SUBJECT INDEX Accessible microvolume, 51 Acid activation, 426 Adsorption properties, 241 Aggregate, 339 AIPO' s, 61 Alkoxides, 306, 339 Alloys, 124 a (s ) -plots, 131 AtPO-5, 137 Alternatives to conventional methods, 124 Alumina, 283, 339, 340, 425 Alumina fibres, 395 Alumina pillared clay, 267 Aluminium (III), 275 Aluminosilicates, 343 Aluminosilicate zeolites, 141 Aminoalkyltrialkoxysilane, 289 Analytical techniques, 139 Anionic clays, 191 Anisotropic materials, 393 Aqueous solutions, 323 Bakken shale, 391 Band gaps, 285 Beidellite, 409 Benzoate, 377 BET, 4, 41, 129, 159, 219, Bimodal pore distribution, Binary oxides, 127 Binuclear complexes, 127 Breaking algorithm, 100 Breck six, 144 246, 273, 295, 342, 173 458 Cacoxeni te, 161 Cadmium sulphide, 286 Catalysts, 191, 401 Catalytic applications, 447 Catalytic properties, 465 Ceramic membranes, 393 Charge-electronegativity diagram, 332 Chemical heterogeneity, 20 Chemically modified electrodes, 473 Chemical sensors, 225, 473 Chemical shift anisotropy, 348 Chessboard arrangement, 296 CA. C Sequeira and M.J. Hudson (eds.), Multifunctional Mesoporous Inorganic Solids. 495-501. 1993 Kluwer Academic Publishers. 495
496 Chiral separations, 232 Chiral zirconium phosphate, 232 Chlorophyll adsorption, 429 Chromia, 280 Chromium (III), 280 Clathrasil, 62 Clay, 401, 425 Clay modified electrodes, 433 Cloverite, 137, 160 Collapsible frameworks, 89 Colloidal, 274 Columnar units, 148 Cornbus ti on, 113 Complexation, 333 Compos.ite electrodes, 476 Covalent bonding, 477 Covalently pillared zirconium diphosphonates, 186 Cross-linked smectites, 50 Crosslinking, 292 Crystallization boundaries, 141, 150 Crystallization mechanisms, 139 Cyclic voltammograms, 439, 443 Dehydrated Na-Y zeolite, 124 Delaminated laponite, 261 Densification, 117, 488 Differential thermal analysis, 39 Diffusion coefficients, 440 Dipolar broadening, 348 Dipolar decoupling of spectra, 349 ECR-1, 150 Electrode modification, 446 Electrokinetic phenomena, 414 Electrokinetic potential measurements, 418 Electron spin echo modulation, 401 Equilibrium isotherms, 99 EPR, 401 ESEEM, 410 ESEM, 402 ESR, 402 Exothermi c reacti on, 113 Fauj asi te, 144 f-plots, 214 Fractals, 27 Fractal dimension, 28 Fractal structure factors, 384
497 Framework conformation, 84 FT-IR spectroscopy, 211 Gels, 340 Geometrical confinement, 22 Glass, 340 Halsey equation, 42 Heterogeneous catalysis, 465 Heteropolymetallic molecules, 122, 124 Heteropoly oxometalates, 459 Highly dispersed metals, 124 Host stabilisation, 57 H2P042- hydrolysis, 183 Hydrothermal synthesis, 107 Hyd~ous alumina sols, 487 Hysteresis loops, 5 Initiation, 113 Inorganic precursors, 321 Inorganics, 275 In-situ polymerization, 280, 479 Intercalates, 195, 218, 374 Intercalation, 127, 233, 275 Interference, 383 Intergrowths, 141, 144 Interlamelar gallery height and texture, 134 Ion exchange, 283, 461 Isobutyric acid, 466 Isolated particles, 381 Isotropic scattering, 390 Kandites, 61 Kelvin equation, 7 K10 montmorillonite, 259 Ladder structures, 149 Lamellar host materials, 290 Langmuir plots, 246 LaNi03, 127 Laponite, 21, 401 Larqe pore zeolites, 161 Layered aluminium-vanadium oxide, 107 Layered compounds, 107 Layered doubl e hydroxides, 191, 217, 373 Layered materials, 225, 273
498 Layered phosphate, 289 Layered zirconium phosphates, 183 Layered zirconium phosphonates, 184 LDH-intercalates, 376 Linde L, 151 Low pressure hysteresis, 14 LTL, 140, 148 Macrokinetics, 115 Magic angle spinning NMR, 347 Mass fractals, 385 Materials production, 114 Mazmori tes, 150 Mazzite, 150 Mercury intrusion porosimetry, 12 Merlinoite, 151 Mesopore, 69, 237 Mesoporosi ty, 3, 127 Mesoporous, 278, 295 Mesoporous clays, 263 Mesoporous materials, 99 Mesoporous zirconium phosphate phosphonate, 172, 185 Metallic nanoprecipitates, 339 Metallurgy, 118 Metal oxide coatings, 489 Metal-oxygen cluster compounds, 451 Mg,Al double hydroxides, 207 Micas, 61 Micropore, 69, 81, 237, 273 Microporosity, 50 Microporous solids, 78, 127, 401 (J.J.4-0)N4(Cu, M, M', M"')4C16' 124 Mixed aluminium iron pillars, 19 Mixed metal catalysts, 124 Mi xed metal oxi des, 123 Mixed oxide sols, 249 Molecular precursors, 312 Molecularly engineered layered structures, 186 Molecular tiling, 29 Monovalent cation salts, 451 Montmorillonite, 237, 404 Montmorillonite-modified Pt electrode, 445 Mordeni te, 150 Nanocomposite, 237 Naphthoate, 375 Network models, 32 Nitrogen adsorption, 7, 37, 282 NMR, 204, 347
499 Non-clay pillared layered materials, 167 Non-clay substrates, 290 Non-collapsible frameworks, 90 Non-zeolites, 138 Non-zeolite molecular sieves, 66 n-propylamine, 273 Nucleation, 60 Octa(aminoalkyl)siloxane, 292 Octameric organosilicon, 291 Offreti te, 151 Organically pillared zirconium phosphonates, 172 Organic bases in synthesis, 61 Organic precursors, 305 Organosilicon precursors, 290 ORMOCERs, 316 Oxidative dehydrogenation, 451 Oxides, 321 Oxyhydroxide iron, 20 Partial charges, 322 Paulingite, 151 Pentasils, 140, 146 Percolation, 31, 33 Phosphates, 232, 274 Phosphonates, 225 Photoactivity, 202 Physical adsorption, 19 Pillared clays, 19, 127, 164, 166, 237, 409, 425 Pillared layered phosphates, 168, 171 Pillared layer structures, 68, 85, 181 Pillared materials, 273 Pillared montmorillonite, 49, 127 Pillaring, 217, 292 Pneumatolysis, 64 Polymerization, 317 Polyoxometalates, 329 Pore characterization, 31, 130 Pore distribution, 339 Pore fractals, 385 Pore size, 273 Pore size distribution, 28, 85, 383 Pore structure, 27, 456 Porosil, 62 Porosity, 20, 49, 159, 213, 220, 282 Porous carbon, 392 Porous crystals, 64 Powders, 116 Precipitation, 331
500 Propylene alkylation, 260 Pyrolysis, 62 Pyrrolle, 273 QCM derivatization, 227 Quantum well, 286 Random packing, 99 Reference material, 37, 127 RHO, 151 Salt-bearing tectosilicates, 63 SANS, 389 SAXS, 387 Self-propagating high-temperature synthesis, 111 SEM, 135, 231, 256 Sensor performance, 481 Sheet structures, 144, 146 Silica gels, 390, 397 Silica-pillar precursors, 291 Silica sols, 238 Sintering, 117 Small-angle scattering, 380 Smectites, 61, 404 Smectite clays, 290 S-methyl hydrazinecarbodithioate ligand, 122 Sodali te, 76, 144 Sol-gel, 305, 339 Sol-gel coatings, 487, 492 Sol-gel method, 486 Solid state Al-NMR, 374 Specialized templates, 83 Specific surface area, 273 Spectral parameters, 350 Standard nitrogen adsorption isotherms, 40, 52, 104, 127 Streaming potential/current method, 416 Structural analysis, 351 Structural characterisation, 299 Structure building units, 143 Structure di recti on, 139 Structure retention, 464 Supercritical drying, 253 Surface area determination, 20, 37, 213, 220 Surface fractals, 384 Synthesis, 193 Synthesis methods, 57, 107
501 Target,.122 Technology, 116 Temperature of burning, 113 Templates, 152 Template agents, 250 Terephthalate, 375 Tetrahedral framework structures, 73 Thermodynamics, 113 Thermogravimetric analysis, 39 Tin (IV), 273 Tin phosphate, 284 t-plots, 52, 244, 264 Topological and chemical diversity, 66 Topology of tetrahedral frameworks, 75 Transmetalation, 121 Transmetalators, 122 Transmission electron microscopy, 208 USAXS, 389 Vanadium, 220 Vibration technique, 100 Voids characterisation, 366 VPI - 5, 137, 161 Welding, 118 X-ray diffraction, 132, 192, 208, 239, 261, 286 Young-Laplace equation, 7 Zeolite, 62, 73, 123, 137, 159, 273, 409 Zeolite crystallization, 141 Zeolite-type compounds, 90 Zeosil, 62 Zeta potential, 415 Zirconium, 273 Zirconium bis(monohydrogen phosphate) monohydrate, 179 Zirconium phosphate, 37, 273, 289 ZSM-5, 146 ZSM-11, 146