Thermodynamics Partial Outline of Topics
|
|
- Elfrieda O’Neal’
- 6 years ago
- Views:
Transcription
1 Thermdynamics Partial Outline f Tpics I. The secnd law f thermdynamics addresses the issue f spntaneity and invlves a functin called entrpy (S): If a prcess is spntaneus, then Suniverse > 0 (2 nd Law!) (1) This means that if a prcess is spntaneus, Suniv increases. This des NOT mean that Ssys always increases!!! UNIV = SYS + SURR Suniverse Ssys + Ssurr (2) Fr sme hypthetical prcesses: -If entrpy increases in the system and the surrundings, then the prcess is bviusly spntaneus -If entrpy decreases in the system and the surrundings, then the prcess is bviusly nt spntaneus (and reverse prcess wuld be spntaneus) -If entrpy increases in the system and decreases in the surrundings, then the prcess is spntaneus if the increase in the system is bigger than the decrease in the surrundings! (i.e., if Ssys > Ssurr ; because that will mean that Ssys + Ssurr > 0) -If entrpy decreases in the system and increases in the surrundings, then the prcess is spntaneus if the decrease in the system is smaller than the increase in the surrundings! (i.e., if Ssys < Ssurr ; because that will mean that Ssys + Ssurr > 0) This is why we care s much abut entrpy(ies)! It is change in ttal entrpy (fr the universe) which ultimately (always!) dictates whether r nt a prcess is spntaneus. II. Sme patterns regarding entrpy f substances: 1. Fr a given amunt f a given substance, entrpy increases a. if energy flws int it: i) If T ges up ii) If it turns frm: s l; l g; r s g (Nte: gases tend t have a much greater entrpy (per mle) than slids r liquids; see Figure 17.5 and Table 17.2 in Tr) b. if vlume increases (applies nly t gases and disslved slutes) 2. The amunt f entrpy in a sample f a given substance depends n the amunt f that substance. Tables list the amunt f entrpy per mle f a given substance (at a given T). J Units are [r JK -1 ml -1 ] (read Jules per Kelvin per mle [f substance]) K ml 3. Different substances (r species) have a different amunt f entrpy (per mle). In general, fr a given physical state f a substance (see 1b abve), substances have a greater entrpy (per mle) if they are: a. Mre cmplex (mre atms/bnds/ins per frmula unit) b. Mre massive (per frmula unit) III. Predicting the sign f Ssys fr prcesses Given the abve pattens in II abve, yu shuld be able t predict whether entrpy increases r decreases (in the system), when certain prcesses ccur (hypthetically). See Examples Ssys Ssurr (NOTE: There likely will be ther tpics and bardwrk befre the next sectin f utline is cvered.) 1
2 IV. Secnd Law, Reprise-Cnnectin t Gibbs Free Energy Functin A. Cnceptual Cnnectins-I Fr any prcess Suniverse > 0 prcess is spntaneus (in frward directin) Suniverse < 0 prcess is nnspntaneus (reverse is spnt.) Suniverse = 0 prcess is nt spntaneus in either directin Fr a prpsed chemical (r physical) change (represented by a chemical equatin), & ccurring under any specific cnditins (T, P cnstant; cncentratins "fixed") spntaneus means "frward rxn is spntaneus" nnspntaneus means "reverse rxn is spntaneus" nt spntaneus in either directin means at equilibrium! Q < K Q > K Q = K Because f ideas intrduced in ur equilibrium unit! S (fr a chemical rxn at fixed T, P, and reactant and prduct cncentratins): Suniverse > 0 Q < K frward rxn is spntaneus Suniverse < 0 Q > K reverse rxn is spntaneus Suniverse = 0 Q = K at equilibrium B. Switching t all system variables (Hw is Ssurr related t system variables?) Recall: If n chemical change is ccurring in the surrundings, if energy flws int the surrundings, its entrpy will increase (Ssurr > 0). Furthermre, if energy flws int the surrundings, it had t have cme frm...the system!! -- Assertin: Ssurr = T (Nte: Hsys < 0 Ssurr > 0) Suniverse = Ssys + Ssurr > 0 spnt. Ssys + T Nw, d sme algebra (fr specific purpse): (Fr a prcess at cnstant T and P) (3) Start with 2 nd Law [Eq. (1)] and Eq.(2), cmbined > 0 spnt. Substitute Eq. (3) int the abve! TSsys + (Hsys) > 0 spnt. (multiplied thrugh by T) TSsys + (Hsys) < 0 spnt. (multiplied thrugh by -1) Hsys TSsys < 0 spnt. Mdified frm f 2nd Law (system variables nly): (swapped first tw terms) Hsys TSsys < 0 spnt. (if T, P cnstant) (1 ) **If we can calculate Hsys and Ssys, we can determine spntaneity. **The Hsys term "matters" because it ultimately is related t the entrpy change f the surrundings. **Nte: TSsys has units f energy C. Define a new functin: G, Gibbs Free Energy such that G = HTS (4) 2
3 Then, (1 ) becmes simply: Gsys < 0 spnt. (if T, P cnstant) Nte: By substituting Eq. (2) and Eq. (3) int Eq. (1), yu can shw that: S universe G T sys (1 ), using G (5) D. Cnceptual Cnnectins-II Thus fr a chemical r physical change at cnstant T & P, but any (i.e. nn-standard) cncentratins: Gsys < 0 spntaneus Q < K ( Suniverse > 0) Gsys > 0 reverse rxn spntaneus Q > K ( Suniverse < 0) Gsys 0 system is at equilibrium Q K ( Suniverse = 0) The relatins abve apply at any fixed set f cncentratins (r partial pressures). (i.e., any "cnditins", nt necessarily "standard state" cnditins). Wherever a "Q" is well defined, a Gsys is als defined (fr thse same set f cncentratins). Nte: As an "actual" reactin ccurs and cncentratins change, Q changes, and s des the Gsys. It is imprtant t realize that if [ ]'s change, the entrpies f species change, the Suniv changes, the Q changes, and the G changes! RECALL: "Standard State Cnditins" means a very specific set f cnditins: It means that all species (R's and P's) are in their standard state, which means: 1) All pure substances are in their mst stable physical state (s, l r g) at the T specified. 2) All species in slutin have a cncentratin f 1 M. 3) All gases have a partial pressure f 1 bar (~1 atm) (relates t [ ]) If a reactin is cnsidered t ccur at "standard state cnditins" THEN THE (very general) EXPRESSIONS ABOVE BECOME THE MUCH MORE SPECIFIC ONES BELOW: < 0 Spntaneus at st. state 1 < K ( P favred!) > 0 Reverse rxn is Spnt at st. state 1 > K ( R favred!) 0 System is at equilibrium at st. state 1 K ( neither R nr P favred) Please nte the fllwing: c d [ C] [ D] Since "standard state" means "all cncentratins are 1 M", Q a b [ A] [ B] 1 at standard state cnditins (i.e., when all species are in their standard state). "Prduct favred" means K > 1, and that means that IF all cncentratins were initially 1 M, frward reactin wuld ccur t reach equilibrium. "Prduct favred" is nw als assciated with the standard free energy change being negative (i.e., < 0). G and are NOT the same thing! The first is MUCH mre general; the secnd is quite specific: G < 0 means a reactin is spntaneus at whatever cnditins (cncentratins) are specified. It des NOT mean "prduct favred" (at equilibrium). K culd be large r small! (Q < K) 3 < 0 means a reactin is spntaneus at standard state cnditins (cncentratins), which means that the prcess is "prduct favred" (at equilibrium). K must be larger than 1! (K > 1)
4 Recall the distinctin that was made (during the discussin f equilibrium) between "prduct favred" (K > 1) and "prduct deficient" (Q < K; t few prducts t be at equilibrium; "net frward reactin ccurs t reach equilibrium [frm this pint]). This is the SAME distinctin I'm trying t get yu t see nw: If G < 0, then frward reactin will ccur t reach equilibrium [frm the specified "pint", where Q is bviusly < K]. If < 0, then frward reactin wuld ccur if the system were t start at standard state cnditins. E. The explicit mathematical cnnectin between Q and G: G = G + RT ln Q The free energy change fr a chemical reactin under any cnditins is equal t what it wuld be if all reactants and prducts were (and remained) in their standard states plus sme crrectin factr t accunt fr the fact that the system is nt at standard state cnditins. Sme imprtant "upshts" f all this: We can tabulate standard Gf's fr all substances, and use them t calculate given prcess. (r we can calculate frm T ) 's fr any This (alne) can tell us whether a prcess is prduct favred r reactant favred (i.e., spntaneus under standard state cnditins) It tells us in which directin there is a driving frce fr reactin t happen if yu started with all R's and P's at 1 M We can even get the specific value f K! G = -RT ln K (Where des this cme frm? Simple! If a system is at equilibrium, we nw knw that TWO things must be true: 1) Q K (frm befre); and 2) G 0. If yu substitute thse tw "values" int G G + RT ln Q, what d yu get? 0 G + RT ln K, which rearranges t the equatin at the left!) K e G RT If the cnditins are NOT standard (generally, Q 1), then we can get the "driving frce" at these (nn-standard) cnditins using G = G + RT ln Q F. Revisit Gsys HsysTSsys at standard state cnditins: T-dependence f It turns ut that Hsys and Ssys are nt very T-dependent. We generally assume that they are cmpletely temperature independent s that we can determine the T-dependence f fr a particular chemical reactin equatin: 4
5 = T = (a cnstant) T (anther cnstant) 1) Think abut the extremes (this is nw dne effectively in the PwerPint presentatin as well): a) If T ges t abslute zer, then T ges t zer, and s. Thus, at lw temperature: endthermic prcesses are nn-spntaneus at standard state cnditins ( exthermic prcesses are spntaneus at standard state cnditins ( < 0) > 0), and This can be ratinalized in entrpy terms as fllws: At very lw T, the entrpy change fr the surrundings will dminate S univ. If energy flws int the system (endthermic), then S fr the surrundings ges dwn by a huge amunt, making S univ < 0 (nnspntaneus). If energy flws ut f the system (exthermic), then S fr the surrundings ges up by a huge amunt, making S univ > 0 (spntaneus). b) If T gets very large (e.g., tward infinity), then T infinity), and s ~ T. Thus, at high temperature: gets very large in magnitude (e.g., tward prcesses that increase entrpy in the system are spntaneus at standard state cnditins ( < 0), and prcesses that decrease entrpy in the system are nnspntaneus at standard state cnditins ( > 0) This can be ratinalized in entrpy terms as fllws: At very high T, the entrpy change fr the surrundings will be negligible, s S univ will essentially equal! 2) Fr prcesses in which the signs f and are the SAME (which means that the signs f and Ssurr are ppsite): there will be sme T between 0 and infinity at which there is a "breakeven" pint where 0 and the system is at equilibrium at standard state cnditins (K = 1). Find this T by putting in 0 fr (Remember, and, and then slving the equatin [0 T ] fr T! are cnsidered t be cnstant fr a given reactin equatin!) 5
Part One: Heat Changes and Thermochemistry. This aspect of Thermodynamics was dealt with in Chapter 6. (Review)
CHAPTER 18: THERMODYNAMICS AND EQUILIBRIUM Part One: Heat Changes and Thermchemistry This aspect f Thermdynamics was dealt with in Chapter 6. (Review) A. Statement f First Law. (Sectin 18.1) 1. U ttal
More informationEntropy, Free Energy, and Equilibrium
Nv. 26 Chapter 19 Chemical Thermdynamics Entrpy, Free Energy, and Equilibrium Nv. 26 Spntaneus Physical and Chemical Prcesses Thermdynamics: cncerned with the questin: can a reactin ccur? A waterfall runs
More informationThermodynamics and Equilibrium
Thermdynamics and Equilibrium Thermdynamics Thermdynamics is the study f the relatinship between heat and ther frms f energy in a chemical r physical prcess. We intrduced the thermdynamic prperty f enthalpy,
More informationChapters 29 and 35 Thermochemistry and Chemical Thermodynamics
Chapters 9 and 35 Thermchemistry and Chemical Thermdynamics 1 Cpyright (c) 011 by Michael A. Janusa, PhD. All rights reserved. Thermchemistry Thermchemistry is the study f the energy effects that accmpany
More informationCHEM Thermodynamics. Change in Gibbs Free Energy, G. Review. Gibbs Free Energy, G. Review
Review Accrding t the nd law f Thermdynamics, a prcess is spntaneus if S universe = S system + S surrundings > 0 Even thugh S system
More informationChapter 17 Free Energy and Thermodynamics
Chemistry: A Mlecular Apprach, 1 st Ed. Nivald Tr Chapter 17 Free Energy and Thermdynamics Ry Kennedy Massachusetts Bay Cmmunity Cllege Wellesley Hills, MA 2008, Prentice Hall First Law f Thermdynamics
More informationAP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY
AP CHEMISTRY CHAPTER 6 NOTES THERMOCHEMISTRY Energy- the capacity t d wrk r t prduce heat 1 st Law f Thermdynamics: Law f Cnservatin f Energy- energy can be cnverted frm ne frm t anther but it can be neither
More informationChapter 17: Thermodynamics: Spontaneous and Nonspontaneous Reactions and Processes
Chapter 17: hermdynamics: Spntaneus and Nnspntaneus Reactins and Prcesses Learning Objectives 17.1: Spntaneus Prcesses Cmparing and Cntrasting the hree Laws f hermdynamics (1 st Law: Chap. 5; 2 nd & 3
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationCHEM 116 Electrochemistry at Non-Standard Conditions, and Intro to Thermodynamics
CHEM 116 Electrchemistry at Nn-Standard Cnditins, and Intr t Thermdynamics Imprtant annuncement: If yu brrwed a clicker frm me this semester, return it t me at the end f next lecture r at the final exam
More informationALE 21. Gibbs Free Energy. At what temperature does the spontaneity of a reaction change?
Name Chem 163 Sectin: Team Number: ALE 21. Gibbs Free Energy (Reference: 20.3 Silberberg 5 th editin) At what temperature des the spntaneity f a reactin change? The Mdel: The Definitin f Free Energy S
More informationCHEM 1001 Problem Set #3: Entropy and Free Energy
CHEM 1001 Prblem Set #3: Entry and Free Energy 19.7 (a) Negative; A liquid (mderate entry) cmbines with a slid t frm anther slid. (b)psitive; One mle f high entry gas frms where n gas was resent befre.
More informationThermochemistry. Thermochemistry
Thermchemistry Petrucci, Harwd and Herring: Chapter 7 CHEM 1000A 3.0 Thermchemistry 1 Thermchemistry The study energy in chemical reactins A sub-discipline thermdynamics Thermdynamics studies the bulk
More informationUnit 14 Thermochemistry Notes
Name KEY Perid CRHS Academic Chemistry Unit 14 Thermchemistry Ntes Quiz Date Exam Date Lab Dates Ntes, Hmewrk, Exam Reviews and Their KEYS lcated n CRHS Academic Chemistry Website: https://cincchem.pbwrks.cm
More informationSpontaneous Processes, Entropy and the Second Law of Thermodynamics
Chemical Thermdynamics Spntaneus Prcesses, Entrpy and the Secnd Law f Thermdynamics Review Reactin Rates, Energies, and Equilibrium Althugh a reactin may be energetically favrable (i.e. prducts have lwer
More informationCHEM 103 Calorimetry and Hess s Law
CHEM 103 Calrimetry and Hess s Law Lecture Ntes March 23, 2006 Prf. Sevian Annuncements Exam #2 is next Thursday, March 30 Study guide, practice exam, and practice exam answer key are already psted n the
More informationMODULE 1. e x + c. [You can t separate a demominator, but you can divide a single denominator into each numerator term] a + b a(a + b)+1 = a + b
. REVIEW OF SOME BASIC ALGEBRA MODULE () Slving Equatins Yu shuld be able t slve fr x: a + b = c a d + e x + c and get x = e(ba +) b(c a) d(ba +) c Cmmn mistakes and strategies:. a b + c a b + a c, but
More informationChemistry 1A Fall 2000
Chemistry 1A Fall 2000 Midterm Exam III, versin B Nvember 14, 2000 (Clsed bk, 90 minutes, 155 pints) Name: SID: Sectin Number: T.A. Name: Exam infrmatin, extra directins, and useful hints t maximize yur
More informationWhen a substance heats up (absorbs heat) it is an endothermic reaction with a (+)q
Chemistry Ntes Lecture 15 [st] 3/6/09 IMPORTANT NOTES: -( We finished using the lecture slides frm lecture 14) -In class the challenge prblem was passed ut, it is due Tuesday at :00 P.M. SHARP, :01 is
More informationCHAPTER Read Chapter 17, sections 1,2,3. End of Chapter problems: 25
CHAPTER 17 1. Read Chapter 17, sectins 1,2,3. End f Chapter prblems: 25 2. Suppse yu are playing a game that uses tw dice. If yu cunt the dts n the dice, yu culd have anywhere frm 2 t 12. The ways f prducing
More informationLecture 12: Chemical reaction equilibria
3.012 Fundamentals f Materials Science Fall 2005 Lecture 12: 10.19.05 Chemical reactin equilibria Tday: LAST TIME...2 EQUATING CHEMICAL POTENTIALS DURING REACTIONS...3 The extent f reactin...3 The simplest
More informationREVIEW QUESTIONS Chapter 18. H = H (Products) - H (Reactants) H (Products) = (1 x -125) + (3 x -271) = -938 kj
Chemistry 102 ANSWER KEY REVIEW QUESTIONS Chapter 18 1. Calculate the heat reactin ( H ) in kj/ml r the reactin shwn belw, given the H values r each substance: NH (g) + F 2 (g) NF (g) + HF (g) H (kj/ml)
More informationGOAL... ability to predict
THERMODYNAMICS Chapter 18, 11.5 Study f changes in energy and transfers f energy (system < = > surrundings) that accmpany chemical and physical prcesses. GOAL............................. ability t predict
More informationExamples: 1. How much heat is given off by a 50.0 g sample of copper when it cools from 80.0 to 50.0 C?
NOTES: Thermchemistry Part 1 - Heat HEAT- TEMPERATURE - Thermchemistry: the study f energy (in the frm f heat) changes that accmpany physical & chemical changes heat flws frm high t lw (ht cl) endthermic
More informationChemical Thermodynamics
Chemical Thermdynamics Objectives 1. Be capable f stating the First, Secnd, and Third Laws f Thermdynamics and als be capable f applying them t slve prblems. 2. Understand what the parameter entrpy means.
More informationLecture 16 Thermodynamics II
Lecture 16 Thermdynamics II Calrimetry Hess s Law Enthalpy r Frmatin Cpyright 2013, 2011, 2009, 2008 AP Chem Slutins. All rights reserved. Fur Methds fr Finding H 1) Calculate it using average bnd enthalpies
More informationSolutions to the Extra Problems for Chapter 14
Slutins t the Extra Prblems r Chapter 1 1. The H -670. T use bnd energies, we have t igure ut what bnds are being brken and what bnds are being made, s we need t make Lewis structures r everything: + +
More informationUnit 11 Solutions- Guided Notes. What are alloys? What is the difference between heterogeneous and homogeneous mixtures?
Name: Perid: Unit 11 Slutins- Guided Ntes Mixtures: What is a mixture and give examples? What is a pure substance? What are allys? What is the difference between hetergeneus and hmgeneus mixtures? Slutins:
More informationNUMBERS, MATHEMATICS AND EQUATIONS
AUSTRALIAN CURRICULUM PHYSICS GETTING STARTED WITH PHYSICS NUMBERS, MATHEMATICS AND EQUATIONS An integral part t the understanding f ur physical wrld is the use f mathematical mdels which can be used t
More informationUniversity Chemistry Quiz /04/21 1. (10%) Consider the oxidation of ammonia:
University Chemistry Quiz 3 2015/04/21 1. (10%) Cnsider the xidatin f ammnia: 4NH 3 (g) + 3O 2 (g) 2N 2 (g) + 6H 2 O(l) (a) Calculate the ΔG fr the reactin. (b) If this reactin were used in a fuel cell,
More informationTypes of Energy COMMON MISCONCEPTIONS CHEMICAL REACTIONS INVOLVE ENERGY
CHEMICAL REACTIONS INVOLVE ENERGY The study energy and its transrmatins is knwn as thermdynamics. The discussin thermdynamics invlve the cncepts energy, wrk, and heat. Types Energy Ptential energy is stred
More informationGeneral Chemistry II, Unit II: Study Guide (part 1)
General Chemistry II, Unit II: Study Guide (part 1) CDS Chapter 21: Reactin Equilibrium in the Gas Phase General Chemistry II Unit II Part 1 1 Intrductin Sme chemical reactins have a significant amunt
More informationElectrochemistry. Reduction: the gaining of electrons. Reducing agent (reductant): species that donates electrons to reduce another reagent.
Electrchemistry Review: Reductin: the gaining f electrns Oxidatin: the lss f electrns Reducing agent (reductant): species that dnates electrns t reduce anther reagent. Oxidizing agent (xidant): species
More informationSemester 2 AP Chemistry Unit 12
Cmmn In Effect and Buffers PwerPint The cmmn in effect The shift in equilibrium caused by the additin f a cmpund having an in in cmmn with the disslved substance The presence f the excess ins frm the disslved
More informationA.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1
A.P. CHEMISTRY. SOLUTIONS AND ACID BASE CHEMISTRY. p 1 (Nte: questins 1 t 14 are meant t be dne WITHOUT calculatrs!) 1.Which f the fllwing is prbably true fr a slid slute with a highly endthermic heat
More informationA Few Basic Facts About Isothermal Mass Transfer in a Binary Mixture
Few asic Facts but Isthermal Mass Transfer in a inary Miture David Keffer Department f Chemical Engineering University f Tennessee first begun: pril 22, 2004 last updated: January 13, 2006 dkeffer@utk.edu
More informationChem 112, Fall 05 (Weis/Garman) Exam 4A, December 14, 2005 (Print Clearly) +2 points
+2 pints Befre yu begin, make sure that yur exam has all 7 pages. There are 14 required prblems (7 pints each) and tw extra credit prblems (5 pints each). Stay fcused, stay calm. Wrk steadily thrugh yur
More informationA Chemical Reaction occurs when the of a substance changes.
Perid: Unit 8 Chemical Reactin- Guided Ntes Chemical Reactins A Chemical Reactin ccurs when the f a substance changes. Chemical Reactin: ne r mre substances are changed int ne r mre new substances by the
More informationChapter 19. Electrochemistry. Dr. Al Saadi. Electrochemistry
Chapter 19 lectrchemistry Part I Dr. Al Saadi 1 lectrchemistry What is electrchemistry? It is a branch f chemistry that studies chemical reactins called redx reactins which invlve electrn transfer. 19.1
More informationSPONTANEITY, ENTROPY, AND FREE ENERGY
CHAER 7 SONANEIY, ENROY, AND FREE ENERGY Questins. Living rganisms need an external surce f energy t carry ut these prcesses. Green plants use the energy frm sunlight t prduce glucse frm carbn dixide and
More informationMaking and Experimenting with Voltaic Cells. I. Basic Concepts and Definitions (some ideas discussed in class are omitted here)
Making xperimenting with Vltaic Cells I. Basic Cncepts Definitins (sme ideas discussed in class are mitted here) A. Directin f electrn flw psitiveness f electrdes. If ne electrde is mre psitive than anther,
More information**DO NOT ONLY RELY ON THIS STUDY GUIDE!!!**
Tpics lists: UV-Vis Absrbance Spectrscpy Lab & ChemActivity 3-6 (nly thrugh 4) I. UV-Vis Absrbance Spectrscpy Lab Beer s law Relates cncentratin f a chemical species in a slutin and the absrbance f that
More informationCompressibility Effects
Definitin f Cmpressibility All real substances are cmpressible t sme greater r lesser extent; that is, when yu squeeze r press n them, their density will change The amunt by which a substance can be cmpressed
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationChapter 4 Thermodynamics and Equilibrium
Chapter Thermdynamics and Equilibrium Refer t the fllwing figures fr Exercises 1-6. Each represents the energies f fur mlecules at a given instant, and the dtted lines represent the allwed energies. Assume
More informationEdexcel IGCSE Chemistry. Topic 1: Principles of chemistry. Chemical formulae, equations and calculations. Notes.
Edexcel IGCSE Chemistry Tpic 1: Principles f chemistry Chemical frmulae, equatins and calculatins Ntes 1.25 write wrd equatins and balanced chemical equatins (including state symbls): fr reactins studied
More informationGeneral Chemistry II, Unit I: Study Guide (part I)
1 General Chemistry II, Unit I: Study Guide (part I) CDS Chapter 14: Physical Prperties f Gases Observatin 1: Pressure- Vlume Measurements n Gases The spring f air is measured as pressure, defined as the
More informationPhysics 2B Chapter 23 Notes - Faraday s Law & Inductors Spring 2018
Michael Faraday lived in the Lndn area frm 1791 t 1867. He was 29 years ld when Hand Oersted, in 1820, accidentally discvered that electric current creates magnetic field. Thrugh empirical bservatin and
More informationHess Law - Enthalpy of Formation of Solid NH 4 Cl
Hess Law - Enthalpy f Frmatin f Slid NH 4 l NAME: OURSE: PERIOD: Prelab 1. Write and balance net inic equatins fr Reactin 2 and Reactin 3. Reactin 2: Reactin 3: 2. Shw that the alebraic sum f the balanced
More informationThis section is primarily focused on tools to aid us in finding roots/zeros/ -intercepts of polynomials. Essentially, our focus turns to solving.
Sectin 3.2: Many f yu WILL need t watch the crrespnding vides fr this sectin n MyOpenMath! This sectin is primarily fcused n tls t aid us in finding rts/zers/ -intercepts f plynmials. Essentially, ur fcus
More informationMore Tutorial at
Answer each questin in the space prvided; use back f page if extra space is needed. Answer questins s the grader can READILY understand yur wrk; nly wrk n the exam sheet will be cnsidered. Write answers,
More informationCHM 152 Practice Final
CM 152 Practice Final 1. Of the fllwing, the ne that wuld have the greatest entrpy (if cmpared at the same temperature) is, [a] 2 O (s) [b] 2 O (l) [c] 2 O (g) [d] All wuld have the same entrpy at the
More informationChem 163 Section: Team Number: ALE 24. Voltaic Cells and Standard Cell Potentials. (Reference: 21.2 and 21.3 Silberberg 5 th edition)
Name Chem 163 Sectin: Team Number: ALE 24. Vltaic Cells and Standard Cell Ptentials (Reference: 21.2 and 21.3 Silberberg 5 th editin) What des a vltmeter reading tell us? The Mdel: Standard Reductin and
More informationChem 75 February 16, 2017 Exam 2 Solutions
1. (6 + 6 pints) Tw quick questins: (a) The Handbk f Chemistry and Physics tells us, crrectly, that CCl 4 bils nrmally at 76.7 C, but its mlar enthalpy f vaprizatin is listed in ne place as 34.6 kj ml
More informationChemistry 132 NT. Electrochemistry. Review
Chemistry 132 NT If yu g flying back thrugh time, and yu see smebdy else flying frward int the future, it s prbably best t avid eye cntact. Jack Handey 1 Chem 132 NT Electrchemistry Mdule 3 Vltaic Cells
More information37 Maxwell s Equations
37 Maxwell s quatins In this chapter, the plan is t summarize much f what we knw abut electricity and magnetism in a manner similar t the way in which James Clerk Maxwell summarized what was knwn abut
More informationComputational modeling techniques
Cmputatinal mdeling techniques Lecture 4: Mdel checing fr ODE mdels In Petre Department f IT, Åb Aademi http://www.users.ab.fi/ipetre/cmpmd/ Cntent Stichimetric matrix Calculating the mass cnservatin relatins
More informationLecture 14 Chapter 16, Sections 3-4 Equilibrium. Nifty K eq math Q and K eq Connection with G Le Chatelier
Lecture 14 Chater 16, Sectins 3-4 Equilibrium Nifty K math Q and K Cnnectin with G Le Chatelier Remember In general fr a reactin like aa + bb dd + ee K [ ] d D [ E] e [ ] a A [ ] b B K s can be cmbined
More informationLecture 4. The First Law of Thermodynamics
Lecture 4. The First Law f Thermdynamics THERMODYNAMICS: Basic Cncepts Thermdynamics: (frm the Greek therme, meaning "heat" and, dynamis, meaning "pwer") is the study f energy cnversin between heat and
More informationCHEM-443, Fall 2013, Section 010 Midterm 2 November 4, 2013
CHEM-443, Fall 2013, Sectin 010 Student Name Midterm 2 Nvember 4, 2013 Directins: Please answer each questin t the best f yur ability. Make sure yur respnse is legible, precise, includes relevant dimensinal
More informationChemistry 114 First Hour Exam
Chemistry 114 First Hur Exam Please shw all wrk fr partial credit Name: (4 pints) 1. (12 pints) Espress is made by frcing very ht water under high pressure thrugh finely grund, cmpacted cffee. (Wikipedia)
More informationWe can see from the graph above that the intersection is, i.e., [ ).
MTH 111 Cllege Algebra Lecture Ntes July 2, 2014 Functin Arithmetic: With nt t much difficulty, we ntice that inputs f functins are numbers, and utputs f functins are numbers. S whatever we can d with
More informationMaterials Engineering 272-C Fall 2001, Lecture 7 & 8 Fundamentals of Diffusion
Materials Engineering 272-C Fall 2001, Lecture 7 & 8 Fundamentals f Diffusin Diffusin: Transprt in a slid, liquid, r gas driven by a cncentratin gradient (r, in the case f mass transprt, a chemical ptential
More informationPreparation work for A2 Mathematics [2017]
Preparatin wrk fr A2 Mathematics [2017] The wrk studied in Y12 after the return frm study leave is frm the Cre 3 mdule f the A2 Mathematics curse. This wrk will nly be reviewed during Year 13, it will
More informationChE 471: LECTURE 4 Fall 2003
ChE 47: LECTURE 4 Fall 003 IDEL RECTORS One f the key gals f chemical reactin engineering is t quantify the relatinship between prductin rate, reactr size, reactin kinetics and selected perating cnditins.
More informationDifferentiation Applications 1: Related Rates
Differentiatin Applicatins 1: Related Rates 151 Differentiatin Applicatins 1: Related Rates Mdel 1: Sliding Ladder 10 ladder y 10 ladder 10 ladder A 10 ft ladder is leaning against a wall when the bttm
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t eep this site up and bring yu even mre cntent cnsider dnating via the lin n ur site. Still having truble understanding the material? Chec ut ur Tutring
More informationLecture 17: Free Energy of Multi-phase Solutions at Equilibrium
Lecture 17: 11.07.05 Free Energy f Multi-phase Slutins at Equilibrium Tday: LAST TIME...2 FREE ENERGY DIAGRAMS OF MULTI-PHASE SOLUTIONS 1...3 The cmmn tangent cnstructin and the lever rule...3 Practical
More information[COLLEGE ALGEBRA EXAM I REVIEW TOPICS] ( u s e t h i s t o m a k e s u r e y o u a r e r e a d y )
(Abut the final) [COLLEGE ALGEBRA EXAM I REVIEW TOPICS] ( u s e t h i s t m a k e s u r e y u a r e r e a d y ) The department writes the final exam s I dn't really knw what's n it and I can't very well
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Answer Key ALE 28. ess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 4 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk neatly using dimensinal analysis
More informationFive Whys How To Do It Better
Five Whys Definitin. As explained in the previus article, we define rt cause as simply the uncvering f hw the current prblem came int being. Fr a simple causal chain, it is the entire chain. Fr a cmplex
More informationMatter Content from State Frameworks and Other State Documents
Atms and Mlecules Mlecules are made f smaller entities (atms) which are bnded tgether. Therefre mlecules are divisible. Miscnceptin: Element and atm are synnyms. Prper cnceptin: Elements are atms with
More informationFall 2013 Physics 172 Recitation 3 Momentum and Springs
Fall 03 Physics 7 Recitatin 3 Mmentum and Springs Purpse: The purpse f this recitatin is t give yu experience wrking with mmentum and the mmentum update frmula. Readings: Chapter.3-.5 Learning Objectives:.3.
More informationFind this material useful? You can help our team to keep this site up and bring you even more content consider donating via the link on our site.
Find this material useful? Yu can help ur team t keep this site up and bring yu even mre cntent cnsider dnating via the link n ur site. Still having truble understanding the material? Check ut ur Tutring
More informationCHEM 1032 FALL 2017 Practice Exam 4 1. Which of the following reactions is spontaneous under normal and standard conditions?
1 CHEM 1032 FALL 2017 Practice Exam 4 1. Which f the fllwing reactins is spntaneus under nrmal and standard cnditins? A. 2 NaCl(aq) 2 Na(s) + Cl2(g) B. CaBr2(aq) + 2 H2O(aq) Ca(OH)2(aq) + 2 HBr(aq) C.
More informationThermochemistry. The study of energy changes that occur during chemical : at constant volume ΔU = q V. no at constant pressure ΔH = q P
Thermchemistry The study energy changes that ccur during chemical : at cnstant vlume ΔU = q V n at cnstant pressure = q P nly wrk Fr practical reasns mst measurements are made at cnstant, s thermchemistry
More informationSupporting information
Electrnic Supplementary Material (ESI) fr Physical Chemistry Chemical Physics This jurnal is The wner Scieties 01 ydrgen perxide electrchemistry n platinum: twards understanding the xygen reductin reactin
More information3. Mass Transfer with Chemical Reaction
8 3. Mass Transfer with Chemical Reactin 3. Mass Transfer with Chemical Reactin In the fllwing, the fundamentals f desrptin with chemical reactin, which are applied t the prblem f CO 2 desrptin in ME distillers,
More informationWork, Energy, and Power
rk, Energy, and Pwer Physics 1 There are many different TYPES f Energy. Energy is expressed in JOULES (J 419J 4.19 1 calrie Energy can be expressed mre specifically by using the term ORK( rk The Scalar
More informationEdexcel GCSE Physics
Edexcel GCSE Physics Tpic 10: Electricity and circuits Ntes (Cntent in bld is fr Higher Tier nly) www.pmt.educatin The Structure f the Atm Psitively charged nucleus surrunded by negatively charged electrns
More informationLecture 13: Electrochemical Equilibria
3.012 Fundamentals f Materials Science Fall 2005 Lecture 13: 10.21.05 Electrchemical Equilibria Tday: LAST TIME...2 An example calculatin...3 THE ELECTROCHEMICAL POTENTIAL...4 Electrstatic energy cntributins
More informationChapter Outline 4/28/2014. P-V Work. P-V Work. Isolated, Closed and Open Systems. Exothermic and Endothermic Processes. E = q + w
Islated, Clsed and Open Systems 9.1 Energy as a Reactant r a Prduct 9.2 Transferring Heat and Ding Wrk 9.5 Heats f Reactin and Calrimetry 9.6 Hess s Law and Standard Heats f Reactin 9.7 Heats f Reactin
More informationPhys. 344 Ch 7 Lecture 8 Fri., April. 10 th,
Phys. 344 Ch 7 Lecture 8 Fri., April. 0 th, 009 Fri. 4/0 8. Ising Mdel f Ferrmagnets HW30 66, 74 Mn. 4/3 Review Sat. 4/8 3pm Exam 3 HW Mnday: Review fr est 3. See n-line practice test lecture-prep is t
More informationKinetic Model Completeness
5.68J/10.652J Spring 2003 Lecture Ntes Tuesday April 15, 2003 Kinetic Mdel Cmpleteness We say a chemical kinetic mdel is cmplete fr a particular reactin cnditin when it cntains all the species and reactins
More informationLecture 24: Flory-Huggins Theory
Lecture 24: 12.07.05 Flry-Huggins Thery Tday: LAST TIME...2 Lattice Mdels f Slutins...2 ENTROPY OF MIXING IN THE FLORY-HUGGINS MODEL...3 CONFIGURATIONS OF A SINGLE CHAIN...3 COUNTING CONFIGURATIONS FOR
More informationCHEM 2400/2480. Lecture 19
Lecture 19 Metal In Indicatr - a cmpund whse clur changes when it binds t a metal in - t be useful, it must bind the metal less strngly than EDTA e.g. titratin f Mg 2+ with EDTA using erichrme black T
More informationSPH3U1 Lesson 06 Kinematics
PROJECTILE MOTION LEARNING GOALS Students will: Describe the mtin f an bject thrwn at arbitrary angles thrugh the air. Describe the hrizntal and vertical mtins f a prjectile. Slve prjectile mtin prblems.
More informationLecture 02 CSE 40547/60547 Computing at the Nanoscale
PN Junctin Ntes: Lecture 02 CSE 40547/60547 Cmputing at the Nanscale Letʼs start with a (very) shrt review f semi-cnducting materials: - N-type material: Obtained by adding impurity with 5 valence elements
More informationENGINEERING COUNCIL CERTIFICATE LEVEL THERMODYNAMIC, FLUID AND PROCESS ENGINEERING C106 TUTORIAL 5 THE VISCOUS NATURE OF FLUIDS
ENGINEERING COUNCIL CERTIFICATE LEVEL THERMODYNAMIC, FLUID AND PROCESS ENGINEERING C106 TUTORIAL 5 THE VISCOUS NATURE OF FLUIDS On cmpletin f this tutrial yu shuld be able t d the fllwing. Define viscsity
More information" 1 = # $H vap. Chapter 3 Problems
Chapter 3 rblems rblem At 1 atmsphere pure Ge melts at 1232 K and bils at 298 K. he triple pint ccurs at =8.4x1-8 atm. Estimate the heat f vaprizatin f Ge. he heat f vaprizatin is estimated frm the Clausius
More informationHow can standard heats of formation be used to calculate the heat of a reaction?
Name Chem 161, Sectin: Grup Number: ALE 28. Hess s Law and Standard Enthalpies Frmatin (Reerence: Chapter 6 - Silberberg 5 th editin) Imprtant!! Fr answers that invlve a calculatin yu must shw yur wrk
More informationLecture 7: Damped and Driven Oscillations
Lecture 7: Damped and Driven Oscillatins Last time, we fund fr underdamped scillatrs: βt x t = e A1 + A csω1t + i A1 A sinω1t A 1 and A are cmplex numbers, but ur answer must be real Implies that A 1 and
More informationElectrochemistry. Half-Reactions 1. Balancing Oxidation Reduction Reactions in Acidic and Basic Solutions
Electrchemistry Half-Reactins 1. Balancing Oxidatin Reductin Reactins in Acidic and Basic Slutins Vltaic Cells 2. Cnstructin f Vltaic Cells 3. Ntatin fr Vltaic Cells 4. Cell Ptential 5. Standard Cell Ptentials
More informationElectrochemistry. Learning Objectives. Half-Reactions 1. Balancing Oxidation Reduction Reactions in Acidic and Basic Solutions
Electrchemistry 1 Learning Objectives Electrchemistry Balancing Oxidatin Reductin Reactins in Acidic and Basic Slutins a. Learn the steps fr balancing xidatin reductin reactins using the half-reactin methd.
More informationLCAO APPROXIMATIONS OF ORGANIC Pi MO SYSTEMS The allyl system (cation, anion or radical).
Principles f Organic Chemistry lecture 5, page LCAO APPROIMATIONS OF ORGANIC Pi MO SYSTEMS The allyl system (catin, anin r radical).. Draw mlecule and set up determinant. 2 3 0 3 C C 2 = 0 C 2 3 0 = -
More informationRevision: August 19, E Main Suite D Pullman, WA (509) Voice and Fax
.7.4: Direct frequency dmain circuit analysis Revisin: August 9, 00 5 E Main Suite D Pullman, WA 9963 (509) 334 6306 ice and Fax Overview n chapter.7., we determined the steadystate respnse f electrical
More informationNUPOC STUDY GUIDE ANSWER KEY. Navy Recruiting Command
NUPOC SUDY GUIDE ANSWER KEY Navy Recruiting Cmmand CHEMISRY. ph represents the cncentratin f H ins in a slutin, [H ]. ph is a lg scale base and equal t lg[h ]. A ph f 7 is a neutral slutin. PH < 7 is acidic
More information188 CHAPTER 6 THERMOCHEMISTRY
188 CHAPTER 6 THERMOCHEMISTRY 4. a. ΔE = q + w = J + 100. J = 77 J b. w = PΔV = 1.90 atm(.80 L 8.0 L) = 10.5 L atm ΔE = q + w = 50. J + 1060 = 1410 J c. w = PΔV = 1.00 atm(9.1 L11. L) = 17.9 L atm 101.
More informationHeat Effects of Chemical Reactions
eat Effects f hemical Reactins Enthalpy change fr reactins invlving cmpunds Enthalpy f frmatin f a cmpund at standard cnditins is btained frm the literature as standard enthalpy f frmatin Δ (O (g = -9690
More information