Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 1 of 14 The following sample(s) was/were submitted and identified by/on behalf of the applicant as : Sample Submitted By Sample Description Style/Item No. Sample Receiving Date Testing Period : : : : : PREPREG HTE-59B-2 2014/05/06 2014/05/06 TO 2014/05/22 ========================================================================================== Test Result(s) : Please refer to next page(s).
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 2 of 14 Test Result(s) PART NAME No.1 Cadmium (Cd) Lead (Pb) Mercury (Hg) Antimony (Sb) Test Item(s) Hexavalent Chromium Cr(VI) : Formaldehyde (CAS No.: 50-00-0) Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified (α- HBCDD, β- HBCDD, γ- HBCDD) (CAS No.: 25637-99-4 and 3194-55-6 (134237-51-7, 134237-50-6, 134237-52-8)) BBP (Benzyl butyl phthalate) (CAS No.: 85-68-7) DEHP (Di- (2-ethylhexyl) phthalate) (CAS No.: 117-81-7) DIDP (Di-isodecyl phthalate) (CAS No.: 26761-40-0; 68515-49-1) DINP (Di-isononyl phthalate) (CAS No.: 28553-12-0; 68515-48-0) DNOP (Di-n-octyl phthalate) (CAS No.: 117-84-0) DBP (Dibutyl phthalate) (CAS No.: 84-74-2) YELLOW SHEET Unit mg/kg With reference to IEC 62321-5: 2013 and performed by ICP-AES. mg/kg With reference to IEC 62321-5: 2013 and performed by ICP-AES. mg/kg With reference to IEC 62321-4: 2013 and performed by ICP-AES. mg/kg mg/kg Method With reference to IEC 62321: 2008 and performed by UV-VIS. With reference to US EPA Method 3052. Analysis was performed by ICP- AES. mg/kg With reference to ISO 17226-1(2008). Analysis was performed by HPLC/DAD. mg/kg With reference to IEC 62321: 2008 method. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. % With reference to EN 14372. Analysis was performed by GC/MS. Result MDL No.1 2 n.d. 2 5 2 n.d. 2 n.d. 2 n.d. 3 n.d. 5 n.d. 0.003 n.d. 0.003 n.d. 0.01 n.d. 0.01 n.d. 0.003 n.d. 0.003 n.d.
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 3 of 14 Perfluorooctane sulfonates (PFOS-Acid, Metal Salt, Amide) PFOA (CAS No.: 335-67-1) PVC Sum of PBBs Monobromobiphenyl Dibromobiphenyl Tribromobiphenyl Test Item(s) Tetrabromobiphenyl Pentabromobiphenyl Hexabromobiphenyl Heptabromobiphenyl Octabromobiphenyl Nonabromobiphenyl Decabromobiphenyl Sum of PBDEs Monobromodiphenyl ether Dibromodiphenyl ether Tribromodiphenyl ether Tetrabromodiphenyl ether Pentabromodiphenyl ether Hexabromodiphenyl ether Heptabromodiphenyl ether Octabromodiphenyl ether Nonabromodiphenyl ether Decabromodiphenyl ether Unit Method mg/kg With reference to US EPA 3550C: 2007. Analysis was performed by LC/MS. mg/kg With reference to US EPA 3550C: 2007. Analysis was performed by LC/MS. ** Analysis was performed by FTIR and FLAME Test. MDL Result No.1 10 n.d. 10 n.d. - Negative mg/kg - n.d. mg/kg With reference to IEC 62321: 2008 and 5 n.d. mg/kg performed by GC/MS. - n.d.
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 4 of 14 Test Item(s) Unit Method MDL Halogen Halogen-Fluorine (F) (CAS No.: 14762-94-8) Halogen-Chlorine (Cl) (CAS No.: 22537-15-1) Halogen-Bromine (Br) (CAS No.: 10097-32-2) Halogen-Iodine (I) (CAS No.: 14362-44-8) Result No.1 mg/kg 50 1100 mg/kg 50 326 With reference to BS EN 14582:2007. mg/kg Analysis was performed by IC. 50 37100 mg/kg 50 n.d. Note: 1. mg/kg = ppm;0.1wt% = 1000ppm 2. n.d. = Not Detected 3. MDL = Method Detection Limit 4. " - " = Not Regulated 5. ** = Qualitative analysis (No Unit) 6. Negative = Undetectable / Positive = Detectable PFOS Reference Information : POPs - (EU) 757/2010 Outlawing PFOS as substances or preparations in concentrations above 0.001% (10ppm), in semi-finished products or articles or parts at a level above 0.1%(1000ppm), in textiles or other coated materials above 1µg/m².
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 5 of 14 1) These samples were dissolved totally by pre-conditioning method according to below flow chart. (Cr 6+ test method excluded) 2) Name of the person who made measurement: Climbgreat Yang 3) Name of the person in charge of measurement: Troy Chang Cutting / Preparation Sample Measurement Pb Cd Acid digestion by suitable acid depended on different sample material (as below table) Hg Microwave digestion with HNO 3 /HCl/HF Cr 6+ (Note**) Add appropriate amount of digestion reagent Filtration Solution ICP-AES Sample Material Residue 1) Alkali Fusion 2) HCl to dissolve Digestion Acid Heat to appropriate temperature to extract Cool, filter digestate through filter Add diphenyl-carbazide for color development Steel, copper, aluminum, solder Aqua regia, HNO 3, HCl, HF, H 2 O 2 Glass Gold, platinum, palladium, ceramic HNO 3 /HF Aqua regia Silver HNO 3 Plastic Others H 2 SO 4, H 2 O 2, HNO 3, HCl Added appropriate reagent to total digestion measure the absorbance at 540 nm by UV-VIS Note** (For IEC 62321) (1) For non-metallic material, add alkaline digestion reagent and heat to 90~95. (2) For metallic material, add pure water and heat to boiling.
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 6 of 14 1) These samples were dissolved totally by pre-conditioning method according to below flow chart. 2) Name of the person who made measurement: Climbgreat Yang 3) Name of the person in charge of measurement: Troy Chang Flow Chart of digestion for the elements analysis performed by ICP-AES Cutting / Preparation Sample Measurement Acid digestion by suitable acid depended on different sample material (as below table) Filtration Solution Residue 1) Alkali Fusion 2) HCl to dissolve ICP-AES Steel, copper, aluminum, solder Aqua regia, HNO 3, HCl, HF, H 2 O 2 Glass Gold, platinum, palladium, ceramic HNO 3 /HF Aqua regia Silver HNO 3 Plastic Others H 2 SO 4, H 2 O 2, HNO 3, HCl Added appropriate reagent to total digestion
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 7 of 14 Formaldehyde analytical flow chart Name of the person who made measurement: Yaling Tu Name of the person in charge of measurement: Troy Chang Test Method:US EPA 8315A ISO 17226-1 Sample pretreatment Sample extraction Derived by DNPH Concentrate/Dilute Extracted solution Analysis was performed by HPLC/DAD Data
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 8 of 14 HBCDD analytical flow chart Name of the person who made measurement: Roman Wong Name of the person in charge of measurement: Troy Chang Sample pretreatment Sample extraction / Ultrasonic method Concentrate/Dilute Extracted solution Filter Analysis was performed by GC/MS Data
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 9 of 14 Analytical flow chart of phthalate content Name of the person who made measurement: Roman Wong Name of the person in charge of measurement: Troy Chang Sample pretreatment/separation Sample extraction by soxhlet method Concentrate/Dilute Extracted solution Analysis was performed by GC/MS Data
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 10 of 14 PFOA/PFOS analytical flow chart of Ultrasonic extraction (LC/MS) procedure Name of the person who made measurement: Roman Wong Name of the person in charge of measurement: Troy Chang Sample pretreatment Sample extraction by Ultrasonic extraction (Reference method: US EPA 3550C) Concentrate/Dilute Extracted solution Analysis was performed by LC/MS Data
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 11 of 14 Analysis flow chart for determination of PVC in material Name of the person who made measurement: Roy Lin Name of the person in charge of measurement: Troy Chang Sample pre-treatment Flame test Sample analyzed by FTIR Check wave-number of C-Cl bonding Data
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 12 of 14 PBB/PBDE analytical FLOW CHART Name of the person who made measurement: Roman Wong Name of the person in charge of measurement: Troy Chang First testing process Optional screen process Confirmation process Sample Sample pretreatment Screen analysis Sample extraction/ Soxhlet method Concentrate/Dilute Extracted solution Filter Analysis by GC/MS Issue Report
Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 13 of 14 Analytical flow chart of halogen content Name of the person who made measurement: Rita Chen Name of the person in charge of measurement: Troy Chang Sample pretreatment / Separation Weighting and putting sample in cell Oxygen Bomb Combustion / Absorption Dilution to fixed volume Analysis was performed by IC
#PIC Test Report No. : CE/2014/50660 Date : 2014/05/22 Page : 14 of 14 * The tested sample / part is marked by an arrow if it's shown on the photo. * ** End of Report **