ug/m3 75-15-0 76.14 Carbon disulfide ND 0.20 0.032 ppbv ND 0.62 ug/m3 108-90-7 112.6 Chlorobenzene ND 0.20 0.027 ppbv ND 0.92 ug/m3 75-00-3 64.52 Chloroethane 5.0 0.20 0.039 ppbv 13 0.53 ug/m3 67-66-3 119.4 Chloroform 0.19 0.20 0.028 ppbv J 0.93 0.98 ug/m3 74-87-3 50.49 Chloromethane 0.67 0.20 0.037 ppbv 1.4 0.41 ug/m3 107-05-1 76.53 3-Chloropropene ND 0.20 0.041 ppbv ND 0.63 ug/m3 95-49-8 126.6 2-Chlorotoluene ND 0.20 0.031 ppbv ND 1.0 ug/m3 56-23-5 153.8 Carbon tetrachloride ND 0.20 0.040 ppbv ND 1.3 ug/m3 110-82-7 84.16 Cyclohexane 38.6 a 0.80 0.13 ppbv 133 a 2.8 ug/m3 75-34-3 98.96 1,1-Dichloroethane 7.9 0.20 0.028 ppbv 32 0.81 ug/m3 75-35-4 96.94 1,1-Dichloroethylene 11.9 0.20 0.046 ppbv 47.2 0.79 ug/m3 106-93-4 187.9 1,2-Dibromoethane ND 0.20 0.027 ppbv ND 1.5 ug/m3 107-06-2 98.96 1,2-Dichloroethane 0.55 0.20 0.043 ppbv 2.2 0.81 ug/m3 78-87-5 113 1,2-Dichloropropane ND 0.20 0.038 ppbv ND 0.92 ug/m3 123-91-1 88.12 1,4-Dioxane ND 0.20 0.056 ppbv ND 0.72 ug/m3 75-71-8 120.9 Dichlorodifluoromethane 0.54 0.20 0.038 ppbv 2.7 0.99 ug/m3 124-48-1 208.3 Dibromochloromethane ND 0.20 0.027 ppbv ND 1.7 ug/m3 156-60-5 96.94 trans-1,2-dichloroethylene 7.5 0.20 0.033 ppbv 30 0.79 ug/m3 156-59-2 96.94 cis-1,2-dichloroethylene 117 a 0.80 0.15 ppbv 464 a 3.2 ug/m3 10061-01-5 111 cis-1,3-dichloropropene ND 0.20 0.043 ppbv ND 0.91 ug/m3 541-73-1 147 m-dichlorobenzene ND 0.20 0.037 ppbv ND 1.2 ug/m3 95-50-1 147 o-dichlorobenzene ND 0.20 0.027 ppbv ND 1.2 ug/m3 106-46-7 147 p-dichlorobenzene ND 0.20 0.025 ppbv ND 1.2 ug/m3 10061-02-6 111 trans-1,3-dichloropropene ND 0.20 0.039 ppbv ND 0.91 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 7 of 15

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 2 of 3 2.2 2 Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA85910-2 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units 64-17-5 46.07 Ethanol 3.2 0.50 0.095 ppbv 6.0 0.94 ug/m3 100-41-4 106.2 Ethylbenzene ND 0.20 0.031 ppbv ND 0.87 ug/m3 141-78-6 88 Ethyl Acetate ND 0.20 0.061 ppbv ND 0.72 ug/m3 622-96-8 120.2 4-Ethyltoluene ND 0.20 0.024 ppbv ND 0.98 ug/m3 76-13-1 187.4 Freon 113 ND 0.20 0.034 ppbv ND 1.5 ug/m3 76-14-2 170.9 Freon 114 ND 0.20 0.031 ppbv ND 1.4 ug/m3 142-82-5 100.2 Heptane 0.14 0.20 0.033 ppbv J 0.57 0.82 ug/m3 87-68-3 260.8 Hexachlorobutadiene ND 0.20 0.046 ppbv ND 2.1 ug/m3 110-54-3 86.17 Hexane 0.78 0.20 0.044 ppbv 2.7 0.70 ug/m3 591-78-6 100 2-Hexanone 0.53 0.20 0.043 ppbv 2.2 0.82 ug/m3 67-63-0 60.1 Isopropyl Alcohol 3.7 0.20 0.059 ppbv 9.1 0.49 ug/m3 75-09-2 84.94 Methylene chloride 0.40 0.20 0.027 ppbv 1.4 0.69 ug/m3 78-93-3 72.11 Methyl ethyl ketone 2.8 0.20 0.048 ppbv 8.3 0.59 ug/m3 108-10-1 100.2 Methyl Isobutyl Ketone ND 0.20 0.036 ppbv ND 0.82 ug/m3 1634-04-4 88.15 Methyl Tert Butyl Ether ND 0.20 0.027 ppbv ND 0.72 ug/m3 80-62-6 100.12 Methylmethacrylate ND 0.20 0.043 ppbv ND 0.82 ug/m3 115-07-1 42 Propylene ND 0.50 0.070 ppbv ND 0.86 ug/m3 100-42-5 104.1 Styrene ND 0.20 0.027 ppbv ND 0.85 ug/m3 71-55-6 133.4 1,1,1-Trichloroethane 0.25 0.20 0.022 ppbv 1.4 1.1 ug/m3 79-34-5 167.9 1,1,2,2-Tetrachloroethane ND 0.20 0.030 ppbv ND 1.4 ug/m3 79-00-5 133.4 1,1,2-Trichloroethane ND 0.20 0.030 ppbv ND 1.1 ug/m3 120-82-1 181.5 1,2,4-Trichlorobenzene ND 0.20 0.051 ppbv ND 1.5 ug/m3 95-63-6 120.2 1,2,4-Trimethylbenzene 0.14 0.20 0.024 ppbv J 0.69 0.98 ug/m3 108-67-8 120.2 1,3,5-Trimethylbenzene ND 0.20 0.028 ppbv ND 0.98 ug/m3 540-84-1 114.2 2,2,4-Trimethylpentane 0.99 0.20 0.028 ppbv 4.6 0.93 ug/m3 75-65-0 74.12 Tertiary Butyl Alcohol 1.2 0.20 0.032 ppbv 3.6 0.61 ug/m3 127-18-4 165.8 Tetrachloroethylene 0.19 0.040 0.028 ppbv 1.3 0.27 ug/m3 109-99-9 72.11 Tetrahydrofuran 0.26 0.20 0.047 ppbv 0.77 0.59 ug/m3 108-88-3 92.14 Toluene 0.19 0.20 0.040 ppbv J 0.72 0.75 ug/m3 79-01-6 131.4 Trichloroethylene 8.1 0.040 0.033 ppbv 44 0.21 ug/m3 75-69-4 137.4 Trichlorofluoromethane 0.46 0.20 0.042 ppbv 2.6 1.1 ug/m3 75-01-4 62.5 Vinyl chloride 34.2 0.20 0.032 ppbv 87.4 0.51 ug/m3 108-05-4 86 Vinyl Acetate ND 0.20 0.057 ppbv ND 0.70 ug/m3 106.2 m,p-xylene 0.18 0.20 0.031 ppbv J 0.78 0.87 ug/m3 95-47-6 106.2 o-xylene ND 0.20 0.031 ppbv ND 0.87 ug/m3 1330-20-7 106.2 Xylenes (total) 0.18 0.20 0.031 ppbv J 0.78 0.87 ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 89% 92% 65-128% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 8 of 15

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 3 of 3 2.2 2 Client Sample ID: RCS-LEAD-1 CARBON EFFLUENT Lab Sample ID: JA85910-2 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A758 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units (a) Result is from Run# 2 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 15 JA85910

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 1 of 2 2.3 2 Client Sample ID: RCS-LAG-1 CARBON EFFLUENT Lab Sample ID: JA85910-3 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A308 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 3W23964.D 1 09/13/11 YXC n/a n/a V3W948 Run #2 Run #1 Run #2 Initial Volume 400 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units 67-64-1 58.08 Acetone ND 0.20 0.036 ppbv ND 0.48 ug/m3 106-99-0 54.09 1,3-Butadiene ND 0.20 0.024 ppbv ND 0.44 ug/m3 71-43-2 78.11 Benzene 0.28 0.20 0.046 ppbv 0.89 0.64 ug/m3 75-27-4 163.8 Bromodichloromethane ND 0.20 0.030 ppbv ND 1.3 ug/m3 75-25-2 252.8 Bromoform ND 0.20 0.037 ppbv ND 2.1 ug/m3 74-83-9 94.94 Bromomethane ND 0.20 0.037 ppbv ND 0.78 ug/m3 593-60-2 106.9 Bromoethene ND 0.20 0.037 ppbv ND 0.87 ug/m3 100-44-7 126 Benzyl Chloride ND 0.20 0.041 ppbv ND 1.0 ug/m3 75-15-0 76.14 Carbon disulfide ND 0.20 0.032 ppbv ND 0.62 ug/m3 108-90-7 112.6 Chlorobenzene ND 0.20 0.027 ppbv ND 0.92 ug/m3 75-00-3 64.52 Chloroethane 4.2 0.20 0.039 ppbv 11 0.53 ug/m3 67-66-3 119.4 Chloroform ND 0.20 0.028 ppbv ND 0.98 ug/m3 74-87-3 50.49 Chloromethane 0.51 0.20 0.037 ppbv 1.1 0.41 ug/m3 107-05-1 76.53 3-Chloropropene ND 0.20 0.041 ppbv ND 0.63 ug/m3 95-49-8 126.6 2-Chlorotoluene ND 0.20 0.031 ppbv ND 1.0 ug/m3 56-23-5 153.8 Carbon tetrachloride ND 0.20 0.040 ppbv ND 1.3 ug/m3 110-82-7 84.16 Cyclohexane 2.6 0.20 0.034 ppbv 8.9 0.69 ug/m3 75-34-3 98.96 1,1-Dichloroethane 2.0 0.20 0.028 ppbv 8.1 0.81 ug/m3 75-35-4 96.94 1,1-Dichloroethylene 3.2 0.20 0.046 ppbv 13 0.79 ug/m3 106-93-4 187.9 1,2-Dibromoethane ND 0.20 0.027 ppbv ND 1.5 ug/m3 107-06-2 98.96 1,2-Dichloroethane ND 0.20 0.043 ppbv ND 0.81 ug/m3 78-87-5 113 1,2-Dichloropropane ND 0.20 0.038 ppbv ND 0.92 ug/m3 123-91-1 88.12 1,4-Dioxane ND 0.20 0.056 ppbv ND 0.72 ug/m3 75-71-8 120.9 Dichlorodifluoromethane 0.49 0.20 0.038 ppbv 2.4 0.99 ug/m3 124-48-1 208.3 Dibromochloromethane ND 0.20 0.027 ppbv ND 1.7 ug/m3 156-60-5 96.94 trans-1,2-dichloroethylene 1.2 0.20 0.033 ppbv 4.8 0.79 ug/m3 156-59-2 96.94 cis-1,2-dichloroethylene 22.2 0.20 0.038 ppbv 88.0 0.79 ug/m3 10061-01-5 111 cis-1,3-dichloropropene ND 0.20 0.043 ppbv ND 0.91 ug/m3 541-73-1 147 m-dichlorobenzene ND 0.20 0.037 ppbv ND 1.2 ug/m3 95-50-1 147 o-dichlorobenzene ND 0.20 0.027 ppbv ND 1.2 ug/m3 106-46-7 147 p-dichlorobenzene ND 0.20 0.025 ppbv ND 1.2 ug/m3 10061-02-6 111 trans-1,3-dichloropropene ND 0.20 0.039 ppbv ND 0.91 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 10 of 15

Accutest LabLink@635393 14:08 23-Sep-2011 Report of Analysis Page 2 of 2 2.3 2 Client Sample ID: RCS-LAG-1 CARBON EFFLUENT Lab Sample ID: JA85910-3 Date Sampled: 09/12/11 Matrix: AIR - Air Summa ID: A308 Date Received: 09/12/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units 64-17-5 46.07 Ethanol 2.0 0.50 0.095 ppbv 3.8 0.94 ug/m3 100-41-4 106.2 Ethylbenzene ND 0.20 0.031 ppbv ND 0.87 ug/m3 141-78-6 88 Ethyl Acetate ND 0.20 0.061 ppbv ND 0.72 ug/m3 622-96-8 120.2 4-Ethyltoluene ND 0.20 0.024 ppbv ND 0.98 ug/m3 76-13-1 187.4 Freon 113 ND 0.20 0.034 ppbv ND 1.5 ug/m3 76-14-2 170.9 Freon 114 ND 0.20 0.031 ppbv ND 1.4 ug/m3 142-82-5 100.2 Heptane 0.13 0.20 0.033 ppbv J 0.53 0.82 ug/m3 87-68-3 260.8 Hexachlorobutadiene ND 0.20 0.046 ppbv ND 2.1 ug/m3 110-54-3 86.17 Hexane 1.3 0.20 0.044 ppbv 4.6 0.70 ug/m3 591-78-6 100 2-Hexanone ND 0.20 0.043 ppbv ND 0.82 ug/m3 67-63-0 60.1 Isopropyl Alcohol 0.72 0.20 0.059 ppbv 1.8 0.49 ug/m3 75-09-2 84.94 Methylene chloride 0.38 0.20 0.027 ppbv 1.3 0.69 ug/m3 78-93-3 72.11 Methyl ethyl ketone 0.30 0.20 0.048 ppbv 0.88 0.59 ug/m3 108-10-1 100.2 Methyl Isobutyl Ketone ND 0.20 0.036 ppbv ND 0.82 ug/m3 1634-04-4 88.15 Methyl Tert Butyl Ether ND 0.20 0.027 ppbv ND 0.72 ug/m3 80-62-6 100.12 Methylmethacrylate ND 0.20 0.043 ppbv ND 0.82 ug/m3 115-07-1 42 Propylene ND 0.50 0.070 ppbv ND 0.86 ug/m3 100-42-5 104.1 Styrene ND 0.20 0.027 ppbv ND 0.85 ug/m3 71-55-6 133.4 1,1,1-Trichloroethane ND 0.20 0.022 ppbv ND 1.1 ug/m3 79-34-5 167.9 1,1,2,2-Tetrachloroethane ND 0.20 0.030 ppbv ND 1.4 ug/m3 79-00-5 133.4 1,1,2-Trichloroethane ND 0.20 0.030 ppbv ND 1.1 ug/m3 120-82-1 181.5 1,2,4-Trichlorobenzene ND 0.20 0.051 ppbv ND 1.5 ug/m3 95-63-6 120.2 1,2,4-Trimethylbenzene ND 0.20 0.024 ppbv ND 0.98 ug/m3 108-67-8 120.2 1,3,5-Trimethylbenzene ND 0.20 0.028 ppbv ND 0.98 ug/m3 540-84-1 114.2 2,2,4-Trimethylpentane 0.79 0.20 0.028 ppbv 3.7 0.93 ug/m3 75-65-0 74.12 Tertiary Butyl Alcohol ND 0.20 0.032 ppbv ND 0.61 ug/m3 127-18-4 165.8 Tetrachloroethylene 0.061 0.040 0.028 ppbv 0.41 0.27 ug/m3 109-99-9 72.11 Tetrahydrofuran ND 0.20 0.047 ppbv ND 0.59 ug/m3 108-88-3 92.14 Toluene 0.26 0.20 0.040 ppbv 0.98 0.75 ug/m3 79-01-6 131.4 Trichloroethylene ND 0.040 0.033 ppbv ND 0.21 ug/m3 75-69-4 137.4 Trichlorofluoromethane 0.36 0.20 0.042 ppbv 2.0 1.1 ug/m3 75-01-4 62.5 Vinyl chloride 27.4 0.20 0.032 ppbv 70.0 0.51 ug/m3 108-05-4 86 Vinyl Acetate ND 0.20 0.057 ppbv ND 0.70 ug/m3 106.2 m,p-xylene 0.13 0.20 0.031 ppbv J 0.56 0.87 ug/m3 95-47-6 106.2 o-xylene ND 0.20 0.031 ppbv ND 0.87 ug/m3 1330-20-7 106.2 Xylenes (total) 0.13 0.20 0.031 ppbv J 0.56 0.87 ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 89% 65-128% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85910 11 of 15

3 Section 3 New Jersey Accutest LabLink@635393 14:08 23-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody Summa Canister and Flow Controller Log 12 of 15 JA85910

3 3.1 JA85910: Chain of Custody Page 1 of 2 13 of 15 JA85910

Accutest Laboratories Sample Receipt Summary Accutest Job Number JA85910 Client: Date / Time Received: 9/12/2011 No. Coolers: 0 Airbill #'s: Project: Delivery Method: 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: Quality Control Preservatio Y or N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y or N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Comments Accutest Laboratories V:732.329.0200 2235 US Highway 130 F: 732.329.3499 Dayton, New Jersey www/accutest.com JA85910: Chain of Custody Page 2 of 2 14 of 15 JA85910

Summa Canister and Flow Controller Log Page 1 of 1 Job Number: JA85910 Account: ROUXNYI Roux Associates Project: ExxonMobil Brooklyn Terminal, 400 Kingsland Avenue, Greenpoint, Brooklyn, NY Received: 09/12/11 3.2 3 SUMMA CANISTERS Shipping Receiving Summa Vac Date SCC SCC Sample Date Vac Pres Final Dil ID L " Hg Out By Batch FileID Number In By " Hg psig psig Fact A634 6 29.4 09/02/11 FZ CP4971 JA85910-1 09/13/11 FZ 4 1 A758 6 29.4 09/02/11 FZ CP4971 JA85910-2 09/13/11 FZ 0 1 A308 6 29.4 09/02/11 FZ CP4971 JA85910-3 09/13/11 FZ 1 1 Accutest Bottle Order(s): KM-12/29/2011-9 Prep Date Room Temp(F) Bar Pres "Hg 09/02/11 70 29.92 JA85910 15 of 15

e-hardcopy 2.0 Automated Report New Jersey 09/27/11 09/27/11 Technical Report for Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY PO#4513473199 WBS#08 Accutest Job Number: JA85694A Sampling Date: 09/08/11 Report to: Roux Associates rpatel@rouxinc.com ATTN: Ritu Patel Total number of pages in report: 24 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova 732-329-0200 Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ 08810 tel: 732-329-0200 fax: 732-329-3499 http://www.accutest.com Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA85694A 1 of 24

Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results... 4 2.1: JA85694-11: OSS-INFLUENT... 5 2.2: JA85694-12: OSS-EFFLUENT... 12 Section 3: Misc. Forms... 19 3.1: Chain of Custody... 20-1- Sections: 1 2 3 2 of 24 JA85694A

1 Accutest LabLink@635844 13:59 27-Sep-2011 Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY Project No: PO#4513473199 WBS#08 Sample Summary Job No: JA85694A Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA85694-11 09/08/11 11:15 BC 09/09/11 AQ Influent OSS-INFLUENT JA85694-12 09/08/11 13:10 BC 09/09/11 AQ Effluent OSS-EFFLUENT 3 of 24 JA85694A

2 Section 2 New Jersey Accutest LabLink@635844 13:59 27-Sep-2011 Sample Results Report of Analysis 4 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69139.D 5 09/15/11 MAH n/a n/a V2E3099 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 250 12 ug/l 107-13-1 Acrylonitrile ND 50 18 ug/l 71-43-2 Benzene 771 5.0 1.4 ug/l 75-27-4 Bromodichloromethane ND 5.0 0.75 ug/l 75-25-2 Bromoform ND 5.0 0.96 ug/l 74-83-9 Bromomethane ND 5.0 1.4 ug/l 56-23-5 Carbon tetrachloride ND 5.0 0.84 ug/l 108-90-7 Chlorobenzene ND 5.0 0.93 ug/l 75-00-3 Chloroethane 71.8 5.0 2.0 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 25 4.4 ug/l 67-66-3 Chloroform ND 5.0 0.73 ug/l 74-87-3 Chloromethane ND 5.0 0.99 ug/l 124-48-1 Dibromochloromethane ND 5.0 0.89 ug/l 95-50-1 1,2-Dichlorobenzene ND 5.0 0.57 ug/l 541-73-1 1,3-Dichlorobenzene ND 5.0 1.0 ug/l 106-46-7 1,4-Dichlorobenzene ND 5.0 1.1 ug/l 75-71-8 Dichlorodifluoromethane ND 10 3.6 ug/l 75-34-3 1,1-Dichloroethane 10.4 5.0 0.70 ug/l 107-06-2 1,2-Dichloroethane ND 5.0 2.0 ug/l 75-35-4 1,1-Dichloroethene 3.6 5.0 1.5 ug/l J 156-59-2 cis-1,2-dichloroethene 634 5.0 1.0 ug/l 156-60-5 trans-1,2-dichloroethene 24.8 5.0 1.4 ug/l 78-87-5 1,2-Dichloropropane ND 5.0 0.88 ug/l 10061-01-5 cis-1,3-dichloropropene ND 5.0 0.58 ug/l 10061-02-6 trans-1,3-dichloropropene ND 5.0 0.90 ug/l 100-41-4 Ethylbenzene 51.4 5.0 0.92 ug/l 75-09-2 Methylene chloride ND 5.0 1.5 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 0.79 ug/l 127-18-4 Tetrachloroethene 351 5.0 0.96 ug/l 108-88-3 Toluene 55.1 5.0 0.58 ug/l 71-55-6 1,1,1-Trichloroethane ND 5.0 0.80 ug/l 79-00-5 1,1,2-Trichloroethane ND 5.0 1.1 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 5 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: SW846 8260B Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 4B09930.D 1 09/12/11 TDN n/a n/a V4B433 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q 1634-04-4 Methyl Tert Butyl Ether 59.9 1.0 0.18 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 101% 77-120% 17060-07-0 1,2-Dichloroethane-D4 105% 70-127% 2037-26-5 Toluene-D8 93% 79-120% 460-00-4 4-Bromofluorobenzene 95% 76-118% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89939.D 1 09/20/11 LP 09/10/11 OP51792 ER3460 Run #2 Initial Volume Final Volume Run #1 940 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.3 1.0 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.3 1.3 ug/l 120-83-2 2,4-Dichlorophenol ND 5.3 1.7 ug/l 105-67-9 2,4-Dimethylphenol ND 5.3 1.7 ug/l 51-28-5 2,4-Dinitrophenol ND 21 0.95 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 11 0.77 ug/l 88-75-5 2-Nitrophenol ND 2.1 1.9 ug/l 100-02-7 4-Nitrophenol ND 21 0.90 ug/l 87-86-5 Pentachlorophenol ND 11 2.0 ug/l 108-95-2 Phenol 5.2 2.1 0.53 ug/l 88-06-2 2,4,6-Trichlorophenol ND 2.1 1.3 ug/l 83-32-9 Acenaphthene 1.5 1.1 0.37 ug/l 208-96-8 Acenaphthylene ND 1.1 0.41 ug/l 120-12-7 Anthracene ND 1.1 0.42 ug/l 92-87-5 Benzidine ND 21 0.30 ug/l 56-55-3 Benzo(a)anthracene ND 1.1 0.38 ug/l 50-32-8 Benzo(a)pyrene ND 1.1 0.39 ug/l 205-99-2 Benzo(b)fluoranthene ND 1.1 0.63 ug/l 191-24-2 Benzo(g,h,i)perylene ND 1.1 0.45 ug/l 207-08-9 Benzo(k)fluoranthene ND 1.1 0.45 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.1 0.32 ug/l 85-68-7 Butyl benzyl phthalate ND 2.1 0.63 ug/l 91-58-7 2-Chloronaphthalene ND 2.1 1.0 ug/l 106-47-8 4-Chloroaniline ND 2.1 0.42 ug/l 218-01-9 Chrysene ND 1.1 0.27 ug/l 111-91-1 bis(2-chloroethoxy)methane ND 2.1 0.70 ug/l 111-44-4 bis(2-chloroethyl)ether ND 2.1 0.56 ug/l 108-60-1 bis(2-chloroisopropyl)ether ND 2.1 0.79 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.1 0.46 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.1 0.22 ug/l 122-66-7 1,2-Diphenylhydrazine ND 2.1 0.48 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.1 0.17 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 8 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 2 of 2 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q 106-46-7 1,4-Dichlorobenzene ND 2.1 0.19 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.1 0.91 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.1 0.59 ug/l 91-94-1 3,3'-Dichlorobenzidine ND 2.1 1.3 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 1.1 0.58 ug/l 84-74-2 Di-n-butyl phthalate ND 2.1 0.63 ug/l 117-84-0 Di-n-octyl phthalate ND 2.1 0.61 ug/l 84-66-2 Diethyl phthalate ND 2.1 0.41 ug/l 131-11-3 Dimethyl phthalate ND 2.1 0.35 ug/l 117-81-7 bis(2-ethylhexyl)phthalate ND 2.1 0.70 ug/l 206-44-0 Fluoranthene ND 1.1 0.26 ug/l 86-73-7 Fluorene ND 1.1 0.48 ug/l 118-74-1 Hexachlorobenzene ND 1.1 0.57 ug/l 87-68-3 Hexachlorobutadiene ND 1.1 0.19 ug/l 77-47-4 Hexachlorocyclopentadiene ND 11 0.43 ug/l 67-72-1 Hexachloroethane ND 5.3 0.30 ug/l 193-39-5 Indeno(1,2,3-cd)pyrene ND 1.1 0.32 ug/l 78-59-1 Isophorone ND 2.1 0.63 ug/l 91-20-3 Naphthalene 20.2 1.1 0.34 ug/l 98-95-3 Nitrobenzene ND 2.1 0.45 ug/l 62-75-9 n-nitrosodimethylamine ND 2.1 0.49 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.1 0.50 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.3 0.55 ug/l 85-01-8 Phenanthrene ND 1.1 0.39 ug/l 129-00-0 Pyrene ND 1.1 0.36 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 1.1 0.36 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 37% 10-111% 4165-62-2 Phenol-d5 24% 10-117% 118-79-6 2,4,6-Tribromophenol 104% 25-151% 4165-60-0 Nitrobenzene-d5 102% 40-131% 321-60-8 2-Fluorobiphenyl 98% 48-117% 1718-51-0 Terphenyl-d14 109% 20-141% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium 233000 5000 ug/l 1 09/19/11 09/21/11 ND EPA 200.7 2 EPA 200.7 4 Copper <10 10 ug/l 1 09/19/11 09/20/11 VC EPA 200.7 1 EPA 200.7 4 Iron 10400 100 ug/l 1 09/19/11 09/21/11 ND EPA 200.7 2 EPA 200.7 4 Manganese 3680 15 ug/l 1 09/19/11 09/20/11 VC EPA 200.7 1 EPA 200.7 4 Mercury <0.20 0.20 ug/l 1 09/21/11 09/21/11 JW EPA 245.1 3 EPA 245.1 5 (1) Instrument QC Batch: MA27108 (2) Instrument QC Batch: MA27116 (3) Instrument QC Batch: MA27124 (4) Prep QC Batch: MP60266 (5) Prep QC Batch: MP60270 RL = Reporting Limit 10 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.1 2 Client Sample ID: OSS-INFLUENT Lab Sample ID: JA85694-11 Date Sampled: 09/08/11 Matrix: AQ - Influent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1820 20 mg/l 10 09/16/11 16:36 AE EPA 300/SW846 9056A HEM Oil and Grease <5.1 5.1 mg/l 1 09/21/11 JOO EPA 1664A Phenols <0.20 0.20 mg/l 1 09/14/11 13:00 JA EPA 420.4/LACHAT Solids, Settleable <0.10 0.10 ml/l 1 09/09/11 14:00 CW SM20 2540F Solids, Total Suspended 21.0 4.0 mg/l 1 09/13/11 RI SM20 2540D Turbidity 107 3.0 NTU 10 09/09/11 19:50 LS EPA 180.1 ph a 6.95 su 1 09/09/11 11:12 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85694A 11 of 24

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 2 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 624 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2E69138.D 1 09/15/11 MAH n/a n/a V2E3099 Run #2 Run #1 Run #2 Purge Volume 5.0 ml VOA PPL List CAS No. Compound Result RL MDL Units Q 107-02-8 Acrolein ND 50 2.3 ug/l 107-13-1 Acrylonitrile ND 10 3.5 ug/l 71-43-2 Benzene ND 1.0 0.28 ug/l 75-27-4 Bromodichloromethane ND 1.0 0.15 ug/l 75-25-2 Bromoform ND 1.0 0.19 ug/l 74-83-9 Bromomethane ND 1.0 0.28 ug/l 56-23-5 Carbon tetrachloride ND 1.0 0.17 ug/l 108-90-7 Chlorobenzene ND 1.0 0.19 ug/l 75-00-3 Chloroethane ND 1.0 0.40 ug/l 110-75-8 2-Chloroethyl vinyl ether ND 5.0 0.89 ug/l 67-66-3 Chloroform ND 1.0 0.15 ug/l 74-87-3 Chloromethane ND 1.0 0.20 ug/l 124-48-1 Dibromochloromethane ND 1.0 0.18 ug/l 95-50-1 1,2-Dichlorobenzene ND 1.0 0.11 ug/l 541-73-1 1,3-Dichlorobenzene ND 1.0 0.20 ug/l 106-46-7 1,4-Dichlorobenzene ND 1.0 0.22 ug/l 75-71-8 Dichlorodifluoromethane ND 2.0 0.72 ug/l 75-34-3 1,1-Dichloroethane ND 1.0 0.14 ug/l 107-06-2 1,2-Dichloroethane ND 1.0 0.39 ug/l 75-35-4 1,1-Dichloroethene ND 1.0 0.30 ug/l 156-59-2 cis-1,2-dichloroethene 3.4 1.0 0.20 ug/l 156-60-5 trans-1,2-dichloroethene ND 1.0 0.27 ug/l 78-87-5 1,2-Dichloropropane ND 1.0 0.18 ug/l 10061-01-5 cis-1,3-dichloropropene ND 1.0 0.12 ug/l 10061-02-6 trans-1,3-dichloropropene ND 1.0 0.18 ug/l 100-41-4 Ethylbenzene ND 1.0 0.18 ug/l 75-09-2 Methylene chloride ND 1.0 0.31 ug/l 79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.16 ug/l 127-18-4 Tetrachloroethene 0.46 1.0 0.19 ug/l J 108-88-3 Toluene ND 1.0 0.12 ug/l 71-55-6 1,1,1-Trichloroethane ND 1.0 0.16 ug/l 79-00-5 1,1,2-Trichloroethane ND 1.0 0.23 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 12 of 24

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: SW846 8260B Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 4B09927.D 1 09/12/11 TDN n/a n/a V4B433 Run #2 Run #1 Run #2 Purge Volume 5.0 ml CAS No. Compound Result RL MDL Units Q 1634-04-4 Methyl Tert Butyl Ether 11.1 1.0 0.18 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 1868-53-7 Dibromofluoromethane 104% 77-120% 17060-07-0 1,2-Dichloroethane-D4 107% 70-127% 2037-26-5 Toluene-D8 96% 79-120% 460-00-4 4-Bromofluorobenzene 93% 76-118% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 14 of 24

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 2 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 R89808.D 1 09/14/11 LP 09/10/11 OP51792 ER3452 Run #2 Initial Volume Final Volume Run #1 1000 ml 1.0 ml Run #2 ABN PPL List CAS No. Compound Result RL MDL Units Q 95-57-8 2-Chlorophenol ND 5.0 0.95 ug/l 59-50-7 4-Chloro-3-methyl phenol ND 5.0 1.2 ug/l 120-83-2 2,4-Dichlorophenol ND 5.0 1.6 ug/l 105-67-9 2,4-Dimethylphenol ND 5.0 1.6 ug/l 51-28-5 2,4-Dinitrophenol ND 20 0.89 ug/l 534-52-1 4,6-Dinitro-o-cresol ND 10 0.72 ug/l 88-75-5 2-Nitrophenol ND 2.0 1.8 ug/l 100-02-7 4-Nitrophenol ND 20 0.84 ug/l 87-86-5 Pentachlorophenol ND 10 1.9 ug/l 108-95-2 Phenol ND 2.0 0.50 ug/l 88-06-2 2,4,6-Trichlorophenol ND 2.0 1.3 ug/l 83-32-9 Acenaphthene ND 1.0 0.35 ug/l 208-96-8 Acenaphthylene ND 1.0 0.38 ug/l 120-12-7 Anthracene ND 1.0 0.40 ug/l 92-87-5 Benzidine ND 20 0.28 ug/l 56-55-3 Benzo(a)anthracene ND 1.0 0.36 ug/l 50-32-8 Benzo(a)pyrene ND 1.0 0.37 ug/l 205-99-2 Benzo(b)fluoranthene ND 1.0 0.59 ug/l 191-24-2 Benzo(g,h,i)perylene ND 1.0 0.42 ug/l 207-08-9 Benzo(k)fluoranthene ND 1.0 0.42 ug/l 101-55-3 4-Bromophenyl phenyl ether ND 2.0 0.30 ug/l 85-68-7 Butyl benzyl phthalate ND 2.0 0.59 ug/l 91-58-7 2-Chloronaphthalene ND 2.0 0.98 ug/l 106-47-8 4-Chloroaniline ND 2.0 0.40 ug/l 218-01-9 Chrysene ND 1.0 0.25 ug/l 111-91-1 bis(2-chloroethoxy)methane ND 2.0 0.65 ug/l 111-44-4 bis(2-chloroethyl)ether ND 2.0 0.53 ug/l 108-60-1 bis(2-chloroisopropyl)ether ND 2.0 0.74 ug/l 7005-72-3 4-Chlorophenyl phenyl ether ND 2.0 0.43 ug/l 95-50-1 1,2-Dichlorobenzene ND 2.0 0.21 ug/l 122-66-7 1,2-Diphenylhydrazine ND 2.0 0.45 ug/l 541-73-1 1,3-Dichlorobenzene ND 2.0 0.16 ug/l ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85694A 15 of 24

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 2 of 2 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Method: EPA 625 EPA 625 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY ABN PPL List CAS No. Compound Result RL MDL Units Q 106-46-7 1,4-Dichlorobenzene ND 2.0 0.18 ug/l 121-14-2 2,4-Dinitrotoluene ND 2.0 0.86 ug/l 606-20-2 2,6-Dinitrotoluene ND 2.0 0.56 ug/l 91-94-1 3,3'-Dichlorobenzidine ND 2.0 1.2 ug/l 53-70-3 Dibenzo(a,h)anthracene ND 1.0 0.54 ug/l 84-74-2 Di-n-butyl phthalate ND 2.0 0.59 ug/l 117-84-0 Di-n-octyl phthalate ND 2.0 0.57 ug/l 84-66-2 Diethyl phthalate ND 2.0 0.39 ug/l 131-11-3 Dimethyl phthalate ND 2.0 0.33 ug/l 117-81-7 bis(2-ethylhexyl)phthalate ND 2.0 0.66 ug/l 206-44-0 Fluoranthene ND 1.0 0.25 ug/l 86-73-7 Fluorene ND 1.0 0.45 ug/l 118-74-1 Hexachlorobenzene ND 1.0 0.54 ug/l 87-68-3 Hexachlorobutadiene ND 1.0 0.18 ug/l 77-47-4 Hexachlorocyclopentadiene ND 10 0.41 ug/l 67-72-1 Hexachloroethane ND 5.0 0.28 ug/l 193-39-5 Indeno(1,2,3-cd)pyrene ND 1.0 0.30 ug/l 78-59-1 Isophorone ND 2.0 0.59 ug/l 91-20-3 Naphthalene ND 1.0 0.32 ug/l 98-95-3 Nitrobenzene ND 2.0 0.42 ug/l 62-75-9 n-nitrosodimethylamine ND 2.0 0.46 ug/l 621-64-7 N-Nitroso-di-n-propylamine ND 2.0 0.47 ug/l 86-30-6 N-Nitrosodiphenylamine ND 5.0 0.52 ug/l 85-01-8 Phenanthrene ND 1.0 0.36 ug/l 129-00-0 Pyrene ND 1.0 0.34 ug/l 120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.34 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 367-12-4 2-Fluorophenol 41% 10-111% 4165-62-2 Phenol-d5 25% 10-117% 118-79-6 2,4,6-Tribromophenol 118% 25-151% 4165-60-0 Nitrobenzene-d5 92% 40-131% 321-60-8 2-Fluorobiphenyl 101% 48-117% 1718-51-0 Terphenyl-d14 129% 20-141% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 16 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY Total Metals Analysis Analyte Result RL Units DF Prep Analyzed By Method Prep Method Calcium 221000 5000 ug/l 1 09/19/11 09/21/11 ND EPA 200.7 2 EPA 200.7 4 Copper <10 10 ug/l 1 09/19/11 09/20/11 VC EPA 200.7 1 EPA 200.7 4 Iron 8010 100 ug/l 1 09/19/11 09/21/11 ND EPA 200.7 2 EPA 200.7 4 Manganese 3550 15 ug/l 1 09/19/11 09/20/11 VC EPA 200.7 1 EPA 200.7 4 Mercury <0.20 0.20 ug/l 1 09/21/11 09/21/11 JW EPA 245.1 3 EPA 245.1 5 (1) Instrument QC Batch: MA27108 (2) Instrument QC Batch: MA27116 (3) Instrument QC Batch: MA27124 (4) Prep QC Batch: MP60266 (5) Prep QC Batch: MP60270 RL = Reporting Limit 17 of 24 JA85694A

Accutest LabLink@635844 13:59 27-Sep-2011 Report of Analysis Page 1 of 1 2.2 2 Client Sample ID: OSS-EFFLUENT Lab Sample ID: JA85694-12 Date Sampled: 09/08/11 Matrix: AQ - Effluent Date Received: 09/09/11 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY General Chemistry Analyte Result RL Units DF Analyzed By Method Chloride 1670 16 mg/l 8 09/16/11 17:00 AE EPA 300/SW846 9056A HEM Oil and Grease <5.1 5.1 mg/l 1 09/21/11 JOO EPA 1664A Phenols <0.20 0.20 mg/l 1 09/14/11 13:03 JA EPA 420.4/LACHAT Solids, Settleable <0.10 0.10 ml/l 1 09/09/11 14:00 CW SM20 2540F Solids, Total Suspended 11.0 4.0 mg/l 1 09/13/11 RI SM20 2540D Turbidity 25.5 0.30 NTU 1 09/09/11 19:50 LS EPA 180.1 ph a 7.97 su 1 09/09/11 11:15 SUB SM20 4500H B (a) Sample received out of holding time for ph analysis. RL = Reporting Limit JA85694A 18 of 24

3 Section 3 New Jersey Accutest LabLink@635844 13:59 27-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody 19 of 24 JA85694A

3 3.1 JA85694A: Chain of Custody Page 1 of 5 20 of 24 JA85694A

3 3.1 JA85694A: Chain of Custody Page 2 of 5 21 of 24 JA85694A

3 3.1 JA85694A: Chain of Custody Page 3 of 5 22 of 24 JA85694A

Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85694 Client: ROUX Immediate Client Services Action Required: Date / Time Received: 9/9/2011 10:15 Delivery Method: FedEx Client Service Action Required at Login: Project: GREENPOINT No. Coolers: Airbill #'s: 9574 9189 9522 Yes No 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: IR Gun 3. Cooler media: Ice (bag) Quality Control Preservation Y N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Broken / Leaking 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: Comments 5. Filtering instructions clear: -6 "RW-H" PHENOL VOLUME REC'D BROKEN Accutest Laboratories V:732.329.0200 2235 US Highway 130 F: 732.329.3499 Dayton, New Jersey www/accutest.com JA85694A: Chain of Custody Page 4 of 5 23 of 24 JA85694A

Sample Receipt Summary - Problem Resolution Accutest Job Number: JA85694 CSR: Michelle Response Date 9/9/2011 3.1 Response: Please preserve a N/P volume w/h2so4 and analyze for PN per Chris Proce 3 Accutest Laboratories V:732.329.0200 2235 US Highway 130 F: 732.329.3499 Dayton, New Jersey www/accutest.com JA85694A: Chain of Custody Page 5 of 5 24 of 24 JA85694A

e-hardcopy 2.0 Automated Report New Jersey 09/23/11 09/23/11 Technical Report for Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY PO#4513473199 WBS#08 Accutest Job Number: JA85709 Sampling Date: 09/08/11 Report to: Roux Associates rpatel@rouxinc.com ATTN: Ritu Patel Total number of pages in report: 13 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Conference and/or state specific certification programs as applicable. David N. Speis VP, Laboratory Director Client Service contact: Matt Cordova 732-329-0200 Certifications: NJ(12129), NY(10983), CA, CT, DE, FL, IL, IN, KS, KY, LA, MA, MD, MI, MT, NC, PA, RI, SC, TN, VA, WV This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories. Test results relate only to samples analyzed. New Jersey 2235 Route 130 Dayton, NJ 08810 tel: 732-329-0200 fax: 732-329-3499 http://www.accutest.com Accutest Laboratories is the sole authority for authorizing edits or modifications to this document. Unauthorized modification of this report is strictly prohibited. JA85709 1 of 13

Table of Contents Section 1: Sample Summary... 3 Section 2: Sample Results... 4 2.1: JA85709-1: OSS-CAT-OX INFLUENT... 5 2.2: JA85709-2: OSS-CAT-OX EFFLUENT... 7 Section 3: Misc. Forms... 10 3.1: Chain of Custody... 11 3.2: Summa Canister and Flow Controller Log... 13-1- Sections: 1 2 3 2 of 13 JA85709

1 Accutest LabLink@635393 14:06 23-Sep-2011 Roux Associates ExxonMobil Off-Site 31097, Brooklyn, NY Project No: PO#4513473199 WBS#08 Sample Summary Job No: JA85709 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID JA85709-1 09/08/11 13:00 BC 09/09/11 AIR Air OSS-CAT-OX INFLUENT JA85709-2 09/08/11 13:10 BC 09/09/11 AIR Air OSS-CAT-OX EFFLUENT 3 of 13 JA85709

2 Section 2 New Jersey Accutest LabLink@635393 14:06 23-Sep-2011 Sample Results Report of Analysis 4 of 13 JA85709

Accutest LabLink@635393 14:06 23-Sep-2011 Report of Analysis Page 1 of 2 2.1 2 Client Sample ID: OSS-CAT-OX INFLUENT Lab Sample ID: JA85709-1 Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A816,A610 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2W32479.D 45.2 09/13/11 YMH n/a n/a V2W1369 Run #2 Run #1 Run #2 Initial Volume 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units 67-64-1 58.08 Acetone ND 18 3.3 ppbv ND 43 ug/m3 106-99-0 54.09 1,3-Butadiene ND 18 2.2 ppbv ND 40 ug/m3 71-43-2 78.11 Benzene 1300 18 4.2 ppbv 4150 58 ug/m3 75-27-4 163.8 Bromodichloromethane ND 18 2.7 ppbv ND 120 ug/m3 75-25-2 252.8 Bromoform ND 18 3.4 ppbv ND 190 ug/m3 74-83-9 94.94 Bromomethane ND 18 3.3 ppbv ND 70 ug/m3 593-60-2 106.9 Bromoethene ND 18 3.3 ppbv ND 79 ug/m3 100-44-7 126 Benzyl Chloride ND 18 3.7 ppbv ND 93 ug/m3 75-15-0 76.14 Carbon disulfide ND 18 2.9 ppbv ND 56 ug/m3 108-90-7 112.6 Chlorobenzene ND 18 2.4 ppbv ND 83 ug/m3 75-00-3 64.52 Chloroethane 361 18 3.5 ppbv 953 47 ug/m3 67-66-3 119.4 Chloroform ND 18 2.5 ppbv ND 88 ug/m3 74-87-3 50.49 Chloromethane ND 18 3.3 ppbv ND 37 ug/m3 107-05-1 76.53 3-Chloropropene ND 18 3.7 ppbv ND 56 ug/m3 95-49-8 126.6 2-Chlorotoluene ND 18 2.8 ppbv ND 93 ug/m3 56-23-5 153.8 Carbon tetrachloride ND 18 3.6 ppbv ND 110 ug/m3 110-82-7 84.16 Cyclohexane 396 18 3.0 ppbv 1360 62 ug/m3 75-34-3 98.96 1,1-Dichloroethane 36.2 18 2.5 ppbv 147 73 ug/m3 75-35-4 96.94 1,1-Dichloroethylene 13.0 18 4.2 ppbv J 51.5 71 ug/m3 106-93-4 187.9 1,2-Dibromoethane ND 18 2.5 ppbv ND 140 ug/m3 107-06-2 98.96 1,2-Dichloroethane ND 18 3.9 ppbv ND 73 ug/m3 78-87-5 113 1,2-Dichloropropane ND 18 3.5 ppbv ND 83 ug/m3 123-91-1 88.12 1,4-Dioxane ND 18 5.1 ppbv ND 65 ug/m3 75-71-8 120.9 Dichlorodifluoromethane ND 18 3.4 ppbv ND 89 ug/m3 124-48-1 208.3 Dibromochloromethane ND 18 2.4 ppbv ND 150 ug/m3 156-60-5 96.94 trans-1,2-dichloroethylene 97.5 18 3.0 ppbv 387 71 ug/m3 156-59-2 96.94 cis-1,2-dichloroethylene 2140 18 3.4 ppbv 8480 71 ug/m3 10061-01-5 111 cis-1,3-dichloropropene ND 18 3.8 ppbv ND 82 ug/m3 541-73-1 147 m-dichlorobenzene ND 18 3.4 ppbv ND 110 ug/m3 95-50-1 147 o-dichlorobenzene ND 18 2.4 ppbv ND 110 ug/m3 106-46-7 147 p-dichlorobenzene ND 18 2.3 ppbv ND 110 ug/m3 10061-02-6 111 trans-1,3-dichloropropene ND 18 3.5 ppbv ND 82 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85709 5 of 13

Accutest LabLink@635393 14:06 23-Sep-2011 Report of Analysis Page 2 of 2 2.1 2 Client Sample ID: OSS-CAT-OX INFLUENT Lab Sample ID: JA85709-1 Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A816,A610 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units 64-17-5 46.07 Ethanol ND 45 8.6 ppbv ND 85 ug/m3 100-41-4 106.2 Ethylbenzene 77.4 18 2.8 ppbv 336 78 ug/m3 141-78-6 88 Ethyl Acetate ND 18 5.5 ppbv ND 65 ug/m3 622-96-8 120.2 4-Ethyltoluene 9.9 18 2.2 ppbv J 49 88 ug/m3 76-13-1 187.4 Freon 113 ND 18 3.1 ppbv ND 140 ug/m3 76-14-2 170.9 Freon 114 ND 18 2.8 ppbv ND 130 ug/m3 142-82-5 100.2 Heptane 14.2 18 3.0 ppbv J 58.2 74 ug/m3 87-68-3 260.8 Hexachlorobutadiene ND 18 4.1 ppbv ND 190 ug/m3 110-54-3 86.17 Hexane 72.6 18 4.0 ppbv 256 63 ug/m3 591-78-6 100 2-Hexanone ND 18 3.9 ppbv ND 74 ug/m3 67-63-0 60.1 Isopropyl Alcohol ND 18 5.3 ppbv ND 44 ug/m3 75-09-2 84.94 Methylene chloride ND 18 2.5 ppbv ND 63 ug/m3 78-93-3 72.11 Methyl ethyl ketone ND 18 4.3 ppbv ND 53 ug/m3 108-10-1 100.2 Methyl Isobutyl Ketone ND 18 3.3 ppbv ND 74 ug/m3 1634-04-4 88.15 Methyl Tert Butyl Ether 144 18 2.5 ppbv 519 65 ug/m3 80-62-6 100.12 Methylmethacrylate ND 18 3.9 ppbv ND 74 ug/m3 115-07-1 42 Propylene ND 45 6.3 ppbv ND 77 ug/m3 100-42-5 104.1 Styrene ND 18 2.5 ppbv ND 77 ug/m3 71-55-6 133.4 1,1,1-Trichloroethane ND 18 2.0 ppbv ND 98 ug/m3 79-34-5 167.9 1,1,2,2-Tetrachloroethane ND 18 2.7 ppbv ND 120 ug/m3 79-00-5 133.4 1,1,2-Trichloroethane ND 18 2.7 ppbv ND 98 ug/m3 120-82-1 181.5 1,2,4-Trichlorobenzene ND 18 4.6 ppbv ND 130 ug/m3 95-63-6 120.2 1,2,4-Trimethylbenzene 9.6 18 2.2 ppbv J 47 88 ug/m3 108-67-8 120.2 1,3,5-Trimethylbenzene 10.5 18 2.5 ppbv J 51.6 88 ug/m3 540-84-1 114.2 2,2,4-Trimethylpentane ND 18 2.6 ppbv ND 84 ug/m3 75-65-0 74.12 Tertiary Butyl Alcohol ND 18 2.9 ppbv ND 55 ug/m3 127-18-4 165.8 Tetrachloroethylene 980 3.6 2.6 ppbv 6650 24 ug/m3 109-99-9 72.11 Tetrahydrofuran ND 18 4.2 ppbv ND 53 ug/m3 108-88-3 92.14 Toluene 135 18 3.6 ppbv 509 68 ug/m3 79-01-6 131.4 Trichloroethylene 636 3.6 2.9 ppbv 3420 19 ug/m3 75-69-4 137.4 Trichlorofluoromethane 11.7 18 3.8 ppbv J 65.7 100 ug/m3 75-01-4 62.5 Vinyl chloride 230 18 2.9 ppbv 588 46 ug/m3 108-05-4 86 Vinyl Acetate ND 18 5.1 ppbv ND 63 ug/m3 106.2 m,p-xylene 248 18 2.8 ppbv 1080 78 ug/m3 95-47-6 106.2 o-xylene 63.5 18 2.8 ppbv 276 78 ug/m3 1330-20-7 106.2 Xylenes (total) 311 18 2.8 ppbv 1350 78 ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 91% 65-128% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85709 6 of 13

Accutest LabLink@635393 14:06 23-Sep-2011 Report of Analysis Page 1 of 3 2.2 2 Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA85709-2 Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2W32501.D 1.13 09/14/11 YMH n/a n/a V2W1369 Run #2 2W32480.D 22.6 09/13/11 YMH n/a n/a V2W1369 Run #1 Run #2 Initial Volume 50.0 ml 200 ml CAS No. MW Compound Result RL MDL Units Q Result RL Units 67-64-1 58.08 Acetone ND 1.8 0.33 ppbv ND 4.3 ug/m3 106-99-0 54.09 1,3-Butadiene ND 1.8 0.22 ppbv ND 4.0 ug/m3 71-43-2 78.11 Benzene 223 1.8 0.42 ppbv 712 5.8 ug/m3 75-27-4 163.8 Bromodichloromethane ND 1.8 0.27 ppbv ND 12 ug/m3 75-25-2 252.8 Bromoform ND 1.8 0.34 ppbv ND 19 ug/m3 74-83-9 94.94 Bromomethane ND 1.8 0.33 ppbv ND 7.0 ug/m3 593-60-2 106.9 Bromoethene ND 1.8 0.33 ppbv ND 7.9 ug/m3 100-44-7 126 Benzyl Chloride ND 1.8 0.37 ppbv ND 9.3 ug/m3 75-15-0 76.14 Carbon disulfide ND 1.8 0.29 ppbv ND 5.6 ug/m3 108-90-7 112.6 Chlorobenzene 11.7 1.8 0.24 ppbv 53.9 8.3 ug/m3 75-00-3 64.52 Chloroethane 156 1.8 0.35 ppbv 412 4.7 ug/m3 67-66-3 119.4 Chloroform 2.7 1.8 0.25 ppbv 13 8.8 ug/m3 74-87-3 50.49 Chloromethane 4.2 1.8 0.33 ppbv 8.7 3.7 ug/m3 107-05-1 76.53 3-Chloropropene ND 1.8 0.37 ppbv ND 5.6 ug/m3 95-49-8 126.6 2-Chlorotoluene ND 1.8 0.28 ppbv ND 9.3 ug/m3 56-23-5 153.8 Carbon tetrachloride ND 1.8 0.36 ppbv ND 11 ug/m3 110-82-7 84.16 Cyclohexane 137 1.8 0.30 ppbv 472 6.2 ug/m3 75-34-3 98.96 1,1-Dichloroethane 7.9 1.8 0.25 ppbv 32 7.3 ug/m3 75-35-4 96.94 1,1-Dichloroethylene 2.1 1.8 0.42 ppbv 8.3 7.1 ug/m3 106-93-4 187.9 1,2-Dibromoethane ND 1.8 0.25 ppbv ND 14 ug/m3 107-06-2 98.96 1,2-Dichloroethane 8.1 1.8 0.39 ppbv 33 7.3 ug/m3 78-87-5 113 1,2-Dichloropropane ND 1.8 0.35 ppbv ND 8.3 ug/m3 123-91-1 88.12 1,4-Dioxane ND 1.8 0.51 ppbv ND 6.5 ug/m3 75-71-8 120.9 Dichlorodifluoromethane ND 1.8 0.34 ppbv ND 8.9 ug/m3 124-48-1 208.3 Dibromochloromethane ND 1.8 0.24 ppbv ND 15 ug/m3 156-60-5 96.94 trans-1,2-dichloroethylene 26.5 1.8 0.30 ppbv 105 7.1 ug/m3 156-59-2 96.94 cis-1,2-dichloroethylene 382 a 9.0 1.7 ppbv 1510 a 36 ug/m3 10061-01-5 111 cis-1,3-dichloropropene ND 1.8 0.38 ppbv ND 8.2 ug/m3 541-73-1 147 m-dichlorobenzene ND 1.8 0.34 ppbv ND 11 ug/m3 95-50-1 147 o-dichlorobenzene ND 1.8 0.24 ppbv ND 11 ug/m3 106-46-7 147 p-dichlorobenzene 1.1 1.8 0.23 ppbv J 6.6 11 ug/m3 10061-02-6 111 trans-1,3-dichloropropene ND 1.8 0.35 ppbv ND 8.2 ug/m3 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85709 7 of 13

Accutest LabLink@635393 14:06 23-Sep-2011 Report of Analysis Page 2 of 3 2.2 2 Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA85709-2 Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units 64-17-5 46.07 Ethanol 15.3 4.5 0.86 ppbv 28.8 8.5 ug/m3 100-41-4 106.2 Ethylbenzene 11.6 1.8 0.28 ppbv 50.4 7.8 ug/m3 141-78-6 88 Ethyl Acetate ND 1.8 0.55 ppbv ND 6.5 ug/m3 622-96-8 120.2 4-Ethyltoluene 5.1 1.8 0.22 ppbv 25 8.8 ug/m3 76-13-1 187.4 Freon 113 ND 1.8 0.31 ppbv ND 14 ug/m3 76-14-2 170.9 Freon 114 ND 1.8 0.28 ppbv ND 13 ug/m3 142-82-5 100.2 Heptane 6.3 1.8 0.30 ppbv 26 7.4 ug/m3 87-68-3 260.8 Hexachlorobutadiene ND 1.8 0.41 ppbv ND 19 ug/m3 110-54-3 86.17 Hexane 28.6 1.8 0.40 ppbv 101 6.3 ug/m3 591-78-6 100 2-Hexanone ND 1.8 0.39 ppbv ND 7.4 ug/m3 67-63-0 60.1 Isopropyl Alcohol ND 1.8 0.53 ppbv ND 4.4 ug/m3 75-09-2 84.94 Methylene chloride ND 1.8 0.25 ppbv ND 6.3 ug/m3 78-93-3 72.11 Methyl ethyl ketone 5.5 1.8 0.43 ppbv 16 5.3 ug/m3 108-10-1 100.2 Methyl Isobutyl Ketone ND 1.8 0.33 ppbv ND 7.4 ug/m3 1634-04-4 88.15 Methyl Tert Butyl Ether 10.7 1.8 0.25 ppbv 38.6 6.5 ug/m3 80-62-6 100.12 Methylmethacrylate ND 1.8 0.39 ppbv ND 7.4 ug/m3 115-07-1 42 Propylene ND 4.5 0.63 ppbv ND 7.7 ug/m3 100-42-5 104.1 Styrene ND 1.8 0.25 ppbv ND 7.7 ug/m3 71-55-6 133.4 1,1,1-Trichloroethane ND 1.8 0.20 ppbv ND 9.8 ug/m3 79-34-5 167.9 1,1,2,2-Tetrachloroethane ND 1.8 0.27 ppbv ND 12 ug/m3 79-00-5 133.4 1,1,2-Trichloroethane ND 1.8 0.27 ppbv ND 9.8 ug/m3 120-82-1 181.5 1,2,4-Trichlorobenzene ND 1.8 0.46 ppbv ND 13 ug/m3 95-63-6 120.2 1,2,4-Trimethylbenzene 14.7 1.8 0.22 ppbv 72.3 8.8 ug/m3 108-67-8 120.2 1,3,5-Trimethylbenzene 7.4 1.8 0.25 ppbv 36 8.8 ug/m3 540-84-1 114.2 2,2,4-Trimethylpentane ND 1.8 0.26 ppbv ND 8.4 ug/m3 75-65-0 74.12 Tertiary Butyl Alcohol ND 1.8 0.29 ppbv ND 5.5 ug/m3 127-18-4 165.8 Tetrachloroethylene 571 a 1.8 1.3 ppbv 3870 a 12 ug/m3 109-99-9 72.11 Tetrahydrofuran ND 1.8 0.42 ppbv ND 5.3 ug/m3 108-88-3 92.14 Toluene 19.7 1.8 0.36 ppbv 74.2 6.8 ug/m3 79-01-6 131.4 Trichloroethylene 261 0.36 0.29 ppbv 1400 1.9 ug/m3 75-69-4 137.4 Trichlorofluoromethane ND 1.8 0.38 ppbv ND 10 ug/m3 75-01-4 62.5 Vinyl chloride 28.9 1.8 0.29 ppbv 73.9 4.6 ug/m3 108-05-4 86 Vinyl Acetate ND 1.8 0.51 ppbv ND 6.3 ug/m3 106.2 m,p-xylene 46.2 1.8 0.28 ppbv 201 7.8 ug/m3 95-47-6 106.2 o-xylene 13.0 1.8 0.28 ppbv 56.5 7.8 ug/m3 1330-20-7 106.2 Xylenes (total) 59.2 1.8 0.28 ppbv 257 7.8 ug/m3 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 95% 89% 65-128% ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JA85709 8 of 13

Accutest LabLink@635393 14:06 23-Sep-2011 Report of Analysis Page 3 of 3 2.2 2 Client Sample ID: OSS-CAT-OX EFFLUENT Lab Sample ID: JA85709-2 Date Sampled: 09/08/11 Matrix: AIR - Air Summa ID: A896,A568 Date Received: 09/09/11 Method: TO-15 Percent Solids: n/a Project: ExxonMobil Off-Site 31097, Brooklyn, NY CAS No. MW Compound Result RL MDL Units Q Result RL Units (a) Result is from Run# 2 ND = Not detected MDL - Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 9 of 13 JA85709

3 Section 3 New Jersey Accutest LabLink@635393 14:06 23-Sep-2011 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: Chain of Custody Summa Canister and Flow Controller Log 10 of 13 JA85709

3 3.1 JA85709: Chain of Custody Page 1 of 2 11 of 13 JA85709

Accutest Laboratories Sample Receipt Summary Accutest Job Number: JA85709 Client: Date / Time Received: 9/9/2011 No. Coolers: 0 Airbill #'s: Project: Delivery Method: 3.1 Cooler Security 1. Custody Seals Present: 2. Custody Seals Intact: Y or N 3. COC Present: 4. Smpl Dates/Time OK Y or N Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3 Cooler Temperature Y or N 3. Sample container label / COC agree: 1. Temp criteria achieved: 2. Cooler temp verification: 3. Cooler media: Quality Control Preservatio Y or N N/A Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Intact 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: Sample Integrity - Instructions 1. Analysis requested is clear: Y or N N/A 3. Samples preserved properly: 2. Bottles received for unspecified tests 4. VOCs headspace free: 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Comments Accutest Laboratories V:732.329.0200 2235 US Highway 130 F: 732.329.3499 Dayton, New Jersey www/accutest.com JA85709: Chain of Custody Page 2 of 2 12 of 13 JA85709

Summa Canister and Flow Controller Log Page 1 of 1 Job Number: JA85709 Account: ROUXNYI Roux Associates Project: ExxonMobil Off-Site 31097, Brooklyn, NY Received: 09/09/11 3.2 3 SUMMA CANISTERS Shipping Receiving Summa Vac Date SCC SCC Sample Date Vac Pres Final Dil ID L " Hg Out By Batch FileID Number In By " Hg psig psig Fact A816 6 29.4 09/02/11 FZ CP4971 JA85709-1 09/09/11 FZ 0 1 A896 6 29.4 09/02/11 FZ CP4971 JA85709-2 09/09/11 FZ 1 1 Accutest Bottle Order(s): KM-12/29/2011-9 Prep Date Room Temp(F) Bar Pres "Hg 09/02/11 70 29.92 JA85709 13 of 13

ATTACHMENT 2 Photographs of Discharge Points and Receiving Water ROUX ASSOCIATES, INC. MC0172.0030Y027.1817/AT-CV

Photos = 4.25 x 5.67 Photograph 1: Former Brooklyn Terminal RCS outfall and receiving water in September 2011 (SPDES Permit No. NY-0267724, Outfall Number 001) 1 Photograph 2: Former Brooklyn Terminal RCS outfall and receiving water in September 2011 (SPDES Permit No. NY-0267724, Outfall Number 001) ROUX ASSOCIATES, INC. 1 MC0172.0030Y027.1817/AT2

Photograph 3: Off-Site System outfall and receiving water in September 2011 (SPDES Permit No. NY-0267724, Outfall Number 002) 2 Photograph 4: Off-Site System outfall and receiving water in September 2011 (SPDES Permit No. NY-0267724, Outfall Number 002) ROUX ASSOCIATES, INC. 2 MC0172.0030Y027.1817/AT2

ATTACHMENT 3 Discharge Monitoring Report Forms ROUX ASSOCIATES, INC. MC0172.0030Y027.1817/AT-CV