Application of SuperPower 2G HTS Wire to High Field Devices

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superior performance. powerful technology. Application of SuperPower 2G HTS Wire to High Field Devices Drew W. Hazelton Principal Engineer, SuperPower, Inc. 2011 MT22 Conference Marseille, France Sept. 13, 2011-2CO-3 SuperPower Inc. is a subsidiary of Royal Philips Electronics N.V.

Demands on conductor for high field applications High current density High strength Long lengths High operating currents (particularly for HEP applications) Low ac losses (to enable fast charge/discharge) Persistent current switches / joints (NMR applications) 1

SuperPower 2G HTS architecture 2

SuperPower 2G HTS current density enables high field magnet work Thin cross-section translates into high engineering current density needed for compact high field magnets Improvements in (RE)BCO thickness and advanced pinning drive current density enhancements Hastelloy C276 substrate provides high strength required for high field inserts No additional reinforcement needed in many designs, enhancing current density 3

Improved pinning by Zr doping of MOCVD (RE)BCO layer Systematic study of improved pinning by Zr addition in MOCVD films at UH Process know how transitioned to SuperPower manufacturing 4

Development of nano-defect pinning sources HREM of nanocluster HREM of nanorod Horizontal (Gd,Y) 2 O 3 nano cluster Vertical BZO Nanorod TEM by F. Kametani (TEM) and D. Larbalestier, FSU 5

Ic improvement by pinning extends to higher fields Advances with Zr-doping locked into production 6

Summary of mechanical properties Yield Stress (77K) 970 MPa (140.7 ksi) @ 0.92 % strain Stress Limit (77K) 98% Ic reversibility 90% Ic(zero strain) at limit (slide 3) Modulus Initial (77K, before Cu limit) Final (77K, after Cu limit) Fatigue Limit (77K) 700 MPa (101.5 ksi) @ 0.6 % strain 122.5 GPa 116.7 GPa > 100,000 cycles, <680 MPa tensile SCS4050 with 40 microns copper 7

SuperPower 2G HTS has excellent mechanical strength 77K Stress Limit 700 MPa Strain at Limit ~ 0.6% Superpower 4mm Wide 2G-HTS Tape Stress-Strain Curves at Room Temperature and 77K Tape ID # M3-383-1-BS504-569M 1200 1100 1000 900 77K 800 Stress [MPa] 700 600 500 Room Temperature 0048.RT 0083.RT 0099.RT 400 0180.RT 300 0037.LN 200 0079.LN 100 0021.LN 0 0.0% 0.5% 1.0% 1.5% 2.0% Strain [%] Data from R. Holtz, NRL 8

React/Wind SuperPower 2G HTS conductor has large operating stress-strain window compared to other conductors 800 700 Stress (MPa) 600 500 400 300 200 100 0 SP 2G HTS - High Je "High Strength" 1G HTS - Moderate Je "Low Strength" 1G HTS - Moderate Je 0 0.1 0.2 0.3 0.4 0.5 Strain (%) Nb 3 Sn - Moderate Je 9

Routine manufacturing of Zr-doped tapes in long length initiated 77 K, sf Long tapes with Zr-doping exhibit critical currents of >250 A/cm in tapes run through the manufacturing facility 10

Low resistance joints/splices readily made Copper stabilizer YBCO substrate solder Lap Joint Bridge Joint No degradation in Ic (1 μv/cm) over the joint or splice Splice resistance typically ~ 10 nω (4 mm x 100 mm) No degradation in Ic and resistance when splice is bent over 25 mm diameter and thermal cycled three times. Variety of solders can be used (InAg, SnSb, PbSn) 11

Coil applications: world record performance achieved in HF insert coils with SP 2G HTS wire 2009: 27.4 Tesla at 4.2K in 19.9 Tesla background field (SP) 2008: 33.8 Tesla at 4.2K in 31 Tesla background field (NHMFL) 2007: 26.8 Tesla at 4.2K in 19 Tesla background field (SP) 2006: 2.4 Tesla at 64K in self field (SP) Look for new results from - NHMFL -MIT -BNL 2009 Insert Coil 12

New superconducting magnetic energy storage (SMES) project initiated ARPA-E funded proof of concept project recently awarded ($5.2M/3yr) Project Participants ABB (lead power electronics / system integration) Brookhaven National Laboratory (high field coil design / fabrication) SuperPower (2G HTS / coil design support) Univ. Houston (enhanced 2G HTS fabrication) Storage capability in proof of concept coil (~2.5 MJ / 20 kwh) 25 Tesla coil Enhanced power electronics >80% round trip efficiency 13

Why high field HTS SMES? Energy stored scales as B 2 * r 3, while losses scale as r 2 2G HTS enables high field operation for a compact, high energy density system Toroidal geometry lessens the external magnetic forces, reducing the size of mechanical support needed. Fields in a toroidal SMES are mainly axial (//a,b), maximizing the use of 2G HTS Due to the low external magnetic field, toroidal SMES can be located near a utility or customer load. 14

Challenges High fields equate to high stresses mainly hoop stress << SP 2G HTS can handle up to 700 MPA hoop stress High performance conductor required for economics to be competitive with advanced batteries (need to be in the $50/kAm range) Persistent current joints / switches highly desirable to reach loss targets Long lengths will be required to minimize / eliminate splices / joints (each splice is a loss source) 15

Questions? Thank you for your interest! For further information about SuperPower, please visit us at: www.superpower-inc.com or e-mail: info@superpower-inc.com 16