Pore-Scale Analysis of Dynamics of Two-Phase Flow. in Porous Media

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Pore-Scale Analysis of Dynamics of Two-Phase Flow Multi-Process Pore-scale Modelling in Porous Media Vahid J. Niasar Collaborators: S. Majid Hassanizadeh (Utrecht University) Nikos Karadimitriou (University of Manchester) Helge Dahle (University of Bergen) Mike Celia (Princeton University)

Filling the gaps across scales; pore-scale imaging & modelling courtesy of D. Wildenschild, Oregon State University, USA Scale of practical interest (>m up to km) Scale of phenomena (<mm down to micrometer) Representative Elementary Volume (REV)? courtesy of Shell R&D

Micro-scale imaging and modelling infrastructures at the University of Manchester

Diamond Light Source (DLS) synchrotron i 13 facility DLS is the UK's national synchrotron facility supporting academic and industrial research. A total of 18 beam lines are operational with funding from The University of Manchester supporting access for academic research. The spatial resolution for this technique is in the micron range. it will be possible to switch the instrument to full-field microscopy with 50nm spatial resolution.

X-radia MicroCT/NanoCT Resolution: 5-120 microns Maximum field of view: ~170 mm Sample sizes: 5mm - 170mm, max load 15 kg Energy range: 225 kv Typical scan time: 30-120 mins Resolution: 150 nm or 50 nm Maximum field of view: 65 microns or 15 microns Maximum sample size: 0.5 kg Maximum Energy: 8 kv

Two-phase flow micromodels lab (Reservoir on Chip) - Karadimitriou, N.K., Joekar-Niasar, V., et al (2012), Lab on a Chip. - Karadimitriou, N., Musterd, M., Kleingeld, P., Kreutzer, M., Hassanizadeh, M., Joekar-Niasar, V. (2012),Water Resources Research

Multi-Process pore-scale modelling Fundamentals of Porous Media: I) Pore-scale two-phase flow simulator; drainage, imbibition, capillary pressure, relperm simulator [WRR (2013), 4244 4256. WRR (2010), W06526., Journal of Fluid Mechanics (2010)655:38-71, Vadose Zone Journal (2012), 11(3); TiPM (2008) 74:201-219, TiPM (2012) 94:465-486]. II) Solute transport module [Comp Geo (2014), 1-23] III) Electro-kinetic flow module and wettability alteration [Comp Geo (2013), 497-513, SPE Journal (2015)20 (01), 8-20]. IV) Particle tracking PetEng Applications: LowSal, Fine migration control, EOR

Today Dynamics of two-phase flow Understanding the fundamentals of constitutive equations of Darcy s extended equations. Understanding physics of two-phase flow in porous media Providing physically-based simulation support for theoretical studies Improving predictive capability and characteristic curves of porous media (e.g. relative permeability, capillary pressure-saturation) The immiscibles: Capillarity effects in porous media - pore-network modelling, ISBN: 978-90-5744-179-0

Motivation: Standard Two-Phase Flow Darcy s Law q α :flow rate for phase α S α :saturation of phase α μ α :viscosity of phase α n: porosity K: absolute permeability P α : pressure of phase α P c : capillary pressure k rα : relative permeability of phase α

Motivation: Extended theories of two-phase flow Hassanizadeh and Gray, WRR, 1993,1998

Pore-network modelling

Major advantages of pore-scale modelling courtesy of D. Wildenschild courtesy of O. Vizika

Conceptual model : definitions Coordination number: number of connections in a pore body Pore body: large pores in the connection points (nodes) Pore throat: long narrow pores connecting the pore bodies

Pore-network modelling Step 1: defining the geometries and the network Step 3: solving a system of equations in a network of inter-connected capillaries Step 2: deriving the analytical pore-scale equations

Quasti-static vs. dynamic PNMs Computationally expensive. Pressure field is solved. Network and fluids properties are important. Not been used as extensively as quasi-static ones; P c -S w, k r -S w,s w -a nw, mobilization of disconnected phase, dynamic pressure field Weak tractability due to nonlinearities at pore scale Computationally very cheap. No pressure field is solved. Pore-scale geometry and topology are only important. Used extensively, for two-phase and three-phase flow; P c -S w, k r -S w, S w -a nw, reactive transport, etc.. as a predictive tool

Dynamic pore-network modeling Previous DPNMs One-pressure solver Simplified physics Inconsistency in fluid configuration versus quasi-static models K ( µ ) n K ( µ ) w n w Equivalent Resistor K = f( K, K ) eff w n Previous DPNMs One-pressure solver Detailed physics Computationally more expensive. K ( µ ) K ( µ ) We gain: Co-current and counter-current flow Piston-like movement vs. snapoff Interface dynamics & Ganglia dynamics n w n w

Quasi-static vs. Dynamic PNMs

Governing equations

Governing equations:pressure field Introducing ¹P i = S w i P w i + S n i P n i We can write: XN i [(K i w j + K i n j )( P ¹ i Pj ¹ )+ j = 1 (K i n j Si w K i w j (1 Si w ))Pi c + (K w i j (1 S w j ) K n i j S w j )P c j ] = 0 Joekar-Niasar, JFM, 2010

Governing equations: saturation update we can write saturation update in a semi-implicit way; as the summation of an advective term and a diffusive term: (Si w ) k+ 1 (Si w ) k V i t P N i j = 1 K n i j K t ot i j Q tot i j + K w i j K n i j K t ot i j @P c i j @S w i j (S w i ) k+ 1 (S w j ) k+ 1 = 0 Joekar-Niasar, JFM, 2010

Local rules P c i = 2¾ nw i Local P c i S w i curve for a pore body: drainage i = 8 < : ( 1 1 r i j ³ 1 S w i S dr i R i )( Sw i ) 3:5 + 1 1 S i dr R i Si w Si dr a ; a = 1 i < Si w < Si dr Local P c i S w i curve for a pore body: imbibition R i Si dr S mi n 2:98Si dr 3:85 i = 8 < : ³ 1 R i 1 1 r i j ³ S w i Si dr ³ S i m b i R i S i dr a ; a = 1 a ³ S w i S i m b i 1 S i m b i 3:5 + 1 R i ³ S i m b i S dr i S mi n 2:98Si dr 3:85 i < Si w < Si i mb a S w i S i mb i

Features of the new formulation II.TWO-PHASE FLOW Fully consistency between quasi-static and dynamic model Numerically stable under a very wide range of capillary number and viscosity ratio Major pore-scale mechanisms included: o Pinston-like invasion o Snap-off o Trapping o Capillary interface dynamics o Mobilization of the disconnected phase Joekar Niasar et al,jfm (2010)

Equilibrium: micromodels simulations vs. experiments Air-water interface [Liu et al Lab Chip, 2012]] -Joekar-Niasar, V., Hassanizadeh, S. M. (2011), International Journal of Multiphase Flow -Joekar-Niasar, V., Hassanizadeh, S.M. (2011), WRR -Joekar-Niasar, V., Hassanizadeh, S.M. (2012), Transport in Porous Media Joekar-Niasar et al, WRR, 2009

Equilibrium: glassbeads simulations vs. experiments An irregular unstrucutred network with hyperbolic polygonal cross sections. Joekar-Niasar et al, WRR, 2010

On hysteresis of P c -S function Capillary pressure-saturation data points measured in laboratory (Morrow and Harris, 1965)

On hysteresis of P c -S function Reeves and Celia1996,Held and Celia 2001, Joekar-Niasar et al, TiPM, 2008, WRR,2009, 2010

Non-equilibrium: flow regime -Joekar-Niasar, V., Hassanizadeh, S. M. (2011), International Journal of Multiphase Flow, 37: 198-214. -Joekar-Niasar, V., Hassanizadeh, S.M. (2011), Water Resources Research, 47, W05513. -Joekar-Niasar, V., Hassanizadeh, S.M. (2012), Transport in Porous Media, doi: 10.1007/s11242-012-9958-3.

Close-to-equilibrium phase pressure difference vs. capillary pressure Joekar-Niasar, Hassanizadeh, Dahle, JFM, 2010

Non-equilibrium phase pressure versus capillary pressure (PCE-Water column experiments) Hassanizadeh, Oung, Mohanty,2004

Non-equilibrium phase pressure versus capillary pressure PP nn PP ww = PP cc ττ ddssww dddd Joekar-Niasar, Hassanizadeh, Dahle, JFM, 2010

Dynamic effect on capillary pressure Joekar-Niasar, Hassanizadeh, Dahle, JFM, 2010

Discussion Flexibilities Physically-based approach to integrate the pore-scale information. Pore space definition is not resolution-dependent. Application to many static and dynamic multi processes. Compared to other pore-scale simulators, computationally cheaper. Post-processing straight forward. Capability to provide up-scaled information. Challenges and limitations: Pre-processing:Idealization of void space topology and geometry is an inevitable nonunique solution. It is not always straight forward!. Processing: a) No detail information within a discrete pore (e.g. pressure field in a pore). b) local rules are important and need to be supported by high resolution singlepore CFD.

Discussion Compared to other pore-scale modelling techniques, porenetwork modelling can still provide more flexibility in tractability and decoupling of processes. There is a huge potential in further development of hybrid pore-scale models. Pore-scale modelling provides valuable insights into physics of porous media phenomena, such as multiphase flow, mixing. Multi-process pore-scale modelling is an important tool for EOR applications.. Investment in benchmarking of various pore-scale models is yet to be done.

Thanks for your attention!

Low salinity effect; wettability alteration

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