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Test Booklet Subject: SC, Grade: HS Student name: Author: California District: California Released Tests Printed: Thursday January 16, 2014

1 Theoretically, when an ideal gas in a closed container cools, the pressure will drop steadily until the pressure inside is essentially that of a vacuum. At what temperature should this occur? A 0 C. B -460 C. C -273 K. D 0 K. 2 The temperature at which all molecular motion stops is 3 A -460 C. B -273 K. C 0 K. D 0 C. Which of the substances in the table can act as either the solute or the solvent when mixed with 100 grams of water at 20 C? 4 A teaspoon of dry coffee crystals dissolves when mixed in a cup of hot water. This process produces a coffee solution. The original crystals are classified as a A solute. B solvent. C reactant. D product. 5 If the attractive forces among solid particles are less than the attractive forces between the solid and a liquid, the solid will A probably form a new precipitate as its crystal lattice is broken and re-formed. B Double click here to edit, then replace this text with your second answer C begin the process of melting to form a liquid. D dissolve as particles are pulled away from the crystal lattice by the liquid molecules. 6 Water is a polar solvent, while hexane is a nonpolar solvent. A NH 3 B C 6 H 5 COOH C MgCI 2 D CH 3 CH 2 OH Which of the examples above illustrates a nonpolar solute in a polar solvent? A NH 4 Cl in water B C 10 H 8 in water C C 2 H 5 OH in hexane D CO (NH 2 ) 2 in hexane Page 1

7 A technician prepared a solution by heating 100 milliliters of distilled water while adding KCl crystals until no more KCl would dissolve. She then capped the clear solution and set it aside on the lab bench. After several hours she noticed the solution had become cloudy and some solid had settled to the bottom of the flask. Which statement best describes what happened? A As the solution cooled, evaporation of water increased the KCl concentration beyond its solubility. B Water molecules, trapped with the KCl crystals, were released after heating. C At lower temperatures the solubility of the KCl decreased and recrystallization occurred. D At increased temperatures the solubility of KCl increased and remained too high after cooling. 8 If the solubility of NaCl at 25 C is 36.2 g/100 g H 2 O, what mass of NaCl can be dissolved in 50.0 g of H 2 O? A 18.1 g B 36.2 g C 72.4 g D 86.2 g 9 How many moles of HNO 3 are needed to prepare 5.0 liters of a 2.0 M solution of HNO 3? A 2.5 B 5 C 10 D 20 10 The Dead Sea is the saltiest sea in the world. It contains 332 grams of salt per 1000 grams of water. What is the concentration in parts per million (ppm)? A 0.332 ppm B 332 ppm C 33,200 ppm D 332,000 ppm 11 The random molecular motion of a substance is greatest when the substance is A condensed. B a liquid. C frozen. D a gas. 12 Which of these is an example of an exothermic chemical process? A evaporation of water B melting ice C photosynthesis of glucose D combustion of gasoline 13 The boiling point of liquid nitrogen is 77 kelvin. It is observed that ice forms at the opening of a container of liquid nitrogen. The best explanation for this observation is A water at zero degrees Celsius is colder than liquid nitrogen and freezes. B the nitrogen boils and then cools to form a solid at the opening of the container. C water trapped in the liquid nitrogen escapes and freezes. D the water vapor in the air over the opening of the liquid nitrogen freezes out. Page 2

14 The specific heat of copper is about 0.4 joules/ gram C. How much heat is needed to change the temperature of a 30-gram sample of copper from 20.0 C to 60.0 C? A 1000 J B 720 J C 480 J D 240 J 16 15 Equal volumes of 1 molar hydrochloric acid (HCl) and 1 molar sodium hydroxide base (NaOH) are mixed. After mixing, the solution will be A strongly acidic. B weakly acidic. C nearly neutral. D weakly basic. The above picture shows a light bulb connected to a battery with the circuit interrupted by a solution. When dissolved in the water to form a 1.0 molar solution, all of the following substances will complete a circuit allowing the bulb to light except A hydrochloric acid. B sodium nitrate. C sucrose. D ammonium sulfate. 17 Which of the following is an observable property of many acids? A They become slippery when reacting with water. B They react with metals to release hydrogen gas. C They produce salts when mixed with other acids. D They become more acidic when mixed with a base. Page 3

18 Copper (II) nitrate and sodium hydroxide solutions react in a test tube as shown below. If nitric acid is added to the test tube, the amount of solid precipitate decreases. The best explanation for this is that the acid A dilutes the solution making the precipitate dissolve. B reacts with the copper (II) nitrate, pulling the equilibrium to the left. C will dissolve most solids, including sodium nitrate. D will react with the copper (II) hydroxide to form water and soluble copper (II) nitrate. 19 Potassium hydroxide (KOH) is a strong base because it A easily releases hydroxide ions. B does not dissolve in water. C reacts to form salt crystals in water. D does not conduct an electric current. 20 Of four different laboratory solutions, the solution with the highest acidity has a ph of A 11. B 7. C 5. D 3. 21 22 23 Which of these describes the rate of this chemical reaction? A an increase in the concentration of HCl and H 2 with time B an increase in the concentration of HCl with time C an increase in H 2 and Cl 2 with time D a decrease in HCl and Cl 2 with time Which of the following changes will cause an increase in the rate of the above reaction? A increasing the concentration of Br 2 B decreasing the concentration of C 6 H 6 C increasing the concentration of HBr D decreasing the temperature If the above reaction takes place inside a sealed reaction chamber, then which of these procedures will cause a decrease in the rate of reaction? A raising the temperature of the reaction chamber B increasing the volume inside the reaction chamber C removing the CO 2 as it is formed D adding more CO to the reaction chamber Page 4

24 A catalyst can speed up the rate of a given chemical reaction by A increasing the equilibrium constant in favor of products. B lowering the activation energy required for the reaction to occur. C raising the temperature at which the reaction occurs. D increasing the pressure of reactants, favoring products. thus 25 Which reaction diagram shows the effect of using the appropriate catalyst in a chemical reaction? A B C D Page 5

26 H 2 O 2, hydrogen peroxide, naturally breaks down into H 2 O and O 2 over time. MnO 2, manganese dioxide, can be used to lower the energy of activation needed for this reaction to take place and, thus, increase the rate of reaction. What type of substance is MnO 2? A a catalyst B an enhancer C an inhibitor D a reactant 27 When a reaction is at equilibrium and more reactant is added, which of the following changes is the immediate result? A The reverse reaction rate remains the same. B The forward reaction rate increases. C The reverse reaction rate decreases. D The forward reaction rate remains the same. 28 In which of the following reactions involving gases would the forward reaction be favored by an increase in pressure? 29 A A + B AB B A + B C+ D C 2A + B C + 2D D AC A + C Which action will drive the reaction to the right? A heating the equilibrium mixture B adding water to the system C decreasing the oxygen concentration D increasing the system s pressure 30 31 The reaction shown above occurs inside a closed flask. What action will shift the reaction to the left? A pumping CO gas into the closed flask B raising the total pressure inside the flask C increasing the NO concentration in the flask D venting some CO 2 gas from the flask What kind of change will shift the reaction above to the right to form more products? A a decrease in total pressure B an increase in the concentration of HCl C an increase in the pressure of NH 3 D a decrease in temperature 32 In a sealed bottle that is half full of water, equilibrium will be attained when water molecules 33 A cease to evaporate. B begin to condense. C are equal in number for both the liquid and the gas phase. D evaporate and condense at equal rates. This chemical equation represents the combustion of propane. When correctly balanced, the coefficient for water is A 2. B 4. C 8. D 16. Page 6

34 Which of the following is a balanced equation for the combustion of ethanol (CH 3 CH 2 OH)? A B C D 35 Hydrazine, N 2 H 4, and dinitrogen tetroxide, N 2 O 4, react to form gaseous nitrogen and water. Which of these represents a properly balanced equation for this reaction? 36 A B C D When the reaction above is completely balanced, the coefficient for NH 3 will be A 2. B 3. C 4. D 6. 37 How many moles of carbon-12 are contained in exactly 6 grams of carbon-12? 38 How many atoms are contained in 97.6 g of platinum (Pt)? A 5.16 10 30 B 3.01 10 23 C 1.20 10 24 D 1.10 10 28 39 When methane (CH 4 ) gas is burned in the presence of oxygen, the following chemical reaction occurs. If 1 mole of methane reacts with 2 moles of oxygen, then A 6.02 10 23 molecules of CO 2 and 6.02 10 23 molecules of H 2 O are produced. B 1.2 10 24 molecules of CO 2 and 1.2 10 24 molecules of H 2 O are produced. C 6.02 10 23 molecules of CO 2 and 1.2 10 24 molecules of H 2 O are produced. D 1.2 10 24 molecules of CO 2 and 6.02 10 23 molecules of H 2 O are produced. 40 How many moles of CH 4 are contained in 96.0 grams of CH 4? A 3.00 moles B 6.00 moles C 12.0 moles D 16.0 moles A 0.5 mole B 2.0 moles C 3.01 10 23 moles D 6.02 10 23 moles Page 7

41 How many atoms are in a chromium sample with a mass of 13 grams? A 1.5 10 23 B 3.3 10 23 C 1.9 10 26 D 2.4 10 24 42 How many moles of chlorine gas are contained in 9.02 10 23 molecules? A 1.5 moles B 2.0 moles C 6.02 moles D 9.03 moles 45 A mass of 5.4 grams of aluminum (Al) reacts with an excess of copper (II) chloride (CuCl 2 ) in solution, as shown below. What mass of solid copper (Cu) is produced? A 0.65 g B 8.5 g C 13 g D 19 g 43 In this reaction, how many grams of Fe 2 O 3 are required to completely react with 84 grams of CO? A 64 g B 80 g C 160 g D 1400 g 44 If 54.0 grams of water are mixed with excess magnesium nitride, then how many grams of ammonia are produced? A 1.00 B 17.0 C 51.0 D 153 Page 8 STOP