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Transcription:

Water Properties

Properties of Water Solid water floats on liquid water High surface tension Universal solvent High specific heat High heat of vaporization

Solid, Liquid, Gas http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp_files/frame.htm

Water Molecule Bent molecule Covalent bonds Polar Dissolves ionic substances

In liquid phase, the water molecules fit closely together Liquid water molecules Polar nature allows them to attract one another Most dense at 4 C http://www.chemlin.net/news/2007/mar2007/water.htm

Liquid id Water H 2 O(l) Water http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp_files/frame.htm

High Surface Tension http://www.webelements.com/nexus/node/786 http://quest.nasa.gov/space/teachers/microgravity/6surf.html

Dissolution of ionic substance

Water Molecule Bent Polar

Solid Ice H 2 O(s) Ice http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp_files/frame.htm

Molecular Structure of Ice Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 455 http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp files/frame.htm

Water Expansion Molecule shape fit together closer in liquid Open structured crystal due to hydrogen bonding of polar molecules upon freezing

Crystal structure of ice In solid phase of water, arrangement becomes more open, less dense Ice floats because of this Expansion of 9% upon freezing http://www.its.caltech.edu/~atomic/snowcrystals/primer/primer.htm

Three phases of water http://www.cdli.ca/cite/glaciers.htm

Three Phases of Water at Liquid Earth s Surface Solid Vapor Energy captured or released upon change from one phase to another

Gas Steam H 2 O(g) Steam http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp_files/frame.htm

Gas, Solid and Liquid Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 441 http://www.unit5.org/christjs/matter%20and%20energy/unit%202%20pp_files/frame.htm

Water phases and molecules

Evaporation Kinetic energy of molecules great enough to escape surface Energy is taken from liquid cools it Gaseous phase or vapor phase

http://en.wikipedia.org/wiki/water_vapor Water vapor

Evaporation or Not http://www.geology.sdsu.edu/classes/geol351/01watercycle/watercyclefigs.htm Air inside glass become saturated with water and no more water can evaporate from the surface Outside glass is open system that is not saturated

http://www.chem.purdue.edu/gchelp/liquids/boil2.html Boiling

Boiling http://www.deepseaimages.com/dsilibrary/showphoto.php?photo=2912&password=&sort=1&size=medium&cat=853&page=1

http://www.chem.purdue.edu/gchelp/liquids/boil2.html Microscopic boiling

Boiling Temperature For any given pressure, there is a temperature at which water boils The temperature of the water remains at that temperature until all of the water has been changed from liquid to vapor The length of time for this to occur does not have an effect on this temperature

Boiling Temp vs.pressure http://www.chem.purdue.edu/gchelp/liquids/boil2.html

Pressure Cooker http://www.goodmans.net/get_item_ma-6qt_maitres-806212-6-qt-cooker.htm

http://hgic.clemson.edu/factsheets/hgic3020.htm Pressure canner

Boiling at less than 100 o C Pour in hot water Reduce Pressure with syringe http://www.micrecol.de/air2.html

Condensation Opposite of evaporation Kinetic energy of molecules running into surface of liquid and joining it Heats environment

Condensation on Glass http://www.geology.sdsu.edu/classes/geol351/01watercycle/watercyclefigs.htm

Atmosphere Evaporation Energy goes into air Cools remaining water Condensation Energy goes from air to surface Warms local environment

Atmosphere Warm air has greater capacity for holding water in the vapor phase Saturation = at capacity Relative Humidity percent t of water contained compared to saturated amount at that temperature

Water Vapor Capacity http://www.wdtv.com/weather/images/weather_review/humidity.htm

Condensation http://observe.arc.nasa.gov/nasa/earth/hydrocycle/graphics/condensation.jpg

Condensation diagram http://weatherstreet.com/weatherquestions/what_is_condensation.htm

http://www.anythingmarine.co.uk/anything/met.htm Sea Fog

http://www.victoriaweather.ca/clouds.php?image=fog Coastal fog

Energy of Water Phase Change Calorie: energy to change 1 g water 1 K or 1 o C Also need energy to change to different state of matter Energy of vaporization/condensation 540 calories per gram of water = 2256 J/g Energy of melting/freezing 80 calories per gram= 334 J/g

Measure of hotness Celsius Temperature 0 o freezing point of pure water at standard pressure 100 o boiling point at standard pressure Fahrenheit 0 o was lowest attained 32 was his age when he performed experiments 212 is boiling point in those increments

Temperature Convert with equations C = Order of operations (F -32) Parentheses first Then multiply or divide Add or subtract last Or use adjacent scales such as p. 142 of Conceptual Physical Science textbook 5 9 9 F = C + 32 5

Temperature Kelvin same size as degree Celsius Absolute Zero is 0 K (notice no degree symbol on K) 0 o C = 273 K Molecular motion ceases at absolute zero