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Whitman College 345 Boyer Avenue Walla Walla, WA 99362 EDUCATION Nathan E. Boland Tel: 509-527-5906 Fax: 509-527-5904 bolandne@whitman.edu Johns Hopkins University, Baltimore, MD Ph. D. in Environmental Chemistry, defended August 2011 (conferral December 2011) Department of Geography and Environmental Engineering Advisor: Alan T. Stone NSF Graduate Research Fellow in Environmental Chemistry Colby College, Waterville, ME B.A. in Chemistry A.C.S., May 2001 Advisor: D. Whitney King Graduated Summa Cum Laude, with Honors, and with Distinction 2011 2001 TEACHING EXPERIENCE Assistant Professor of Analytical Chemistry Whitman College, Walla Walla WA Courses taught: General Chemistry Lecture and Lab (CHEM 125, 126, 136), Quantitative Analysis and Chemical Equilibria (CHEM 240), Instrumental Methods of Analysis (CHEM 320), Environmental Chemistry and Engineering (CHEM 388), Capillary Electrophoresis (CHEM 432), Chemistry Seminar (CHEM 481/482). Visiting Assistant Professor of Analytical Chemistry University of Puget Sound, Tacoma, WA Taught Instrumental Analysis lecture and laboratory (CHEM 330), Fundamental Chemistry laboratory (CHEM 110), Chemical Analysis and Equilibrium lecture and laboratory (CHEM 230). Teaching Assistant/Laboratory Instructor Johns Hopkins University, Baltimore, MD Guest lectured for Environmental Inorganic Chemistry (570.441). Guest lectured and graded problem sets for Aquatic Chemistry (570.443). Developed, organized and facilitated laboratory for Experimental Methods in Environmental Engineering and Chemistry (570.452). Organized and facilitated the aquatic chemistry laboratory for Environmental Engineering and Science Laboratory (570.304). Teach For America Corps Member/High School Teacher Scotlandville High School, Baton Rouge, LA Served as Teach For America corps member, 2001-2003. Taught Honors, Magnet, and Comprehensive Chemistry I (11 th Grade), Chemistry II (12 th Grade), Physical Science (9 th Grade). Chaired the Science Department, 2003-2004. School Improvement Team, 2002 2004, and Management Subcommittee, 2003-2004. 2012 pres. 2011 2012 2005 2011 2001 2004

Colby College/Teach For America Internship Co-Creator Teach For America, Baton Rouge, LA Developed a curriculum and administered a January Term Internship for Colby College students to explore an educational topic within the context of rural and urban schools in South Louisiana. Chemistry Content Seminar Co-Writer The New Teacher Project, New York, NY Developed curriculum for a national alternative certification program for high school chemistry teachers. Exploratory Geochemistry Summer Program for Minority Students Co-Creator Colby College, Waterville, ME and Scotlandville High School, Baton Rouge, LA Developed a summer research program with Dr. D. Whitney King that was funded by a grant from the NSF Geosciences division (NSF EAR-0220224). Tutored, mentored, and supervised two minority high school students in preparation for and during a summer research internship. 2003 2003 2002 GRANTS FUNDED M. J. Murdock, Natural Sciences Grant - $75,000 (incl. matching funds) (with 6+ student stipends) Influence of Low Molecular Weight Organic Acids on the Mechanism of Multidentate Ligand Exchange Reactions Whitman College, Louis B. Perry Research Award - $5,200 (with 1 student stipend) Evaluating Chelating Resin Identity on Metal Bioavailability Analyses Whitman College, Louis B. Perry Research Award - $7,175 (with 1 student stipend) Pathways for Inhibition of Chelating Agent Exchange Reactions Whitman College, Louis B. Perry Research Award - $10,850 (with 2 student stipends) Pathways and Catalysis of Chelating Agent Exchange Reactions Whitman College, Louis B. Perry Research Award - $12,500 (with 3 student stipends) Mechanisms and Rates of Ligand Exchange Reactions Involving Strong Chelating Agents Whitman College, Louis B. Perry Research Award - $8,500 (with 1 student stipend) Surface Catalysis of Ligand Exchange Reactions between Strong Chelating Agents 2017-2019 2018 2016 2015 2014 2013 HONORS, AWARDS AND FELLOWSHIPS NSF Graduate Research Fellowship in Environmental Chemistry Dean Robert H. Roy Fellowship (merit-based fellowship for the Whiting School of Engineering at Johns Hopkins University) United Way Brotherhood/Sisterhood Award (for contribution to school community), Scotlandville Magnet High School Teacher of the Year Award, Scotlandville Magnet High School 2005 2008 2004 2005 2002 2003 2002 2003 Boland, N. - 2

PROFESSIONAL ACTIVITIES Review Panel Member, EMSL Environmental Sciences Area Proposal Review Panel, Pacific Northwest National Laboratory, Richland, WA Review Panel Member, EMSL Terrestrial Subsurface Ecosystems Proposal Review Panel, Pacific Northwest National Laboratory, Richland, WA Symposium Co-Chair, Approaching the surface: Interrogating chemical interactions at the mineral-water interface, 245 th ACS National Meeting, New Orleans, LA Invited Participant, SCEWest Meeting for Civic Engagement Network in NW, Seattle University, Seattle, WA May 2018 May 2015 Spring 2013 Spring 2013 Peer Reviewer for International Journal of Environmental Protection and Policy, Environmental Science & Technology Letters, and Geochimica et Cosmochimica Acta. Member of American Chemical Society (Environmental Chemistry and Geochemistry Divisions), Council on Undergraduate Research PUBLICATIONS (*UNDERGRADUATE STUDENT CO-AUTHOR, **HIGHSCHOOL STUDENT CO-AUTHOR) Peer-Reviewed Articles Rea, L.T.*; Xu, Y.*; Boland, N.E. Effects of calcium ion on the kinetics of a model disjunctive ligand exchange reaction. Environ. Sci.: Process. Impacts. 2018 doi:10.1039/c8em00301g Boland, N.E.; Stone, A.T. Rates of Nickel(II) Capture from Complexes with NTA, EDDA, and Related Tetradentate Chelating Agents by the Hexadentate Chelating Agents EDTA and CDTA: Evidence of a "semijunctive" ligand exchange pathway. Geochim. Cosmochim. Acta 2017, 212, 176-195 doi:10.1016/j.gca.2017.06.003 Boland, N.E.; Stone, A.T. Capillary electrophoresis facilitates determination of metal complex stoichiometry by Job s method of continuous variation. Environ. Chem. 2013, 10, 409. doi:10.1071/en13103 Dissertations/Theses Boland, N.E. Nickel and Chelating Agent Speciation by Capillary Electrophoresis: Exploration of pathways, rates and structurereactivity relationships pertaining to exchange reactions. Johns Hopkins University: Baltimore, MD, 2011. Boland, N. E.; King, D.W. Flow Injection Analysis of Superoxide in Aqueous Solution: A quantitative determination using the chemiluminescent probe MCLA. Senior Honors Thesis. Chemistry Department, Colby College, Waterville, ME, 2001. Other Publications Boland, N. E. Inspiring a New Generation of Chemists. inchemistry Magazine, March/February 2003, pg 21-23. Maddin, B.; Boland, N. Teaching for Results: Secondary Chemistry, 1st Edition. New York, NY: The New Teacher Project, Inc., 2003. Presentations Boland, N.E.; Stone, A.T.; Rea, L.T.*; Xu, Y.*; Wildman, A.*; Briody-Pavlik, L.*; Huang, Z.* GEOC 85 Constituent ions and spectator low molecular weight organic acids influence ligand exchange kinetics: geochemical implications. Abstracts of Papers, 255 th American Chemical Society National Meeting. New Orleans, LA, March 2018. (oral) Rea, L.*; Boland, N.E. Modeling the Kinetics of Trace Metal Ion Speciation: The influence of calcium ion on disjunctive ligand exchange. Abstracts of Papers, 253rd American Chemical Society National Meeting. San Francisco, CA, April 2017. Boland, N. - 3

Wildman, A.*; Boland, N.E. The Influence of a Metal Oxide Surface on Ligand Exchange Reactions between Strong Chelating Agents. Abstracts of Papers, 251st American Chemical Society National Meeting. San Diego, CA, March 2016. Xu, Y.*; Boland, N.E. The Influence of a Metal Oxide Surface on Ligand Exchange Reactions between Strong Chelating Agents. Abstracts of Papers, 251st American Chemical Society National Meeting. San Diego, CA, March 2016. Boland, N.E.; Stone, A.T.; Nelson, T.*; Wildman, A.*; Harned, M.*; Xu, Y.* Structure-reactivity relationships for multidentate ligand exchange reaction pathways. Chemistry Department Seminar, Eastern Washington University, February 10, 2016 (invited oral) Boland, N.E.; Stone A.T.; Nelson, T.*; Harned, M.V.*; Wildman, A.* GEOC 108 Adjunctive, Disjunctive and Interjunctive? Influence of ligand structure on kinetic pathways of ligand exchange. Abstracts of Papers, 249 th American Chemical Society National Meeting. Denver, CO, March 2015. (oral) Conrad, J.P.*; Boland, N.E. The Influence of a Metal Oxide Surface on Ligand Exchange Reactions between Strong Chelating Agents. Abstracts of Papers, 249 th American Chemical Society National Meeting. Denver, CO, March 2015. Harned, M.V.*; Nelson, T.*; Boland, N.E. Influence of ph on Ligand Exchange Rate with Phosphonate-Containing Chelating Agents Abstracts of Papers, 249 th American Chemical Society National Meeting. Denver, CO, March 2015. Hinkle, S.M.*; Boland, N.E. The use of CYCLAM and other tetraamines to probe the mechanism of surface-influenced ligand exchange. Abstracts of Papers, 249 th American Chemical Society National Meeting. Denver, CO, March 2015. Nelson, T.*; Boland, N.E. Influence of Lewis base identity on rates of ligand exchange. Abstracts of Papers, 247 th American Chemical Society National Meeting. Dallas, TX, April 2014. Stone, A.T.; Boland, N.E.; Carbonaro, R.F. Chelating Agent Selection From A Kinetic Perspective: New Insights From Capillary Electrophoresis. 3 rd Annual American Chemical Society Green Chemistry Institute Roundtable, 17 th Annual Green Chemistry & Engineering Conference, North Bethesda, MD, June 19, 2013. Boland, N.E.; Stone, A.T. Capillary Electrophoresis-Based Methods for Determining Metal Ion and Chelating Agent Speciation, and Their Use in Environmental Chemistry. 17 th International Symposium on Electro- and Liquid Phase-separation Techniques. Baltimore, MD, August 2010. (poster, oral) Boland, N.E.; Stone, A.T. Nickel Exchange Reactions: Effect of chelating agent functional groups and structure on pathways and rates. Gordon Conference on Environmental Sciences: Water. Holderness School, Holderness, NH, June 2010. Boland, N.E.; Stone, A.T. GEOC 27 Chelating Agent Capture of Nickel in Heterogeneous Media: Structure-reactivity relationships. Abstracts of Papers, 238 th American Chemical Society National Meeting. Washington, DC, August 2009. (oral) Boland, N.E.; Stone, A.T. Chelating Agents, Surfaces, and Nickel: Structure-Reactivity Relationships. Chemodynamics of Ecosystems. Monte Verità, Ascona, Switzerland, October 2008. (poster, oral) Boland, N.E.; Stone, A.T. GEOC 76 Siderophores, surfaces, and metals: How siderophore structure affects exchange rates. Abstracts of Papers, 236 th American Chemical Society National Meeting. Philadelphia, PA, August 2008. (oral) Boland, N.E.; Stone, A.T.; Chaney, R.L. Yehuda, Z. Phytosiderophore Speciation by Capillary Electrophoresis. Gordon Conference on Environmental Bioinorganic Chemistry. Proctor Academy, Andover, NH, June 2006. King, D.W.; Boland, N.E. An Exploratory Summer Research Program: Creating opportunities for under-represented high school students and their teachers. Abstracts of Papers, 225 th American Chemical Society National Meeting. New Orleans, LA, March 2003. Boland, N. - 4

Bazille, C.;** Jackson, S.;** Boland, N.E.; King, D.W. Superoxide Detection in Surface Waters of Maine Lakes. Sigma Xi Student Research Conference. Galveston, TX, November 2002. Boland, N. E.; King, D.W. Flow Injection Analysis of Superoxide in Aqueous Solution: A quantitative determination using the chemiluminescent probe MCLA. Abstracts of Papers, 219 th American Chemical Society National Meeting. San Diego, CA, March 2001. Boland, N. - 5