SOLUZIONI PER L ENERGIA TERMICA THERMAL ENERGY SOLUTIONS

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Table on chemical resistance of rubber materials Class 1 little or no effect Class 2 minor effect Class 3 moderate effect Class 4 severe effect Chemical Conc. Temp. EPDM NBR VITON % C Acetic acid 10 50 3 4 4 50 50 4 3 4 25 100 4 4 4 100 70 1 2 4 Acetone RT 1 4 4 Ammonia gas Cold 1 1 4 Hot 2 3 4 Ammonia Liquid RT 4 4 2 Benzene RT 4 4 2 Boric acid 10 100 1 1 1 Bunker oil 4 1 1 Butadiene RT 3 4 2 Butanol 50 1 1 1 100 1 1 Butylene 4 2 1 Calcium hydroxide 100 2 1 Calcium hypochlorite 15 1 3 1 Carbon dioxide 1 1 1 Carbon tetrachloride RT 4 3 1 Castor oil 100 1 2 1 Chlorine (gas) 3 2 Chlorine water RT 4 4 1 Chloroform RT 4 4 1 Chromic acid 40 50 4 4 1 Citric acid sat 70 1 1 1 Coconut oil 2 1 1 Cod liver oil RT 2 1 1 Corn oil RT 2 1 1 Diacetone 1 1 4 Diesel oil (see fuel oil) Dioxane RT 2 4 4 Ethane 4 1 1 Ethanol 50 1 1 1 Ether RT 3 2 4 Ethyl acetate RT 1 4 4 Ethylene 1 1 Ethylene glycol 100 1 1 1 Ethylene oxide 3 4 4 Fluid 101 (diester oil) 100 4 1 1 Fluorine liquid 3 2 Formaldehyde 40 RT 1 1 40 70 4 Formic acid sat RT 2 2 3 sat 70 2 3 4 Freon 12 RT 2 1 2 Freon 22 RT 1 3 Freon 112 RT 4 2 1

Fuel oil (diesel) 70 4 1 1 Fumaric acid 1 1 Glucose 1 1 1 Glycerine 100 1 1 1 Hexane RT 4 1 1 Hexanol RT 3 1 1 Hydrobromic acid 37 RT 1 4 1 Hydrocloric acid 10 100 4 2 1 21 50 2 2 1 37 RT 1 2 1 48 RT 1 3 1 Hydrofluoric acid 48 RT 1 3 1 75 1 2 Hydrogen peroxide 30 RT 1 1 1 90 3 4 2 Hydrogen sulfide sat RT 1 4 4 Isobutyl alcohol RT 1 2 1 Isopropyl alcohpl 1 2 1 Kerosene 70 1 1 Latic acid 70 1 1 1 Lard 70 3 1 1 Magnesium hydroxide 1 Methane 4 1 1 Methanol 50 1 1 3 Methyl chloride 3 4 2 Milk 1 1 1 Mineral oil 1 100 4 1 1 Mineral oil 2 100 4 1 1 Mineral oil 3 100 4 1 1 Natural gas 4 1 1 Nitric acid conc. 65 RT 4 4 1 Nitric acid diluted 10 50 1 2 1 Nitrogen 1 1 1 Olei acid RT 3 1 1 Olive oil 50 3 1 1 Oxygen RT 1 1 1 Phenol 100 2 4 2 Phosporic acid 60 50 1 3 1 Propanol 50 1 2 1 Salicylic acid 1 1 1 Salt sat 70 1 1 1 Soap sol. 1 1 1 Sodium carbonate 20 100 1 1 1 Sodium hydroxide 10 100 1 1 4 25 100 1 4 4 Sodium hypochlorite 10 50 1 2 1 Sodium peroxide 1 1 Soybean oil RT 3 1 1 Sucrose sol. 1 1 Sulfur dioxide RT 3 1 Sulfuric acid 10 100 1 3 1 20 RT 1 1 1 25 100 1 4 1 50 100 1 4 1 60 100 1 4 1

75 100 4 4 1 95 RT 4 1 Toluene RT 4 4 2 Transformer oil 4 1 1 Turpentine RT 4 1 1 Veget. Oils 2 1 1 Vynil chloride 1 Water D.I. 100 1 1 1

Plate materials - corrosion tables 0 corrosion rate less than 0,1 mm/year. The material is corrosion proof 1 corrosion rate 0,1-1 mm/year. The material is not corrosion proof, but can be used in certain cases. 2 corrosion rate over 1 mm/year. Serious corrosion. The material is not usable. P,p Risk of pitting and crevice corrosion S,s Risk of stress corrosion cracking BP Boiling solution Corrosive medium Conc. Temp. 304 316 254 TI TI SMO PD Acetic acid 1 90 0 0 0 0 0 5 20 0 0 0 0 0 10 20 0 0 0 0 0 20 20 0 0 0 0 0 20 100 2 0 0 0 0 50 20 0 0 0 0 0 50 90 1 0 0 0 0 80 20 0 0 0 0 0 80 85 1 0 0 0 0 100 20 0 0 0 0 0 100 100 1 0 0 0 0 Acetone 100 20 0 0 0 0 0 Ammonium chloride 1 20 p0 p0 p0 0 0 5 BP p0s p0s p0s 0 0 10 20-50 p0 p0 p0 0 0 20 20-50 p0 p0 p0 0 0 50 115 p2s p1s p1s 0 0 Beer 20-70 0 0 0 0 0 Benzene 20-BP 0 0 0 0 0 Butyl alcohol 20-BP 0 0 0 0 0 Calcium chloride 5 20 p0 p0 p0 0 0 5 50 p0 p0 p0 0 0 10 100 p0s p0s p0s 0 0 10 20 p0 p0 p0 0 0 20 100 p0s p0s p0s 0 0 25 100 p0s p0s p0s 0 0 40 100 p0s p0s p0s 0 0 Calcium hydroxide all 20-BP 0 0 0 0 0 Carbon tetrachloride 100 20 0 0 0 0 0 100 76 0 0 0 0 0 Chromic acid 2 75 0 0 0 0 0

10 40 0 0 0 0 0 10 BP 2 2 2 0 0 20 200 0 0 0 0 0 20 50 1 1 1 0 0 40 20 1 1 0 0 40 40 2 2 2 0 0 50 20 2 2 2 0 0 Detergents 1 80 0 0 0 0 0 Dextrose 20 0 0 0 0 0 Ether 20-BP 0 0 0 0 0 Ethyl alcohol all conc. 20-BP 0 0 0 0 0 Fatty acids 100 20 0 0 0 0 0 100 80-130 0 0 0 0 0 100 150 0 0 0 0 0 100 180 1 0 0 0 0 100 235 1 0 0 0 0 100 300 2 0 0 0 0 Fluorine dry gas 20 0 0 0 0 0 most 20 2 2 1 2 2 Formaldehyde pure 2-BP 0 0 0 0 0 Freon <200 0 0 0 0 0 Fruit juices 20 0 0 0 0 0 Wines BP 0 0 0 0 0 Glucose all conc. 20 0 0 0 0 0 Ethylene glycol all conc. 20 0 0 0 0 0 Hydrochloric acid 0,1 20-50 p1 p0 p0 0 0 0,1 100 p1s p0s p0s 0 0 0,2 20 p1 p0 p0 0 0 0,5 20 p1 p0 p0 0 0 0,5 100 2 2 2 1 0 1 20 p1 p0 p0 0 0 1 50 2 p0 p0 0 0 2 20 2 p0 p0 0 0 2 60 2 2 2 0 0 3 20 2 p0 p0 0 0 3 60 2 p1 p1 0 0 3 100 2 2 2 2 0 5 20-70 2 2 2 1 0 10 20-35 2 2 2 1 0 20 20-35 2 2 2 2 1 Hydrogen peroxide 5 20 0 0 0 0 0

10 40 0 0 0 1 1 15 30-40 0 0 0 1 1 30 40-80 0 0 0 2 2 50 40 0 0 0 2 2 Lithium chloride 10 BP p0s p0s p0s 0 0 10 135 p1s p0s p0s p0 0 40 115 p1s p1s p0s 0 0 Magnesium chlordie 2,5 20 p0 p0 p0 0 0 5 BP p0s p0s p0s 0 0 Phosporic acid 1,3 25 1 0 0 2 1 75 2 1 0 2 2 1,5 20 2 0 0 2 1 75 2 1 0 2 2 Potassium chromate all conc BP 0 0 0 0 0 Potassium hydroxide 10 BP 0 0 0 0 0 20 20 0 0 0 0 0 25 BP 0 0 0 1 1 50 20 0 0 0 0 0 50 BP 1s 1s 1s 2 2 70 120 1s 1s 1s 2 2 Saccharin all conc 100 0 0 0 0 0 Salicylic acid 5 20-85 0 0 0 0 0 20 100 0 0 0 0 0 Silver nitrate all conc 20-BP 0 0 0 0 0 Sodium bromide 5-10,1 20 p0 p0 p0 0 0 20 80 p0s p0s p0s 0 0 Sodium carbonate all conc 20-BP 0 0 0 0 0 Sodium fluoride 5-10,1 20-100 0 0 0 2 1 Sodium hydroxide 10 20 0 0 0 0 0 10 90 0 0 0 0 0 20 20 0 0 0 0 0 20 90 0 0 0 0 0 25 20 0 0 0 0 0 25 BP 0 0 0 1 1 30 20 0 0 0 0 0 30 100 0 0 0 1 1 40 80 0 0 0 1 1 40 100 1 1 0 1 1 50 60 0 0 0 0 0 50 90 1 1 0 1 1 50 BP 1s 1s 1s 1 1 60 90 1 1 0 0 0 70 90 1 1 0 0 0

90 300 2s 1s 1s 2 2 Sodium hypochlorite 5 20 p1 p1 p0 0 0 5 BP p1s p1s p1s 0 0 Starch all conc 60 0 0 0 0 0 Sulphuric acid 0,1 100 2 1 0 1 0 0,5 20 0 0 0 0 0 0,5 50 1 0 0 0 0 0,5 100 2 1 1 1 0 1 20 0 0 0 0 0 1 50 1 0 0 0 0 1 70 1 0 0 1 0 1 85 2 1 0 1 0 1 100 2 1 1 1 0 2 20 0 0 0 0 0 2 50 1 0 0 0 0 2 60 1 0 0 1 0 3 20 0 0 0 0 0 3 35 1 0 0 0 0 3 50 1 0 0 1 0 3 85 2 1 0 1 1 3 100 2 2 1 2 1 5 20 1 0 0 0 0 5 35 1 0 0 1 0 5 60 2 1 0 1 0 5 75 2 1 0 2 1 5 85 2 2 1 2 1 5 BP 2 2 2 2 1 Sulphuric acid 10 20 2 0 0 1 0 10 50 2 1 0 2 0 10 60 2 1 0 2 1 10 80 2 2 1 2 1 10 BP 2 2 2 2 2 20 20 2 0 0 2 0 20 40 2 1 0 2 0 20 50 2 1 0 2 1 20 60 2 2 1 2 1 20 100 2 2 2 2 2 30 20 2 1 2 1 0 30 40 2 2 0 2 1 30 60 2 2 1 2 2 40 20 2 2 0 2 0 40 40 2 2 0 2 1 40 60 2 2 1 2 2 40 90 2 2 2 2 2 50 20 2 2 0 2 1 50 40 2 2 0 2 2 50 70 2 2 2 2 2 60 20 2 2 0 2 2 60 40 2 2 1 2 2 60 70 2 2 2 2 2 70 20 2 2 0 2 2 70 40 2 2 1 2 2

70 70 2 2 2 2 2 80 20 2 1 0 2 2 80 40 2 2 1 2 2 80 60 2 2 2 2 2 85 20 1 0 0 2 2 85 30 1 0 0 2 2 85 40 1 1 1 2 2 85 50 2 1 1 2 2 90 20 0 0 0 2 2 90 30 0 0 0 2 2 90 40 2 1 1 2 2 90 70 2 2 2 2 2 94 20 0 0 0 2 2 94 30 0 0 0 2 2 94 40 1 1 1 2 2 94 50 1 1 1 2 2 96 20 0 0 0 2 2 96 30 0 0 0 2 2 96 40 0 0 1 2 2 96 50 1 1 1 2 2 98 30 0 0 0 2 2 98 40 0 0 1 2 2 98 50 2 0 1 2 2 98 80 2 2 2 2 2 100 70 0 0

TABELLA COMPATIBILITA' MATERIALI Acciaio AISI 316 e rame ACQUA CONTENENTE CONCENTRAZIONE (mg/l) AISI 316 RAME Elementi organici + 0 Conduttività elettrica <500S/cm + + >500S/cm + - NH3 <2 + + 2-20 + 0 >20 + - Cloruri <300 + + >300 0 + Solfiti senza cloruri <5 0 + >5 0/- 0 Ferro in soluzione <10 + + >10 + 0 Acido carbonico libero <20 + 0 20-50 + - 50 + - Manganese in soluzione <1 + + >1 + 0 Valore PH <6 0 + 6-9 0/+ + >9 + 0 Ossigeno <2 + + >2 + + Solfati <70 + + 70-300 + 0 >300 - - * max. 60 C LEGENDA + buona resistenza in condizioni normali 0 problemi di corrosione possono manifestarsi in particolar modo quando più fattori portano la valutazione 'o' - da evitare