INSTALLATION OF PORTABLE O3 MONITORING STATION NATIONAL PARK SERVICE AMBIENT AIR QUALITY AND METEOROLOGY MONITORING NETWORK

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INSTALLATION OF PORTABLE O3 MONITORING STATION TIOL PARK SERVICE AMBIENT AIR QUALITY AND METEOROLOGY MONITORING NETWORK ASSATEAGUE ISLAND TIOL SEASHORE APRIL 24, 2006 prepared for John Ray TIOL PARK SERVICE Research and Monitoring Branch Air Resources Division P.O. Box 25287 Denver, Colorado 80225 NPS Contract No. C2350010840 prepared by AIR RESOURCE SPECIALISTS, INC. 1901 Sharp Point Drive Suite E Fort Collins, Colorado 80525

1.0 CALIBRATION SUMMARY In accordance with NPS Gaseous Pollutant Monitoring Program (GPMP) guidelines, ARS performed a maintenance and calibration visit at the following air quality station: Park or Monument: Assateague Island National Seashore Air quality site: Maintenance Yard Subject: Re-Installation Visit Service date: April 24, 2006 Service technician: Michael Slate A summary of pre- and post-maintenance calibration results is presented in Table 1-1. Pre Maintenance Calibration Summary: All sensors passed the pre-maintenance checks except rainfall, which was found to be 10 percent low. Maintenance Action Summary: Ozone: The 2B Technologies O3 monitor (SN 173) was calibrated at ARS prior to this installation trip. No on-site calibration was required. The 2B instrument installed has the Nafion desiccant and the memory card. During the installation, the analyzer responded as expected. Meteorological: The wind speed/direction sensor was rebuilt, aligned, and passed all checks. The relative humidity/ambient temperature sensor was replaced with a recent calibrated unit and checked against a reference sensor onsite with good results. The solar radiation sensor was compared to a reference sensor with good results. The rainfall sensor failed the first tipping test. The tipping points were adjusted, and the test was performed again with excellent results. Post Maintenance Calibration Summary: All systems were within specifications.

STATION OPERATOR 2.0 ADDITIOL NOTES AND OBSERVATIONS Eric Sherry is the station operator and was refreshed to perform the weekly checks on the air quality station. Eric also assisted in the installation of the system. MONITORING EQUIPMENT This station operated at this location last season. The tripod and solar system were not moved. There is substantial evidence that birds like to perch on the equipment, especially the solar radiation sensor. The operator may try using an owl or snake decoy to keep the birds away. The Campbell Scientific Data Logger, Model 23X has serial number 5453. The ORBCOMM Satellite Modem, Model Q2000 manufactured by Quake, has serial number 1400. Campbell Scientific Relay Driver has serial number 2791. SITE LOCATION The following coordinates of the site location were determined by a hand held GPS unit: N 38 o 15 03.6 W 75 o 09 33.6 Elevation: 7 feet 3.0 CALIBRATION FORMS All calibration forms are attached. These forms present the details of pre- and postmaintenance calibrations.

Calibration Summary Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Parameter Criteria Accuracy Goal Precipitation max error <= ± 5.0 Pre-Maintenance Mfg, & Value Texas Electronics 525M 33788-604 -10.1 FAIL Calibration Results Post Maintenance Mfg, & Value Texas Electronics 525M 33788-604 -2.5 PASS Relative Humidity PRE Sensor ID# Z1730047 max error <= ± 5.0 Vaisala HMP45C Z1730047 3.4 PASS Vaisala HMP45C Z4430018 4.8 PASS Solar Radiation average error <= ± 5 LiCor Pyranometer PY 48449-4 PASS LiCor Pyranometer PY 48449 0 PASS Temperature max error Climatronics <= ± 0.2º C; RM Young <= ± 0.5º C; Rotronics <= ± 1.0º C Vaisala HMP45C Z1730047 1.0º PASS Vaisala HMP45C Z4430018 1.0º PASS Wind Direction Alignment max error <= ± 5º 2º PASS 2º PASS Linearity max error <= ± 3º Climatronics 100076 2º PASS Climatronics 100076 3º PASS 41318 54061 Starting Threshold max error Climatronics <= 6 g-cm; RM Young AQ <= 9 g-cm; RM Young MA <= 30 g-cm, RM Young RE <= 7 g-cm Wind Speed max Wind Speed <5 max error <= ± 0.2 m/s N/A N/A N/A N/A max Wind Speed >= 5 max error <= ± 5 RM Young AQ 4.3 PASS RM Young AQ 4.3 PASS 05305 41318 05305 54061 Starting Threshold max error Climatronics <= 0.2 g-cm; RM Young AQ <= 0.3 g-cm; RM Young MA <= 2.9 g-cm, RM Young RE <= 0.3 g-cm

Calibration Standards Field Specialist: Operator: Network: Location: Site: Date: Last Site Visit: Slate, Mike Eric Sherry NPS Assateague Island ASIS-MA 4/24/2006 6/16/2005 Parameter Device Manufacturer Model S/N Calibration Date Voltage Fluke 87 III 81370250 2/9/2006 Voltage Source Calib. Inc. DVC-350A Ozone Transfer Standard TECO 49PS Gas Dilution Mass flow ERT Gas Dil Barometric Pressure Barometer/Altimeter AIR AIR-HB-1A 3F2502 5/21/2004 High Flow Dry cal BIOS DC2 Low Flow Dry cal BIOS DC2 Precipitation PPT Calibrator Novalynx 260-2595 10/8/2002 Volume (ml): 936 Relative Humidity RH Sensor Rotronics MP101A 75276 11/17/2005 Solar Radiation Thermopile LiCor Pyranometer PY12080 4/11/2003 Multiplier 95.64 Temperature Digital Thermometer Eutechinics 4400 305454 3/7/2006 Torque Gauge RM Young 18331 4548 Wind Direction Linearity Jig RM Young 18212 Compass Brunton 5006LM 506595000 Wind Speed Torque Disk RM Young 18310 4548 Anemometer Drive RM Young 18802 CA 02409 8/2/2002 Volumetric Flow Comments:

WETNESS, PRECIPITATION AND BAROMETRIC PRESSURE CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Barometric Pressure Reference S/N: 3F2502 Calibration Date: 05/21/04 Precipitation Reference S/N: Calibration Volume: 936 ml Calibration Date: 10/08/02 WETNESS Pre-Maintenance Post Maintenance DRY WET PRE-MAINTENCE SENSOR RESPONSE LED (ON/OFF) off on DRY WET POST MAINTENCE SENSOR RESPONSE LED (ON/OFF) off on Pre-Maint Wetness Comments: Post Maint Wetness Comments: PRECIPITATION Reference Pre-Maintenance Post Maintenance Calibration Inlet Volume Diameter mm mm/tip Texas Electronics Texas Electronics 6.06 48.3 4.73 525M 525M 8.00 27.8 8.23 33788-604 33788-604 900 cc 9.66 19.0 4.73 Inlet Novalynx 9.66" 9.66" Diameter 260-2500 27.8 8.24 RM Young 52202 45.0 2.0 PRE-MAINTENCE POST MAINTENCE 6.06 50.3 4.73 Cal Volume Designated Cal Volume Designated mm mm (ml) value in mm (ml) value in mm 8.00 28.9 8.23 936 19.8 17.8-10.1 FAIL 936 19.8 19.3-2.5 PASS 936 CC 9.66 19.8 4.73 Novalynx 260-2500 28.9 8.2 RM Young 52202 46.8 2.0 Pre-Maint Precipitation Comments: Adjusted tipping points to 4.73 ml. Post Maint Precipitation Comments: BAROMETRIC PRESSURE PRE-MAINTENCE POST MAINTENCE SENSOR RESPONSE PRE-MAINTENCE POST MAINTENCE Reference (Volts) (mm Hg) Reference (Volts) (mm Hg) Maximum: Maximum: Pre-Maint Barometric Pressure Comments: Post Maint Barometric Pressure Comments:

SOLAR RADIATION CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Solar Radiation Reference S/N: PY12080 Reference Factor: 95.64(W/m2) Calibration Date: 04/11/03 High Flow Standard Reference S/N: N/A Calibration Date: SOLAR RADIATION PRE-MAINTENCE LiCor Pyranometer POST MAINTENCE LiCor Pyranometer PY 48449 PY 48449 Translator TRANSLATOR CARD PRE-MAINTENCE POST MAINTENCE SETTING (W/m2) (W/m2) Zero Span SENSOR RESPONSE PRE-MAINTENCE POST MAINTENCE HOUR (W/m2) T.STD HOUR (W/m2) T.STD 09:00 159 168-5 11:00 779 783-1 10:00 245 252-3 12:00 702 705 0 11:00 13:00 762 763 0 12:00 14:00 13:00 15:00 14:00 16:00 Average : -4 Average : 0 : PASS : PASS Pre-Maint Solar Radiation Comments: Post Maint Solar Radiation Comments:

TEMPERATURE, DELTA TEMPERATURE AND RELATIVE HUMIDITY CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Reference Thermometer S/N: 305454 Calibration Date: 03/07/06 Relative Humidity Reference S/N: 75276 Calibration Date: 11/17/05 TEMPERATURE / DELTA TEMPERATURE Temperature Delta Temp. Translator Pre-Maintenance Vaisala HMP45C Z1730047 Post Maintenance Vaisala HMP45C Z4430018 PRE-MAINTENCE SENSOR RESPONSE PRE- TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE 15.1 14.1-1.0 PASS Zero 16.1 15.2-0.9 PASS Span Maximum : 1.0 PASS Maximum : POST MAINTENCE SENSOR RESPONSE POST TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE 17.9 16.9-1.0 PASS Zero 23.1 22.2-0.9 PASS Span 23.3 22.3-1.0 PASS Maximum : 1.0 PASS Maximum : Pre-Maint Temperature Comments: AT/RH replaced at 9:30 EDT on 4/24/06. Post Maint Temperature Comments: RELATIVE HUMIDITY Pre-Maintenance Vaisala HMP45C Z1730047 Post Maintenance Vaisala HMP45C Z4430018 PRE-MAINTENCE SENSOR RESPONSE POST MAINTENCE SENSOR RESPONSE HOUR T.STD HOUR T.STD 9:00 92.3 88.9 3.4 PASS 11:00 83.4 78.6 4.8 PASS

WIND DIRECTION CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike To Landmark #1: 326 Degrees True From Landmark #1: 146 LM Description: To Landmark #2: 61 Degrees True From Landmark #2: 241 LM Description: Declination: Degrees Wind Direction Reference S/N: 506595000 Calibration Date: Tower Tall Tree WIND DIRECTION WIND DIRECTION ALIGNMENT PRE-MAINTENCE POST MAINTENCE PRE-MAINTENCE POST MAINTENCE Land Mark Reference Degrees Degrees Climatronics Climatronics (degrees) (degrees) 100076 100076 To 1 328 2 PASS 327 1 PASS 41318 54061 From 1 148 2 PASS 145-1 PASS Translator To 2 63 2 PASS 61 0 PASS From 2 242 1 PASS 243 2 PASS WIND DIRECTION TRANSLATOR CARD Average : 2 PASS Average : 1 PASS Card Setting Zero PRE POST Maximum : 2 PASS Maximum : 2 PASS WIND DIRECTION LINEARITY Span Check PRE-MAINTENCE POST MAINTENCE Point 360 Oscillator Frequency (Hz) = Data Logger Should Read (degrees) Degrees (degrees) Degrees 1 0 1 PASS 0 0 PASS 2 44-1 PASS 42-3 PASS WIND DIRECTION STARTING THRESHOLD 3 89 0 PASS 86-1 PASS PRE POST 4 133-1 PASS 131 0 PASS Torque gm-cm Torque gm-cm 5 178 0 PASS 178 2 PASS 6 225 2 PASS 226 3 PASS Wind direction starting threshold accuracy goal: Climatronics <= 6 g-cm 7 269-1 PASS 271 0 PASS 8 314 0 PASS 315-1 PASS Average : 1 PASS Average : 1 PASS Maximum : 2 PASS Maximum : 3 PASS Pre-Maint Wind Direction Comments: Installed rebuilt WD sensor. Post Maint Wind Direction Comments:

WIND SPEED CALIBRATION FORM Network: NPS Location: Assateague Island Site: ASIS-MA Date: 04/24/06 Date of Last Site Visit: 06/16/05 Field Specialist: Slate, Mike Wind Speed Reference S/N: CA 02409 Calibration Date: 08/02/02 WIND SPEED WIND SPEED TRANSLATOR CARD PRE-MAINTENCE POST MAINTENCE Card PRE POST Setting RM Young AQ RM Young AQ 05305 05305 Zero 41318 54061 Span Translator Oscillator Frequency (Hz) = Data Logger Should Read WIND SPEED STARTING THRESHOLD PRE POST Torque gm-cm Torque gm-cm Wind speed starting threshold accuracy goal: RM Young AQ <= 0.3 g-cm Motor Speed (rpm) Climatronics RM Young WIND SPEED PRE-MAINTENCE WIND SPEED POST MAINTENCE 100 2.574 0.510 300 7.274 1.540 1.470-0.070 PASS 1.470-0.070 PASS 600 14.324 3.070 2.940-0.130 PASS 2.940-0.130 PASS 900 21.375 4.610 4.410-0.200 PASS 4.410-0.200 PASS 1200 28.425 6.140 5.880-0.260-4.2 PASS 5.880-0.260-4.2 PASS 1800 42.526 9.220 8.820-0.400-4.3 PASS 8.820-0.400-4.3 PASS 4000 N/A 20.480 19.600-0.880-4.3 PASS 19.600-0.880-4.3 PASS 7000 N/A 35.840 34.300-1.540-4.3 PASS 34.300-1.540-4.3 PASS Maximum ABS (use if Wind Speed <5): 1.540 1.540 Maximum ABS (use if Wind Speed >=5): 4.3 PASS 4.3 PASS Pre-Maint Wind Speed Comments: Post Maint Wind Speed Comments: