GEOCHEMICAL TRACERS OF ARCTIC OCEAN CIRCULATION

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GEOCHEMICAL TRACERS OF ARCTIC OCEAN CIRCULATION Earth Sciences Division Lawrence Berkeley National Laboratory

Fresh Water Cycle Maintains Stratification of Upper Arctic Ocean Stably stratified surface layer -- ice formation -- plankton growth Formation of cold halocline layer Export of positive buoyancy flux to North Atlantic

Arctic Ocean Freshwater Budget Reference Salinity = 34.4 Goldner (1999), JGR, 104, 29,757-29,770. FLUX Q (Sv) Salinity (PSS) Effective Freshwater Flux (km 3 yr -1 ) River runoff Bering Strait inflow Net Precipitation (P-E) Arctic Archipelago outflow Barents Sea inflow 0.108 0.81 0.012-1.37 1.49 0.0 32.5 0.0 33.2 35 3400 1420 380-1460 -820 Fram Strait Outflow Ice EGC Polar Water EGC Atlantic Water EGC Deep Water Subtotal -0.07-1.16-2.14-1.03-4.40 3.5 33.9 34.9 34.9-1980 -560 960 490-1090 Fram Strait Inflow WSC Atlantic Water WSC Deep Water Subtotal 2.65 0.73 3.38 35.0 34.9-1490 -340-1830 NET 0.0 0.0 ESD/ LBNL

Arctic Ocean Freshwater Budget Reference Salinity = 34.4 Goldner (1999), JGR, 104, 29,757-29,770. FLUX Q (Sv) Salinity (PSS) Effective Freshwater Flux (km 3 yr -1 ) River runoff Bering Strait inflow Net Precipitation (P-E) Arctic Archipelago outflow Barents Sea inflow 0.108 0.81 0.012-1.37 1.49 0.0 32.5 0.0 33.2 35 3400 1420 380-1460 -820 Fram Strait Outflow Ice EGC Polar Water EGC Atlantic Water EGC Deep Water Subtotal -0.07-1.16-2.14-1.03-4.40 3.5 33.9 34.9 34.9-1980 -560 960 490-1090 Fram Strait Inflow WSC Atlantic Water WSC Deep Water Subtotal 2.65 0.73 3.38 35.0 34.9-1490 -340-1830 NET 0.0 0.0

Discharge of Major Arctic Rivers (km 3 yr -1 ) Total Arctic Runoff: 3400 km 3 yr -1 [10% of global total]

Arctic Ocean Freshwater Budget Reference Salinity = 34.4 Goldner (1999), JGR, 104, 29,757-29,770. FLUX Q (Sv) Salinity (PSS) Effective Freshwater Flux (km 3 yr -1 ) River runoff Bering Strait inflow Net Precipitation (P-E) Arctic Archipelago outflow Barents Sea inflow 0.108 0.81 0.012-1.37 1.49 0.0 32.5 0.0 33.2 35 3400 1420 380-1460 -820 Fram Strait Outflow Ice EGC Polar Water EGC Atlantic Water EGC Deep Water Subtotal -0.07-1.16-2.14-1.03-4.40 3.5 33.9 34.9 34.9-1980 -560 960 490-1090 Fram Strait Inflow WSC Atlantic Water WSC Deep Water Subtotal 2.65 0.73 3.38 35.0 34.9-1490 -340-1830 NET 0.0 0.0

T and S alone are not sufficient tracers of freshwater in upper Arctic Ocean Two major freshwater sources: Runoff and Ice-melt Temperature is non-conservative -- heat gain/loss in open water areas -- seasonal temperature variability of river runoff

T and S alone are not sufficient tracers of freshwater in upper Arctic Ocean Two major freshwater sources: Runoff and Ice-melt Temperature is non-conservative -- heat gain/loss in open water areas -- seasonal temperature variability of river runoff Additional conservative tracer: Oxygen isotopes δ 18 O ( ) = ( 18 O/ 16 O) sample -( 18 O/ 16 O) SMOW x 1000 ( 18 O/ 16 O) SMOW

Salinity-δ 18 O Mass Balance for the Beaufort Sea [Macdonald et al. (2002), DSR I, 49, 1769-1785]

1997 Shelf-Basin Transect to Initial SHEBA Site Macdonald et al. (2002) DSR I, 49, 1769-1785.

Dissolved Barium in Major Arctic Rivers Guay and Falkner (1998) Cont Shelf Res, 18, 859-882 End-Member Concentrations (nmol Ba L -1 ) Mackenzie River Eurasian Rivers Atlantic Inflow Pacific Inflow 520 90-150 42-45 65-73

1993 Surface Mixed Layer Composite from six cruises Guay and Falkner (1997) DSR II, 44(8), 1543-1569.

1997 Shelf-Basin Transect to Initial SHEBA Site Macdonald et al. (1999) GRL, 26(15), 2223-2226.

Using Nutrients to Differentiate Atlantic/Pacific Waters Jones et al. (1998), GRL, 26(6), 765-768.

Water Mass Composition Derived From Multiple Tracers (S, δ 18 O, Ba, nutrients) 1998 ARKTIS-XIV/2 Taylor et al., JGR (in press).

AOMIP April Mean Sea Surface Salinity Steele et al. (2001) GRL, 28, 2935-2938.

Response to Shift in Atmospheric Forcing Steele and Boyd (1998), JGR, 103, 10,419-10435. Figure: I. Rigor (UW/IABP) Negative AO Index Positive AO Index Weak polar vortex/high SLP Anti-cyclonic ocean circulation Eurasian runoff enters at Lomonosov Ridge Cold halocline formation in Eurasian Basin Strong polar vortex/low SLP Cyclonic ocean circulation Eurasian runoff enters at Mendeleyev Ridge Cold halocline retreat from Eurasian Basin

Scientific Questions Freshwater cycle river runoff halocline formation ice formation/melting Arctic Ocean inflows/outflows export through Canadian Archipelago Long-term trends (relation to global climate change?) changes in circulation regime changes in terrestrial environment/signals changes in biota/ecosystem changes in carbon cycling

Required Geochemical Measurements 1. Circulation tracers -- nutrients (N, P, Si, O 2 ) -- stable isotopes (d18o, d13c, d15n, etc.) -- trace metals (Ba, etc.) -- radioisotopes ( 137 Cs, 128 I) -- DOC, biomarkers -- inorganic C: alkalinity, ΣCO 2, DIC 2. Water mass age tracers -- He-tritium, CFCs 3. Particulate flux tracers -- U, Th, POC, PON

Critical Areas Shelf Break shelf-basin exchanges river water pathways

Critical Areas Inflows/Outflows communication with global ocean export to North Atlantic areas of deep water formation export through Canadian Archipelago

Critical Areas Atlantic/Pacific Front boundary between Atlantic/Pacific, Eurasian/North American water mass assemblages Transpolar Drift area north of Greenland and Archipleago

Critical Areas Beaufort Gyre expands/contracts with changes in circulation regime storage/release of freshwater

FUTURE DATA SETS NEEDED Long-term time series High-resolution (temporal and spatial) observations Need for autonomous, in situ sensors -- optical -- chemical (MEMS/nanotechnology)