Atmospheric CO2 Observations

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ATS 760 Global Carbon Cycle Atmospheric CO2 Observations (in-situ) BRW MLO Point Barrow, Alaska Scott Denning CSU ATS Mauna Loa, Hawaii 1

ATS 760 Global Carbon Cycle SPO SMO American Samoa South Pole Interannual Variability Global trend known very accurately Provides an integral constraint on the total carbon budget Interannual variability is of the same order as anthropogenic emissions! Mechanisms are not well understood Scott Denning CSU ATS 2

ATS 760 Global Carbon Cycle Spatial Patterns of Interannual Variability Atmospheric Carbon Observations 1987-88 pulse originated in tropics, propagated to higher latitudes Minima in 1989, 92, 96, 99 mostly in NH Huge pulse in 1998 was global Recent fluctuations driven strongly in NH HIAPER Pole-to-Pole Observations (HIPPO) HIPPO boat: NCAR Gulfstream V "HIAPER" GV launch in the rain, Anchorage, January, 2009 (HIPPO-1) Scott Denning CSU ATS 3

HIAPER Pole-to-Pole Obs The Warm and Cold Conveyor Belts [Bader et al 1995, adapted from Carlson, 1980] Signal? Noise? Which is which? Effects of height-time concentration variation near the ground Cape Grim Usual approach is to exclude spikes as non- background 460 OASIS, Oct 1995, Wagga, NSW Law et al inverted the spikes instead! Mixing Ratio / ppmv 440 420 400 380 360 340 358 ppm 22 m 14 m 8 m 4 m 2 m 1 m 0.5 m 00:00 03:00 06:00 09:00 12:00 15:00 18:00 21:00 24:00 Hour of Day Scott Denning CSU ATS 4

Simulated PBL CO 2 2008 SiB2 coupled to CSU RAMS Nocturnal respiration produces extremely high concentrations in morning stable layer Surface heating and TKE generation causes entrainment of lower-co 2 air from aloft Photosynthesis depletes CO 2 in surface layer Buoyant plumes of low-co 2 air fill the convective boundary layer Corn, as seen from 100 m Nighttime 100 ft. level 400 Summer, 2007 CO2 (ppm) 330 Scott Richardson & Tasha Miles, Penn State Univ Sunset Sunrise May August Scott Denning CSU ATS 5

Transport Advection: Stuff that was upstream moves here with the wind: q q q q = u v w + Source( q) t x y z To predict the future amount of q, we simply need to keep track of gradients and wind speed in each direction What spatial scales are involved? Can we resolve advective transports by turbulent eddies and convective clouds (thunderstorms) in a global model? (No) Synthesis Inversion Procedure ( Divide and Conquer ) 1. Divide carbon fluxes into subsets based on processes, geographic regions, or some combination 1. Spatial patterns of fluxes within regions? 2. Temporal phasing (e.g., seasonal, diurnal, interannual?) 2. Prescribe emissions of unit strength from each basis function as lower boundary forcing to a global tracer transport model 3. Integrate the model for three years ( spin-up ) from initially uniform conditions to obtain equilibrium with sources and sinks 4. Each resulting simulated concentration field shows the influence of the particular emissions pattern 5. Combine these fields to synthesize a concentration field that agrees with observations Forward Transport Step Temperate North America Pattern Fossil Fuel Pattern Discretize emissions into spatial and seasonal basis functions Obtain archived winds from NWP reanalysis, or run a full GCM Advection by resolved winds Specify convective transports: HOW? Responses to Unit Flux from N.A. Some models (e.g., CSU) show stronger gradients near source region Others (e.g., GISS) appear more thoroughly mixed Scott Denning CSU ATS 6

Fossil Fuel Response Functions Some models (e.g., CSIRO) show stronger gradients near source region Others (e.g., UCI) appear more thoroughly mixed Vertical Structure: FF Response Annual mean latitudepressure cross sections show strong sensitivity to vertical mixing Strong vertical gradient in NH Barrier to crossequator transport Reversed vertical gradient in SH Most of NS structure at surface in in NH subtropics Vertical Transport is Crucial Some models treat convection as diffusive mixing between adjacent layers Others treat convection as penetrative updrafts and downdrafts ( express elevators ) Much of the surface structure actually related to vertical mixing Meridional Gradients (Tans et al, 1990) Simulated gradient way too steep for most emission scenarios Scott Denning CSU ATS 7

Scott Denning CSU ATS 8