Report No.: J-123456 Date: March 1, 2016 P.O. No.: PO 1234A GC/MS Analysis Laboratory Report Prepared for: Mr. Customer Name Company Name, Inc. 123 First St. Your City, State Prepared by: Bradley J. Cline Scientist I Chemical Analysis Group
Introduction This report summarizes the analysis of * samples submitted by * of Company Name, Inc. The samples consisted of.and analyzed by GC/MS Headspace. The purpose of the analysis was to determine if contaminants will be off-gassed during bake. The headspace oven temperature was set to 250 o C with one hour equilibration, per Mr. Customer name s request. Sample Preparation A portion of the sample was transferred with forceps to a tared 20 ml headspace vial, then weighed and sealed with a High Performance septum. The mass of sample * analyzed was *** g and the mass of sample ** analyzed was ***g. Analytical Conditions Instrument: Agilent 7697A Headspace Autosampler coupled to an Agilent 7890A GC/ 5975C Mass Spectrometer operated in negative EI mode. Helium carrier gas is used for all systems. Headspace analysis was performed with an oven temperature of 250 o C with 60 minutes equilibration. MS scan range was 35 to 550 amu. The lower MS scan range is set to 35 amu in order to avoid interferences from atmospheric air, including (N2 Nitrogen (m/z 28), O2 Oxygen (m/z 32), moisture (m/z 18), etc). Due to the lower MS scan range, components with m/z <35 are not detected (including methanol, formaldehyde, etc). Results The ten major compounds detected during the analysis are summarized on page 3. Concentrations are based on relative area percentages. Units reported are Relative %/gram, which is the relative % concentration as compared to other components detected, divided by the mass of sample analyzed. As such, results are semi-quantitative only and should be considered rough estimates. The tentatively identified compounds listed are those which can be identified with a high degree of certainty. Any unknowns listed are those which cannot be identified with a certainty of >80%. In some instances compounds are tentatively identified with <80% certainty. Those identifications should be considered less confident due to low concentration and background interferences, but were identified based on analyst experience. Chromatograms of the Control Blank and samples, and overlays of any detected discrepancies, are included on pages 4 through 6. 2
GC/MS Analysis Tentatively Identified Compounds Client Name: Company Name, Inc. ORS Project Number: J-123456 Client Sample ID: Sample 1 Lot12345 ORS Sample ID: J123456-1 Date Received: 2/8/2012 Date Analyzed: 2/9/2012 Analysis Method: ( Headspace, Direct Injection, Ampulization) Headspace D.I. Solvent:(if applicable) NA Ampulized in:(vacuum, Nitrogen, Air) NA Sample wt/vol: 0.0460 g Date Prepared: 2/9/2012 Prepared By: BJC Ampule Pre-bake:(if applicable) Temp: NA o C Time: NA Headspace parameters:(if applicable) Oven temp: 250 o C Equilib time: 1 Hour Number TICS found: 51 Result Units: Relative %/ gram Tentatively Identified Compounds Ret. Time Compound Name CAS # Est. Conc. Q Value 1.78 coelution of Acrolein and Acetone 107-02-8/67-64-1 265.6 94/35 2.04 Allyl Alcohol 107-18-6 28.4 86 2.34 Acetic Acid * 64-19-7 130.2 86 3.53 Unknown HC NA 8.87 NA 3.78 Unknown HC (possibly Methyl Cellosolve Acetate) 110-49-6 11.3 NA 5.27 Methyl Isobutyl Ketone 108-10-1 21.5 82 12.45 2-methyl-p-Benzoquinone 553-97-9 74.3 93 13.62 -Cresol (isomer) NA 16.5 NA 19.63 coelution of Alkane and unknown HC NA 30.8 NA 21.58 Hexamethylcyclotrisiloxane 541-05-9 59.9 93 NA = Not Applicable HC = Hydrocarbon * Compound also detected in Control Blank at lower concentration. 3
A b u n d a n c e 2. 5 e + 0 7 T I C : 0 2 1 5 0 5. D \ d a t a. m s 2. 4 e + 0 7 2. 3 e + 0 7 2. 2 e + 0 7 2. 1 e + 0 7 2 e + 0 7 1. 9 e + 0 7 1. 8 e + 0 7 1. 7 e + 0 7 1. 6 e + 0 7 1. 5 e + 0 7 1. 4 e + 0 7 1. 3 e + 0 7 1. 2 e + 0 7 1. 1 e + 0 7 1 e + 0 7 9 0 0 0 0 0 0 8 0 0 0 0 0 0 7 0 0 0 0 0 0 6 0 0 0 0 0 0 5 0 0 0 0 0 0 T i m e - - > 5. 0 0 1 0. 0 0 1 5. 0 0 2 0. 0 0 2 5. 0 0 3 0. 0 0 Figure 1: Chromatogram of Control Blank. Peak at 1.4 minutes is room air. A b u n d a n c e T I C : 0 2 1 5 0 5. D \ d a t a. m s 1 3 0 0 0 0 0 1 2 0 0 0 0 0 1 1 0 0 0 0 0 9 0 0 0 0 0 8 0 0 0 0 0 7 0 0 0 0 0 6 0 0 0 0 0 5 0 0 0 0 0 4 0 0 0 0 0 3 0 0 0 0 0 2 0 0 0 0 0 T im e - - > 1 0 0 0 0 0 5. 0 0 1 0. 0 0 1 5. 0 0 2 0. 0 0 2 5. 0 0 3 0. 0 0 Figure 2: Control Blank chromatogram magnified for definition. Extraneous peaks are chromatographic artifacts that are not of interest and not included in sample results. 4
A b u n d a n c e 2. 4 e + 0 7 T I C : 0 2 1 5 0 6. D \ d a t a. m s 2. 3 e + 0 7 2. 2 e + 0 7 2. 1 e + 0 7 2 e + 0 7 1. 9 e + 0 7 1. 8 e + 0 7 1. 7 e + 0 7 1. 6 e + 0 7 1. 5 e + 0 7 1. 4 e + 0 7 1. 3 e + 0 7 1. 2 e + 0 7 1. 1 e + 0 7 1 e + 0 7 9 0 0 0 0 0 0 8 0 0 0 0 0 0 7 0 0 0 0 0 0 6 0 0 0 0 0 0 5 0 0 0 0 0 0 T i m e - - > 5. 0 0 1 0. 0 0 1 5. 0 0 2 0. 0 0 2 5. 0 0 3 0. 0 0 Figure 3: Chromatogram of sample J123456-1, client ID Sample 1 Lot 12345. A b u n d a n c e 1. 2 e + 0 7 T I C : 0 2 1 5 0 6. D \ d a t a. m s T I C : 0 2 1 5 0 5. D \ d a t a. m s ( * ) 1. 1 5 e + 0 7 1. 1 e + 0 7 1. 0 5 e + 0 7 1 e + 0 7 9 5 0 0 0 0 0 9 0 0 0 0 0 0 8 5 0 0 0 0 0 8 0 0 0 0 0 0 7 5 0 0 0 0 0 7 0 0 0 0 0 0 6 5 0 0 0 0 0 6 0 0 0 0 0 0 5 5 0 0 0 0 0 5 0 0 0 0 0 0 4 5 0 0 0 0 0 3 5 0 0 0 0 0 2 5 0 0 0 0 0 1 5 0 0 0 0 0 5 0 0 0 0 0 0 1. 5 0 2. 0 0 2. 5 0 3. 0 0 3. 5 0 4. 0 0 4. 5 0 5. 0 0 T i m e - - > Figure 4: Magnified overlay of chromatograms for Control Blank (blue ink) and Sample 1 Lot 12345 (black ink) from 1.0 to 5.0 minutes indicating multiple components detected. 5
A b u n d a n c e 4 4. 0 S c a n 2 4 9 (1. 5 5 2 m in ): 0 2 0 9 0 7. D \ d a t a. m s (-2 4 2 ) (-) 3 5 0 0 0 0 0 2 5 0 0 0 0 0 1 5 0 0 0 0 0 5 0 0 0 0 0 m / z --> 0 7 4. 0 1 0 6. 2 1 5 4. 1 1 8 5. 9 2 1 5. 8 2 4 8. 8 2 8 3. 1 3 1 0. 9 3 4 4. 4 4 3 1. 0 40 60 80 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0 2 2 0 2 4 0 2 6 0 2 8 0 3 0 0 3 2 0 3 4 0 3 6 0 3 8 0 4 0 0 4 2 0 Figure 5: Mass spectrum of Sample 1 Lot 12345 peak at 1.55 minutes indicating Acetaldehyde. Abundanc e 1000000 T IC: 021506.D \ data.ms T IC: 021505.D \ data.ms (*) 900000 800000 700000 600000 500000 400000 300000 200000 100000 T ime--> 0 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 Figure 6: Magnified overlay of chromatograms for Control Blank (blue ink) and Sample 1 Lot 12345 (black ink) from 5.0 to 15.0 minutes indicating multiple components detected. 6