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Chapter Problem Solutions 1. If Planck's constant were smaller than it is, would quantum phenomena be more or less conspicuous than they are now? Planck s constant gives a measure of the energy at which quantum effects are observed. If Planck s constant had a smaller value, while all other physical quantities, such as the speed of light, remained the same, quantum effects would be seen for phenomena that occur at higher frequencies or shorter wavelengths. That is, quantum phenomena would be less conspicuous than they are now. 3. Is it correct to say that the maximum photoelectron energy KE max is proportional to the frequency ν of the incident light? If not, what would a correct statement of the relationship between KE max and ν be? No: the relation is given in Equation (.8) and Equation (.9), KE max hν φ h( ν So that while KE max is a linear function of the frequency ν of the incident light, KE max is not proportional to the frequency. ν o ),

5. Find the energy of a 700-nm photon. From Equation (.11), 6 1. 4 10 ev m E 1. 77 ev. -9 700 10 m Or, in terms of joules, 34 8 (. 63 10 J s)(3.0 10 m/s) E. 84 10 9 700 10 m 6 19 J 7. A 1.00-kW radio transmitter operates at a frequency of 880 khz. How many photons per second does it emit? The number of photons per unit time is the total energy per unit time(the power) divided by the energy per photon, or P E P hν 3 1. 00 10 J/s 30 1. 7 10 photons/s. 34 3 ( 6. 63 10 J s)(880 10 Hz)

9. Light from the sun arrives at the earth, an average of 1.5 x 10 11 m away, at the rate of 1.4 x 10 3 W/m of area perpendicular to the direction of the light. Assume that sunlight is monochromatic with a frequency of 5.0 x 10 14 Hz. (a) How many photons fall per second on each square meter of the earth's surface directly facing the sun? (b) What is the power output of the sun, and how many photons per second does it emit? (c) How many photons per cubic meter are there near the earth? (a) The number of photons per unit time per unit are will be the energy per unit time per unit area (the power per unit area, P/A), divided by the energy per photon, or 3 P / A 1. 4 10 W/m 1 4. 10 photons/(s m ). hν -34 14 (6.63 10 J s)(5.0 10 Hz) (b) With the reasonable assumption that the sun radiates uniformly in all directions, all points at the same distance from the sun should have the same flux of energy, even if there is no surface to absorb the energy. The total power is then, R E S 3 ( P / A) 4π ( 1. 4 10 W/m ) 4π( 1. 5 10 m) 4. 0 10 W, where R E-S is the mean Earth-Sun distance, commonly abbreviated as 1 AU, for astronomical unit. The number of photons emitted per second is this power divided by the energy per photon, or 6 4. 0 10 J/s 45 1. 10 photons/s. -34 14 (6.63 10 J s)( 5. 0 10 Hz) 11 6

(c) The photons are all moving at the same speed c, and in the same direction (spreading is not significant on the scale of the earth), and so the number of photons per unit time per unit area is the product of the number per unit volume and the speed. Using the result from part (a), 4 1. 10 photons/(s m ) 13 3 1. 4 10 photons/m 8 3. 0 10 m/s. 11. The maximum wavelength for photoelectric emission in tungsten is 30 nm. What wavelength of light must be used in order for electrons with a maximum energy of 1.5 ev to be ejected? Expressing Equation (.9) in terms of λ c/ν and λ 0 c/ν 0, and performing the needed algebraic manipulations, hc λ ( hc / λ ) + K o max 9 ( 1. 5eV)( 30 10 m) ( 30 nm) 1 + 6 1. 4 10 ev m K λ0 1 + λ hc max o 1 1 180 nm.

13. What is the maximum wavelength of light that will cause photoelectrons to be emitted from sodium? What will the maximum kinetic energy of the photoelectrons be if 00-nm light falls on a sodium surface? The maximum wavelength would correspond to the least energy that would allow an electron to be emitted, so the incident energy would be equal to the work function, and 6 hc 1. 4 10 ev m λmax 539 nm φ. 3eV where the value of φ for sodium is taken from Table.1. From Equation (.8), 6 hc 1. 4 10 ev m Kmax hν φ φ. 3eV 3.9eV. λ 9 00 10 m 15. 1.5 mw of 400-nm light is directed at a photoelectric cell. If 0.10 percent of the incident photons produce photoelectrons, find the current in the cell. Because only 0.10% of the light creates photoelectrons, the available power is (1.0x10-3 )(1.5x10-3 W) 1.5x10-6 W. the current will be the product of the number of photoelectrons per unit time and the electron charge, or I e P E P e hc / λ Pλ e hc 6 ( 1. 5 10 J/s)( 400 10 ( 1e ) -6 1.4 10 ev m 9 m) 0. 48 µ A

17. A metal surface illuminated by 8.5 x 10 14 Hz light emits electrons whose maximum energy is 0.5 ev The same surface illuminated by 1.0 x 10 14 Hz light emits electrons whose maximum energy is 1.97 ev From these data find Planck's constant and the work function of the surface. Denoting the two energies and frequencies with subscripts 1 and, K hν φ K ν φ. max, 1 1, max, h Subtracting to eliminate the work function φ and dividing by ν 1 - ν, Kmax, Kmax, 1. 7eV 0. 5eV h 4. 1 10 ν 14 14 ν1 1. 0 10 Hz 8. 5 10 Hz to the allowed two significant figures. Keeping an extra figure gives 15 19 15 ev s h 4. 14 10 ev s 6.64 10 J s The work function φ may be obtained by substituting the above result into either of the above expressions relating the frequencies and the energies, yielding φ 3.0 ev to the same two significant figures, or the equations may be solved by rewriting them as Kmax, 1ν hν1ν φν, K max, ν1 hν ν1 φν1, subtracting to eliminate the product hν 1 ν and dividing by ν 1 - ν to obtain K 14 14 max, ν1 Kmax, 1ν ( 19. 7 ev)(8.5 10 Hz) ( 0. 5 ev)(1.0 10 Hz) φ 3. 0 ev ν 14 14 ν1 (1.0 10 Hz 8. 5 10 Hz) (This last calculation, while possibly more cumbersome than direct substitution, reflects the result of solving the system of equations using a symbolic-manipulation program; using such a program for this problem is, of course, a case of "swatting a fly with a sledgehammer".) -34

19. Show that it is impossible for a photon to give up all its energy and momentum to a free electron. This is the reason why the photoelectric effect can take place only when photons strike bound electrons. Consider the proposed interaction in the frame of the electron initially at rest. The photon's initial momentum is p o E o /c, and if the electron were to attain all of the photon's momentum and energy, the final momentum of the electron must be p e p o p, the final electron kinetic energy must be KE E o pc, and so the final electron energy is E e pc + m e c. However, for any electron we must have E e (pc) + (m e c ). Equating the two expressions for E e or ( m c ) ( pc + m c ) ( pc) + ( pc) ( m c ) ( m c ), Ee ( pc) + e e e + 0 ( pc)( m c ). e This is only possible if p 0, in which case the photon had no initial momentum and no initial energy, and hence could not have existed. To see the same result without using as much algebra, the electron's final kinetic energy is p c + m e c 4 m e c for nonzero p. An easier alternative is to consider the interaction in the frame where the electron is at rest after absorbing the photon. In this frame, the final energy is the rest energy of the electron, m e c, but before the interaction, the electron would have been moving (to conserve momentum), and hence would have had more energy than after the interaction, and the photon would have had positive energy, so energy could not be conserved. pc e

1. Electrons are accelerated in television tubes through potential differences of about 10 kv. Find the highest frequency of the electromagnetic waves emitted when these electrons strike the screen of the tube. What kind of waves are these? For the highest frequency, the electrons will acquire all of their kinetic energy from the accelerating voltage, and this energy will appear as the electromagnetic radiation emitted when these electrons strike the screen. The frequency of this radiation will be 3 E ev ( 1e)( 10 10 V) 18 ν. 4 10 Hz h h 15 4. 14 10 ev s which corresponds to x-rays. 3. The distance between adjacent atomic planes in calcite (CaCO 3 ) is 0.300 nm. Find the smallest angle of Bragg scattering for 0.030-nm x-rays. Solving Equation (.13) for θ with n 1, λ 0. 030 nm θ arcsin arcsin. 9 d 0.300 nm o

5. What is the frequency of an x-ray photon whose momentum is 1.1 x 10-3 kg m/s? From Equation (.15), ν cp h 8-3 ( 3. 0 10 m/s)(1.1 10 kg m/s) 18 5. 0 10 Hz 34 6. 63 10 J s 7. In See..7 the x-rays scattered by a crystal were assumed to undergo no change in wavelength. Show that this assumption is reasonable by calculating the Compton wavelength of a Na atom and comparing it with the typical x-ray wavelength of 0.1 nm. Following the steps that led to Equation (.), but with a sodium atom instead of an electron, λ C, Na 34 6 17 h. 63 10 J s 5. 8 10 cm 8-6 (3.0 10 m/s)(3.8 10 kg) Na or 5.8 x 10-8 nm, which is much less than o.1 nm. (Here, the rest mass M Na 3.8 x 10-6 kg was taken from Problem -4.) m,

9. A beam of x-rays is scattered by a target. At 45 o from the beam direction the scattered x-rays have a wavelength of. pm. What is the wavelength of the x-rays in the direct beam? Solving Equation (.3) for λ, the wavelength of the x-rays in the direct beam, o λ λ λ C ( 1 cosφ). pm (. 46 pm)(1 cos 45 ) 1. 5 pm to the given two significant figures. 31. An x-ray photon of initial frequency 3.0 x 10 19 Hz collides with an electron and is scattered through 90 o. Find its new frequency. Rewriting Equation (.3) in terms of frequencies, with λ c/ν and λ c/ν, and with cos 90 o 0, c c + λc ν ν and solving for ν gives 1 1 1 19 1 λ 1. 43 10 m ν + C + 4 10 19 8. ν c 3. 0 10 Hz 3. 0 10 m/s The above method avoids the intermediate calculation of wavelengths. Hz

33. At what scattering angle will incident 100-keV x-rays leave a target with an energy of 90 kev? Solving Equation (.3) for cos φ, λ λ 511keV 511 kev cos 1 1 mc mc φ + + 1 + 0. 43 λc λ C E E 100 kev 90 kev from which φ 64 o to two significant figures. 35. A photon of frequency ν is scattered by an electron initially at rest. Verify that the maximum kinetic energy of the recoil electron is KE max (h ν /mc )/(1 + hν/mc ). For the electron to have the maximum recoil energy, the scattering angle must be 180 0, and Equation (.0) becomes mc KE max (hv) (hv'), where KE max (hv - hv') has been used. To simplify the algebra somewhat, consider λ ν ν ν ν ν, λ 1 + ( λ/ λ) 1 + ( λc / λ) 1 + ( νλ C / c) where λ λ C for φ 180 o. With this expression, ( hν)( hν ) ( hν) /( mc ) KEmax. mc 1 + ( νλ C / c) Using λ C h/(mc) (which is Equation (.)) gives the desired result.

37. A photon whose energy equals the rest energy of the electron undergoes a Compton collision with an electron. If the electron moves off at an angle of 40 o with the original photon direction, what is the energy of the scattered photon? As presented in the text, the energy of the scattered photon is known in terms of the scattered angle, not the recoil angle of the scattering electron. Consider the expression for the recoil angle as given preceding the solution to Problem -5: sin φ sin φ sin φ tanθ. ( λ/ λ) + ( 1 cosφ) ( λc / λ)( 1 cosφ) + ( 1 cosφ) λ 1 + C ( 1 cosφ) λ For the given problem, with E mc, λ hc/e h/(mc) λ C, so the above expression reduces to sinφ tanθ. ( 1 cosφ) At this point, there are many ways to proceed; a numerical solution with θ 40 o gives φ 61.6 0 to three significant figures. For an analytic solution which avoids the intermediate calculation of the scattering angle φ, one method is to square both sides of the above relation and use the trigonometric identity sin φ 1 - cos φ (1 + cos φ)(1 cos φ) to obtain 1 + cosφ 4tan θ 1 cosφ (the factor 1 - cos φ may be divided, as cos φ 1, φ 0, represents an undeflected photon, and hence no interaction). This may be re-expressed as

( 1 cosφ)( 4tan θ ) 1 + cosφ ( 1 cosφ), 1 cosφ, cosφ 1+ 4tan θ Then with λ λ + λ C (1 cos φ) λ C ( cos φ), 3 + 4tan 1 + 4tan λ 1 + 4tan θ 1 + 4tan ( 40 ) E E E ( 511keV) 335 ev λ o 3 + 4tan θ 3 + 4tan ( 40 ) An equivalent but slightly more cumbersome method is to use the trigonometric identities φ φ φ sin φ sin cos, 1 cosφ sin in the expression for tan θ to obtain 1 φ tanθ cot, yielding the result θ 61.6 o more readily. φ 1 arctan tan θ θ. θ o or

39. A positron collides head on with an electron and both are annihilated. Each particle had a kinetic energy of 1.00 MeV Find the wavelength of the resulting photons. The energy of each photon will he the sum of one particle's rest and kinetic energies, 1.511 MeV (keeping an extra significant figure). The wavelength of each photon will be 6 hc 1. 4 10 ev m 13 λ 8. 1 10 m 0.81pm E 6 1. 51 10 ev 41. Show that, regardless of its initial energy, a photon cannot undergo Compton scattering through an angle of more than 60 o and still be able to produce an electron-positron pair. (Hint: Start by expressing the Compton wavelength of the electron in terms of the maximum photon wavelength needed for pair production.) Following the hint, λ h hc hc C, mc mc E min where E min mc is the minimum photon energy needed for pair production. The scattered wavelength (a maximum) corresponding to this minimum energy is λ max (h/e min ), so λ C λ max. At this point, it is possible to say that for the most energetic incoming photons, λ ~ 0, and so 1 - cos φ ½ for λ ' λ C /, from which cos φ ½ and φ 60 o. As an alternative, the angle at which the scattered photons will have wavelength λ max can m be found as a function of the incoming photon energy E; solving Equation (.3) with λ ' λ' max )

cosφ λmax λ λmax hc / E 1 mc 1 1 + + λ λ λ E C C This expression shows that for E >> mc, cos φ ½ and so φ 60 o, but it also shows that, because cos φ must always be less than 1, for pair production at any angle, E must be greater than mc, which we know to be the case. 43. (a) Show that the thickness x 1/, of an absorber required to reduce the intensity of a beam of radiation by a factor of is given by x 1/ 0.693/µ. (b) Find the absorber thickness needed to produce an intensity reduction of a factor of 10. (a) The most direct way to get this result is to use Equation (.6) with I o /I, so that µ x ln 0. 693 I Ioe x1 /. µ µ (b) Similarly, with I o /I 10, ln10. 30 x1 / 10. µ µ C.

45. The linear absorption coefficient for 1-MeV gamma rays in lead is 78 m -1. find the thickness of lead required to reduce by half the intensity of a beam of such gamma rays. From either Equation (.6) or Problem -43 above, ln 0. 693 x1 / 8. 9 mm µ -1 78 m 47. The linear absorption coefficients for.0-mev gamma rays are 4.9 m -1 in water and 5 in -1 in lead. What thickness of water would give the same shielding for such gamma rays as 10 mm of lead? Rather than calculating the actual intensity ratios, Equation (.6) indicates that the ratios will be the same when the distances in water and lead are related by µ x µ x, or H O Pb or 11 cm two significant figures. x x µ µ H H Pb O O H O ( 10 10 Pb 3 Pb -1 5 m m) 4. 9 m -1 0. 106 m

49. What thickness of copper is needed to reduce the intensity of the beam in Exercise 48 by half. Either a direct application of Equation (.6) or use of the result of Problem -43 gives ln 5 x1/ 1. 47 10 m, 4-1 4. 7 10 m which is 0.015 mm to two significant figures. 51. The sun's mass is.0 x 10 30 kg and its radius is 7.0 x 10 8 m. Find the approximate gravitational red shift in light of wavelength 500 nm emitted by the sun. In Equation (.9), the ratio 11 30 6. 67 10 N m / kg)(. 0 10 kg) 6 1 10 8 4-1 GM (. c R ( 3. 0 10 m/s) ( 7. 0 10 m ) (keeping an extra significant figure) is so small that for an approximate red shift, the ratio λ/λ will be the same as ν/ν, and λ GM λ c R ( 500 10 9 m)(.1 10-6 ) 1.06 10-1 m 1.06 pm.

53. As discussed in Chap. 1, certain atomic nuclei emit photons in undergoing transitions from "excited" energy states to their ground or normal states. These photons constitute gamma 57 rays. When a nucleus emits a photon, it recoils in the opposite direction. (a) The 7Co nucleus 57 decays by K capture to 6 Fe, which then emits a photon in losing 14.4 kev to reach its ground 57 state. The mass of a 6 Fe atom is 9.5 x 10-6 kg. By how much is the photon energy reduced from the full 14.4 kev available as a result of having to share energy and momentum with the recoiling atom? (b) In certain crystals the atoms are so tightly bound that the entire crystal recoils when a gamma-ray photon is emitted, instead of the individual atom. This phenomenon is known as the Mössbauer effect. By how much is the photon energy reduced in this situation if the ex- cited 576Fe nucleus is part of a 1.0-g crystal? (c) The essentially recoil-free emission of gamma rays in situations like that of b means that it is possible to construct a source of virtually monoenergetic and hence monochromatic photons. Such a source was used in the experiment described in See..9. What is the original frequency and the change in frequency of a 14.4-keV gamma-ray photon after it has fallen 0 m near the earth's surface? (a) The most convenient way to do this problem, for computational purposes, is to realize that the nucleus will be moving nonrelativistically after the emission of the photon, and that the energy of the photon will be very close to E 14.4 kev, the energy that the photon would have if the nucleus had been infinitely massive. So, if the photon has an energy E, the recoil momentum of the nucleus is E/c, and its kinetic energy is p / M E /( Mc ), here M is the rest mass of the nucleus. Then, conservation of energy implies

E + E E Mc. This is a quadratic in E, and solution might be attempted by standard methods, but to find the change in energy due to the finite mass of the nucleus, and recognizing that E will be very close to E, the above relation may be expressed as E E E E Mc Mc ( 14. 4 kev) ( 1. 60 10 J/keV) 6 1. 9 10 kev -6 8 (9.5 10 kg)(3.0 10 m/s) If the approximation E E, is not made, the resulting quadratic is which is solved for E E 16 + Mc E Mc E E Mc 1 + 1. Mc 0, 1.9 10 However, the dimensionless quantity E /(Mc ) is so small that standard calculators are not able to determine the difference between E and E. The square root must be expanded, using (1 + x) 1/ 1 + (x/) - (x /8), and two terms must be kept to find the difference between E and E. This approximation gives the previous result. 3 ev.

It so happens that a relativistic treatment of the recoiling nucleus gives the same numerical result, but without intermediate approximations or solution of a quadratic equation. The relativistic form expressing conservation of energy is, with pc E and before, + E ( Mc ) + E Mc + E, or E + ( Mc ) Mc + E E. Squaring both sides, canceling E and (Mc ), and then solving for E, E + ( /( )). ( ) ( /( )) + Mc E 1 E Mc E E + Mc E 1 + E Mc From this form, E 1 E E, Mc 1 + E /( Mc ) giving the same result. (b) For this situation, the above result applies, but the nonrelativistic approximation is by far the easiest for calculation; 3 19 E ( 14. 4 10 ev) ( 1. 6 10 J/eV) 5 E E 1. 8 10 ev. -3 8 Mc (1.0 10 kg)(3.0 10 m/s) 3 E 14 4 10 ev 18 (c) The original frequency is. ν 3 48 10 Hz. h 15 4. 14 10 ev s. From Equation (.8), the change in frequency is gh ( 9. 8 m/s )( 0 m) 18 ν ν ν ( 3. 48 10 Hz) 7. 6 Hz. ν 8 c (3.0 10 m/s)

55. The gravitational potential energy U relative to infinity of a body of mass m at a distance R from the center of a body of mass M is U -GmM/R. (a) If R is the radius of the body of mass M, find the escape speed v, of the body, which is the minimum speed needed to leave it permanently. (b) Obtain a formula for the Schwarzschild radius of the body by setting v c c, the speed of light, and solving for R. (Of course, a relativistic calculation is correct here, but it is interesting to see what a classical calculation produces.) (a) To leave the body of mass M permanently, the body of mass m must have enough kinetic energy so that there is no radius at which its energy is positive. That is, its total energy must be nonnegative. The escape velocity v e is the speed (for a given radius, and assuming M >> m) that the body of mass m would have for a total energy of zero; 1 GMm GM mve 0, or ve. R R (b) Solving the above expression for R in terms of v e, GM R, and if v e c, Equation (.30) is obtained. v e