Twice-Annual Station Maintenance and Calibration Report BIG BEND NATIONAL PARK February 1, 212 National Park Service Gaseous Pollutant Monitoring Program Prepared by Air Resource Specialists, Inc. under Contract P11PC19 CALIBRATION SUMMARY Air Quality Site: K-Barr Primary Site Operator: Jenny Goucher & Raquel Acosta Field Specialist: Martin Valvur Backup Site Operator: Jeff Bennett All site visit and calibration forms are attached, detailing the pre- and post-maintenance calibrations. Pre-Maintenance Calibration Summary: All sensors were within specifications, with the exceptions of wind direction and rainfall. Maintenance Activity Summary: O 3 A pre-maintenance multipoint calibration was performed on the analyzer and the calibrator with good results. Routine maintenance was performed, followed by a post-maintenance multipoint, and both units passed. Following the pre-maintenance multipoint check, the calibrator s coefficient was adjusted. WS/WD The wind speed sensor passed both the pre- and post- maintenance testing. The wind direction sensor failed at one cardinal point, but the linearity results were good. The sensor was replaced and rechecked; again, it passed. AT A three-point check was performed on the temperature sensor and it passed. The aspirator fan was running. SR A calibration check confirmed this sensor to be within the 5 tolerance level. No adjustment was necessary. The sensor was found to be clean and level. PRECIP A precipitation test was performed on this instrument using 45 ml of water; it did not pass. The tipping mechanism was adjusted and retested, but still failed. Another adjustment was made and it failed again. The tipping mechanism was checked and it was not being obstructed by any wires. A 1 ml syringe was utilized to calibrate the tipping mechanism and it appeared correct, but when 45 ml were passed through, the final result was low. The signal wires have lost their coating, so this may be a reason for the incorrect tip count. New wiring will be installed during the next visit. 191 Sharp Point Drive, Suite E Fort Collins, CO 8525 Telephone: 97-484-7941
RH The existing unit was compared to a reference standard and confirmed to be within specifications. It was not replaced, as no spares were available. The aspirator fan was working and the netting was in place to prevent the birds from nesting in the aspirator. CASTNET A flow check was performed and the system was found to be in good calibration. The pump was rebuilt between the pre-maintenance testing and the flow calibration. The post-maintenance check passed. Post-Maintenance Calibration Summary: All systems were within specifications. ADDITIONAL NOTES AND OBSERVATIONS Station Operator Jenny Goucher and Raquel Acosta assisted with the wind checks. Monitoring Shelter The shelter, an 8 ft. X 1 ft. EKTO, is in good condition. 191 Sharp Point Drive, Suite E Fort Collins, CO 8525 Telephone: 97-484-7941
Calibration Summary Network: NPS Location: Big Bend Site: BIBE-KB Date: 2/1/12 Last Site Visit: 7/6/11 Parameter Criteria Accuracy Goal Pre-Maintenance Mfg, & Value Calibration Results Post Maintenance Mfg, & Value O 3 Analyzer Average average error <= ± 5. 1.5 PASS 1.2 PASS Maximum max error <= ± 5. 1.9 PASS 1.3 PASS TECO 49C 53468- TECO 49C 53468- Correlation actual r >.995 1. PASS 1. PASS 318 318 Intercept actual <= ± 3. ppb -1.1 PASS. PASS Slope actual.95 <= m <= 1.5 1.2 PASS 1.12 PASS O 3 Reference Average average error <= ± 5. 2.9 PASS.9 PASS Maximum max error <= ± 5. 3.8 PASS 1.7 PASS Correlation actual r >.995 TECO 49C 332753 1. PASS TECO 49C 332753 1. PASS Intercept actual <= ± 3. ppb -1.5 PASS -.7 PASS Slope actual.95 <= m <= 1.5 1.4 PASS 1.14 PASS CASTNet Flow Flow Rate (low) 1.2 PASS.5 PASS Flow Rate (target) max error <= ± 5. 1. PASS.2 PASS Tylan FC28SAV-45 Tylan FC28SAV-45 AW94318 AW94318 Flow Rate (high).5 PASS.2 PASS Leak Check max error <= ±.3.1 PASS.1 PASS Precipitation max error <= ± 5. 158 417 / NPS 1474-7.4 FAIL 158 417 / NPS 1474-6.3 FAIL Relative Humidity PRE Sensor ID# 5265 max error <= ± 5. Rotronics RH MP61A 5265.3 PASS Rotronics RH MP61A 5265 Solar Radiation average error <= ± 5 11655 PY35732 4 PASS 11655 PY35732 Temperature max error <= ±.2º C; RM Young <= ±.5º C; Rotronics <= ± 1.º C 188-2 EPA 1149.1º PASS 188-2 EPA 1149 Wind Direction Alignment max error <= ± 5º 8º FAIL 4º PASS Linearity max error <= ± 3º 176 3º PASS 176 6º FAIL 4231 / NPS 9152 2228 / NPS 9839 Starting Threshold max error <= 6 g-cm; RM Young AQ <= 9 g-cm; RM Young MA <= 3 g-cm, RM Young RE <= 7 g-cm 2 PASS Wind Speed max Wind Speed <5 max error <= ±.2 m/s N/A N/A N/A N/A max Wind Speed >= 5 max error <= ± 5 175.9 PASS 175 2.6 PASS 488 / NPS 9122 2961 / NPS 9846 Starting Threshold max error <=.2 g-cm; RM Young AQ <=.3 g-cm; RM Young MA <= 2.9 g-cm, RM Young RE <=.3 g-cm.2 PASS 281118
Calibration Standards Field Specialist: Operator: Network: Location: Site: Date: Last Site Visit: Valvur, Martin Jenny Goucher NPS Big Bend BIBE-KB 2/1/212 7/6/211 Latitude: Longitude: Elevation: Parameter Device Manufacturer Model S/N Calibration Date Voltage Fluke 87V Voltage Source Calib. Inc. DVC-35A 67991 Ozone Transfer Standard TECO 49i 1345196 11/9/211 Gas Dilution Mass flow ERT Gas Dil Barometric Pressure Barometer/Altimeter AIR AIR-HB-1A 3F252 8/4/21 High Flow Dry cal BIOS DC2 12798 11/9/21 Low Flow Dry cal BIOS DC2 1293 2/2/211 Precipitation PPT Calibrator Novalynx 26-2595 N/A 3/6/26 Volume (ml): 45 Relative Humidity RH Sensor Rotronics MP61 5686 6/28/211 Solar Radiation Thermopile LI-Cor Pyranometer PY319 7/19/211 Multiplier 78.8 Temperature Digital Thermometer Eutechinics 44 3419 1/1/211 Torque Gauge RM Young 18331 299 Wind Direction Linearity Jig RM Young 18212 299 Compass Brunton 56LM 54791146 Wind Speed Torque Disk RM Young 1831 Anemometer Drive RM Young 1882A CA 2293 1/24/212 Volumetric Flow Comments: 27119
OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference TECO TECO TECO 49i 49C 49C 1345196 53468-318 332753 Span Setting/ O3 Coefficient 1.37 1.36 1.196 Zero/ O3 Bkg 1.5 Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B Flow (Lpm)/ Flow A, Flow B Offset 95523.652 /.721 76519.77 /.74 7671 9431 77178 124477.64 /.634 Cell Temp / Pressure 36.7 / 686.1 39.7 / 658.4 35.4 / 689.8 STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO -1 -.2-1 Pass/ Fail Display -2 -.4-1 Pass/ Fail 1 422 422 43.86 43 8 1.9 PASS 439.875 438 16 3.8 PASS 2 321 321 326.652 326 5 1.6 PASS 331.662 331 1 3.1 PASS 3 175 175 176.354 177 2 1.1 PASS 18.358 181 6 3.4 PASS 4 83 83 83.169 84 1 1.2 PASS 85.173 84 1 1.2 PASS 5 ZERO -1 -.2-1. Target ranges for O3 points are: 3-8, 15-2, 3-35, 4-45 Average : 1.5 PASS Average : 2.9 PASS Maximum : 1.9 PASS Maximum : 3.8 PASS LINEAR REGRESSION PLOT RESIDUALS PLOT 5 y = 1.24x - 1.823 R 2 = 1 15 1 4 5 Analyzer 3 2 Residual -5 1-1 -15 1 2 3 4 5 5 1 15 2 25 3 35 4 45 5 Transfer Standard Conc. Regression Concentration Value CALIBRATION TIME From: To: EVENT RESPONSE RESULTS Station Reference Analyzer Response Linear Regression Calibration Point Mechanical Setting Display Recorder () Parameter Analyzer Station Reference ZERO N/A Slope 1.2 PASS 1.4 PASS Precision Span Y Intercept Correlation Coefficient -1.1 PASS -1.5 PASS 1. PASS 1. PASS Pre-Maint Ozone Comments: 27627
POST-MAINTENANCE OZONE CALIBRATION FORM EQUIPMENT IDENTIFICATION Transfer Standard Analyzer Station Reference TECO TECO TECO 49i 49C 49C 1345196 53468-318 332753 Span Setting/ O3 Coefficient 1.37 1.36 1.179 Zero/ O3 Bkg 1.5 Sample Freq/ Intensity A/ Lamp Control Frequency/ Intensity B 95523 9431 86914 85149 78978 124134 Flow (Lpm)/ Flow A, Flow B.652 /.721.77 /.74.64 /.634 Offset Cell Temp / Pressure 36.7 / 686.1 39.7 / 658.4 35.4 / 689.8 STATION TUBING Transfer Standard Analyzer Station Reference OFFSET = ppb OFFSET = ppb OFFSET = ppb Calibration Point Mechanical Setting Conc. Display ZERO -1-1 -.2-1 Pass/ Fail Display -2 -.4-2 Pass/ Fail 1 423 423 427.854 428 5 1.2 PASS 428.856 428 5 1.2 PASS 2 323 319 323.648 323 4 1.3 PASS 323.648 322 3.9 PASS 3 179 179 181.362 181 2 1.1 PASS 181.361 182 3 1.7 PASS 4 8 8 81.161 81 1 1.3 PASS 81.161 8. PASS 5 ZERO -1 -.2-1 -2 -.4-2 Target ranges for O3 points are: 3-8, 15-2, 3-35, 4-45 Average ABS : 1.2 PASS Average ABS :.9 PASS Maximum : 1.3 PASS Maximum : 1.7 PASS LINEAR REGRESSION PLOT RESIDUALS PLOT 5 y = 1.12x +.1 R 2 = 1 15 1 4 5 Analyzer 3 2 Residual -5 1-1 -15 1 2 3 4 5 5 1 15 2 25 3 35 4 45 Transfer Standard Conc. Regression Concentration Value CALIBRATION TIME From: To: EVENT RESPONSE RESULTS Station Reference Analyzer Response Linear Regression Calibration Point Mechanical Setting Display Recorder () Parameter Analyzer Station Reference ZERO N/A Slope 1.12 PASS 1.14 PASS Precision Span Y Intercept Correlation Coefficient. PASS -.7 PASS 1. PASS 1. PASS Post Maint Ozone Comments: 27627
WETNESS, PRECIPITATION AND BAROMETRIC PRESSURE CALIBRATION FORM Barometric Pressure Reference S/N: 3F252 Calibration Date: 8/4/1 Precipitation Reference S/N: N/A Calibration Volume: 45 ml Calibration Date: 3/6/6 WETNESS Pre-Maintenance Post Maintenance DRY WET SENSOR RESPONSE LED (ON/OFF) off on DRY WET SENSOR RESPONSE LED (ON/OFF) off on Pre-Maint Wetness Comments: Post Maint Wetness Comments: Pre-Maintenance Post Maintenance Calibration Volume Inlet Diameter Reference 6.6 48.3 4.73 158 158 8. 27.8 8.23 417 / NPS 1474 417 / NPS 1474 9 cc 9.66 19. 4.73 Inlet Diameter PRECIPITATION 9.66" Novalynx 26-25 27.8 8.24 RM Young 5222 45. 2. 6.6 5.3 4.73 Cal Volume Designated Cal Volume Designated mm mm (ml) value in mm (ml) value in mm 8. 28.9 8.23 45 9.5 8.8-7.4 FAIL 45 9.5 8.9-6.3 FAIL 936 CC 9.66 19.8 4.73 Novalynx 26-25 28.9 8.2 RM Young 5222 46.8 2. mm mm/tip Pre-Maint Precipitation Comments: Ran several checks and adjusted each with the syringe but, the amount of tips would not change. Post Maint Precipitation Comments: BAROMETRIC PRESSURE SENSOR RESPONSE Reference (Volts) (mm Hg) Reference (Volts) (mm Hg) Maximum: Maximum: Pre-Maint Barometric Pressure Comments: Post Maint Barometric Pressure Comments: 27627
CASTNET FLOW CHECK FORM High Flow Standard (BIOS) Reference S/N: 12798 Cell #: Calibration Date: 11/9/1 MFC Date PREVIOUS LINEAR REGRESSION 7/6/11 FLOW CALIBRATION LINEAR REGRESSION 2/1/12 Tylan Tylan MFC Display Set Point 3.4 3.4 FC28SAV-45 FC28SAV-45 Slope 1.8748 1.8748 AW94318 AW94318 Intercept -.2351 -.2351 PUMP IDENTIFICATION Standard Temp. and Pressure (STP) TEMP PRESSURE (mmhg) Thomas Thomas 25 76 17CAB18 17CAB18 N/A N/A FLOW CHECK ITEM PRE MAINTENANCE ITEM AS FOUND AS LEFT Vacuum 2" hg Full Scale 5.37 5.37 Flow (Operating) 3 2.99 Zero.7.7 MFC Flow Value (Operating) 3.4 3.4 Flow Target 3. 3. BIOS SLPM 2.96 2.98 SENSOR RESPONSE ACTION BIOS (SLPM) MFC Display Rotometer Flow Flow Value (SLPM) MFC VOLTS DC Target Flow Points 1.5 SLPM 3. SLPM SLPM PASS/FAIL Zero (pump off). -.1..94.23 N/A N/A Leak Test..2..1.29 N/A N/A.56 PASS Point 1 (low) 2.18 2.15 2.18 2.134 1.947.75 to 1. 2. to 2.25.257 1.2 PASS Point 2 (target) 2.961 3.4 3.5 2.99 2.755 1.5 3..294 1. PASS Point 3 (high) 3.868 3.97 4.1 3.888 3.62 2. to 2.25 3.75 to 4..196.5 PASS Max Flow Test 4.1 4.13 4.2 4.35 3.741 2.5 4..338.8 PASS Calibration Required? Point 1 (low) *Note: A calibration is required if the difference between the transfer 1.2 NOT REQUIRED standard and the value is greater than +/- 2. MFC Zero/Leak Test Diff:.3 Point 2 (target) at the target setting or greater than +/- 2.5 at either the low 1. NOT REQUIRED or high point. Leak Present? NO Point 3 (high) *Note: A leak is present if the difference.5 NOT REQUIRED between the zero and leak test value is greater than.1 SENSOR RESPONSE ACTION BIOS (SLPM) MFC Display Rotometer Flow Flow Value (SLPM) MFC VOLTS DC Target Flow Points 1.5 SLPM 3. SLPM SLPM PASS/FAIL Zero (pump off). -.1..96.25 N/A N/A Leak Test..2..12.31 N/A N/A.534 PASS Point 1 (low) 2.224 2.25 2.3 2.234 2.42.75 to 1. 2. to 2.25.12.5 PASS Point 2 (target) 2.983 3.4 3.5 2.99 2.755 1.5 3..7.2 PASS Point 3 (high) 3.881 3.97 4.1 3.887 3.61 2. to 2.25 3.75 to 4..6.2 PASS Max Flow Test 4.54 4.15 4.2 4.63 3.767 2.5 4..86.2 PASS Pre-Maint CASTNet Flow Comments: Rebuilt pump between pre and post flow check. Post Maint CASTNet Flow Comments: 27627
CASTNET FLOW CALIBRATION FORM High Flow Standard (BIOS) Reference S/N: 12798 Cell #: Calibration Date: 11/9/1 MFC Tylan FC28SAV-45 AW94318 Tylan FC28SAV-45 AW94318 PUMP IDENTIFICATION Standard Temp. and Pressure (STP) TEMP PRESSURE (mmhg) Thomas Thomas 25 76 17CAB18 17CAB18 N/A N/A CASTNET FLOW CALIBRATION RESULTS ACTION BIOS (SLPM) MFC Display Flow Value (SLPM) MFC VOLTS DC Target Flow Points Linear Regression 1.5 SLPM 3. SLPM Parameter MFC MFC VOLTS DC Zero (pump off) Slope Leak Test Point 1 1. 2. Y Intercept Correlation Coefficient Point 2 1.25 2.5 Point 3 1.5 3. MFC Set Point Zero/FS Set Point Point 4 1.75 3.5 1.5 s 3. s Zero Full Scale Point 5 2. 4. 4.5 4. 3.5 3. MFC Volts DC 2.5 2. 1.5 1..5...5 1. 1.5 2. 2.5 3. 3.5 4. 4.5 BIOS SLPM Pre-Maint CASTNet Flow Comments: Post Maint CASTNet Flow Comments: 27627
SOLAR RADIATION CALIBRATION FORM Solar Radiation Reference S/N: PY319 Reference Factor: 78.8(W/m2) Calibration Date: 7/19/11 SOLAR RADIATION 11655 PY35732 11655 PY35732 Translator 385 385 TRANSLATOR CARD SETTING (W/m2) Zero..2.7555 Span 5.1 1396 (W/m2) SENSOR RESPONSE HOUR (W/m2) T.STD HOUR (W/m2) T.STD 1: 352 345 2 12: 11: 546 528 3 13: 12: 685 662 3 14: 13: 768 731 5 15: 14: 774 731 6 16: 15: 17: Average : 4 Average : : PASS : Pre-Maint Solar Radiation Comments: Sensor was found clean and level. Post Maint Solar Radiation Comments: 27627
TEMPERATURE, DELTA TEMPERATURE AND RELATIVE HUMIDITY CALIBRATION FORM Reference Thermometer S/N: 3419 Calibration Date: 1/1/11 Relative Humidity Reference S/N: 5686 Calibration Date: 6/28/11 TEMPERATURE / DELTA TEMPERATURE Pre-Maintenance 188-2 Post Maintenance 188-2 Temperature Delta Temp. Translator EPA 1149 EPA 1149 482 482 BATH TEMP TEMPERATURE SENSOR RESPONSE SETTING PRE- TRANSLATOR CARD RESPONSE TEMPERATURE. 1.881.1.1 PASS Zero. -3. 46.7 4.794 46.7. PASS Span 5. 5. 24.5 3.43 24.5 -.1 PASS Δ TEMPERATURE Maximum :.1 PASS Maximum : Δ TEMPERATURE SENSOR RESPONSE POST TRANSLATOR CARD RESPONSE BATH TEMP TEMPERATURE Δ TEMPERATURE SETTING TEMPERATURE Δ TEMPERATURE Zero Span Maximum : Maximum : Pre-Maint Temperature Comments: Post Maint Temperature Comments: RELATIVE HUMIDITY Pre-Maintenance Rotronics RH MP61A Post Maintenance Rotronics RH MP61A 5265 5265 SENSOR RESPONSE SENSOR RESPONSE HOUR T.STD HOUR T.STD 1: 26.8 27.1 -.3 PASS 1: 11: 34.3 34..3 PASS 11: 12: 27.5 27.5. PASS 12: 13: 2.3 2.5 -.2 PASS 13: 14: 19.2 19.1.1 PASS 14: 15: 15: Average ABS :.2 PASS Average ABS : Maximum :.3 PASS Maximum : Screen dirty/clogged on RH pre-maintenance sensor? (check one): Yes No Pre-Maint Relative Humidity Comments: Sensor was not replaced as a spare was not available. Post Maint Relative Humidity Comments: 27627
WIND DIRECTION CALIBRATION FORM To Landmark #1: 151 Degrees True From Landmark #1: 331 LM Description: To Landmark #2: 245 Degrees True From Landmark #2: 65 LM Description: Declination: Degrees Wind Direction Reference S/N: 54791146 Calibration Date: V Rock Peak to the SW WIND DIRECTION WIND DIRECTION ALIGNMENT Land Mark Reference Degrees Degrees (degrees) (degrees) 176 176 To 1 53-8 FAIL 57-4 PASS 4231 / NPS 9152 2228 / NPS 9839 From 1 329-2 PASS 332 1 PASS Translator 688 688 To 2 245 PASS 247 2 PASS From 2 42-5 PASS 423-2 PASS Card Setting WIND DIRECTION TRANSLATOR CARD Average : 4 PASS Average : 2 PASS PRE POST Maximum : 8 FAIL Maximum : 4 PASS 36 3.335 36. Oscillator Frequency (Hz) = Zero.4.4 WIND DIRECTION LINEARITY Span 3.335 36. Check Point Data Logger Should Read (degrees) Degrees (degrees) Degrees 1 44-2 PASS 397-3 PASS 2 45 1 PASS 442 PASS WIND DIRECTION STARTING THRESHOLD 3 495 PASS 486-1 PASS PRE POST 4 183 3 PASS 529-2 PASS Torque gm-cm Torque gm-cm 5 227-1 PASS 22 6 FAIL 2 PASS 6 273 1 PASS 264-1 PASS Wind direction starting threshold accuracy goal: <= 6 g-cm 7 318 PASS 39 PASS 8 361-2 PASS 355 1 PASS Average : 1 PASS Average : 2 PASS Maximum : 3 PASS Maximum : 6 FAIL Pre-Maint Wind Direction Comments: Post Maint Wind Direction Comments: 27627
WIND SPEED CALIBRATION FORM Wind Speed Reference S/N: CA 2293 Calibration Date: 1/24/12 WIND SPEED WIND SPEED TRANSLATOR CARD Card PRE POST Setting 175 175 Zero.25.2 488 / NPS 9122 2961 / NPS 9846 Span 2.492 24.9 Translator 688 688 Oscillator Frequency (Hz) = Data Logger Should Read WIND SPEED STARTING THRESHOLD PRE POST Torque gm-cm Torque gm-cm.2 PASS Wind speed starting threshold accuracy goal: <=.2 g-cm Motor Speed (rpm) RM Young Met One WIND SPEED WIND SPEED 1 2.574.51.45 3 7.274 1.54 8.45 7.25 -.24 -.3 PASS 7.45.176 2.4 PASS 6 14.324 3.7 16.44 14.2 -.124 -.9 PASS 14.7.376 2.6 PASS 9 21.375 4.61 24.44 21.2 -.175 -.8 PASS 21.2 -.175 -.8 PASS 12 28.425 6.14 N/A 28.2 -.225 -.8 PASS 28.2 -.225 -.8 PASS 18 42.526 9.22 48.44 42.2 -.326 -.8 PASS 42.2 -.326 -.8 PASS 4 N/A 2.48 N/A 7 N/A 35.84 N/A Maximum ABS (use if Wind Speed <5):.326.376 Maximum ABS (use if Wind Speed >=5):.9 PASS 2.6 PASS FOR REFERENCE ESC Met Card ESC Analog Input Card CSI 23X Instruction P3 M/S Output RMY Gray Prop RMY Black Prop Aluminum Cups Lexan Cups WSP High Input WSP Low Input WSP High Output (E.U.'s) WSP Low Output (E.U.'s) WSP High Input WSP Low Input WSP High Output (E.U.'s) WSP Low Output (E.U.'s) Config. Multiplier Offset 488.3 Hz 5 m/s m/s 1V V 5 m/s m/s 21.124 51 Hz Hz 5 m/s m/s 1V V 47.8 m/s m/s 21.98 159.2-4.76 5 m/s m/s 1(or 5)V V 5 m/s m/s 2.4699.134 Pre-Maint Wind Speed Comments: Post Maint Wind Speed Comments: 27627