[13CII] observations to constrain fractionation chemistry and + column densities of C

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[13CII] observations to constrain fractionation chemistry and + column densities of C V. Ossenkopf, M. Röllig, C. Joblin, U. Graf, A. Fuente, D. Lis, J. Stutzki, P. Pilleri, F. van der Tak, E. Bergin C+ as an Astronomical Tool, Leiden, February 5, 2013

Theory See talk by M. Röllig Fractionation reaction drives transition from C+ to CO to different depths for 12C and 13C The 12C+/13C+ ratio can be enhanced by factor > 100 Chemical structure of a spherical PDR for χ=1000χ0

Theory In most cases, the true intensity ratio is rather governed by the optical depth of the [CII] line where we assume the standard abundance ratio (without chemical fractionation) FR 67 in the solar neighborhood If all carbon is ionized: AV=1 NC+= 2.5 1017 cm-2 <τ[cii]> = 0.8 [CII] turns optically thick for AV 1!

Theory Result for spherical clouds: Integrated [CII]/[13CII] intensity ratio for spherical PDRs PDRs bright in [CII] have an abundance ratio FR 67 They are optically thick in [CII] intensity ratio < 67 determined by τ[cii]

Observations: Case 1: NGC 7023 Spitzer IRAC (Joblin et al. 2008) Focus on Northern PDR (H2-peak) [CII] distribution (Joblin et al. in prep.)

NGC 7023 [CII]: Self-absorption dip indicates moderate optical depth for emission in line center [13CII]: All 3 HF detected Slightly stronger than expected from [CII] and optically thin emission τcenter 0.7-0.8 Tentative detection of enhanced FR in blue wing (scaled [CII] above [13CII]) [13CII] hyperfine components compared to [CII] scaled by normal HF ratio (remember the recent correction) and FR=67 for optically thin emission (Ossenkopf et al. 2013)

Case 2: The Orion Bar Clumpy in high-density tracers, but very smooth in [CII] CO 6-5 (color), 13CO 3-2 (white contours), OI 1.32µm (red), H2 v=1-0 S(1) (black), H13CN 1-0 (blue) (Lis & Schilke 2003) Extremely high S/N (> 100 for individual channels)

[13CII] Average profile of the two strongest [13CII] hyper-fine components compared to the scaled [12CII] profile that would be expected from the canonical abundance ratio and optically thin lines. Average peak optical depth of [CII] line τcenter 2.2

Optical depth from [CII]/[13CII] Contours of the [CII] line center optical depth overlaid on integrated [CII] intensities Peak optical depth exceeds three at intensity maximum Optical depth (= column density) layering shifted relative to intensity structure into the molecular cloud

C+ column density Combine intensity and optical depth to derive C+ column density and excitation temperature Contours of [CII] excitation temperature overlaid on the column densities. Temperature gradient in C+ consistent with stratification of the Orion Bar

Modeling: see poster by S. Andree Based on Orion Bar picture from Hogerheijde et al. (1995): Clumpy model stratification of clumpy layers deeper layer sees weaker FUV field due to attenuation

Case 3: Mon R2 Observed cut in Mon R2 overlaid on 13CO 2-1 and H recombination lines (dashes) showing the HII region p-v diagram along the cut: CO 9-8 (colors) + [CII] (contours) Broad wings and doublepeak structure of [CII] profiles

Interpretation Large-scale infalling cloud Increasing density Accelerated infall Large-scale rotation Expanding walls of HII region Harbors bipolar outflow [CII] mainly from walls of HII region Wings trace ionized flow Some self-absorption in the HII region cf. van Dishoeck

[13CII] Comparison of the profiles of the [13CII] hyperfine lines in Mon R2 with the scaled [CII] profiles from the same position. The blue-shifted [13CII] component is enhanced by factor 3 τ[cii] > 3 But: non-detection of the red component in [13CII] First observation of 13C+ fractionation in a PDR? But [CI] also shows only the blue component

Case 4: NGC2024 Optical image with mapped region Structure of the source: The HII region expands into an inhomogeneous medium with a denser hotter PDR in the back (Graf et al. 1993)

[13CII] vs. [CII] Integrated intensities of [CII] (contours) and [13CII] (colors) Comparison of the average profiles of the [13CII] hyperfine lines in NGC2024 with a scaled [CII] profile (Graf et al. 2012). Deep self-absorption in [CII] High foreground optical depth

Modelling Background: N(C+) = 1.0 1019 cm-2, Tex = 400 K Foreground: N(C+) = 2.4 1018 cm-2, Tex = 80 K Model fit to [CII] and [13CII] lines (left) and separate foreground and background [CII] spectra (right) (Stutzki et al. 2013) Very high C+ column density required

Column densities Other sources: C+ column densities consistent with known gas column assuming C/H=1.2 10-4, but all carbon being in ionized form!

Summary [CII] very extended Emission broad in space and velocity space Very smooth emission structure across the Orion Bar Origin probably mainly in a diffuse gas component Indications for carbon fractionation, i.e. enhanced [CII]/[ 13CII] in few velocity components, in particular the red component of MonR2 Where detected [13CII] allows to measure actual C+ column density Large columns in all sources Too large?

Compare spatial structure [CII] 13 CO 3-2 C2H (v.d. Wiel et al. 2010) CO 10-9 C18O 9-8 Best correlation with C2H

[CII] Very smooth structure No clumpiness in [CII] Similar to MIR FORECAST: 19.7 and 37µm (Shuping et al. 2012)