Atomic Structure. The center of the Atom is called the Nucleus

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Transcription:

Basic Chemistry Review

Atomic Structure The center of the Atom is called the Nucleus It is about 100,000 times smaller than the entire atom It makes up 99.9% of the mass of the atom

In the Nucleus There are two Subatomic Particles 1. Proton: Which is a positively charged particle 2. Neutron: Which is a neutrally charged particle» These 2 subatomic particles are nearly equal in mass

Is that it?? There is one final subatomic particle in an atom This is called an Electron Electrons have a negative charge They are also not located IN the nucleus They travel throughout the atom at high speeds The potential energy that a molecule possesses is directly related to the electron s energy level

Electron Shells An electron s energy level is correlated with its average distance from the nucleus Electrons exist only at fixed levels of energy potential called shells Electrons in the first shell have the lowest potential energy (closest to the nucleus) Electrons in the second shell have more potential energy Electrons in the third shell have even more energy An electron can change which shell it occupies if it gains/loses exactly the amount of energy required

Balanced Equations The Law of Conservation of Matter told us that energy CAN NOT be created or destroyed. This is true at all times Even when considering chemical equations. For this reason the Reactants in a chemical equation must always equal the product This means you MUST have the same number of elements on either side of the yields arrow ( )

The Rules of Balancing Equations You are not allowed to change the atoms within a compound, you can only change the amount of the compound Meaning, you can NOT change the small numbers (subscript) but you can add big numbers in front of the compound IE: C + H 2 O + N 2 CH 4 + N 2 O 2 Balanced: C+ 2H 2 O + N 2 CH 4 +N 2 O 2 Adding the 2 in front of the H2O is saying that you are adding two molecules of water which balances the equation

Properties of H2O Hydrogen bonds: Because water is a polar molecule it can form hydrogen bonds This allows water to have certain properties: Cohesion is the attractive force between molecules of the same substance This allows water to stick to itself This is why water beads on a window This is why some organisms can stand on top of water Adhesion is the attraction between molecules of different substances This allows for water to stick to other things This is why water moves up the xylem of a plant

Van Der Waals Forces When molecules are close together, a slight attraction can occur between the positively and negatively charged regions of nearby molecules This does not require the molecules to have a specific or complete charge THIS HAPPENS WITH WATER

H H H O H O O H H

Atomic Number The number of protons not only tells you what the positive charge is, it also tells you of the atoms atomic number. Its atomic number tells you what Element the atom is Remember** An Element consists of entirely ONE type of atom -Change the # of protons & you change the type of atom (which changes the element)

Periodic Table of Elements Why do we need one? What is the point of classifying things? Does it speed things up? Do you think it was easy to make?

Periods & Families The periodic table is a useful tool that organizes all of the chemical elements known to man. It tells us the atomic #, atomic mass, and electron orbits of each element It is also arranged specifically into periods and families that tell us things about the elemental behavior The Period is the horizontal row on the table and shows important relationships of behavior such as the relationship between transition metals The Family (also called group) is the vertical column in the table and shows electron activity and behavior (most important of the 2)

Isotope When you change the number of Neutrons in an atom you get what is called an

Isotopes & a Mass Number Every element on the periodic table has a specific Mass Number This number indicates the mass of the atom The mass comes primarily from the protons & neutrons in an atom Therefore, having a different number of neutrons (Isotope) will change the mass number Isotopes are represented by adding the mass number to the atom symbol

Numbering & Isotopes

Radioactive Isotopes

Radioactive Isotopes Many isotopes are unstable in their natural forms This instability can make radioactive material hazardous to living material It can cause changes (mutations) in DNA that can lead to cancer If used correctly, however, radioactive isotopes have very important uses Chemical tracers, military tracers, chemotherapy, carbon dating

Radioactive Isotope Chemical Tracer

Chemo Therapy

Carbon 14 Dating

Types of Bonds When elements join together they form molecular compounds that are hooked together by bonds Atoms always want to satisfy their outermost ring or orbit For this class we will consider only the first 2 orbits. The first orbit wants 2 electrons and the second wants to form 8. There are three types of bonds: Covalent Bond Ionic Bond Hydrogen Bond

Covalent Bonds Covalent bonds are reasonably strong bonds in which two or more elements share electrons. They do this as a way of satisfying their outermost ring of electrons. Usually, covalent bonds Require energy to form & Release energy when broken If this happens it is termed an endergonic reaction For example, H 2 O is a covalent bonding of Oxygen and 2 Hydrogen molecules

Ionic Bonding Is the strongest bonding in which one or more elements take an electron from another molecule Once the electron is taken, the additional electron causes a negative charge on the molecule doing the taking The molecule that lost the electron has a positive charge due to the missing electron For this reason the opposite charges cause a strong molecular binding IE Table Salt, Na + Cl -, is an ionic bond

Hydrogen Bonding Is the Weakest form of bonding that occurs as an interaction of a hydrogen atom with an electronegative atom, such as nitrogen, oxygen or fluorine This should not be confused with a covalent bond to hydrogen. This weak bond can occur spontaneously and breaks apart very easily

Potential of Hydrogen ph = Potential of Hydrogen Amount of H + ions present in a solution However, the measurement formula for ph is actually log function (algebraic function) This means the more H+ ions present in a solution, the lower the ph score The ph scale, like the metric system, is a base 10 scale. This means there are 10 units between each # on the ph scale IE: The difference between 4 and 5 on the ph scale is 10 H + ions

Acids & Bases Acids are solutions that contain higher levels of H+ ions than are present in pure water Remember, the ph scale is a log function meaning that the higher the # of H + ions the lower the ph scale score This means ACIDS have a ph score of less than 7. Pure water has a ph of 7 and is considered to be Neutral Bases are solutions that lack H + ions and instead have high concentrations of OH - ions This causes bases to have a low potential of hydrogen and therefore a high ph scale score This means bases have a ph score of more than 7.