Thermodynamics. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
|
|
- Annabella Andrews
- 5 years ago
- Views:
Transcription
1 Thermodynamics Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
2 Thermodynamics is the scientific study of the interconversion of heat and other kinds of energy. The system is the specific part of the universe that is of interest in the study. open closed isolated Exchange: mass & energy energy nothing 2
3 Energy is the capacity to do work. Radiant energy comes from the sun and is earth s primary energy source Thermal energy is the energy associated with the random motion of atoms and molecules Chemical energy is the energy stored within the bonds of chemical substances Nuclear energy is the energy stored within the collection of neutrons and protons in the atom Potential energy is the energy available by virtue of an object s position 3
4 Energy Changes in Chemical Reactions Heat is the transfer of thermal energy between two bodies that are at different temperatures. Temperature is a measure of the thermal energy. Temperature = Thermal Energy 4
5 Exothermic process is any process that gives off heat transfers thermal energy from the system to the surroundings. 2H 2 (g) + O 2 (g) 2H 2 O(l) + energy H 2 O(g) H 2 O(l) + energy Endothermic process is any process in which heat has to be supplied to the system from the surroundings. energy + 2HgO(s) energy + H 2 O(s) 2Hg(l) + O 2 (g) H 2 O(l) 5
6 Thermochemistry is the study of heat change in chemical reactions. State functions are properties that are determined by the state of the system, regardless of how that condition was achieved. energy, pressure, volume, temperature ΔU = U final - U initial ΔP = P final - P initial ΔV = V final - V initial ΔT = T final - T initial Potential energy of hiker 1 and hiker 2 is the same even though they took different paths. 6
7 First law of thermodynamics energy can be converted from one form to another, but cannot be created or destroyed. ΔU system + ΔU surroundings = 0 or ΔU system = -ΔU surroundings C 3 H 8 + 5O 2 3CO 2 + 4H 2 O Exothermic chemical reaction! Chemical energy lost by combustion = Energy gained by the surroundings 7 system surroundings
8 Another form of the first law for ΔU system ΔU = q + w ΔU is the change in internal energy of a system q is the heat exchange between the system and the surroundings w is the work done on (or by) the system w = -PΔV when a gas expands against a constant external pressure 8
9 w = F x d Work Done On the System w = -P ΔV P x V = F d 2 x d 3 = F x d = w ΔV > 0 -PΔV < 0 w sys < 0 Work is not a state function. Δw = w final - w initial initial final 9
10 A sample of nitrogen gas expands in volume from 1.6 L to 5.4 L at constant temperature. What is the work done in joules if the gas expands (a) against a vacuum and (b) against a constant pressure of 3.7 atm? w = -PΔV (a) ΔV = 5.4 L 1.6 L = 3.8 L P = 0 atm W = -0 atm x 3.8 L = 0 L atm = 0 joules (b) ΔV = 5.4 L 1.6 L = 3.8 L P = 3.7 atm w = -3.7 atm x 3.8 L = L atm w = L atm x J 1L atm = J 10
11 Enthalpy and the First Law of Thermodynamics ΔU = q + w At constant pressure: q = ΔH and w = -PΔV ΔE = ΔH - PΔV ΔH = ΔU + PΔV 11
12 Enthalpy (H) is used to quantify the heat flow into or out of a system in a process that occurs at constant pressure. ΔH = H (products) H (reactants) ΔH = heat given off or absorbed during a reaction at constant pressure H products > H reactants ΔH > 0 H products < H reactants ΔH < 0 12
13 Thermochemical Equations Is ΔH negative or positive? System absorbs heat Endothermic ΔH > kj are absorbed for every 1 mole of ice that melts at 0 0 C and 1 atm. H 2 O(s) H 2 O(l) ΔH = 6.01 kj/mol 13
14 Thermochemical Equations Is ΔH negative or positive? System gives off heat Exothermic ΔH < kj are released for every 1 mole of methane that is combusted at 25 0 C and 1 atm. CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O(l) ΔH = kj/mol 14
15 Thermochemical Equations The stoichiometric coefficients always refer to the number of moles of a substance H 2 O(s) H 2 O(l) ΔH = 6.01 kj/mol If you reverse a reaction, the sign of ΔH changes H 2 O(l) H 2 O(s) ΔH = kj/mol If you multiply both sides of the equation by a factor n, then ΔH must change by the same factor n. 2H 2 O(s) 2H 2 O(l) ΔH = 2 x 6.01 = 12.0 kj 15
16 Thermochemical Equations The physical states of all reactants and products must be specified in thermochemical equations. H 2 O(s) H 2 O(l) ΔH = 6.01 kj/mol H 2 O(l) H 2 O(g) ΔH = 44.0 kj/mol How much heat is evolved when 266 g of white phosphorus (P 4 ) burn in air? P 4 (s) + 5O 2 (g) P 4 O 10 (s) ΔH = kj/mol 266 g P 4 x 1 mol P g P 4 x 3013 kj 1 mol P 4 = 6470 kj 16
17 A Comparison of ΔH and ΔU 2Na(s) + 2H 2 O(l) ΔU = ΔH - PΔV 2NaOH(aq) + H 2 (g) ΔH = kj/mol At 25 C, 1 mole H 2 = 24.5 L at 1 atm PΔV = 1 atm x 24.5 L = 2.5 kj ΔU = kj/mol 2.5 kj/mol = kj/mol 17
18 The specific heat (s) of a substance is the amount of heat (q) required to raise the temperature of one gram of the substance by one degree Celsius. The heat capacity (C) of a substance is the amount of heat (q) required to raise the temperature of a given quantity (m) of the substance by one degree Celsius. C = m x s Heat (q) absorbed or released: q = m x s x Δt q = C x Δt Δt = t final - t initial 18
19 How much heat is given off when an 869 g iron bar cools from 94 o C to 5 o C? s of Fe = J/g C Δt = t final t initial = 5 C 94 C = -89 C q = msδt = 869 g x J/g C x 89 C = -34,000 J 19
20 Constant-Volume Calorimetry q sys = q water + q bomb + q rxn q sys = 0 q rxn = - (q water + q bomb ) q water = m x s x Δt q bomb = C bomb x Δt Reaction at Constant V ΔH = q rxn No heat enters or leaves! ΔH ~ q rxn 20
21 Constant-Pressure Calorimetry q sys = q water + q cal + q rxn q sys = 0 q rxn = - (q water + q cal ) q water = m x s x Δt q cal = C cal x Δt Reaction at Constant P ΔH = q rxn No heat enters or leaves! 21
22 22
23 Because there is no way to measure the absolute value of the enthalpy of a substance, must I measure the enthalpy change for every reaction of interest? Establish an arbitrary scale with the standard enthalpy of formation (ΔH f ) as a reference point for all enthalpy expressions. Standard enthalpy of formation (ΔH f ) is the heat change that results when one mole of a compound is formed from its elements at a pressure of 1 atm. The standard enthalpy of formation of any element in its most stable form is zero. ΔH ΔH f (C, graphite) = 0 f (O 2 ) = 0 ΔH (O 3 ) = 142 kj/mol f ΔH (C, diamond) = 1.90 kj/mol f 23
24 24
25 The standard enthalpy of reaction (ΔH a reaction carried out at 1 atm. rxn ) is the enthalpy of aa + bb cc + dd ΔH rxn = [ cδh f (C) + dδh (D)] - [ aδh f (A) + bδh f (B) ] ΔH rxn f = Σ nδh f (products) - Σ mδh f (reactants) Hess s Law: When reactants are converted to products, the change in enthalpy is the same whether the reaction takes place in one step or in a series of steps. (Enthalpy is a state function. It doesn t matter how you get there, only where you start and end.) 25
26 C (graphite) + 1/2O 2 (g) CO(g) + 1/2O 2 (g) C (graphite) + O 2 (g) CO 2 (g) CO(g) CO 2 (g) 26
27 Calculate the standard enthalpy of formation of CS 2 (l) given that: C(graphite) + O 2 (g) CO 2 (g) ΔH rxn = kj/mol S(rhombic) + O 2 (g) SO 2 (g) ΔH rxn = kj/mol CS 2 (l) + 3O 2 (g) CO 2 (g) + 2SO 2 (g) ΔH = kj/mol rxn 1. Write the enthalpy of formation reaction for CS 2 C(graphite) + 2S(rhombic) CS 2 (l) 2. Add the given rxns so that the result is the desired rxn. + C(graphite) + O 2 (g) CO 2 (g) ΔH rxn = kj/mol 2S(rhombic) + 2O 2 (g) 2SO 2 (g) ΔH rxn = kj/mol x 2 CO 2 (g) + 2SO 2 (g) CS 2 (l) + 3O 2 (g) ΔH = kj/mol rxn CS 2 (l) ΔH = (2x-296.1) = 86.3 kj/mol rxn C(graphite) + 2S(rhombic) 27
28 Benzene (C 6 H 6 ) burns in air to produce carbon dioxide and liquid water. How much heat is released per mole of benzene combusted? The standard enthalpy of formation of benzene is kj/mol. 2C 6 H 6 (l) + 15O 2 (g) 12CO 2 (g) + 6H 2 O (l) ΔH rxn = Σ nδh f (products) - Σ mδh (reactants) ΔH rxn = [ 12ΔH (CO 6ΔH 2 ) + (H 2 O) ] - [ 2ΔH (C 6 H 6 )] f ΔH rxn = [ 12x x ] [ 2x49.04 ] = kj f f f kj 2 mol = kj/mol C 6 H 6 28
Exothermic process is any process that gives off heat transfers thermal energy from the system to the surroundings. H 2 O (l) + energy
Exothermic process is any process that gives off heat transfers thermal energy from the system to the surroundings. H 2 O (g) H 2 O (l) + energy Endothermic process is any process in which heat has to
More informationThermochemistry-Part 1
Brad Collins Thermochemistry-Part 1 Chapter 7 Thermochemistry Thermodynamics: The study of energy Thermochemistry: The study of energy in chemical reactions Energy: The capacity to do work Work = force
More informationThermochemistry. Chapter 6. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Thermochemistry Chapter 6 Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Energy is the capacity to do work. Radiant energy comes from the sun and is earth s
More informationTopic 05 Energetics : Heat Change. IB Chemistry T05D01
Topic 05 Energetics 5.1-5.2: Heat Change IB Chemistry T05D01 5.1 Exothermic and endothermic reactions - 1 hour 5.1.1 Define the terms exothermic reaction, endothermic reaction and standard enthalpy change
More informationChapter 5. Thermochemistry
Chapter 5 Thermochemistry Dr. A. Al-Saadi 1 Preview Introduction to thermochemistry: Potential energy and kinetic energy. Chemical energy. Internal energy, work and heat. Exothermic vs. endothermic reactions.
More informationChapter 8. Thermochemistry 강의개요. 8.1 Principles of Heat Flow. 2) Magnitude of Heat Flow. 1) State Properties. Basic concepts : study of heat flow
강의개요 Basic concepts : study of heat flow Chapter 8 Thermochemistry Calorimetry : experimental measurement of the magnitude and direction of heat flow Thermochemical Equations Copyright 2005 연세대학교이학계열일반화학및실험
More informationThermochemistry. Energy. 1st Law of Thermodynamics. Enthalpy / Calorimetry. Enthalpy of Formation
THERMOCHEMISTRY Thermochemistry Energy 1st Law of Thermodynamics Enthalpy / Calorimetry Hess' Law Enthalpy of Formation The Nature of Energy Kinetic Energy and Potential Energy Kinetic energy is the energy
More informationChapter 5 Thermochemistry
Chapter 5 Thermochemistry Learning Outcomes: Interconvert energy units Distinguish between the system and the surroundings in thermodynamics Calculate internal energy from heat and work and state sign
More informationThermochemistry Chapter 4
Thermochemistry Chapter 4 Thermochemistry is the study of energy changes that occur during chemical reactions Focus is on heat and matter transfer between the system and the surroundings Energy The ability
More informationChapter 8. Thermochemistry
Chapter 8 Thermochemistry Copyright 2001 by Harcourt, Inc. All rights reserved. Requests for permission to make copies of any part of the work should be mailed to the following address: Permissions Department,
More informationThermochemistry is the study of the relationships between chemical reactions and energy changes involving heat.
CHEM134- F18 Dr. Al- Qaisi Chapter 06: Thermodynamics Thermochemistry is the study of the relationships between chemical reactions and energy changes involving heat. Energy is anything that has the capacity
More information33. a. Heat is absorbed from the water (it gets colder) as KBr dissolves, so this is an endothermic process.
31. This is an endothermic reaction so heat must be absorbed in order to convert reactants into products. The high temperature environment of internal combustion engines provides the heat. 33. a. Heat
More informationmeasure ΔT in water to get q = q surroundings and use q system = q surroundings
example using water: Calculate the amount of energy required to heat 95.0 g of water from 22.5 C to 95.5 C. q = s m ΔT ( C (4.184 J g 1 C 1 ) (95.0 g) (73.0 = = 2.90 x 10 4 J or 29.0 kj Constant Pressure
More informationChapter 6. Thermochemistry
Chapter 6 Thermochemistry Section 5.6 The Kinetic Molecular Theory of Gases http://www.scuc.txed.net/webpages/dmackey/files /chap06notes.pdf ..\..\..\..\..\..\Videos\AP Videos\Thermochemistry\AP
More informationCHEM 1105 S10 March 11 & 14, 2014
CHEM 1105 S10 March 11 & 14, 2014 Today s topics: Thermochemistry (Chapter 6) Basic definitions Calorimetry Enthalpy Thermochemical equations Calculating heats of reaction Hess s Law Energy and Heat Some
More informationThe Nature of Energy. Chapter Six: Kinetic vs. Potential Energy. Energy and Work. Temperature vs. Heat
The Nature of Energy Chapter Six: THERMOCHEMISTRY Thermodynamics is the study of energy and its transformations. Thermochemistry is the study of the relationship between chemical reactions and energy changes
More information10/1/ st Law of Thermodynamics (Law of Conservation of Energy) & Hess s Law. Learning Targets
1 st Law of Thermodynamics (Law of Conservation of Energy) & Hess s Law 1 Learning Targets LT 5.02: I can relate temperature to the motions of particles and average kinetic energy. LT 5.03: I can generate
More informationChapter 5 - Thermochemistry
Chapter 5 - Thermochemistry Study of energy changes that accompany chemical rx s. I) Nature of Energy Energy / Capacity to do work Mechanical Work w = F x d Heat energy - energy used to cause the temperature
More informationChapter 3. Thermochemistry: Energy Flow and Chemical Change. 5.1 Forms of Energy and Their Interconversion
Chapter 3 Thermochemistry: Energy Flow and Chemical Change 5.1 Forms of Energy and Their Interconversion 5.2 Enthalpy: Chemical Change at Constant Pressure 5.3 Calorimetry: Measuring the Heat of a Chemical
More informationThermodynamics - Energy Relationships in Chemical Reactions:
Thermodynamics - Energy Relationships in Chemical Reactions: energy - The capacity to do work. Types of Energy: radiant-energy from the sun. potential-energy due to an objects position. chemical-energy
More informationTypes of Energy Calorimetry q = mc T Thermochemical Equations Hess s Law Spontaneity, Entropy, Gibb s Free energy
Unit 7: Energy Outline Types of Energy Calorimetry q = mc T Thermochemical Equations Hess s Law Spontaneity, Entropy, Gibb s Free energy Energy Energy is the ability to do work or produce heat. The energy
More informationName Date Class THE FLOW OF ENERGY HEAT AND WORK
17.1 THE FLOW OF ENERGY HEAT AND WORK Section Review Objectives Explain the relationship between energy, heat, and work Distinguish between exothermic and endothermic processes Distinguish between heat
More informationChapter 6. Thermochemistry: Energy Flow and Chemical Change
Chapter 6 Thermochemistry: Energy Flow and Chemical Change Thermochemistry involves the monitoring of energy transformations that occur with a chemical reaction. CH4(g) + 2 O2 ==> CO2 + 2 H2O + HEAT Reaction
More informationChapter 5 Thermochemistry. 許富銀 ( Hsu Fu-Yin)
Chapter 5 Thermochemistry 許富銀 ( Hsu Fu-Yin) 1 Thermodynamics The study of energy and its transformations is known as thermodynamics The relationships between chemical reactions and energy changes that
More informationThermochemistry: Part of Thermodynamics
Thermochemistry: Part of Thermodynamics Dr. Vickie M. Williamson @vmwilliamson Student Version 1 Chemical Thermodynamics! Thermodynamics: study of the energy changes associated with physical and chemical
More informationChemistry Chapter 16. Reaction Energy
Chemistry Reaction Energy Section 16.1.I Thermochemistry Objectives Define temperature and state the units in which it is measured. Define heat and state its units. Perform specific-heat calculations.
More informationThermochemistry: Heat and Chemical Change
Thermochemistry: Heat and Chemical Change 1 Heat or Thermal Energy (q) Heat is a form of energy Is heat the same as temperature? Heat flows between two objects at different temperatures. Hot Cold 2 Chemical
More informationChapter 6: Thermochemistry
Chapter 6: Thermochemistry 1. Light the Furnace: The Nature of Energy and Its Transformations a. Thermochemistry is the study of the relationships between chemistry and energy i. This means that we will
More informationLearning Check. How much heat, q, is required to raise the temperature of 1000 kg of iron and 1000 kg of water from 25 C to 75 C?
Learning Check q = c * m * ΔT How much heat, q, is required to raise the temperature of 1000 kg of iron and 1000 kg of water from 25 C to 75 C? (c water =4.184 J/ C g, c iron =0.450 J/ C g) q Fe = 0.450
More informationLecture Presentation. Chapter 6. Thermochemistry. Sherril Soman Grand Valley State University Pearson Education, Inc.
Lecture Presentation Chapter 6 Thermochemistry Sherril Soman Grand Valley State University Chemical Hand Warmers Most hand warmers work by using the heat released from the slow oxidation of iron 4 Fe(s)
More informationFirst Law of Thermodynamics
Energy Energy: ability to do work or produce heat. Types of energy 1) Potential energy - energy possessed by objects due to position or arrangement of particles. Forms of potential energy - electrical,
More informationChapter 5 Thermochemistry
Chapter 5 Thermochemistry Section 17.1 The Flow of Energy Heat and Work OBJECTIVES: Explain how energy, heat, and work are related. 2 Section 17.1 The Flow of Energy Heat and Work OBJECTIVES: Classify
More informationStudy Guide Chapter 5
Directions: Answer the following 1. When writing a complete ionic equation, a. what types of substances should be shown as dissociated/ionized? soluble ionic compounds, acids, bases b. What types of substances
More informationEnergy Relationships in Chemical Reactions
Energy Relationships in Chemical Reactions What is heat? What is a state function? What is enthalpy? Is enthalpy a state function? What does this mean? How can we calculate this? How are the methods the
More informationLaw of conservation of energy: energy cannot be created or destroyed, only transferred One object to another One type of energy to another
ch6blank Page 1 Chapter 6: Thermochemistry Thermochemistry: study of the relationships between chemistry and energy Energy: capacity to do work Work:result of a force acting over a certain distance, one
More informationEnergy and Chemical Change
Energy and Chemical Change Section 16.1 Energy In your textbook, read about the nature of energy. In the space at the left, write true if the statement is true; if the statement is false, change the italicized
More informationSection 9: Thermodynamics and Energy
Section 9: Thermodynamics and Energy The following maps the videos in this section to the Texas Essential Knowledge and Skills for Science TAC 112.35(c). 9.01 Law of Conservation of Energy Chemistry (11)(A)
More informationChapter 11. Thermochemistry. 1. Let s begin by previewing the chapter (Page 292). 2. We will partner read Pages
Chapter 11 Thermochemistry 1. Let s begin by previewing the chapter (Page 292). 2. We will partner read Pages 293-94 The Flow of energy - heat Thermochemistry concerned with the heat changes that occur
More informationThermochemistry. Energy and Chemical Change
Thermochemistry Energy and Chemical Change Energy Energy can change for and flow, but it is always conserved. The Nature of Energy Energy the ability to do work or produce heat Potential energy Kinetic
More informationEnergy and Chemical Change
Energy and Chemical Change Section 15.1 Energy In your textbook, read about the nature of energy. In the space at the left, write true if the statement is true; if the statement is false, change the italicized
More informationChapter 6 Energy and Chemical Change. Brady and Senese 5th Edition
Chapter 6 Energy and Chemical Change Brady and Senese 5th Edition Index 6.1 An object has energy if it is capable of doing work 6.2 Internal energy is the total energy of an object s molecules 6.3 Heat
More informationThe Nature of Energy Energy is the ability to do work or produce Heat, q or Q, is ; flows due to temperature differences (always to )
CP Chapter 17 Thermochemistry 2014-2015 Thermochemistry Thermochemistry is the study of energy that occur during chemical and physical changes (changes of state) The Nature of Energy Energy is the ability
More informationThermochemistry: the study of energy (in the from of heat) changes that accompany physical & chemical changes
Thermochemistry Thermochemistry: the study of energy (in the from of heat) changes that accompany physical & chemical changes heat flows from high to low (hot cool) endothermic reactions: absorb energy
More informationChapter 6. Heat Flow
Chapter 6 Thermochemistry Heat Flow Heat (q): energy transferred from body at high T to body at low T Two definitions: System: part of universe we are interested in Surrounding: the rest of the universe
More informationChapter 6 Problems: 9, 19, 24, 25, 26, 27, 31-33, 37, 39, 43, 45, 47, 48, 53, 55, 57, 59, 65, 67, 73, 78-82, 85, 89, 93
Chapter 6 Problems: 9, 19, 24, 25, 26, 27, 31-33, 37, 39, 43, 45, 47, 48, 53, 55, 57, 59, 65, 67, 73, 78-82, 85, 89, 93 Chapter 6 Thermochemistry The study of chemical reactions and the energy changes
More informationMeasuring and Expressing Enthalpy Changes. Copyright Pearson Prentice Hall. Measuring and Expressing Enthalpy Changes. Calorimetry
Measuring and Expressing Enthalpy Changes A burning match releases heat to its surroundings in all directions. How much heat does this exothermic reaction release? You will learn to measure heat flow in
More informationThermochemistry. Energy (and Thermochemistry) World of Chemistry Chapter 10. Energy. Energy
Thermochemistry Thermodynamics is the science of the relationship between heat and other forms of energy. (and Thermochemistry) World of Chemistry Chapter 10 is defined as the ability to do work or produce
More informationFirst Law of Thermodynamics: energy cannot be created or destroyed.
1 CHEMICAL THERMODYNAMICS ANSWERS energy = anything that has the capacity to do work work = force acting over a distance Energy (E) = Work = Force x Distance First Law of Thermodynamics: energy cannot
More informationChapter 6 Thermochemistry
Chapter 6 Thermochemistry Thermochemistry Thermochemistry is a part of Thermodynamics dealing with energy changes associated with physical and chemical reactions Why do we care? - Will a reaction proceed
More informationEnergy, Heat and Chemical Change
Energy, Heat and Chemical Change Chemistry 35 Fall 2000 Thermochemistry A part of Thermodynamics dealing with energy changes associated with physical and chemical reactions Why do we care? -will a reaction
More informationLecture outline: Chapter 5
Lecture outline: Chapter 5 1. The nature of energy Thermochemistryh 2. First law of thermodynamics 3. Enthalpies of reaction 4. Hess law 5. Enthalpies of formation 1 Chemical Reactivity (1) Does a chemical
More information6.5 Hess s Law of Heat Summation. 2 Chapter 6: First Law. Slide 6-2
1/3/11 Thermochemistry: Energy Flow and Chemical Change Chapter 6 6.1 Forms of Energy and Their Interconversion 6.2 Enthalpy: Heats of Reaction and Chemical Change Thermochemistry: Energy Flow and Chemical
More informationChapter 8 Thermochemistry: Chemical Energy. Chemical Thermodynamics
Chapter 8 Thermochemistry: Chemical Energy Chapter 8 1 Chemical Thermodynamics Chemical Thermodynamics is the study of the energetics of a chemical reaction. Thermodynamics deals with the absorption or
More informationChapter 6. Thermochemistry
Chapter 6. Thermochemistry 1 1. Terms to Know: thermodynamics thermochemistry energy kinetic energy potential energy heat heat vs. temperature work work of expanding gases work of expanding gases under
More informationCh. 17 Thermochemistry
Ch. 17 Thermochemistry 17.1 The Flow of Energy Energy Transformations Thermochemistry: study of energy changes in chemical reactions and changes in state Chemical potential energy: energy stored in bonds
More informationThermochemistry. Energy and Chemical Change
Thermochemistry Energy and Chemical Change Energy Energy can change for and flow, but it is always conserved. The Nature of Energy Energy the ability to do work or produce heat Potential energy Kinetic
More information47 people in recitation yesterday. Expect quizzes there and in class.
Announcements 47 people in recitation yesterday. Expect quizzes there and in class. Chapter 6 Problems: 6.9, 6.11, 6.13(except c), 6.19, 6.23, 6.34, 6.38, 6.42, 6.51, 6.53, 6.54, 6.57, 6.64, 6.66, 6.69,
More informationChapter 6 Thermochemistry 許富銀
Chapter 6 Thermochemistry 許富銀 6.1 Chemical Hand Warmers Thermochemistry: the study of the relationships between chemistry and energy Hand warmers use the oxidation of iron as the exothermic reaction: Nature
More information11B, 11E Temperature and heat are related but not identical.
Thermochemistry Key Terms thermochemistry heat thermochemical equation calorimeter specific heat molar enthalpy of formation temperature enthalpy change enthalpy of combustion joule enthalpy of reaction
More informationChapter 6: Thermochemistry
Chapter 6: Thermochemistry 9/27 Energy is the capacity to do work. Work: force X distance Potential Energy: available by virtue of an object s position Kinetic Energy: energy of motion Radiant Energy:
More informationThermochemistry. Energy. 1st Law of Thermodynamics. Enthalpy / Calorimetry. Enthalpy of Formation
Thermochemistry Energy 1st Law of Thermodynamics Enthalpy / Calorimetry Hess' Law Enthalpy of Formation The Nature of Energy Kinetic Energy and Potential Energy Kinetic energy is the energy of motion:
More informationChapter 5 Principles of Chemical Reactivity: Energy and Chemical Reactions
Chapter 5 Principles of Chemical Reactivity: Energy and Chemical Reactions Jeffrey Mack California State University, Sacramento Energy & Chemistry Questions that need to be addressed: How do we measure
More informationMost hand warmers work by using the heat released from the slow oxidation of iron: The amount your hand temperature rises depends on several factors:
Lecture Presentation Chapter 6 Thermochemistry Chemical Hand Warmers Most hand warmers work by using the heat released from the slow oxidation of iron: Exothermic reaction 4 Fe(s) + 3 O 2 (g) 2 Fe 2 O
More informationENERGY (THERMOCHEMISTRY) Ch 1.5, 6, 9.10, , 13.3
ENERGY (THERMOCHEMISTRY) Ch 1.5, 6, 9.10, 11.5-11.7, 13.3 Thermochemistry Prediction and measurement of energy transfer, in the form of heat, that accompanies chemical and physical processes. Chemical
More informationChapter 6. Thermochemistry
Chapter 6 Thermochemistry This chapter develops for the student the concepts of thermochemistry. Upon completion of Chapter 6, the student should be able to: 1. Define and explain the following terms:
More informationAP* Chapter 6. Thermochemistry
AP* Chapter 6 Thermochemistry Section 6.1 The Nature of Energy Energy Capacity to do work or to produce heat. Law of conservation of energy energy can be converted from one form to another but can be neither
More informationChemical Thermodynamics. Chemical Thermodynamics. Changes of State. Chemical Thermodynamics. State Functions. State Functions 11/25/13
Chemical Thermodynamics n Thermodynamics is the study of the energetics and order of a system. n A system is the thing we want to study it can be a chemical reaction, a solution, an automobile, or the
More informationChapter 6. Thermochemistry. Chapter 6. Chapter 6 Thermochemistry. Chapter 6 Thermochemistry Matter vs Energy 2/16/2016
Chapter 6 Thermochemistry Chapter 6 Chapter 6 Thermochemistry 6.1 Chemical Hand Warmers 6.2 The Nature of Energy: Key Definitions 6.3 The First Law of Thermodynamics: There is no Free Lunch 6.4 6.5 Measuring
More informationChapter 8 Thermochemistry
William L Masterton Cecile N. Hurley http://academic.cengage.com/chemistry/masterton Chapter 8 Thermochemistry Edward J. Neth University of Connecticut Outline 1. Principles of heat flow 2. Measurement
More informationTHERMOCHEMISTRY & DEFINITIONS
THERMOCHEMISTRY & DEFINITIONS Thermochemistry is the study of the study of relationships between chemistry and energy. All chemical changes and many physical changes involve exchange of energy with the
More informationChemistry Slide 1 of 33
Chemistry 17.2 1 of 33 17.2 Measuring and Expressing Enthalpy Changes A burning match releases heat to its surroundings in all directions. How much heat does this exothermic reaction release? You will
More informationCh. 6 Enthalpy Changes
Ch. 6 Enthalpy Changes Energy: The capacity to do work. In Physics, there are 2 main types of energy Kinetic (energy of motion) = ½ mv 2 Potential (energy of position due to gravity)= mgh In Chemistry,
More informationTHERMOCHEMISTRY -1. Dr. Sapna Gupta
THERMOCHEMISTRY -1 Dr. Sapna Gupta THERMODYNAMICS Thermodynamics: Relationship between heat and other forms of energy Thermochemistry: Study of heat absorbed or evolved by chemical reactions. Energy: Capacity
More informationLecture Outline. 5.1 The Nature of Energy. Kinetic Energy and Potential Energy. 1 mv
Chapter 5. Thermochemistry Common Student Misconceptions Students confuse power and energy. Students confuse heat with temperature. Students fail to note that the first law of thermodynamics is the law
More informationThermochemistry 14.notebook. November 24, Thermochemistry. Energy the capacity to do work or produce heat. translational.
Thermochemistry Energy the capacity to do work or produce heat POTENTIAL ENERGY KINETIC ENERGY (energy of motion) "stored" bond energy TEMPERATURE and HEAT vibrational rotational translational a measure
More informationI. The Nature of Energy A. Energy
I. The Nature of Energy A. Energy is the ability to do work or produce heat. It exists in 2 forms: 1. Potential energy is energy due to the composition or position of an object. 2. Kinetic energy is energy
More informationTHERMOCHEMISTRY CHAPTER 11
THERMOCHEMISTRY CHAPTER 11 ENERGY AND HEAT nthermochemistry: The study of the energy changes that accompany chemical reactions and changes in the physical states of matter. ENERGY AND HEAT nwork: Energy
More informationCP Chapter 17 Thermochemistry
CP Chapter 17 Thermochemistry Thermochemistry Thermochemistry is the study of energy that occur during chemical reactions and phase changes (changes of state) The Nature of Energy Energy is the ability
More informationMr Chiasson Advanced Chemistry 12 / Chemistry 12 1 Unit B: Thermochemical Changes
Mr Chiasson Advanced Chemistry 12 / Chemistry 12 1 Unit B: Thermochemical Changes Students will be expected to: Compare the molar enthalpies of several combustion reactions involving organic compounds.
More informationCHEMISTRY. Chapter 5 Thermochemistry
CHEMISTRY The Central Science 8 th Edition Chapter 5 Thermochemistry Dr. Kozet YAPSAKLI The Nature of Energy Kinetic and Potential Energy Potential energy can be converted into kinetic energy. E p = mgh
More information10/23/10. Thermodynamics and Kinetics. Chemical Hand Warmers
10/23/10 CHAPTER 6 Thermochemistry 6-1 Chemical Hand Warmers Most hand warmers work by using the heat released from the slow oxidation of iron 4 Fe(s) + 3 O2(g) 2 Fe2O3(s) The amount your hand temperature
More informationThermodynamics. Thermodynamics of Chemical Reactions. Enthalpy change
Thermodynamics 1 st law (Cons of Energy) Deals with changes in energy Energy in chemical systems Total energy of an isolated system is constant Total energy = Potential energy + kinetic energy E p mgh
More informationThermochemistry Ch. 8
Definitions I. Energy (E): capacity to do work. II. Heat (q): transfer of energy from a body at a high temp. to a body at a low temp. III. Reaction perspectives: A. System: the focus. B. Surroundings:
More informationCHAPTER 17 Thermochemistry
CHAPTER 17 Thermochemistry Thermochemistry The study of the heat changes that occur during chemical reactions and physical changes of state. Chemical Change: new substances created during chemical reaction
More informationEnergy & Chemistry. Internal Energy (E) Energy and Chemistry. Potential Energy. Kinetic Energy. Energy and Chemical Reactions: Thermochemistry or
Page III-5-1 / Chapter Five Lecture Notes Energy & Chemistry Energy and Chemical Reactions: Thermochemistry or Thermodynamics Chapter Five Burning peanuts supplies sufficient energy to boil a cup of water
More informationChapter 8 Thermochemistry: Chemical Energy
Chapter 8 Thermochemistry: Chemical Energy 國防醫學院生化學科王明芳老師 2011-11-8 & 2011-11-15 Chapter 8/1 Energy and Its Conservation Conservation of Energy Law: Energy cannot be created or destroyed; it can only be
More informationEnthalpies of Reaction
Enthalpies of Reaction Enthalpy is an extensive property Magnitude of H is directly related to the amount of reactant used up in a process. CH 4 (g) + 2O 2 (g) CO 2 (g) + 2H 2 O(l) H = 890 kj 2CH 4 (g)
More informationChemistry: The Central Science. Chapter 5: Thermochemistry
Chemistry: The Central Science Chapter 5: Thermochemistry Study of energy and its transformations is called thermodynamics Portion of thermodynamics that involves the relationships between chemical and
More informationThermochemistry. Chapter 6. Chemistry E1a
Thermochemistry Chapter 6 Chemistry E1a Energy: What is it? How is it transformed? What is energy? What are the SI units for energy? Give examples of some energy What types of energy are we going to be
More informationGravity is a force which keeps us stuck to the earth. The Electrostatic force attracts electrons to protons in an atom.
Energy Relations in Chemistry: Thermochemistry The Nature of Energy Sugar you eat is "combusted" by your body to produce CO 2 and H 2 O. During this process energy is also released. This energy is used
More informationThermochemistry: Energy Flow and Chemical Reactions
Thermochemistry: Energy Flow and Chemical Reactions Outline thermodynamics internal energy definition, first law enthalpy definition, energy diagrams, calorimetry, theoretical calculation (heats of formation
More informationName: Class: Date: ID: A
Name: Class: _ Date: _ ID: A Chpter 17 review Multiple Choice Identify the choice that best completes the statement or answers the question. 1. Which of these phase changes is an endothermic process? a.
More informationChapter 5. Thermochemistry
Chapter 5 Thermochemistry Energy Thermodynamics Study of the relationship between heat, work, and other forms of energy Thermochemistry A branch of thermodynamics Focuses on the study of heat given off
More informationName: General Chemistry Chapter 11 Thermochemistry- Heat and Chemical Change
Name: General Chemistry Chapter 11 Thermochemistry- Heat and Chemical Change Notepack 1 Section 11.1: The Flow of Energy Heat (Pages 293 299) 1. Define the following terms: a. Thermochemistry b. Energy
More informationSection 3.0. The 1 st Law of Thermodynamics. (CHANG text Chapter 4) 3.1. Revisiting Heat Capacities Definitions and Concepts
Section 3.0. The 1 st Law of Thermodynamics (CHANG text Chapter 4) 3.1. Revisiting Heat Capacities 3.2. Definitions and Concepts 3.3. The First Law of THERMODYNAMICS 3.4. Enthalpy 3.5. Adiabatic Expansion
More informationSection 1 - Thermochemistry
Reaction Energy Section 1 - Thermochemistry Virtually every chemical reaction is accompanied by a change in energy. Chemical reactions usually absorb or release energy as heat. You learned in Chapter 12
More informationTHE ENERGY OF THE UNIVERSE IS CONSTANT.
Chapter 6 Thermochemistry.notebook Chapter 6: Thermochemistry Jan 29 1:37 PM 6.1 The Nature of Energy Thermodynamics: The study of energy and its interconversions Energy: the capacity to do work or to
More informationUnit 7 Thermochemistry Chemistry 020, R. R. Martin
Unit 7 Thermochemistry Chemistry 020, R. R. Martin 1. Thermochemistry Heat is a form of energy - which may take many forms: - Kinetic energy due to motion, ½ mv 2 - Potential energy due to position - Electrical
More informationThermochemistry. Chapter 6. Concept Check 6.1. Concept Check 6.2. Solution
Chapter 6 Thermochemistry Concept Check 6.1 A solar-powered water pump has photovoltaic cells on protruding top panels. These cells collect energy from sunlight, storing it momentarily in a battery, which
More informationReaction Energy. Thermochemistry
Reaction Energy Thermochemistry Thermochemistry The study of the transfers of energy as heat that accompany chemical reactions & physical changes Thermochemistry -In studying heat changes, think of defining
More information