Karst found mostly in limestone (rock with at least 50% carbonate minerals), depends on 1) permeability & porosity

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KARST LANDFORMS produced by weathering & erosion in regions of carbonate rocks and evaporites processes called karstification mainly below ground surface predominantly underground drainage poorly-developed surface network of streams occurs everywhere, but most common in temperate & tropical climates; in US, occurs in PA, MD, central Florida, east-central Missouri, belt from south-central Indiana to east-central Kentucky, Edwards Plateau in Texas, NM (karst terms listed in text)

Karst found mostly in limestone (rock with at least 50% carbonate minerals), depends on 1) permeability & porosity increase permeability & porosity = increase solution = increase karst 2) secondary porosity along fractures, joints, faults, etc 3) bedding thickness: massive-bedded limestone is better for karst than thin-bedded limestone, where insoluble materials concentrate along bedding planes & restrict water flow 4) available relief: height above baselevel should be enough to permit free circulation of water in system Warm, wet = ideal for karst because chemical reactions occur faster at higher temperatures, & lush vegetation & microbe activity give tropical soil water a high partial pressure of CO 2 [P CO2 ]

Solution process: CO 2 dissolved in water reacts to form weak carbonic acid (H 2 CO 3 ): CO 2 + H 2 O H 2 CO 3 amount of CO 2 dissolved in water is function of P CO2 & water temperature CO 2 increases as P CO2 increases & T water decreases CaCO 3 + H 2 O + CO 2 Ca 2+ + 2HCO 3 - Karst is related to groundwater

GROUNDWATER PROFILE zone of aeration: pore spaces occupied by air & water capillary fringe: all pore spaces are occupied by water held in tension, so the water won t drain freely phreatic zone: water drains freely because hydrostatic pressure exceeds atmospheric pressure water table: hydrostatic pressure = atmospheric pressure The movement of groundwater is controlled by the amount of potential energy, which is a function of pressure & elevation above datum, and porosity (% of rock s volume taken up by void spaces measure of rock s ability to hold water) / permeability (measure of capability of rocks to transmit fluid size and connectedness of voids)

Groundwater profile zone of soil moisture zone of aeration (vadose water) water table capillary fringe phreatic zone

Groundwater flows from higher to lower potential zones, & perpendicular to equipotential surfaces v, Q are proportional to loss of potential occurring as water moves from one point to another aquifers: lithologic bodies that store & transmit water unconfined: open to atmosphere, & hydrostatic level (level at which water stands in an open hole) is within the waterbearing unit itself confined: water rises above aquifer when aquifer is penetrated; rises to piezometric surface determined by difference in potential at point where precipitation enters aquifer (recharge zone) & position of hole artesian flow: where piezometric level is above ground aquitard: impermeable layer

As a well is pumped, a cone of depression develops as the hydrostatic level around the well is lowered With respect to karst, carbonate aquifers are a) diffuse flow: cavities limited in size & number, caves rare, well-defined water table present b) free flow: water moves through integrated conduits under influence of gravity; flow can transport sediment; discharge through springs c) confined flow: water moves in response to pressure Springs in karst areas are 1) exsurgences: from flow in diffuse aquifers; fed by seepage 2) resurgences: fed by groundwater moving through distinct conduits Springs are generally controlled by large structural or stratigraphic features, & in turn control surface topography (eg. n vs s Grand Canyon)

regional dip of bedrock

karst spring, Glenwood Canyon, CO karst spring, Vasey s Paradise, Grand Canyon, AZ

travertine dam, Jemez Creek, New Mexico hot springs travertine, Jemez Creek close-up of travertine along Ribbon Falls, Grand Canyon, AZ

tufa formations, Mono Lake, CA travertine dam, Hanging Lake, CO travertine terraces, Havasu Creek, AZ

travertine formation & hot springs, Yellowstone

travertine formation & geysers, Yellowstone

Surficial Landforms 1) Closed depressions dolines/sinks/sinkholes: closed hollow of small or moderate size, wider (10-100 m) than deep (2-100 m), circular or elliptical, usually in groups solutional: water infiltrating into joints & fissures enlarges cracks by solution; function of slope (low is best), lithology & structure (dense, well-jointed limestone is best), & vegetation & soil cover (increase solution) collapse: depressions initiated by solution occurring beneath surface uvalas & poljes: larger than dolines; as dolines enlarge, they coalesce into hollows with undulating floors 2) Karst valleys allogenic valleys: head in impermeable rocks adjacent to karstic area blind valley: valley terminates at cliff face due to sink

Chichen Itza, Yucatan cenote (sinkhole) uvala, West Virginia Florida sinkhole

karst collapse terrain, Yellowstone

2) Karst valleys (continued) pocket valley: begins where groundwater resurges as springs dry valleys: don t have well-defined water courses, or carry only ephemeral flow when flooding 3) Minor solution features (karren) grooves, pits, flutes, pinnacles, etc of cm to a few m in size dry valley, West Virginia

arid-region carbonate weathering patterns, southern AZ

Establishment of plants in solutional weathering pits, Big Bend National Park, Texas

humid-region carbonate weathering patterns, Niagara Escarpment, Ontario

seasonal tropics carbonate weathering patterns (rillenkarren), northwestern Australia

Tropical Karst all temperate landforms are present, but the landscape is dominated by residual hills rather than the closed depressions of temperate karst higher temperature, total precipitation, & precipitation intensity produce rapid & prolonged corrosion rapid plant growth & decay combine with extreme microbial activity to supercharge infiltrating water with CO2 and intensify the solution process examples are cone karst, cockpits (depressions around cones), towers, phytokarst (type of karren that develop into spongelike pinnacles under biochemical action of blue-green algae)

cockpit & tower karst, Goundong Province, China

Jamaica

small towers, western Australia

Caves: natural underground cavities that include entrances, passages, & rooms Caves form 1) above water table by corrosive action of vadose water 2) beneath water table by deep circulation of phreatic water 3) at water table or in shallow phreatic zone, associated with fluctuations of water table Plan view & cross section shapes of cave passages

cave, southern Australia Wind Cave National Park, South Dakota

cave, southern Australia