Utsunomiya University Experiments, September - November 2011

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Colm O Gorman 1, Thomas Cummins 1, Takamitsu Otsuka 2, Noboru Yugami 2,4,Weihua Jiang 5, Akira Endo 6, Bowen Li 1, Padraig Dunne 1,Emma Sokell 1, Gerry O Sullivan 1 and Takeshi Higashiguchi 2,4 Utsunomiya University Experiments, September - November 2011

Motivation Interest in Gd, 6.7 nm and shorter wavelength sources Experiment 1 Investigation of the effect of pulse duration and laser intensity on Gd plasma as a viable future lithography source Experiment 2 Investigation of the effect of viewing angle on the spectral behaviour of a Gd plasma source near 6.7nm Discussion Possible use of laser-produced Gd plasma as a future BEUV source

Motivation Interest in Gd, 6.7 nm and shorter wavelength sources Experiment 1 Investigation of the effect of pulse duration and laser intensity on Gd plasma as a viable future lithography source Experiment 2 Investigation of the effect of viewing angle on the spectral behaviour of a Gd plasma source near 6.7nm Discussion Possible use of laser-produced Gd plasma as a future BEUV source

Y. Platinov et al., Status of multilayer coatings for EUV Lithography 2011 Int. Workshop on EUV Lithography, Hawaii

Maximum CE of 0.44% for mass limited target and 0.52% for double pulse scheme. Defined by 0.6% BW of MLM Mass limited Gd targets; 10% - green triangles, 30% - red circles and 100% - blue squares. Irradiated with 1.06 µm laser light Dashed lines correspond to single shots of 30% (red) and 100% (blue) Gd. Double pulse using delay between pulses of Nd:YAG laser Higashiguchi et al. (2011) Appl. Phys. Lett. 99, 191502

Pumping of pre formed plasma, with CO 2 laser on liquid Xenon microjet targets (4d-4f resonant transition lines of 7 + - 11 + ions) Nd:YLF (1047 nm) irradiation of a thin liquid water jet target (12.99 and 12.85 nm oxygen lines) Ueno et al. (2007) Appl. Phys. Lett. 90, 191503 Vogt et al. (2001) Appl. Phys. Lett. 79, 2336

Motivation Interest in Gd, 6.7 nm and shorter wavelength sources Experiment 1 Investigation of the effect of pulse duration and laser intensity on Gd plasma as a viable future lithography source Experiment 2 Investigation of the effect of viewing angle on the spectral behaviour of a Gd plasma source near 6.7nm Discussion Possible use of laser-produced Gd plasma as a future BEUV source

T λ E max Nd:YAG 10 ns 1064 nm 420 mj Nd:YAG 150 ps 1064 nm 210 mj Ti:Sapphire 140 fs 800 nm 30 mj Laser intensity range: 10 11-10 15 W/cm 2

-17 V Schematic of experimental set-up

CE Defined within a 0.6% bandwidth of La/B 4 C mirrors in 2π sr,centered on 6.76 nm. Max 0.4% @ 7 10 13 W cm -2 T. Cummins et al. Appl. Phys. Lett. 038207

ps laser ns laser fs laser (note scale)

T. Cummins et al. Appl. Phys. Lett. 038207

Longer flight times recorded for ions from the ps and fs LPPs than from ns LPPs 2 μs for optimum intensity of ns laser and 9 μs for optimum intensity of ps laser Due to smaller plasma source created, meaning a smaller electrostatic potential for accelerating ions Therefore ps Nd:YAG demonstrated both an increase in TOF and increased CE

Electron temperature dependence on laser intensity demonstrated for high-z material, using a 1-D hydrodynamic code and λ=1.06 µm φ of 7x10 13 W/cm 2 generates T e close to 130 ev T. Cummins et al. Appl. Phys. Lett. 038207 Calculation by Hao Tan

By use of a steady-state collisional radiative (CR) model, Gd ion populations calculated at 1x10 21 cm -3 Producing optimum ion population requires tuning of the T e between 80 to 130 ev T. Cummins et al. Appl. Phys. Lett. 038207 Calculation by Bowen Li

Motivation Interest in Gd, 6.7 nm and shorter wavelength sources Experiment 1 Investigation of the effect of pulse duration and laser intensity on Gd plasma as a viable future lithography source Experiment 2 Investigation of the effect of viewing angle on the spectral behaviour of a Gd plasma source near 6.7nm Discussion Possible use of laser-produced Gd plasma as a future BEUV source

(b) (d) (a) (c) Nd:YAG Laser Lens 45 o 90 o Nd:YAG Laser Lens 0 o 45 o w Target w Target Pumping outlet Pumping outlet f = 10 cm, spot size = 30 40um λ= 1064 nm t = 10 ns or 150 ps

C O Gorman et. al - Appl. Phys. Lett 100-141108 (2012)

Morris et. al (Appl. Phys. Lett 92-231503)

1064nm 10 ns Gd I - IV [1] J. White et. Al (Appl. Phys. Lett. 92 151501 (2008) )

M. Richter, et.al Phys. Rev. A 40 7007 7019

C O Gorman et. al - Appl. Phys. Lett 100-141108 (2012)

C O Gorman et. al - Appl. Phys. Lett 100-141108 (2012)

C O Gorman et. al - Appl. Phys. Lett 100-141108 (2012)

Maximum CE of 0.4% achieved with ps at 7x10 13 W/cm 2 However, emission not optimized due to some EUV suppression by self absorption effects Ion TOF from ps laser produced plasma is greater than double that compared to that of ns. Hence lower ion kinetic energy This will assist with debris mitigation and reduce the damage to optical components by fast ion bombardment

There may be an optimum angle for collection Typical experimental setup fixed angle of measurement Isotropic emission assumed extrapolated in to 2pi Target geometries and angle of measurement must be reported along with CE

Results point towards use of ps lasers, perhaps carbon dioxide (CO 2 ), for optimum EUV emission from Gd plasma Emission will increase due to the reduction in opacity and produce ions with prolonged flight times Mass limited targets or novel plasma targets required Gd, in some form, can play a significant role in future application as a BEUV source Sn (droplet target) Melting point: 505.05 K Boiling point: 2543.15 K Gd (planar target?) Melting point: 1584.15 K Boiling point: 3506.15 K

UCD: Dr. Fergal O Reilly, Dr. Tony Donnelly, Dr. Paul Sheridan, Dr. Ken Fahy, Dr. Rebekah D Arcy, Dr. Deirdre Kilbane, Dr. Tom McCormack, Dr. Larissa Juschkin, Dr. Niksa Krstulovic, Enda Scally, Robert Stefaunuik, Colm S Harte, Imam Kambali, Brian Doohan, Niall Kennedy and Elaine Long Utsunomiya University: Hao Tan Collaborators: DCU: Prof. John Costello, Dr. Paddy Hayden, Colm Fallon, TCD: Prof. James Lunney and Issac Tobin Science Foundation Ireland under Principal Investigator Research Grant No. 07/IN.1/1771.