Estimating the radiation environment in the Great Barrier Reef

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Estimating the radiation environment in the Great Barrier Reef by Itsara Masiri M.Sc. (Physics) Submitted in fulfilment of the requirements for the Degree of Doctor of Philosophy University of Tasmania December 2008

Declaration This thesis contains no material which has been accepted for the award of any other degree or diploma by the University of Tasmania or any other institute, except by way of background information that is duly acknowledged. To the best of my knowledge and belief this thesis contains no material previously published or written by another person, except where due reference is made in the text. (Itsara Masiri) Authority of Access This Thesis may be available for loan and limited copying in accordance with the Copyright Act 1968. (Itsara Masiri)

Abstract There are a number of studies that have examined solar irradiance in the environment above and below the ocean surface. Unlike other previous studies, this thesis maps both surface and underwater irradiances using a combination of geostationary and Sea WiFS satellite data and surface measurements. Detailed estimates of broadband, PAR and UVB solar radiation, both above and below water, is obtained for the Great Barrier Reef region in northeast Australia. The study area covers the Coral Sea including the Great Barrier Reef (GBR), northeast of Queensland (1 0 o S - 26 S, 142" E - 155 E). Geostationary meteorological satellite (GMS) data collected for periods between 1995 and 2005 are combined with the models to obtain broadband solar radiation at the surface. PAR and UVB underwater irradiance are estimated from the attenuation coefficients Kd derived from the Sea WiFS instrument for the period of 1998-2005. In developing algorithms, a look-up table (LUT), which contains senes of broadband surface solar radiation and the Earth-atmosphere reflectivity, is created from the Streamer radiative transfer model. The broadband Earth-atmosphere reflectivity a lla derived from the GMS data is used to estimate the surface solar radiation from the LUT algorithms. The attenuation coefficients Kd for PAR, UVB and Sea WiFS wavebands are obtained from Monte Carlo models, and relationships between these Kd values are derived as a result. Using Sea WiFS-derived Kd data, PAR and UVB underwater irradiance are estimated across the regions from the Kd relationships. Comparisons between the satellite-derived surface solar radiation and the measurements at Rockhampton and Cairns give good agreement with root-mean-square 111

difference (RMSD) of 2.26 MJ-m- 2 -day" 1 and 2.85 MJ-m- 2 -day" 1, respectively. The Sea WiFS-derived Kd at six different wavebands obtained from Monte Carlo models are compared to the measurements at Heron Island, with a smallest RMSD value of 0.075 -I m. Maps of solar radiation both above and below the water surface are provided for the study area. On average, strong solar radiation is exhibited in summer and autumn periods at latitude bands between 18 S and 26 S. The temporal information suggests there is a small increase in solar radiation of about 1 percent per decade. The underwater PAR and UVB irradiances along the GBR coastline at 2.5 m depth were in magnitude of ~300 W-m- 2 and ~120 mw-m- 2, respectively. Monthly distribution at 2.5 m depth underwater for PAR shows an outstanding feature throughout between September and February. There are patterns of high PAR irradiance throughout the summer months of 2001/2002 and 2002/2003. Results of the satellite-derived solar radiation are used to examine the 2002 coral bleaching events. A correlation between maximum solar radiation and the bleaching data are seen in summer months of 2001/2002. iv

Acknowledgements The completion of this thesis would not be possible without valuable guidance and support from my supervisors, Dr. Manuel Nunez and Dr. Kelvin Michael. I would like to thank both of them. Without these two people, I could not have overcome so many difficult tasks that I encountered during this study. Thanks to my fellow student, Evan Weller, for all the discussions that we had during my study. Also, the investigation involving the SST data would not have been completed without his help. Thanks to Cameron Veal who contributed to the underwater solar irradiances at Heron Island. Sincere thanks go to Dr. Peter Gies, who provided me the UVB measurement data, which were used for model validation. I am most grateful to Dr. Carol Freeman for reviewing my thesis, also providing such very useful advice about writing to me, thank you. Finally, I would like to thank my family and friends for their encouragement and care. Their continued support was a driving force pushing me to arrive at this success. v

Contents Abstract Acknowledgements 1 Introduction iii v 1 1.1 Aims of the study 0 0 0 0 0 0 0 0 0 0 0. 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0. 0 0 0 0...... 3 102 Thesis structure 0. 0. 0 0 0 0. 0 0 0 0. 0 0 0 0 0 0 0 0 0 0. 0 0. 0... 4 2 Background theory 5 2.1 Solar radiation... 0... 0 0 0. 0 0... 0 0. 0. 0.. 0. 5 201.1 Spectral distribution of solar radiation 0. 0 0 0 0 0 0 0 0 0 0. 0 0. 5 20102 Ultraviolet radiation and PAR 0 0 0 0 00 0 0 0 0 0 0. 0 0 0 0 0 0 0... 6 20103 Solar and longwave infrared Radiation 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0.. 09 202 Solar radiation at the top of atmosphere and solar constant 0 0. 0 10 203 Solar radiation at the ground. 0 0 00.. 0 0. 0 0.. 0 0. 0 0 0 0.. 0 0 12 20301 The atmosphere. 0. 00. 0 00 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0. 0 0 0 0. 0 0 0 0 12 20302 Attenuation of solar irradiance in the atmosphere. 0 0 0 0. 0 0 0 0 0 0 0 0 12 20303 Solar radiation at the Earth surface and its transmission. 0 0 0.. 0 0 0 0 13 2.4 The description of radiative transfer theory 0 0. 0 0. 0. 0. 0 0 0 0 0 0 0 00.. 15 205 Solar radiation in the water body 0 0. 0 0 0 0 0 0 0 0. 0 0 0. 0 0 0. 19 2.5ol Boundary condition of solar radiation in water bodies 0 0 0 0 0 0 0 0 0 0 19 20501.1 Refraction and Reflection at air-water interface 0 0 0. 00 0 0 0 19 2.501.2 Effect of shallow bottom 0 0. 0 0 0 0 0 0.. 0. 00. 0 23 20501.3 Optical property of water 0 00 0. 0 0 0 0 0 0 0 0.. 0 0.... 24 20502 Underwater radiation field... 0 0... 00 0 0 0 0 0 0 0 0.. 0.. 0. 27 205.201 Monte Carlo Method 00 0 0. 0 0 0 0. 0 0. 0. 0. 0... 28 2050202 Monte Carlo approximation based on measurements. 0.. 00 030 Vl

2.5.2.3 Other numerical models.... 31 a) Discrete-ordinate radiative transfer method.... 31 b) N-stream approximation... 32 c) Hydrolight.... 33 3 Literature review 35 3.1 Cloud algorithms... 37 3.2 Statistical models... 38 3.3 Physical models... 46 3.4 Conclusions for solar radiation mapping from satellites................... 62 3.5 Previous studies on underwater solar radiation... 63 3.5.1 Studies based on surface measurements... 65 3.5.2 Previous studies based on remote sensing algorithms... 68 3.5.3 Need for further development... 71 4 Methodology 72 4.1 Study area... 72 4.1.1 Morphology... 74 4.1.2 Cli1nate... 74 4.1.3 Current... 76 4.2 In situ measurements... 76 4.2.1 Measurements of surface broadband solar radiation... 76 4.2.2 Measurements of surface UVB irradiance... 77 4.2.3 Measurements of underwater PAR and spectral UV irradiances... 79 4.3 Method for estimating solar radiation at the surface... 85 4.3.1 Satellite Data... 85 Vll

4.3.2 Relationship between satellite and broadband reflectivity... 92 4.3.3 Cloud fraction... 93 4.3.4 Ozone data... 94 4.3.5 Model for estimating surface broadband solar radiation... 96 4.3.5.1 Creating a Look-up Table.... 97 4.3.5.2 LUT algorithm...... 100 4.3.6 Method for estimating UVB irradiance at the surface... 102 4. 3. 7 Method for estimating PAR irradiance at the surface... 103 4.4 Method for estimating underwater UVB and PAR irradiances............. 104 4.4.1 Sea WiFS data... 104 4.4.2 Ocean surface albedo... 110 4.4.3 Model for estimating UVB and PAR underwater irradiances... 112 4.4.3.1 Monte Carlo based empirical models... 114 4.4.3.2 Method for deriving the linear relationships of Kd between P ARIUVB and Sea WiFS regions..................... 119 5 Validation 124 5.1 Validation of satellite-derived broadband surface solar radiation........... 124 5.2 Validation of satellite-derived surface UVB irradiance... 127 5.3 Validation of satellite-derived underwater solar irradiance... 128 6 Results 135 6.1 Statistics of surface broadband solar radiation... 135 6.1.1 Long-term averages and seasonal variations... 135 6.1.2 Maximum exposure of daily solar radiation... 138 6.1.3 Yearly averages and long-term trends of daily solar radiation... 140 Vlll

6.1.3.1 Yearly averages... 140 6.1.3.2 Long-term trends... 142 6.1.4 Frequency distribution of daily solar radiation.......... 144 6.2 Surface broadband solar radiation at Heron Island...................... 146 6.2.1 Diurnal variation of hourly solar radiation... 146 6.2.2 Monthly variation of daily solar radiation... 150 6.3 Profile ofpar and UVB underwater irradiance... 153 6.3.1 Vertical distribution ofpar and UVB underwater... 153 6.3.2 Long-term monthly average ofpar irradiance at the 2.5 m depth... 155 6.3.3 Variation ofpar irradiance at 2.5 m during summer periods... 157 6.3.4 Long-term monthly average ofuvb irradiance at the 2.5 m depth... 159 6.3.5 Variation ofuvb irradiance during summer periods... 161 6.3.6 Distribution ofuvb and PAR across the lagoon... 162 6.3.7 Monthly averages ofuvb and PAR at 2.5 m depth: implications for 22 S, 152 E... 163 6.4 Discussion... 167 7 Solar radiation during coral bleaching events 170 7.1 Climatology of solar radiation during the 2002 coral bleaching event... 171 7.2 The anomaly of maximum solar radiation during the 2002 coral bleaching Episode... 177 7.3 Responses of solar radiation and sea surface temperature to coral bleaching.. 179 8 Conclusion 186 References 190 IX

Appendix I GMS Calibration Table... 204 Appendix II Spectral responses of GMS-5 and GOES-9 satellites... 206 Appendix III Look-Up Tables (LUT) and a computer codes to access the values.. 208 Appendix IV SST time series during the 2002 coral bleaching event... 210 X