CHEMISTRY - BURDGE-ATOMS FIRST 3E BONUS: MATHEMATICAL OPERATIONS AND FUNCTIONS

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CONCEPT: MULTIPLICATION AND DIVISION When you multiply values in scientific notation you the coefficients and the exponents. (A 10 x ) (B 10 y ) = When you divide values in scientific notation you the coefficients and the exponents. (A 10 x ) (B 10 y ) = After multiplying and/or dividing remember that for the coefficient will have the. EXAMPLE 1: Using the method discussed above, determine the answer when the following values are multiplied. (2.134 10 5 ) (1.6 10 3 ) (3.07 10 6 ) EXAMPLE 2: Using the methods discussed above, determine the answer for the following mixed operations question. (7.33 10 8 ) (9.89 10 1 ) (6.12 10 11 ) Page 2

CONCEPT: ADDITION AND SUBSTRACTION When you add or subtract values in scientific notation they must have the same exponents. The coefficients add or subtract, but the exponents. A 10 x B 10 x (A B) 10 x A 10 x + B 10 x (A + B) 10 x If the exponents are not the same then we transform the value so that they do. Remember when adding or subtracting values that the final answer must have the. EXAMPLE 1: Using the method discussed above, determine the answer to the following question. 8.17 10 8 +1.25 10 9 EXAMPLE 2: Using the method discussed above, determine the answer to the following question. 9.08 10 11 1.17 10 12 3.35 10 13 Page 3

CONCEPT: POWERS AND ROOT FUNCTIONS When we raise a value in scientific notation to a particular power we raise the coefficient to that power, but then we the exponent and the power. (3.0 10 2 ) 3 = When we take a value in scientific notation to the nth root we raise the coefficient to the reciprocal power and we the exponent portion by that reciprocal power value. 3 6.0 10 9 = EXAMPLE: Using the method discussed above, determine the answer to the following question. (7.5 10 3 ) 5 4 (8.6 10 21 Page 4

CONCEPT: LOGARITHMIC FUNCTIONS The logarithmic base 10 form represents the exponent that 10 must be raised in order to obtain that specific number. For example: 10 1 =10 log10 =1 10 4 =10, 000 10 1 = 0.10 10 0 =1 EXAMPLE 1: Without using a calculator, determine the answer to the following questions. log1.0 10 7 log1000 EXAMPLE 2: Without using a calculator, determine the answer to the following questions. log1.0 10 5 log0.0001 Page 5

CONCEPT: INVERSE LOGARITHMIC FUNCTIONS The inverse or anti logarithmic function can be seen as the opposite of the logarithmic function. logx = y inv log y =10 y = x So applying this logic the example below would go as follows: log100 = 2 invlog 2 = EXAMPLE: The Henderson-Hasselbalch equation is a useful equation for the determination of the ph of a buffer. With its equation, shown below, determine the ratio of conjugate base to weak acid when the ph = 4.17 and pka = 3.83. ph = pka + log conjugate base weak acid a) 0.469 b) 0.457 c) 2.19 d) 1.0 x 10-8 Page 6

CONCEPT: NATURAL LOGARITHMIC FUNCTIONS The natural logarithm, sometimes shortened to just ln, of a value is the exponent to which e must be raised to determine that number. For example: ln1000 = 6.908 This means that e, the inverse of the natural logarithm, had to be said to 6.908 in order to obtain 1000. The inverse of the natural logarithm again symbolized by the variable e can be seen as the opposite of the natural logarithm ln. ln x = y invln y = e y = x So applying this logic the example below would go as follows: ln2 = 0.693 invln 0.693 EXAMPLE: Based on your understanding of natural logarithmic functions solve for the missing variable in the following question: ln[x] = (2.13 10 1 )(12.3)+ ln[1.25] Page 7

CONCEPT: MATHEMATICAL RELATIONSHIPS USING LOGARITHMS When dealing with the logarithmic form or the natural logarithmic form it is important to remember the following relationships. MULTIPLICATION log(a b) = ln(a b) = DIVISION log a b = ln a b = RAISED TO A POWER loga x = lna x = TAKEN TO THE n th ROOT log x x a = ln a = EXAMPLE: Solve the following without the use of a calculator. If log 3 = 0.48 and log 2 = 0.30, what would be the value of log 12? Page 8

CONCEPT: THE QUADRATIC FORMULA The quadratic formula is used for algebraic equations that contain an x variable raised to the second power:. x = b ± b2 4ac 2a The quadratic formula is most commonly used for questions dealing with chemical equilibrium. Although the presence of the ± sign gives two possible values for x, only one of them will be significant and used as the answer. EXAMPLE: Using the quadratic formula solve for x when given the following algebraic expression: 4x = 2.13 10 4 + 1.75 10 5 x Page 9