Chemistry SOL Review Packet. beaker evaporating dish Erlenmeyer flask watch glass. volumetric flask graduated cylinder mortar & pestle crucible

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Chemistry SOL Review Packet Name 1. Match the following lab equipment with its name: beaker evaporating dish Erlenmeyer flask watch glass volumetric flask graduated cylinder mortar & pestle crucible 2. Put the following values into correct scientific notation and indicate the number of significant figures in each measurement. Measurement # of significant figures Scientific Notation 0.00005607 m 205.00 ml 345000 J 0.00300 kg 250. g 3.159 x 10-3 L 2.14 x 10 4 mg 3. Perform the calculations & round your answer to the correct number of significant figures Problem Raw Answer Rounded Answer 1.35 x 2.467 12.01 + 35.2 + 6 55.46-28.9 0.021 x 3.2 x 100.1 1

4. The boiling point of water is 100.0 o C. Give an example of data for the boiling point (BP) of water that is PRECISE BUT NOT ACCURATE: Trial 1: Trial 2: Trial 3: Trial 4: 5. What is the measurement in the graduated cylinder? Make sure you estimate each measurement to the correct number of decimal places! 6. Complete the table below about separation techniques and the physical property the mixtures are separated by. Separation Techniques: distillation, filtration, chromatography Physical Properties: size/state of matter, boiling point, polarity Image of separation technique Name of technique Separated by this differing physical property 7. What is the difference between an element and a compound? A homogeneous and heterogeneous mixture? 2

Empirical/Molecular Formula, Molar Mass, Percent Composition Empirical Molecular Molar Mass WORK HERE % comp Formula Formula of MF CH2 C2H4 26.06 g/mol %C:85.6% %H:14.4% N2O5 %N: %O: CH3 30.07 g/mol %C: %H: 220 g/mol %P: 56.3% %O: 43.7% Molar Conversions Problem Work Circle final answer with correct sig figs and unit How many moles are present in a 100.0 g sample of C2H6O? What is the mass of 9.25 x 10 22 molecules of water? What is the volume of a 3.56g of O2 at STP? What is the volume of 3.01 x 10 23 atoms of He gas at STP? 3

Molarity & Dilutions Problem Work Circle final answer with correct sig figs and unit What is the molarity of a 3.89g sample of CaCl2 dissolved in 500.mL? How many grams of KCl are required to prepare 500 ml of a 0.125 M solution? A 35.0 ml 5.0M solution is diluted to 1.67M. What is the volume of the new solution? A 12.3M solution is diluted to a volume of 990.0mL. If the new molarity is 3.0M, what is the initial volume of solution needed? Chemical vs. Physical Changes, Reactions, Balancing Equations, Stoichiometry 1. Balance and identify the type of reaction represented by the chemical equations below (synthesis, decomposition, single replacement, double replacement, combustion, neutralization): Chemical Equation Type of Reaction H 2 + O 2 H 2 O LiCl + MgBr 2 LiBr + MgCl 2 C 6 H 12 O 6 C + O 2 + H 2 C 4 H 8 + O 2 H 2 O + CO 2 Cu + H 3 PO 4 H 2 + CuPO 4 2. What is the difference between a chemical and a physical change? Chemical and physical property? 4

Stoichiometry: Problem Work Circle final answer with correct sig figs and unit 2H 2 + O 2 2H 2O What is the mass of water produced from 9.67g of hydrogen gas? 2 C 2H 6 + 7 O 2 4 CO 2 + 6 H 2O If 5.2 moles of ethane (C 2H 6) is burned, how many moles of O 2 are required? Pb(NO 3) 2 + 2 KI PbI 2 + 2 KNO 3 If 5.00 grams of potassium iodide reacts according to the equation above, how many grams of lead iodide will be produced? Gas Laws 1. A 5.67L sample of a gas has a pressure of 1.45atm. What is the new volume of the gas at 2.00atm? 2. A 120.0mL sample of gas has a temperature of 256K and a pressure of 600.torr. What is the new pressure if the volume is decreased to 55.0mL at a temperature of 301K? 3. What is the temperature of a 5.00 mole gas sample with a pressure of 1.57kPa and a volume of 3.56L? 4. What is the partial pressure of oxygen gas if it is mixed with 0.50atm of nitrogen gas? The total pressure of the mixture is 1.30atm? 5

5. Physical Behavior of Matter, Interpreting Graphs 6. What is the relationship between strength of intermolecular forces and boiling point? 6

7

8. What is the energy needed to heat 5.55g of water to boiling? ( H vap =51.5cal/g) 9. What is the energy needed to heat 30.7g of water from 55 C to 85 C? (Cp=4.186kJ/gC) 8

Atomic Theory 1. Complete the following table with element symbol, # of protons, neutrons, electrons, valence electrons, electron configuration, and valence electrons Element Mass Symbol Number 52 24Cr +3 p + e - n o Long form E.C. # of valence electrons 52 28 1s 2s 2p 3s 3p 4s 3d 4p 2. What is different between ions of the same element? What is the same? C-13 35 16 18 50 22 20 33 33 45 1s 2s 2p 3s 3p 4s 3d 4p 1s 2s 2p 3s 3p 4s 3d 4p 1s 2s 2p 3s 3p 4s 3d 4p 1s 2s 2p 3s 3p 4s 3d 4p 3. What is the difference between isotopes of the same element? What is the same? Mg-24 1s 2s 2p 3s 3p 4s 3d 4p 4. The natural abundances of all of nitrogen s isotopes are: 70.% N-14, 15% N-15, and 15% N- 16? Calculate the average atomic mass of nitrogen. 5. Fill in the blanks about the history of the atom: a. The model says the electrons orbit the nucleus b. The model says the electrons can be found in clouds around the nucleus c. Thomson discovered the during the cathode ray tube experiment. d. The gold foil experiment, performed by, which allowed him to conclude the atom was mostly with a dense, positive central core 6. What is the ion formed for Magnesium? Oxygen? 7. Complete the following orbital diagrams and electron configurations: Ground state Phosphorous Excited State Phosphorus 9

Periodic Table and Trends 1. Complete the table below. Group # Group/Family Name 1 ns 1 2 ns 2 Valence Configuration # of Valence Electrons 3-12 It varies It varies 13 The Boron Family ns 2 np 1 14 The Carbon Family 15 The Nitrogen Family 16 The Oxygen Family 17 18 ns 2 np 6 2. Complete the following sentences with the words increase or decrease. A. As you move from left to right across a period on the periodic table, the number of protons will B. As you move from left to right across a period on the periodic table, the atomic radius will C. As you move from left to right across a period on the periodic table, the 1 st ionization energy will D. As you move from left to right across a period on the periodic table, the electronegativity will E. As you move from top to bottom down a group on the periodic table, the atomic radius will F. As you move from top to bottom down a group on the periodic table, the 1 st ionization energy will G. As you move from top to bottom down a group on the periodic table, the electronegativity will 3. In Group 1, the most reactive element would be. This can be explained because metals need to electrons when they undergo chemical reactions, and so the the atom, the more reactive it will be. 4. In Group 17, the most reactive element would be. This can be explained because nonmetals need to electrons when they undergo chemical reactions, and so the the atom, the more reactive it will be. 10

Bonding and Nomenclature 1. Complete the table below by finding the term that fills in the blank correctly Ionic Covalent Metallic electrons Composed of and To name ionic compounds that have transition metals, use Roman numerals to indicate the electrons Composed of only To name covalent molecules, use prefixes to indicate the number of for each element. electrons Composed of only To name metallic compounds, it is the name of the. 2. Write the name or formula for the following polyatomic ions. Name Formula Name Formula Name Formula Ammonium Carbonate Nitrate OH 1- SO 4 2- PO 4-3 3. Complete the table below. Correctly write the name or formula for each and indicate whether it is ionic (I) or covalent (C). Name Formula Type magnesium chloride sulfur trioxide iron (III) iodide CaBr 2 N 2 O 3 CrSO 4 11

Complete the following table: Essential Information: Total valence electrons: Structure: Essential Questions: Additional Information: VSEPR Formula Polar or Nonpolar Molecule: CCl4 Electrons in Bonds: Electrons in Lone Pairs: Total valence electrons: Shape: Hybridization VSEPR Formula Major intermolecular force: Oxidation Number: C: Cl: Polar or Nonpolar Molecule: H2O Electrons in Bonds: Electrons in Lone Pairs: Total valence electrons: Shape: Hybridization VSEPR Formula Major intermolecular force: Oxidation Number: H: O: Polar or Nonpolar Molecule: CO2 Electrons in Bonds: Electrons in Lone Pairs: Shape: Hybridization Major intermolecular force: Oxidation Number: C: O: 12