Semiconductors & LEDs

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Semiconductors & LEDs Day 37, Phys 2130 Questions? Semiconductors &LEDs Next up: EPR, Entanglement, Bell, Bound State Sim.. Many Wells 2 1

In solid, `10 22 atoms/cm 3, many!! electrons, and levels countless levels smeared together, individual levels indistinguishable. "bands" of levels. Each level filled with 2 electrons until run out. conduction band band gap ~ few ev Energy atom level 3 2 1 more atoms filled with electrons filled with electrons bands valence band 3 conductor- levels very close insulator- big jump to empties. ENERGY gap- no ALLOWED levels electron like ball rolling on almost flat ground electron like in pit. move easily Stuck. Can t move without big boost. semiconductor-- half way in between. Little gap to levels, shallow pit. 2

+ + + + + 4/13/16 LEDs -- don t burn out, high efficiency. Stoplights, bike lights, fancy flashlights. Really good LEDs reach laser conditions-- diode lasers p-doped n-doped -- -- -- -- -- http://www.howstuffworks.com/index.htm Insulators and conductors Good in wires, electricity for lights and heating, electric motors, telegraph (I=V/R stuff). For more interesting electrical stuff need more controlsmall currents &voltages control higher powers ( nonlinear circuit elements ). Semiconductor-- half way in between. Little gap to levels. how many have class on semicond? sensitive enough so people can affect conductivity of material What are possible ways could get electron to higher level (out of pit), so could move to conduct electricity? Discuss as many as can think of that are practical. n.b. Applying a voltage across (battery) will not work why? Think about voltage /electron. (how much V how many e s?) 3

Change conductivity of semiconductors by: 1) light, 2) heat 3) (most important) designer dirt doping basis of diodes and transistors (all electronics) diodes- pass current in only one direction. junction of P doped and N doped semiconductors. (also light emitting diodes LEDs, diode lasers-pointer). Analogy: turn-style for current. transistors- use voltage (low power) to control large currents and voltages. Analogy: valve for current PhET conductivity sim on phet site (also semiconductor and diode sim there) https://phet.colorado.edu/en/simulation/conductivity http://phet.colorado.edu/en/simulation/semiconductor 4

Diodes and transistors -Junctions of P doped and N doped semiconductors. pure Si semiconductor p type semicond. Si + 10-7 boron fr/ B atoms Si, 4 electrons in valence band, n type semicond Si + 10-7 Phosphorus B, 3 electrons into valence band, leave one level/atom unfilled, 10-7 fraction P, 4 electrons go into valence band, 1 extra up into conduction How conduct? a) all ~same b) pure best, c) pure no, P and N ~same, d) only N conducts, e) only P cond. n type semiconductor p type semiconductor Si + tiny fraction Phosphorus n- electrons in conduction (top) band can move. p- electrons at top of valence band move into levels. ans. c. n and p type both conduct ok (not great), pure Si does not conduct. See phet sim. DOPING--EXTRA OR MISSING FREE/MOVEABLE ELECTONS, IS NOT(!) EXTRA TOTAL CHARGE. ATOMS ARE ALSO EXTRA OR MISSING PROTONS! TYPICALLY BOOKS (AND THESE NOTES) JUST SHOW MOVEABLE ELECTRONS! Have to pay careful attention to keep straight moveable electrons vs. net charge,but distinction is important. Take some notes to refer to later in class. 5

n type semiconductor p type semiconductor Si + tiny fraction Phosphorus n and p type both conduct ok (not great) Si + tiny fraction Boron n- electrons in conduction (top) p- electrons at top of valence (lower) band band can move. can move into levels. DOPING--EXTRA OR MISSING FREE ELECTONS, NOT(!) EXTRA CHARGE. ARE ALSO EXTRA OR MISSING PROTONS! Book leaves out!! pure, no flow when tilt n, water in top flow p, water in bottom flows, but if small bubble, see it. Doped semiconductors, add or subtract some charges to allow charges to move. N type- atoms with extra free electrons - - - - - - - - - - I e e e e e e e e in nearly band move easily + V _ lower level DOPING--EXTRA OR MISSING FREE ELECTONS, NOT(!) EXTRA CHARGE. IS ALSO EXTRA OR MISSING PROTONS! Book leaves out!!! + + + + + + ++ + + I + V _ electrons missing, holes, leave room to move easily 6

When semiconductors get really useful-- P and N types stuck together. Diodes (& LEDs) - PN junctions. Transistors- PNP or NPN junctions p-type P- N junction- put together + + + + - - - - - + + + + - - - - - n type diode conducting p type n type E As electron moves across junction going from N type on right to P type on left a. it stays at the same energy b. it gains potential energy (if so from where?) c. it loses potential energy (if so to where?) c. loses potential energy- goes into 1) heat (vibrating atoms) or 2) if proper materials, light ( light emitting diode) 7

+ + + + + 4/13/16 LEDs -- don t burn out, high efficiency. Stoplights, bike lights, fancy flashlights. Really good LEDs reach laser conditions-- diode lasers p-doped n-doped -- -- -- -- -- http://www.howstuffworks.com/index.htm insulator + + + + + + + + + + + + - - - - - - - - V control control electrode (gate) + + + + + + + + + + + P-N-P doped semicond. P type transistor(?!) transistors- have two NP junctions NPN or PNP sandwiches-- double depletion region. Plus have gate electrode to control depletion region. Control voltage sucks in or pushes out moveable electrons from depletion region. Controls whether current can flow or not. Just FYI: not responsible for HW /exams 8

Transistor like plunger valve on spring that blocks flow of water as the block moves in and out. Positive voltage applied is like pulling plunger back, big current, Zero voltage lets plunger block flow, no current. water flow +++ +++ Little push of valve in or out changes big volume of water (current) that flows. voltage Lots of excess off, NO + excess charges + charges, on gate (voltage) plunger closes, current plunger off out, current on. Transistor RESISTANCE Transistor RESISTANCE IS LARGE. (behaving IS SMALL. like insulator now) Prelude to Long Answer What does it take to: - Change the current? - Change the brightness? (how?) - Change the color? (How?) 9

The Farmer and the Seeds (a parable of scientific reasoning) A seed is a square with some dots on it. The farmer always plants 4 seeds in a group. First Group: Second Group: Farmer observes # of sprouts each group produces. The Farmer and the Seeds Possible Schemes 1. Totally Random (Numbers aren t related to # of sprouts) 2. (Largest Number) = (# of Sprouts) 3. (Number that is even) = (# of Sprouts) 4. (Second Largest Number) + (Smallest Number) = (# of Sprouts) 5. [(Sum of all Numbers) 3] / 2 = (# of Sprouts) 10

The Farmer and the Seeds Another seed grouping the farmer tried: What is the prediction of each of the different schemes the class has come up with for this seed grouping? Another seed grouping the farmer tried: 2 sprouts! Possible Schemes 1. Totally Random (???) 2. (Largest Number) = 3 Sprouts 3. (Number that is even) = 2 Sprouts 4. (Second Largest Number) + (Smallest Number) = 3 Sprouts 5. [(Sum of all Numbers) 3] / 2 = 2 Sprouts 11

Questions from this story: Possible Schemes 1. Totally Random (???) 2. (Number that is even) = 2 Sprouts 3. [(Sum of all Numbers) 3] / 2 = 2 Sprouts 1. How could we decide if any of these three schemes is the correct one? 2. If the farmer had to wait to plant more seeds, are there reasons we might in the meantime favor one scheme over another? 3. How do we know if we ve figured out all the possible schemes? 4. Where did these schemes we ve been discussing come from? (Note: This question is not about the elements of the schemes, but the decisions as to what elements to use and how to use them.) A MODEL 12

COMPETING THEORIES EVEN NUMBER THEORY OF SPROUTS & SEEDS (# OF SPROUTS) = 2 SPROUTS 2 sprouts! COMPLEX THEORY OF SEEDS & SPROUTS (# OF SPROUTS) = [(1 + 1 + 2 + 3) - 3] / 2 = 2 SPROUTS constrained by observa^on INTERPRETATION Why even? EVEN NUMBER THEORY OF SPROUTS & SEEDS (# OF SPROUTS) = 2 SPROUTS 2 sprouts! What does combining these numbers physically represent? COMPLEX THEORY OF SEEDS & SPROUTS (# OF SPROUTS) = [(1 + 1 + 2 + 3) - 3] / 2 = 2 SPROUTS Why subtract 3? 13

Summary Scientists make up theories to explain the evidence they see. These theories are constrained by experiment. We can t always open up the seed and look inside. Have to make inferences from indirect evidence. A theory with a plausible mechanism is more convincing than a rote algorithm. The more different cases our theory works on, the more we believe it. But it could always be wrong 14