Titan s Atomic and Molecular Nitrogen Tori

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s Atomic and Molecular Nitrogen Tori H.T. Smith a, R.E. Johnson a, V.I. Shematovich b a Materials Science and Engineering, University of Virginia, Charlottesville, VA 9 USA b Institute of Astronomy, RAS, Moscow, RUSSIA

Abstract Shematovich et al. (3), recently showed plasma induced sputtering in s atmosphere is a source of neutral nitrogen in s magnetosphere comparable to the photo-dissociation source. These sources form a toroidal nitrogen cloud roughly centered at s orbital radius but gravitationally bound to. Once ionized, these particles contribute to s plasma. When is inside s magnetopause, newly formed ions can diffuse inward becoming inner magnetospheric energetic nitrogen where they can sputter and be implanted into icy satellite surfaces. Our 3-D simulation produces the first consistent generated N and N neutral clouds; solar UV radiation and magnetospheric plasma subject these particles to dissociation and ionization. The cloud morphologies and associated nitrogen plasma source rates are predicted in anticipation of Cassini data. Since the amount of molecular nitrogen ejected from by photo-dissociation is small, molecular nitrogen ion detection by Cassini will be an indicator of atmospheric sputtering. 1. Introduction Beyond s five inner icy satellites lies, its largest satellite. Pioneer 11, Voyager 1 &, Earth based observations and more recently, Hubble Space Telescope (HST) observations contributed much of our limited knowledge about the magnetosphere between and. In the vicinity of the icy satellites, neutral atoms and molecules dominate the magnetosphere with only about 1% of these particles present as ions (Richardson 199). However, we know little about the magnetosphere composition at s orbit. Because s magnetic field rotates on an axis approximately aligned with planetary rotation, the thermal plasma efficiently interacts with the neutrals at average relative velocities varying with distance from the planet. Since lacks a magnetic field, these plasma particles can also penetrate its dense N atmosphere and eject neutrals into the magnetosphere, a process often referred to as atmospheric sputtering (Johnson 199). Initial estimates from Voyager observations placed the generated N source rate at 3 x 1 N/s (Strobel and Shemansky 19). Later, Strobel et al (199) estimated that electron (magnetospheric and photo) impact and photodissociation produced less than or equal to 1 5 N/s. Using a 1-D Monte Carlo simulation and the pickup ions flux from Brecht et al. (), Shematovich et. al. (3), calculated an atmospheric sputtering source rate at approximately x 1 5 N/s, which is comparable to the photo- and electron impact dissociation source. Michael et al () using a 3-D Monte Carlo model with improved cross sections obtained a slightly higher loss rate. In spite of the considerable uncertainties in these calculations, it is possible to conclude provides a significant source of both atomic and molecular nitrogen forming a neutral torus in s magnetosphere. Electron impact, charge exchange and UV photons subsequently ionize these neutrals. Some of these ions diffuse inward toward providing a hot nitrogen source for implantation into the surfaces of the icy satellites (Sittler et al. ). Therefore, Cassini s plasma instruments will also search for nitrogen containing molecules ejected from the icy satellites surfaces. We describe here a 3-D Monte Carlo simulation that calculates the density of the N and N neutral clouds. We optimized the model to provide efficient execution over many years. Principal outputs are the neutral N and N cloud topography and the spatial distribution of the freshly produced atomic and molecular nitrogen ions. The UV instrument and the energetic neutral imaging on Cassini might detect these neutrals and the Cassini Plasma Science instrument (CAPS) will directly detect freshly ionized nitrogen. Our model can readily accommodate new data as it becomes available. Although the model

does not assume azimuthal symmetry, until Cassini plasma data is available we will use azimuthally symmetric ionization rates.. Model Description loses atmosphere through Jeans escape; photo- and electron-impact dissociation; ionization and sweeping, and atmospheric sputtering. Whereas ionization and sweeping is a direct source of molecular ions for s magnetosphere, the other processes produce neutrals. Jean s escape primarily yields molecular hydrogen, dissociation produces atomic N and H, and atmospheric sputtering produces atomic and molecular neutrals, primarily N and N. Here we model the neutral nitrogen atoms and molecules ejected from. Our model has two main components. The satellite model replicates the environment close to s exobase and the model reproduces the torus around. The satellite model produces high-resolution results within the Hill sphere and provides input to the model, which generates particle densities for the entire neutral cloud. This separation will allow us to make the best use of the expected Cassini data at and in the torus. We designed the model for rapid execution over relatively large time periods and we account for neutrals reabsorbed by. The simulations are initiated using nitrogen source fluxes from (Michael et. al., ; Shematovich et al., 3), ejected by ion and photon bombardment of its upper atmosphere. In the satellite model, N and N are ejected in a centered inertial reference frame. Although the model is 3-D, we use isotropic ejection from until the plasma flow onto the exobase is better defined. We compare these to results using the standard atmospheric sputtering distribution (Johnson 199): (1) F( E) = U ( E + U ) where U is the escape energy from s exobase (~.3 ev for N and ~. ev for N ). We characterize the nitrogen atoms and molecules escaping from using the N and N energy spectra in Fig.1 in combination with the source rates in Table 1. Michael et al. () generated the pick-up ion source using energetic N to represent molecular pick-up ions such as N +, C H 5 + etc. We used the photon-induced source from Shematovich et al. (3). The model ejects N and N particles from s exobase and propagates their trajectories until they exceed s Hill Sphere. At this point the satellite model transfers particles to the model. These particle trajectories are then propagated within the model until they impact, a satellite or the main rings, escape from or become ionized. 3. Results Particle lifetimes and the initial energy distribution of particles escaping from primarily determine neutral cloud densities. We used the same set of photo and electron impact cross sections

used in Shematovich et. al. (3) and charge exchange cross-sections are from our database (http://www.people.virginia.edu/rej/cross_section). We then applied these cross sections to two radial distributions of the plasma in s magnetosphere. The solid lines shown in Figs. a and b apply when lies within s magnetosphere, representing lifetimes derived from Richardson and Sittler (199) and Voyager data. Fig. a also shows the average lifetime used by Barbosa (197) at s orbit. When we conservatively extrapolated the lifetimes beyond 1 Rs with photon-induced lifetimes dominating at s orbit (as shown by the dotted lines in Figs. a and b). This gives an approximate lower bound to the ionization and dissociation rates and can roughly represent periods when is outside of the magnetosphere. Fig. 3 shows the N and N densities based on the solid line lifetimes in Figs. a & b and the energy distributions in Fig. 1. The N cloud includes dissociated N products. This combination of short lifetimes and energetic nitrogen results in the lowest densities. Approximately 7% of the N and 7% of the N escape beyond 5 radii and therefore do not contribute significantly to the nitrogen cloud s morphology. In addition, reabsorbs a few percent. To examine the initial energy s effect on cloud density distribution, we also used the standard energy distribution in Fig. 1 and the longer lifetimes (dotted lines) in Figs. a and b to create a rough upper bound to the nitrogen densities. Fig. shows the resulting neutral cloud densities. These are noticeably increased as only 3% of the N and 3% of the N escape beyond 5 radii. These simulations give a neutral cloud with a significantly different morphology from the simple model of Barbosa (197). Barbosa s estimated cloud extends inward to Radii (Rs) while ours extends several Rs closer to and his cloud thickness is -1 Rs while ours is much less than Rs. Additionally, Barbosa estimates an average nitrogen density of /cm 3, but our average density is lower. Although he assumed a much larger vertical scale, his assumed source rate is over an order of magnitude larger, leading to higher densities. Ip (199) also predicted higher densities (3 /cm 3 ) near. He also assumed an order of magnitude higher source rate. In both of the simulations presented here, the nitrogen clouds extend inward towards and therefore are a source of fresh nitrogen ions in inner magnetosphere as well as in the outer magnetosphere. Fig.5 gives the source rate of fresh atomic and molecular nitrogen ions for the clouds in Fig. 3. Nitrogen is ionized faster in the inner magnetosphere so in this model the N + source rate peaks in this region despite the smaller neutral particle density. Finally, our results show in the vicinity of s orbital radius, the neutral nitrogen density is larger than the Voyager-based ion density as is the case in the inner magnetosphere (Richardson et al. 199). However, both the nitrogen ion densities and our model for the neutrals are based on a number of assumptions and extrapolations which we will update as Cassini data becomes available.. Conclusions In this paper we calculated the neutral tori at generated by N and N escaping from. The cloud density and morphology, and the spatial distribution of the nitrogen ions produced are given in anticipation of Cassini. These results can be scaled, as better source rates are determined. The tori are centered on and extend into the inner magnetosphere, with most of the density remaining close to the orbital plane. Our initial results indicate that neutral nitrogen may dominate the nitrogen

ion population near s orbital radius. The initial nitrogen energy distribution noticeably affects the cloud morphology and density. Relatively small increases in this energy distribution can cause many more particles to escape from since is more than Rs from in a region of relatively weak gravitational attraction. At this distance, the total escape energy from is only.3 ev for N and. ev for N. Therefore, Cassini measurements of the morphology will help constrain models of the plasma interaction with. Since is not always within s magnetopause, we used ionization and dissociation rates that roughly bracket the times when it is inside and outside the magnetosphere. However, care must be taken, because even when lies outside of the magnetopause on the dayside, it will re-enter the magnetosphere before reaching the night side. Because each orbit is approximately sixteen days but the lifetimes are such that steady state requires a number of years of simulation, one would need to average these cases for the fraction of the time spent outside of the magnetopause. When Cassini data is available, we will use 3-D ionization rates to generate a correct time-varying model that allows for azimuthal asymmetry and varies over the solar cycle. We have also given ion source rates for one case. It is seen, surprisingly, that there is a small secondary peak in the nitrogen ion formation rate at smaller distance from caused by centrifugal confinement and higher ionization rates in this region. Although the H source rate is higher than either N or N, the heavier nitrogen ions are of interest to us because of their potential impact on inner magnetospheric objects. The nitrogen ions that diffuse inward become energized and can be implanted in and sputter these moons (Sittler et al. ), ultimately driving nitrogen chemistry (Delitsky and Lane ). Because atmospheric sputtering is a significant source of N as well as N, but photo-dissociation is not, detection of freshly produced N + ions in s torus by the Cassini plasma science instrument (CAPS) can determine the relative importance of atmospheric sputtering and the nature of the plasma/atmosphere interaction. Acknowledgements This work is supported by NASA s Planetary Atmospheres Program, the NASA Graduate Student Research Program, the Virginia Space Grant Consortium Graduate Research Fellowship program and the CAPS Cassini instrument team.. References Barbosa, D.D. (197), s Atomic Nitrogen Torus: Inferred Properties and Consequences for the ian Aurora. Icarus. 7, 531. Brecht, S. H., J. G. Luhmann and D. J. Larson (), Simulation of the ian magnetospheric interaction with, J. Geophys. Res., 15, 13,119-13,13. Delitsky, M. L. and A. L. Lane (), s inner satellites: Ice chemistry and magnetospheric effects, J. Geophys. Res., 17(E11), 593. Eviatar, A. (19), Plasma in s Magnetosphere. J. Geophys. Res. 9, 31-3. Ip, W.-H. (199), Nitrogen tori of and Triton. Adv. Space Res.1 (), 73. Johnson, R.E. (199), Plasma-induced sputtering of an atmosphere, Space Science Reviews, 9, 15-53. Johnson, R E. (199), Energetic Charged Particle Interactions with Atmospheres and Surfaces. Springer-Verlag, NY.

Johnson, R. E., and Sittler, E. C. (199), Sputter-produced Plasma as a Measure of Satellite Surface Composition: Cassini Mission Geophys. Res. Letts. 17, 19-13. Michael, M., R.E. Johnson, F. Leblanc, M. Liu, J.G. Luhmann, V. I. Shematovich (), Ejection of Nitrogen from s Atmosphere by Magnetospheric Ions and Pick-up Ions. Submitted to Icarus. Richardson, J.D. (199), Thermal Plasma and Neutral Gas in s Magnetosphere, Rev of Geophys. 3, 51-5. Richardson, J.D., and E.C. Sittler, Jr. (199), A Plasma Density Model for Based on Voyager Observations, J. Geophys. Res., 95, 1,19-1,31. Shematovich, V.I., Johnson, R.E., Michael, M. and Luhmann (3), J.G. Nitrogen Loss Form, 1, 57, DOI: 1.19/3JE9. Sittler, E.C., Jr., K.W. Ogilvie, and J.D. Scodder (193), Survey of Low-Energy Plasma Electrons in s Magnetosphere: Voyagers 1 and, J. Geophys. Res.,, 77. Strobel, D.F. and Shemansky, D.E., EUV Emissions from s Upper Atmosphere: Voyager 1 Encounter. J. Geophys. Res. 7, 131, 19. Strobel, D.F., Summers, M.E. and Zhu, X., s Upper Atmosphere: Structure and Ultraviolet Emissions. Icarus 1, 51, 199. Table 1. Source rates for nitrogen escaping from for all modeled processes Ejection Process Source Rate (particles / second) N from N +(1).5E+ +(1) N from N 1.15E+5 N from N +(1) 1.E+ +(1) N from N.1E+ N from hv ().93E+5 Total 3.55E+5 (1) Michael et al. ; () Shematovich et al. (3) Figure Captions Normalized Distribution 1.E+ 1.E-1 1.E- N (from N+) N (from N+) N (from N+) N (from N+) N (from Photons) (U/(E+U)^) 1.E-3 9 13 17 31 35 39 Particle Energy (E) / Escape Energy (U)

Figure 1. Normalized energy distributions for atomic and molecular nitrogen escaping from vs. E/U (U=.3eV for N and. ev for N ) (Shematovich et al. 3; Michael et al. ). Thin solid line: standard atmospheric sputtering distribution (Johnson 199). (a) (b) 1.E+9 N Lifetimes 1.E+9 N Lifetimes Lifetime (s) 1.E+ 1.E+7 Lifetime (s) 1.E+ 1.E+7 1.E+ 1 1 1 1 1 Distance from (Rs) 1.E+ 1 1 1 1 1 Distance from (Rs) Figure. Total lifetimes for N (a) and N (b) vs. distance from in Rs. Solid line: based on Richardson and Sittler (199) and Voyager data, approximates periods when is inside s magnetopause; Dotted line: beyond ~1Rs used a conservative extrapolation so that photo processes dominate at s orbit, which would be the case when is outside s magnetopause. Thick lines (b) for ionization and thin lines (b) for dissociation. Diamond: lifetime (a) used by Barbosa (197). (a) (b) NDensity (/cm 3 ).1..1..31.39 5 1 15 5 N Density (/cm 3 ).1...11.15.1 5 1 15 5 Figure 3 Atomic (a) and molecular (b) nitrogen densities using lifetimes from solid curves in Fig.a and b. A -D vertical slice of the 3-dimensional torus in particles per cm 3. is on the left; position of s orbit indicated by dashed line. (a) (b)

NDensity (/cm 3 ).1 1.9.5 3. 5.15.3 5 1 15 5 N Density (/cm 3 ).1.11.1.31..5 5 1 15 5 Figure. Atomic (a) and molecular (b) nitrogen densities generated when the conservative ionization and dissociation rates are used (dotted curves in Fig.a and b): as in Fig.3 (a) (b) N+ Source (/cm 3 second).3e-1 1.1E.1E 5 1 15 5 N+ Source (/cm 3 second) 1.E-1 1.E-9.3E-9 5 1 15 5 Figure 5. Computed N (a) and N (b) ion source rates using lifetimes from solid curves in Fig.a and b. A -D vertical slice of the 3-dimensional source distribution in particles per cm 3 per second. is on the left; position of s orbit indicated by dashed line.