A few final review points to emphasize on: Topic #6 Atmospheric Structure & Composition...

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FYI: Test #2 will cover: Topic 5: Radiation Law #6 (absorption curves) Topic 6 : Atmo Structure & Composition (all) Topic 7: Thermodynamics (content covered today & next Monday) A few final review points to emphasize on: Topic #6 Atmospheric Structure & Composition....

SUMMARY OF KEY CONCEPTS: short version 1. Four gases N 2, O 2, Ar, & CO 2 comprise about 99% of the volume but minor trace Greenhouse Gases are extremely important. Q. Which of these 4 is a GHG? 2. Most of the MASS of the atmosphere is in the bottom few kilometers (i.e. the Toposphere!) 3. Different gases are abundant at certain levels in the atmosphere. The effect of radiation absorbed by these gases is seen in the vertical temperature profile 4.... which leads to the vertical structure of the atmosphere p 35

Visualization of the info in the table on the top of Class Notes p 33: Percent Concentration (by volume) of the major GASES in the Atmosphere FROM: Dire Predictions pp 28-29

Greenhouse Gas Concentrations in Atmosphere in parts per billion (ppb) CARBON Compare concentrations w/ TABLE on p 33 ( RF column in Table = an indicator of GH Gas effectiveness) DIOXIDE All other Greenhouse Gases

UV UV UVA + Vis Earth is WARMED when Solar UV, Vis & NIR reach the surface and are absorbed Near IR Earth+ Atmosphere are COOLED when Terrestrial IR escapes thru IR Atmospheric Window IR IR Troposphere AND Surface are WARMED when Terrestrial IR is absorbed & emitted by GH Gases concentrated in Tropopause IR Q: Why do we say: The atmosphere is heated from BELOW? Review p 33

WHERE IS Near IR? 0.7-1.0 m UV Visible Far IR Near IR 0.4 0.7 1.0 Absorption by Individual Gases Absorption by Total Atmosphere p 28

WHOLE ATMOSPHERE: Absorption + Transmission thru UV / Vis atmospheric window TRANSMISSION OF Incoming SW UV+Vis+NIR is how the SUN WARMS the EARTH thru IR atmospheric window TRANSMISSION OF Outgoing LW / IR is how the Earth COOLS ITSELF 0.5 10 UV VISIBLE NIR Far IR Bottom row p 28

CHECKPOINT THINK... then share What s still fuzzy... what s now perfectly clear about Topic #6?

TOPIC # 7 LAWS OF THERMODYNAMICS & ENERGY TRANSFORMATIONS The Next Piece in the Puzzle to Understand Global Changes Featuring....

OUR QUOTE OF THE DAY... In this house, we obey the LAWS of THERMODYNAMICS!... is from HOMER SIMPSON

PART A - Thermal Energy Background THERMODYNAMICS (def) = The study of the general properties of ENERGY. Thermal ENERGY plays a central role, so... the STUDY OF ENERGY can also be called THERMODYNAMICS.

PART A - Thermal Energy Background Forms of Energy - Review Kinetic (KE ) = energy of motion or the ability of a mass to do work. (related to mass and velocity) Potential (PE) = energy a system possesses if it is capable of doing work, but is NOT doing work now [ Includes: gravitational, elastic, chemical, electrical, magnetic... and ELECTROMAGNETIC ] review

PART A - Thermal Energy Background Thermal Energy (def) = the grand TOTAL of all energies inside a substance... specifically: a measure of the quantity of atomic kinetic & potential energy contained in every object p 37

PART A - Thermal Energy Background Thermal Energy vs Temperature: Temperature is a measure of the AVERAGE kinetic energy of each molecule in a body. Temperature = tells how warm or cold a body is with respect to some standard scale: K C F Absolute Zero 0-273.15 C - 459.15 F Freezing Point of H 2 O: 273.15 0 C 32 F Boiling Point of H 2 O: 373.15 100 C 212 F p 37

PART A - Thermal Energy Background If a body has a high temperature, each of its molecules has, on the average, a large amount of kinetic energy. if a body has a low temperature, each molecule on the average has a small amount of kinetic energy. (and if atoms lose all their kinetic energy, they reach the "ABSOLUTE ZERO of temperature) p 37

PART A - Thermal Energy Background Thermal Energy vs. Heat: HEAT = Thermal Energy Transfer (or Flow) Heat = the thermal energy that is transferred from one body to another because of a temperature difference. HOT COLD p 40

PART A - Thermal Energy Background Heat will always flow from a substance of higher temperature to a substance of lower temperature, until both come to a common temperature. p 40

CLICKER Q

Clicker Q1 - Which way is heat being transferred? 1. From the cold beer can into Homer s warmer beer belly 2. From Homer s beer belly to the colder beer can 3. From BOTH the beer can to Homer and Homer to the beer can

Clicker Q 1- Which way is heat being transferred? 1. From the cold beer can into Homer s warmer beer belly 2. From Homer s beer belly to the colder beer can 3. From BOTH the beer can to Homer and Homer to the beer can

PART A - Thermal Energy Background Cold chamber DOOR CLOSED Warm chamber What will happen? Reaches equilibrium Cold chamber warms up Now let s open the door! with door open Warm chamber cools down Will not spontaneously return to previous condition!

CHECKPOINT Got all that Homer? OK, LET S MOVE ON TO PART B..... on p 38

PART B Temperature Responses & Thermal Energy Storage (in Different Substances) Background needed..... Units of Measure of Thermal Energy (i.e., the joule or calorie) Specific Heat & Heat Capacity p 38

1 cm Thermal Energy Units Review: Units for Thermal Energy = the joule or calorie. A CALORIE is the amount of THERMAL ENERGY required to change the temperature of 1 gram of water by 1 C * 1 calorie = 4.186 joules 1 joule = 0.239005736 calories Simple ways to envision one gram = * specifically from 14.5 C to 15.5 C 1 cm tiny cube of water Mass of a paperclip p 38

STUDY THE TABLE ON TOP of p 38 and pick out 3 substances we could use to make estimates about the Temperature Response & Thermal Energy Storage of different parts of our Earth s environment

Specific Heat & Heat Capacity for Different Substances Substance Specific Heat Heat Capacity cal joules water 1.00 4.186 1.00 air 0.24 1.005 0.00024-0.00034 concrete 0.21.879 0.50 sand 0.20.837 0.10-0.60 (higher if wet) iron 0.105.440 0.82 silver 0.056.234 0.59 Note the HEAT CAPACITY differences between higher density substances (like water, iron) vs. the low density substance of AIR. p 38

Key Term #1 Specific Heat = the amount of thermal energy (in calories) required to raise the temperature of 1 gram of any substance by 1 C.

Key Term #2 Heat Capacity = Specific Heat x Mass (density) MASS of a substance for a given VOLUME GRAMS / CUBIC CENTIMETER Heat capacity represents the capacity of a substance to absorb and store heat in relation to its volume and density.

Clicker Q2 - Why will he burn his tongue, even if the pie crust is cool enough to hold? 1 - Because due to the high specific heat of the water in the apple pie filling, the filling will heat up faster and to a much higher temperature than the crust can achieve 2 Because, due to the high specific heat and heat capacity of the water in the apple pie filling, the filling will hold the thermal energy longer than the crust will after the pie is taken out of the oven. 3 - BOTH p 38

Clicker Q2 - Why will he burn his tongue, even if the pie crust is cool enough to hold? 1 - Because due to the high specific heat of the water in the apple pie filling, the filling will heat up faster and to a much higher temperature than the crust can achieve 2 Because, due to the high specific heat and heat capacity of the water in the apple pie filling, the filling will hold the thermal energy longer than the crust will after the pie is taken out of the oven. 3 - BOTH p 38

QUESTION: Assume you have an equal volume of WATER, AIR & SAND. Which will HEAT UP THE FASTEST if the same amount of thermal energy is transferred into the substance... WHY? AIR WATER SAND HINT: the greater the heat capacity, the LONGER it will take to heat up the substance.

ANSWER - Assume you have an equal volume of WATER, AIR & SAND. Which will HEAT UP THE FASTEST if the same amount of thermal energy is transferred into the substance? 1. AIR 2. WATER 3. SAND Explanation: The lower the heat capacity, the quicker the response to a transfer of heat into the substance!

QUESITON: What s wrong with this TEMPERATURE MAP? COLD HOT COLD Answer: The map shows NO DIFFERENCE in the way that continents and oceans heat up when solar energy is absorbed in tropical low latitudes Source: Dire Predictions pp 10-15

QUESTION: As global warming is occurring WHERE will we be able to detect a temperature change FIRST? OCEAN or CONTINENT NEITHER: They will both heat up at the same rate!

ANSWER As global warming is occurring we will be able to detect it FIRST where? 1 = the ocean temperature 2 = the land surface temperature (i.e., soil) 3 = actually, they will both heat up at the same rate A better temperature map! Note where the hottest temperatures occur

Thought Q1. Why does the ocean surface warm more slowly than the land surface? http://www.ncdc.noaa.gov/cmb-faq/anomalies.php p 38

Clicker Q3 - Which component of the EARTH SYSTEM has the ability to store thermal energy the longest -- once it heats up? 1. The ATMOSPHERE 2. The CONTINENTS 3. The OCEAN

Clicker Q3 - Which component of the EARTH SYSTEM has the ability to store thermal energy the longest -- once it heats up? 1. The ATMOSPHERE 2. The CONTINENTS 3. The OCEAN

Thought Q2. Why is the total heat CONTENT of the ocean so much greater than the land? Figure: http://www.skepticalscience.com/earths-climate-system.html updated Dec 2013 p 38

CHECKPOINT Got all that Homer? OK, LET S MOVE ON TO PART C..... on p 39

PART C Thermal Energy Transfer Heat Transfer the process by which thermal energy moves from one place to another... READ IT! 3 ways of heat transfer p 39

PART C Thermal Energy Transfer VIDEO: There are three ways that HEAT can travel https://www.youtube.com/watch?feature=player_embedded&v=7y3mfagvn1c p 39

HEAT TRANSFER CONDUCTION Jiggling molecule jiggling molecule transfer of heat (kinetic energy at molecular scale) CONVECTION Mass of warm air or liquid heats, expands, rises RADIATION Photon /wave transport: even through a void! p 39

PART C Thermal Energy Transfer WRAP-UP Electromagnetic Radiation (a KEY POINT about it!) Electromagnetic energy (radiation) is not HEAT energy. It does not become heat (jiggling molecules) until it strikes an object, is absorbed by the object and sets the molecules in the object in motion, thereby heating up the object.

How does this concept relate to & this FIGURE? Electromagnetic energy is not HEAT energy.

Electromagnetic Radiation WHAT IS THE LINK TO GLOBAL CHANGE? The sun's energy comes in as radiant (electromagnetic) energy, and is converted to measurable heat only after it is absorbed (e.g., by the surface of the earth, by certain gases in the atmosphere -- by the GREENHOUSE GASES p 39

Got all that Homer?

THINKING DEEPLY WRAP-UP Participation Point Activity: BONUS POINTS FOR THOSE WHO WERE PRESENT IN CLASS TODAY! Get a blank index card from you group folder, put Name & Group # on it & all present sign your names! As a Group, pick one NEW thing you learned today about THERMODYNAMICS & reflect on what it has to do with GLOBAL CLIMATE CHANGE. Then explain this in a short paragraph

Can I go now???? YES!!