RESEARCH AND DEVELOPMENT DEPARTMENT

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1 RESEARCH AND DEVELOPMENT DEPARTMENT REPORT NO RIDGELAND AVENUE SOLIDS MANAGEMENT AREA MONITORING DATA FOR SECOND QUARTER 2006 August 2006

2 August 31, 2006 Mr. S. an Keller, P.E. Manager, Permit Section Illinois Environmental Protection Agency 1021 North Grand Avenue East P.O. Box Springfield, IL Dear Mr. Keller: Subject: Ridgeland Avenue Solids Management Area - Stickney WRP, Contract No P, IEPA Permit No AO-4283, Monitoring Data for April, May, and June 2006 The attached six tables contain the monitoring data for the Ridgeland Avenue Solids Management Area for April, May, and June 2006 as required by IEPA Operating Permit No AO During the quarter, there was a minor problem with Lysimeter L-1N and no sample could be collected. The problem was, however, corrected later in the quarter and samples were obtained. The data reported are as follows: Table 1, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on April 12, 2006 Table 2, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on April 26, 2006 Table 3, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on May 10, 2006 Table 4, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on May 24, 2006 Table 5, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on June 7, 2006

3 Mr. S. an Keller 2 August 31, 2006 Subject: Ridgeland Avenue Solids Management Area - Stickney WRP, Contract No P, IEPA Permit No AO-4283, Monitoring Data for April, May, and June 2006 Table 6, Analysis of Water from Lysimeters L-1 through L-4N at the Ridgeland Avenue Solids Management Area Sampled on June 21, 2006 June. No biosolids were placed in or removed from the solids drying area during the period of April to Very truly yours, LK:PL:spy Enclosure cc w/enc: Records Unit (IEPA) Sulski (IEPA) Louis Kollias Director Research and Development cc via MWRDGC Web Site: Levy/Sharma Stuba/Granato O'Connor/Cox Lindo/Patel, M.

4 TABLE 1 SAMPLED ON APRIL 12, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph 1 EC ms/m j j j j j Total Dissolved Solids mg/l j j j j L Total Dissolved Organic rbon j j j j Y j j j j S SO D 4 j j j j I j j j j M E L L L L T Y Y Y Y E S S S S R I I I I M M M M V E E E E A T T T T L E E E E V R R R R E D D D D D R R R R E Hg g/l Y Y Y Y F K mg/l E j j j j C j j j j T j j j j I j j j j V j j j j E j j j j j

5 TABLE 1 (Continued) SAMPLED ON APRIL 12, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m Total Dissolved Solids mg/l 1,424 1,360 1,034 Total Dissolved Organic rbon D SO < < < < < < < < Hg g/l < 0.05 < 0.05 < 0.05 K mg/l < < < < < < ph analyzed beyond recommended holding time of 15 minutes.

6 TABLE 2 SAMPLED ON APRIL 26, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph 1 EC ms/m j j j j j Total Dissolved Solids mg/l j j j j L Total Dissolved Organic rbon j j j j Y j j j j S SO D 4 j j j j I j j j j M E L L L L T Y Y Y Y E S S S S R I I I I M M M M V E E E E A T T T T L E E E E V R R R R E D D D D D R R R R E Hg g/l Y Y Y Y F K mg/l E j j j j C j j j j T j j j j I j j j j V j j j j E j j j j j

7 TABLE 2 (Continued) SAMPLED ON APRIL 26, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m Total Dissolved Solids mg/l 1,862 1,946 1,170 Total Dissolved Organic rbon D SO < 0.05 < < < < < < < Hg g/l < 0.05 < 0.05 < 0.05 K mg/l ph analyzed beyond recommended holding time of 15 minutes.

8 TABLE 3 SAMPLED ON MAY 10, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph 1 EC ms/m j j j j j Total Dissolved Solids mg/l j j j j L Total Dissolved Organic rbon j j j j Y j j j j S SO D 4 j j j j I j j j j M E L L L L T Y Y Y Y E S S S S R I I I I M M M M V E E E E A T T T T L E E E E V R R R R E D D D D D R R R R E Hg g/l Y Y Y Y F K mg/l E j j j j C j j j j T j j j j I j j j j V j j j j E j j j j j

9 TABLE 3 (Continued) SAMPLED ON MAY 10, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m Total Dissolved Solids mg/l 1,722 1,736 1,064 Total Dissolved Organic rbon D SO < < < < < < < Hg g/l 0.07 < 0.05 < 0.05 K mg/l < < < ph analyzed beyond recommended holding time of 15 minutes.

10 TABLE 4 SAMPLED ON MAY 24, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph EC ms/m j j j j 393 Total Dissolved Solids mg/l j j j j 3,866 Total Dissolved Organic rbon j j j j 5 j j j j 661 SO D 4 j j j j 899 j j j j 2.7 L L L L 1.4 Y Y Y Y 0.08 S S S S 0.10 I I I I 527 M M M M E E E E < T T T T 459 E E E E R R R R < < D D D D R R R R 1.31 Hg g/l Y Y Y Y 0.12 K mg/l 10 j j j j 306 j j j j j j j j j j j j 138 j j j j < j j j j

11 TABLE 4 (Continued) SAMPLED ON MAY 24, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m j Total Dissolved Solids mg/l 1,664 1,768 L Total Dissolved Organic rbon 7 3 Y S D SO I M E T E R V < < A L V < E < < D E Hg g/l F K mg/l 15 5 E C T I V < E j ph analyzed beyond recommended holding time of 15 minutes.

12 TABLE 5 SAMPLED ON JUNE 7, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph EC ms/m j 282 j j 427 Total Dissolved Solids mg/l j NA j j 4,280 Total Dissolved Organic rbon j NA j j 4 j 55 j j 178 SO D 4 j NA j j 879 j j j L 0.32 L L 1.0 Y 4.9 Y Y 0.06 S 0.18 S S < 0.05 I 708 I I 474 M M M E < E E < T 435 T T 527 E E E R R R < < D D D R R R 7.69 Hg g/l Y < 0.10 Y Y < 0.05 K mg/l 17 9 j 195 j j 281 j j j j j j j 60 j j 152 j j j < j j j

13 TABLE 5 (Continued) SAMPLED ON JUNE 7, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m Total Dissolved Solids mg/l 1,884 1,792 NA Total Dissolved Organic rbon 2 2 NA NA D SO NA NA NA NA 0.08 < 0.05 NA NA < < NA NA NA NA < < NA NA Hg g/l 0.05 < 0.05 NA K mg/l 15 6 NA NA NA NA < NA NA NA 1 ph analyzed beyond recommended holding time of 15 minutes. NA = No analysis; insufficient sample.

14 TABLE 6 SAMPLED ON JUNE 21, 2006 Parameter Unit L-1 L-2 L-3 L-4 L-1N ph EC ms/m j j j j 408 Total Dissolved Solids mg/l j j j j 4,612 Total Dissolved Organic rbon j j j j 4 j j j j 697 SO D 4 j j j j 918 j j j j 1.7 L L L L 0.84 Y Y Y Y 0.03 S S S S < 0.05 I I I I 533 M M M M E E E E < T T T T 504 E E E E R R R R < < D D D D R R R R 5.46 Hg g/l Y Y Y Y < 0.05 K mg/l 9 j j j j 278 j j j j j j j j j j j j 146 j j j j j j j j <

15 TABLE 6 (Continued) SAMPLED ON JUNE 21, 2006 Parameter Unit L-2N L-3N L-4N ph EC ms/m Total Dissolved Solids mg/l 1,854 1,854 1,048 Total Dissolved Organic rbon D SO < < < < < < < Hg g/l < 0.05 < 0.05 < 0.05 K mg/l < < < < ph analyzed beyond recommended holding time of 15 minutes.

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