J. Am. Chem. Soc., 1997, 119(41), , DOI: /ja964223u

J. Am. Chem. Soc., 1997, 119(41), 9624-9631, DOI:1.121/ja964223u Terms & Conditions Electronic Supporting Information files are available without a subscription to ACS Web Editions. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting Information. Files available from the ACS website may be downloaded for personal use only. Users are not otherwise permitted to reproduce, republish, redistribute, or sell any Supporting Information from the ACS website, either in whole or in part, in either machinereadable form or any other form without permission from the American Chemical Society. For permission to reproduce, republish and redistribute this material, requesters must process their own requests via the RightsLink permission system. Information about how to use the RightsLink permission system can be found at http://pubs.acs.org/page/copyright/permissions.html Copyright 1997 American Chemical Society

PWRKIN ELMER 13.51- / ~;:z" 61 u I to ) to CD N 1 O. CID Cl) 1 CD '.4.~J. Co ~-1 '.4 Cu Cu C21 4 35 3 25 2 15 1 cm'1 96/5/15 21: 59 X: 4 scans, 2.cm-1, flat, smooth

GZ-III-3-7 BR K4F. 3 AU PROG: XOO.AU DATE 5-11-96 TIME 14: 21 N ":~ ( SOLVENT CDC13 SF 3.133 SY 1. 1 4633.5 SI 65535 TD 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 1 TE 297 FM 76 2 32. OP 63L DO LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -.8OOP HZ/CM 85.754 PPM/CM.286 SR 3373. Di 1. PO 5. RGA RD. PM. DE 13.8 DS 5.1 NE 1 4. 3. 2. PPM

z T r a n B 8 t a n C B 4 38 36 34 32 3 28 26 24 22 2 18 16 14 Wavenumbers (cm-)

GZ-III-281 B R ML15F. 125 AU PROG: X.AU DATE 15-B-96 TIME 19: 16 SOLVENT CDC13 SF 4.134 SY. 1 682.9 SI 65536 TO 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 8 TE 297 FM 76 2 32. DP 63L PO LB.18 GB. CX 35. CY 2. Fi F2 9.2P -.BOOP HZ/CM 114.323 PPM/CM.286 SR 442.8 Di i. PO 7.2 RGA RD. PW. DE 13.8 DS D5.1 NE I 9. B. 7. 4. PPM 1.

PERKIN ELMER 4.23 9 % T 16/ p 1.35 I 4 35 96/4/15 18: 14 X: 8 scans, 4.cm-1, 3 25 2 15 1 cm' flat, smooth

Z-III-217N 4.4,19 Z i MI15OF.138 AU PROG: XOO.AU DATE 15-5-96 d TIME 22: 12 SOLVENT CDC13 SF 4.134 i. 1 682.9 SI TD 32768 32768 SW 624.96 HZ/PT.368 BRR AG 2.72 RG 32 TE 297 FW 76 2 32. OP 63L PO LB.18 GB. CX 35. CY 2. Fl 9.21P F2 -. 799P HZ/CM 114.317 PPM/CM.286 SR 442.8 1 1. PA RD RGA. 7.2 PW. DE 13.8 DS DS.1 NE 1 I. ITI I T I T -- T- T-1T - 9. B. L.... ( 1. (.

PERK IN ELJ ER AlJ-- 2. 81 Tif4 jrvltl 4. (3 Cu C CD CO N to1 to *3 C~u, ID 1 ID ~1 u '.1 CD 8.3 - --- - -- 1 4 35 96/6/7 21: 22 X: 4 scans, 4.cm-i. Cu r 3 25 flat, smooth I 2 15 1 ~1 cm'

ft q / BSR KTi7F.112 AU PROG: XOO.AU DATE 17-4-97 TIME 13: 1 FA / C OC4,2 SOLVENT [EfW SF 3.133 SY 1. 1 4873.7 SI 32768 TD 32768 SW 624.96 HZ/PT.368 AG 2.72 RG 2 NS TE 32 297 FW 76 2 32. OP 63L LB.9 GB.5 CX 35. CY 3. Fl 12.P F2 -.799P HZ/CM 19.758 PPM/CM.366 SR 3373. D1 1. PO 5. RGA RD. PW. DE 13.8 DS D5.1 NE I I-. 6. PPM 4. 3. 2. 1..

ERK IN ELMER CiIA CO C' t~om to-. VI) to 1 * a, M: t) (11 C,, to 1 CD 24.57-- - --- -F -- - 4 35 3 25 96/6/8 9: 54 X: 4 scans, 4.cm-i. flat, smooth 2 i~oo - -- - 1 Cur'

UZ-IV-6i B R KT17F.12 AU PROG: XOO.AU DATE 17-4-97 TIME 14: 22 -j-fa/icrc SOLVENT AuSM SF 3.133 SY oo. 1 5383.9 SI 32768 TD 32768 SW 624.96 HZ/PT.368 AG 2.72 RG 2 TE 297 FW 76 2 32. DP 63L LB.9 GB.5 CX 35. CY 2. Fi 14.21P F2 -.799P HZ/CM 128.626 PPM/CM.429 SR 3373. Di 1. PO 5. RGA RD. PW. DE 13.8 DS DS.1 NE i 14. 13. 12. i /. b. 5. 4. 3. 2. 1.. PPM

P.E3KIN ELE2 6 24.53J %T 'I _ d14 j2 r) L*fl1 In Mv M' M'- "'C In r-.m 1OO t- IV C') 1 ) N Mv wt1 (f~ 14.324.-- 4-3 -- - - 35 3 25 2 15 1 cm- 1 96/5/2 14: 26 X: 4 scans. 4.cm-i, flat, smooth

GZ-IV-63 B R L I,' KT17F.Hi AU PROG: XOO.AU DATE 17-4-97 TIME 12: 51 SOLVENT dew SF 3.133 SY 1. 4873.7 SI 32768 TD 32768 SW 624.96 HZ/PT.368 AG 2.72 RG 2 TE 297 FW 76 2 32. DP 63L DO LB.9 GB.5 CX 35. CY. Fi 12.OOOP F2 -. 799P HZ/CM 19.758 PPM/CM.366 SR 3373. D1 1. PO 5. RGA RD. PW. DE 13.8 DS 5.1 NE 1 1. 9. PPM 5. 4. 1..

lv2- - (FO 28.2-3 ~ '-I It U, to rl. j L xj Cu (Ir to,ri (O Cu F, ; I Cr) 7. 64 4 35 3 25 2 :boo 1 cm~ 96/5,'28 12: X: 4 scans, 27 4.Ocm-1, flat, smooth

GZ-IV-7 19- A4 3 B R K4F.129 AU PROG: XOO.AU DATE 5-11-96 TIME 14: 14 C SOLVENT CDC13 SF 3.133 SY 1. 1 4633.5 SI 65536 TO 32768 SW 624.96 O HZ/PT.184 AG 2.72 RG 1 TE 297 FM 76 2 32. DP 63L DO LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -. 8OP HZ/CM 85.754 < PPM/CM.286 SR 3373. Di 1. PO 5. RGA RD. PW. DE 13.8 DS D5.± NE I 9. 8. 6. 5. PPM4. 2. 1.

PERKIN ELMER 3.77 %T 1% 'a Co Cu Cli avv rm I I CDn to aa Eo N ) Cu to ZZ3 to a) O) CD U ) 18.33±- 4 -- -3 35 3 96/6/8 17: 3 X: 4 scans, 4.cm-i, flat, -5 25 smooth 2 2 15 1 cm-1

Filename: M497JUn24_12:18 U8C Mercury 4 STANDARD 1 OBBERVE Qz-III-224 I expl stdh ganpha cc. date Jun 24 97 dfrg solvent CDC13 da file exp dpwr ACQUISITION dof sfrq 4.114 di tol E1 dam at 2.999 daf up 384 P sw 641.8 tfil tb 36 proc be 16 fn tpwr 55 pw 7.7 werr di 1. Vexp tof 382.6 wbm nt 16 Mt at 16 alock n gain 22 FLAGS 11 ni in n y DISPLAT sp -8. VP 5281.5 Vs 586 so wa 25 him 21.13 in 5. rfl 78.5 rfy -19.7 th 17 inn 1. al cdc ph & VT 4.114 m1 4 ROCZSIG a 14 ft not used react glidevexp ~%' I; <.73.8 28.65m

P'ERKIN ELER 21.61 %T *-b # OD * Wctil N* Cu Co WI CD In vi1 CI ED N (f~ 4 35 3 25 2 15 1 cm~ 97/4/9 14: 11 X: 4 scans, 4.cm-1, flat, smooth

-s GZ (/D B8R KTOBOF.125 AU PROG: XOO.AU DATE 8-4-97 TIME 19: 55 SOLVENT CDC13 SF 3.133 SY 1. 1 4873.7 SI 65536 TO 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 8 TE 297 FM 76 2 DP 32. 63L LB.9 GB.5 CX 35. CY 2. F1 9.2P F2 -.8P HZ/CM 85.754 PPM/CM.286 SR 3373. D1 1. PO 5. RGA RD PM.. DE 13.8 Ds 5.1 NE I 7. I I I I I I I I I I I II~I 6. 5. 4. 3. 2. PPM 1 IiII I j I I I I 1..

PEMCIN ELMER 4 35 3 25 2 15 1 cm 97/3/6 2* 58 X 4 scans, 4.cm-i. flat, smooth

GZ- BS R SHOF.118 AU PROG: XOO.AU DATE 11-3-97 TIME 21: 29 SOLVENT COC13 SF 3.133 SY 1. 4633.5 SI 65536 TD 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 1 / B TE 297 FM 76 2 DP 32. 63L DO LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -.8OOP HZ/CM 85.754 PPM/CM.286 SR 3373. 1. PO 5. RGA RD. PM DE. 13.8 OS D5.1 11 NE I PPM 3. 2. 1..

19.9-4 35 97/3/13 14: 55 Y: 4 scans, 4.Cm-1, 3 25 flat, smooth 2 15 1 cm-1

V B8R N7> KSIOOF 118 AU PROG: XOO.AU DATE 1-3-97 TIME 21: 13 SOLVENT CDC13 SF 3.133 SY 1. 1 4633.5 SI 65536 TD 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 2 TE 297 FW 76 2 32. DP 63L DO LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -.8P HZ/CM 85.754 PPM/CM.286 SR 3373. Di 1. PO 5. RGA RD. PW. DE 13.8 DS 5.1 NE I 7. 6. 5. PPM 1..

psitin amiv 22 4 aeo 97/2/27 19: 17 X* 4 scans, 4.cm-1i. flat. smooth soo 2 25 2 15 I 1 co-'

Gz-Iv- B R kr2if.11 AU PROG: XOO.AU DATE 21-2-97 TIME ±1: 7 SOLVENT Other SF 3.132 SY 1. 1 3594.4 SI 65536 TD 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 4 TE 297 FM 76 2 DP 32. 63L DO TEA LB GB.9.5 CX 35. CY 2. F1 12.OOOP F2 -.799P HZ/CM 19.758 PPM/CM.366 SR 294.45 Di 1. PO 5. AGA RD. PM. DE 13.8 DS 5.1 NE 1 11. 1. 9. 8. 7. 6. PPM.

-1FawN JER U'- ~ I J- pi",la A a,,/ %T /1-, / N N ~1 ti~ C ~1 eu aie Nu cc PI vi i CD~ 3.27-- 1 4 3eo 97/3/3 It 31 X: 4 scans. 4.cm-1. s1oo flat, smooth aooo 15 1 cm-

GZ-IV-125,- KR2iOF. 16 AU PROG: XOO.AU DATE 23-2-97 TIME 19:4 SOLVENT COC13 SF 3.133 SY ioo.o 1 4633.5 SI 65536 TD 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 4 TE 297 FW 76 <, 2 OP 32. 63L LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -.8P HZ/CM 85.754 PPM/CM.286 SR 3373. Di PO i. 5. RGA RD PW.. DE 13.8 DS D5.1 NE A PPM 9. 6. 7/. 63. 5. 4, 3. 2. 1.. IIZ

TJR"IN ET lvf.8. 51- -AP -7, C) U) to at) -Cu w tf) cn Cu Cx. 1.78-1 I- -,-- 4C 35 31,1 rico 1 crln- 9.16/1-18 O:? KL. ~.3t, smcoth smcot"

GZ-IV-198 B R C)- D KViOOF. 2 AU PRO: XOO.AU DATE 1-6-97 TIME 19: 44 SOLVENT CDC13 SF 3.133 SY 1oo. 1 4633.5 SI 65536 TO 32768 SW 624.96 HZ/PT.184 AG 2.72 RG 32 TE 297,r FW 76 2 32. OP 63L DO LB.9 GB.5 CX 35. CY 2. Fi 9.2P F2 -.BOOP HZ/CM 85.754 PPM/CM.286 SR 3373. /I Di i. PO 5. RGA RD. PW. DE 13.8 Os 5.1 NE I cc (D z 7. 6. PPM 1..