Station Maintenance and Calibration Report ABRAHAM LINCOLN BIRTHPLACE NATIONAL HISTORIC SITE March 13, 2007

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Station Maintenance and Calibration Report ABRAHAM LINCOLN BIRTHPLACE NATIONAL HISTORIC SITE March 13, 2007 National Park Service Gaseous Pollutant Monitoring Program Prepared by Air Resource Specialists, Inc. under Contract C2350064024 CALIBRATION SUMMARY Park: Abe Lincoln Birthplace Nat'l Historic Site Service Date: 03/13/07 Air quality site: Near Visitor's Center Field Specialist: Mike Bagby Subject: Seasonal start-up Site Operator: Jenny Jones All site visit and calibration forms are attached, detailing the pre- and post-maintenance calibrations. Pre-Maintenance Calibration Summary: All sensors except for the rain guage were within specifications. Maintenance Activity Summary: O3 A replacement 2B ozone analyzer was installed during this visit, and a pre-zero test was performed with the as-found charcoal canister and zero tubing. A final zero-air calibration check was performed after a new charcoal canister and new tubing were installed. These one-minute updates are documented on the calibration forms. This machine was turned off, until May 1, 2007, when the operator has been instructed to turn the machine back on again for the season. WS/WD Sensors were replaced with rebuilt and calibrated units (standard). AT/RH The AT/RH sensor was calibration checked, and found within correct tolerances. A new sensor was installed during this visit. A final calibration check was also performed. SR A calibration check showed this sensor was within correct tolerances. No adjustments were made during this visit. PRECIP A calibration check was performed, showing this rain gauge was incorrectly adjusted. The tipping mechanism was inspected and adjusted before a final calibration check. Final calibration values were within correct tolerances. Post-Maintenance Calibration Summary: All systems were within specifications. 1901 Sharp Point Drive, Suite E Fort Collins, CO 80525 Telephone: 970-484-7941

ADDITIONAL NOTES AND OBSERVATIONS Station Operator Jenny Jones is the current station operator and was briefly trained during the station visit. She has agreed to turn on the ozone monitor on May 1, 2007, to begin the summer ozone season. Monitoring Shelter This is a portable tripod system, with a solar panel array, storage batteries, and Orbcomm satellite transmitter. 1901 Sharp Point Drive, Suite E Fort Collins, CO 80525 Telephone: 970-484-7941

Calibration Summary Network: NPS Location: Abraham Lincol Site: ABLI-KC Date: 03/13/07 Last Site Visit: 03/09/06 Parameter Criteria Accuracy Goal Pre-Maintenance Mfg, & Value Calibration Results Post Maintenance Mfg, & Value O 3 Analyzer Average average error <= ± 5.0 Maximum max error <= ± 5.0 Correlation actual r > 0.9950 2B Tech 234 2B Tech 234 Intercept actual <= ± 3.0 ppb Slope actual 0.950 <= m <= 1.050 O 3 Reference Average average error <= ± 5.0 Maximum max error <= ± 5.0 Correlation actual r > 0.9950 Intercept actual <= ± 3.0 ppb Slope actual 0.950 <= m <= 1.050 Precipitation max error <= ± 5.0 Relative Humidity PRE Sensor ID# Z 2220055 max error <= ± 5.0 Texas Instruments TR 525M 31929-0103 (Tex. Inst) Vaisala HMP45C Z 2220055-10.5 FAIL 2.1 PASS Texas Instruments TR 525M 31929-0103 (Tex. Inst) Vaisala HMP45C Y 3250078-2.6 PASS 2.4 PASS Solar Radiation average error <= ± 5 LiCor Pyranometer 1 PASS LiCor Pyranometer Temperature max error Climatronics <= ± 0.2º C; <= ± 0.5º C; Rotronics <= ± 1.0º C Vaisala HMP45C Z 2220055 0.6º PASS Vaisala HMP45C Y 3250078 0.9º PASS Wind Direction Alignment max error <= ± 5º 2º PASS 3º PASS Linearity max error <= ± 3º AQ 2º PASS AQ 3º PASS 05305 none 05305 51200 Starting Threshold max error Climatronics <= 6 g-cm; AQ <= 9 g-cm; MA <= 30 g-cm, RE <= 7 g-cm Wind Speed max Wind Speed <5 max error <= ± 0.2 m/s N/A N/A N/A N/A max Wind Speed >= 5 max error <= ± 5 AQ 4.3 PASS AQ 4.3 PASS 05305 none 05305 51200 Starting Threshold max error Climatronics <= 0.2 g-cm; AQ <= 0.3 g-cm; MA <= 2.9 g-cm, RE <= 0.3 g-cm

Calibration Standards Field Specialist: Operator: Network: Location: Site: Date: Last Site Visit: Bagby, Mike Jennie Jones NPS Abraham Lincoln ABLI-KC 3/13/2007 3/9/2006 Latitude: 37 degrees 31 minutes 53 seconds Longitude: 85 degrees 44 minutes 5 seconds Elevation: Parameter Device Manufacturer Model S/N Calibration Date Voltage Fluke 8060A 5340209 4/7/2006 Voltage Source Calib. Inc. Ozone Transfer Standard Gas Dilution Mass flow ERT Barometric Pressure Barometer/Altimeter AIR High Flow Dry cal BIOS Low Flow Dry cal BIOS Precipitation PPT Calibrator Volume (ml): 900 Relative Humidity RH Sensor Visala HM 34C X 3220002 5/15/2006 Solar Radiation Thermopile LiCor LI 200 PY13273 6/26/2006 Multiplier 100.53 Temperature Digital Thermometer Visala Hm34C X 3220002 5/15/2006 Torque Gauge Wind Direction Linearity Jig Compass Brunton Wind Speed Torque Disk Anemometer Drive Volumetric Flow Comments:

PRE-MAINTENANCE OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference 2B Tech 234 Span Setting/ O3 Coefficient Zero/ O3 Bkg Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B Flow (Lpm)/ Flow A, Flow B Offset Cell Temp / Pressure STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO 0-6.5 Pass/ Fail Display Pass/ Fail 1 0-11 2 0-8.9 3 0-7.8 4 0-7.6 5 0-9.9 ZERO 0-6.9 Average : Maximum : Average : Maximum : LINEAR REGRESSION PLOT RESIDUALS PLOT Analyzer 500 400 300 200 100 Residual 15 10 5 0-5 -10 0 0 100 200 300 400 500 Transfer Standard Conc. -15 0 0 0 0 0 1 1 1 1 1 1 Regression Concentration Value

POST-MAINTENANCE OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference 2B Tech 234 Span Setting/ O3 Coefficient Zero/ O3 Bkg Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B Flow (Lpm)/ Flow A, Flow B Offset Cell Temp / Pressure STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO 0 0-1.3 Pass/ Fail Display Pass/ Fail 1 0-2.2 2 0-0.8 3 0-3 4 0-1.7 5 0-1.5 ZERO 0-0.4 Average ABS : Maximum : Average ABS : Maximum : LINEAR REGRESSION PLOT RESIDUALS PLOT Analyzer 500 400 300 200 100 Residual 15 10 5 0-5 -10 0 0 100 200 300 400 500 Transfer Standard Conc. -15 0 0 0 0 0 1 1 1 1 1 1 Regression Concentration Value

WETNESS, PRECIPITATION AND BAROMETRIC PRESSURE CALIBRATION FORM Barometric Pressure Reference S/N: N/A Calibration Date: Precipitation Reference S/N: N/A Calibration Volume: 900 ml Calibration Date: WETNESS Pre-Maintenance Post Maintenance DRY WET PRE-MAINTENANCE SENSOR RESPONSE LED (ON/OFF) off on DRY WET POST MAINTENANCE SENSOR RESPONSE LED (ON/OFF) off on Pre-Maint Wetness Comments: Post Maint Wetness Comments: PRECIPITATION Reference Pre-Maintenance Post Maintenance Calibration Inlet Volume Diameter mm mm/tip Texas Instruments Texas Instruments 6.06 48.3 4.73 TR 525M TR 525M 8.00 27.8 8.23 31929-0103 (Tex. Inst) 31929-0103 (Tex. Inst) 900 cc 9.66 19.0 4.73 Inlet Novalynx 9.66" 9.66" Diameter 260-2500 27.8 8.24 52202 45.0 2.0 PRE-MAINTENANCE POST MAINTENANCE 6.06 50.3 4.73 Cal Volume Designated Cal Volume Designated mm mm (ml) value in mm (ml) value in mm 8.00 28.9 8.23 900 19.0 17.0-10.5 FAIL 900 19.0 18.5-2.6 PASS 936 CC 9.66 19.8 4.73 Novalynx 260-2500 28.9 8.2 52202 46.8 2.0 Pre-Maint Precipitation Comments: made adjustments to tipping mechanism after pre-cal check. Post Maint Precipitation Comments: BAROMETRIC PRESSURE PRE-MAINTENANCE POST MAINTENANCE SENSOR RESPONSE PRE-MAINTENANCE POST MAINTENANCE Reference (Volts) (mm Hg) Reference (Volts) (mm Hg) Maximum: Maximum: Pre-Maint Barometric Pressure Comments: Post Maint Barometric Pressure Comments:

SOLAR RADIATION CALIBRATION FORM Solar Radiation Reference S/N: PY13273 Reference Factor: 100.53(W/m2) Calibration Date: 06/26/06 SOLAR RADIATION PRE-MAINTENANCE LiCor Pyranometer POST MAINTENANCE LiCor Pyranometer Translator TRANSLATOR CARD PRE-MAINTENANCE POST MAINTENANCE SETTING (W/m2) (W/m2) Zero Span SENSOR RESPONSE PRE-MAINTENANCE POST MAINTENANCE HOUR (W/m2) T.STD HOUR (W/m2) T.STD 11:00 622 615 1 12:00 12:00 13:00 13:00 14:00 14:00 15:00 15:00 16:00 16:00 17:00 Average : 1 Average : : PASS : Pre-Maint Solar Radiation Comments: Post Maint Solar Radiation Comments:

TEMPERATURE, DELTA TEMPERATURE AND RELATIVE HUMIDITY CALIBRATION FORM Reference Thermometer S/N: X 3220002 Calibration Date: 05/15/06 Relative Humidity Reference S/N: X 3220002 Calibration Date: 05/15/06 TEMPERATURE / DELTA TEMPERATURE Temperature Delta Temp. Translator Pre-Maintenance Vaisala HMP45C Z 2220055 Post Maintenance Vaisala HMP45C Y 3250078 PRE-MAINTENANCE SENSOR RESPONSE PRE- TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE 21.0 20.4-0.6 PASS Zero Span Maximum : 0.6 PASS Maximum : POST MAINTENANCE SENSOR RESPONSE POST TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE 25.6 24.7-0.9 PASS Zero Span Maximum : 0.9 PASS Maximum : Pre-Maint Temperature Comments: installed replacement AT/RH sensor during this visit. Post Maint Temperature Comments: RELATIVE HUMIDITY Pre-Maintenance Vaisala HMP45C Post Maintenance Vaisala HMP45C Z 2220055 Y 3250078 PRE-MAINTENANCE SENSOR RESPONSE POST MAINTENANCE SENSOR RESPONSE HOUR T.STD HOUR T.STD 10:00 10:00

WIND DIRECTION CALIBRATION FORM To Landmark #1: 180 Degrees True From Landmark #1: 360 LM Description: To Landmark #2: 90 Degrees True From Landmark #2: 270 LM Description: Declination: Degrees Wind Direction Reference S/N: N/A Calibration Date: jig Jig WIND DIRECTION WIND DIRECTION ALIGNMENT PRE-MAINTENANCE POST MAINTENANCE PRE-MAINTENANCE POST MAINTENANCE Land Mark Reference Degrees Degrees AQ AQ (degrees) (degrees) 05305 05305 To 1 179-1 PASS 177-3 PASS none 51200 From 1 2 2 PASS 363 3 PASS Translator To 2 92 2 PASS 87-3 PASS From 2 272 2 PASS 267-3 PASS WIND DIRECTION TRANSLATOR CARD Average : 2 PASS Average : 3 PASS Card Setting Zero PRE POST Maximum : 2 PASS Maximum : 3 PASS WIND DIRECTION LINEARITY Span Check PRE-MAINTENANCE POST MAINTENANCE Point 360 Oscillator Frequency (Hz) = Data Logger Should Read (degrees) Degrees (degrees) Degrees 1 45 0 PASS 89 0 PASS 2 91 1 PASS 135 1 PASS WIND DIRECTION STARTING THRESHOLD 3 134-2 PASS 181 1 PASS PRE POST 4 180 1 PASS 224-2 PASS Torque gm-cm Torque gm-cm 5 227 2 PASS 271 2 PASS 6 270-2 PASS 316 0 PASS Wind direction starting threshold accuracy goal: AQ <= 9 g-cm 7 315 0 PASS 2 1 PASS 8 0 0 PASS 44-3 PASS Average : 1 PASS Average : 1 PASS Maximum : 2 PASS Maximum : 3 PASS Pre-Maint Wind Direction Comments: Post Maint Wind Direction Comments:

WIND SPEED CALIBRATION FORM Wind Speed Reference S/N: N/A Calibration Date: WIND SPEED WIND SPEED TRANSLATOR CARD PRE-MAINTENANCE POST MAINTENANCE Card PRE POST Setting AQ AQ 05305 05305 Zero none 51200 Span Translator Oscillator Frequency (Hz) = Data Logger Should Read WIND SPEED STARTING THRESHOLD PRE POST Torque gm-cm Torque gm-cm Wind speed starting threshold accuracy goal: AQ <= 0.3 g-cm Motor Speed (rpm) Climatronics Met One WIND SPEED PRE-MAINTENANCE WIND SPEED POST MAINTENANCE 100 2.574 0.510 0.45 300 7.274 1.540 8.45 600 14.324 3.070 16.44 3.030-0.040 PASS 3.030-0.040 PASS 900 21.375 4.610 24.44 4.410-0.200 PASS 4.410-0.200 PASS 1200 28.425 6.140 N/A 1800 42.526 9.220 48.44 8.820-0.400-4.3 PASS 8.820-0.400-4.3 PASS 4000 N/A 20.480 N/A 7000 N/A 35.840 N/A 34.300-1.540-4.3 PASS 34.300-1.540-4.3 PASS Maximum ABS (use if Wind Speed <5): 1.540 1.540 Maximum ABS (use if Wind Speed >=5): 4.3 PASS 4.3 PASS Pre-Maint Wind Speed Comments: Post Maint Wind Speed Comments: