The Kelvin-Planck statement of the second law
|
|
- Vivian May
- 6 years ago
- Views:
Transcription
1 The Kelvin-Planck statement of the second law It is impossible for any device that operates on a cycle to receive heat from a single reservoir and produce a net amount of work Q W E =ΔE net net net, mass sys Q net W = net 0 ( Q H + W ) ( Q L + W ) = 0 in out Q H = W out Due to friction and dissipative effect, no heat engine can have a thermal efficiency of 100 percent A heat engine that violates the Kelvin-Planck statement of the second law 1
2 The Causius statement of the second law It is impossible to construct a device that operates in a cycle and produces no effect other than the transfer of heat from a low temperature body to a higher - temperature body. Q W E =ΔE net net net, mass sys Q net = 0 Q = Q H Heat can not move from low temperature source to high temperature source without external work! L A refrigerator that violates the Clausius statement of the second law 2
3 Reversible or Irreversible process? Reversible process: a process that can be reversed without leaving any trace on the surroundings. - Both the system and the surroundings are returned to their initial states at the end of the reverse process -W gas gas gas gas A irreversible process -Q - For combined (original and reverse) process, if the net heat and net work exchange between the system and surrounding is zero, then it is a reversible process. Q net = 0 and W net = 0 3
4 Reversible or Irreversible process? Consider a heat reservoir giving up heat to a reversible heat engine, which in turn gives up heat to a piston-cylinder device. From 1 st law of Thermodynamics E E = ΔE in out c δq ( δw + δw ) = de R rev sys c δq δw = de δq T R R c c To prove reversible process, we assume a Q net = 0 R δ = δq = T δq QR TR T 4
5 Reversible or Irreversible process? Now the total work done is For a cycle and the total net work becomes If W c > 0 then a cyclic device exchanging energy with a single heat reservoir and producing an equivalent amount of work Thus, the Kelvin-Planck statement of the second law is violated! Since T R > 0 (absolute temperature), we conclude Here Q is the net heat added to the system, Q net. or This equation is called the Clausius inequality. The equality holds for the reversible process and the inequality holds for the irreversible process. 5
6 Definition of Entropy In the reversed cycle case, all the quantities will have the same magnitude but the opposite sign. Therefore, the work W C, which could not be a positive quantity in the regular case, cannot be a negative quantity in the reversed case. Then W C,int rev = 0 since it cannot be a positive or negative quantity, and therefore for internally reversible cycles. Thus we conclude that the equality in the Clausius inequality holds for totally or just internally reversible cycles and the inequality for the irreversible ones. Clausius (1865) defined entropy, ds δq = T int rev 6
7 Entropy Consider the cycle shown below composed of two reversible processes A and B. Apply the Clausius inequality for this cycle. What do you conclude about these two integrals? P 2 B A 1 A cycle composed of two reversible processes. V Apply the Clausius inequality for the cycle made of two internally reversible processes: 7
8 Entropy You should find: Since the quantity (δq net /T) int rev is independent of the path and must be a property, we call this property the entropy S. The entropy change occurring during a process is related to the heat transfer and the temperature of the system. The entropy change during a reversible process, sometimes called an internally reversible process, is defined as 8
9 Entropy Consider the cycle 1-A-2-B-1, shown below, where process A is arbitrary that is, it can be either reversible or irreversible, and process B is internally reversible. P 2 B A 1 A cycle composed of reversible and irreversible processes. V The integral along the internally reversible path, process B, is the entropy change S 1 S 2. Therefore, 9
10 Entropy or In general the entropy change during a process is defined as where ds Q δ T = holds for the internally reversible process > holds for the irreversible process Consider the effect of heat transfer on entropy for the internally reversible case. net ds Q = δ T Which temperature T is this one? If then ds > net δ Q net > 0 0 δ Q net = 0 then ds = 0 δ < 0 then ds < 0 Q net 10
The Second Law of Thermodynamics
he Second Law of hermodynamics So far We have studied the second law by looking at its results We don t have a thermodynamic property that can describe it In this chapter we will develop a mathematical
More informationCHAPTER 2 THE SECOND LAW OF THERMODYNAMICS Instructor: Prof. Dr. Uğur Atikol
CHAPTER 2 THE SECOND LAW OF THERMODYNAMICS Instructor: Prof. Dr. Uğur Atikol Chapter 2 The Second Law of Thrmodynamics Outline Closed Systems History One-thermal reservoir Reversibility and irreversible
More informationClassical Approach to 2 nd Law for CM
Classical Approach to 2 nd aw for CM Start with observations about the ability to build devices (thermodynamic cycles) Clausius Statement of 2 nd aw concerns cycles that cause heat transfer from low temperature
More informationEquivalence of Kelvin-Planck and Clausius statements
Equivalence of Kelvin-Planck and Clausius statements Violation of Clausius statement Violation of Kelvin-Planck statement Violation of Kelvin-Planck statement Violation of Clausius statement Violation
More informationBasic thermodynamics. heat to the high temperature reservoir.
Consider a heat engine that is operating in a cyclic process takes heat (QH) from a high temperature reservoir & converts completely into work (W), violating the Kelvin Planck statement. Let the work W,
More informationCLAUSIUS INEQUALITY. PROOF: In Classroom
Chapter 7 ENTROPY CLAUSIUS INEQUALITY PROOF: In Classroom 2 RESULTS OF CLAUSIUS INEQUALITY For internally reversible cycles δq = 0 T int rev For irreversible cycles δq < 0 T irr A quantity whose cyclic
More information= for reversible < for irreversible
CHAPER 6 Entropy Copyright he McGraw-Hill Companies, Inc. Permission required for reproduction or display. he Clausius Inequality: δ 0 Cyclic integral his inequality is valid for all cycles, reversible
More informationChapter 7. Entropy: A Measure of Disorder
Chapter 7 Entropy: A Measure of Disorder Entropy and the Clausius Inequality The second law of thermodynamics leads to the definition of a new property called entropy, a quantitative measure of microscopic
More informationChapter 5. The Second Law of Thermodynamics (continued)
hapter 5 he Second Law of hermodynamics (continued) Second Law of hermodynamics Alternative statements of the second law, lausius Statement of the Second Law It is impossible for any system to operate
More informationIntroduction to Aerospace Propulsion. Prof. Bhaskar Roy. Prof. A. M. Pradeep. Department of Aerospace Engineering
Introduction to Aerospace Propulsion Prof. Bhaskar Roy Prof. A. M. Pradeep Department of Aerospace Engineering Indian Institute of Technology, Bombay Module No. # 01 Lecture No. # 11 Reversible and irreversible
More informationChapter 20. Heat Engines, Entropy and the Second Law of Thermodynamics. Dr. Armen Kocharian
Chapter 20 Heat Engines, Entropy and the Second Law of Thermodynamics Dr. Armen Kocharian First Law of Thermodynamics Review Review: The first law states that a change in internal energy in a system can
More informationChapter 7. Entropy. by Asst.Prof. Dr.Woranee Paengjuntuek and Asst. Prof. Dr.Worarattana Pattaraprakorn
Chapter 7 Entropy by Asst.Prof. Dr.Woranee Paengjuntuek and Asst. Prof. Dr.Worarattana Pattaraprakorn Reference: Cengel, Yunus A. and Michael A. Boles, Thermodynamics: An Engineering Approach, 5th ed.,
More informationTHERMODYNAMICS Lecture 5: Second Law of Thermodynamics
HERMODYNAMICS Lecture 5: Second Law of hermodynamics Pierwsza strona Second Law of hermodynamics In the course of discussions on the First Law of hermodynamics we concluded that all kinds of energy are
More informationFree expansion (Joule); Constant U Forced expansion (Joule-Kelvin); Constant H. Joule-Kelvin coefficient - heating or cooling on JK expansion?
...Thermodynamics Adiabats: How c P and c V get into the exponent PV γ Free expansion (Joule); Constant U Forced expansion (Joule-Kelvin); Constant H Joule-Kelvin coefficient - heating or cooling on JK
More informationEntropy and the Second and Third Laws of Thermodynamics
CHAPTER 5 Entropy and the Second and Third Laws of Thermodynamics Key Points Entropy, S, is a state function that predicts the direction of natural, or spontaneous, change. Entropy increases for a spontaneous
More informationLecture 29-30: Closed system entropy balance
ME 200 Thermodynamics I Spring 2016 Lecture 29-30: Closed system entropy balance Yong Li Shanghai Jiao Tong University Institute of Refrigeration and Cryogenics 800 Dong Chuan Road Shanghai, 200240, P.
More informationEntropy and the second law of thermodynamics
Chapter 4 Entropy and the second law of thermodynamics 4.1 Heat engines In a cyclic transformation the final state of a system is by definition identical to the initial state. he overall change of the
More informationReversibility. Processes in nature are always irreversible: far from equilibrium
Reversibility Processes in nature are always irreversible: far from equilibrium Reversible process: idealized process infinitely close to thermodynamic equilibrium (quasi-equilibrium) Necessary conditions
More informationTwo mark questions and answers UNIT II SECOND LAW 1. Define Clausius statement. It is impossible for a self-acting machine working in a cyclic process, to transfer heat from a body at lower temperature
More informationOctober 18, 2011 Carnot cycle - 1
Carnot Cycle In 1824, Sadi Carnot (1796-1832) published a short book, eflections on the Motive Power of Fire (The book is now free online You should try it out) To construct an engine, Carnot noted, at
More informationI.D The Second Law Q C
I.D he Second Law he historical development of thermodynamics follows the industrial revolution in the 19 th century, and the advent of heat engines. It is interesting to see how such practical considerations
More informationReversibility, Irreversibility and Carnot cycle. Irreversible Processes. Reversible Processes. Carnot Cycle
Reversibility, Irreversibility and Carnot cycle The second law of thermodynamics distinguishes between reversible and irreversible processes. If a process can proceed in either direction without violating
More informationME 2322 Thermodynamics I PRE-LECTURE Lesson 23 Complete the items below Name:
Lesson 23 1. (10 pt) Write the equation for the thermal efficiency of a Carnot heat engine below: T η = T 1 L H 2. (10 pt) Can the thermal efficiency of an actual engine ever exceed that of an equivalent
More informationSECOND LAW OF THERMODYNAMICS
SECOND LAW OF THERMODYNAMICS 2 ND Law of Thermodynamics Puts a limitation on the conversion of some forms of energy Determines the scope of an energy conversion and if an energy conversion is possible
More informationT104. c Dr. Md. Zahurul Haq (BUET) Second Law of Thermodynamics ME 201 (2015) 2 / 23 T136
Some Observations in Work & Heat Conversions & Second Law of Thermodynamics Dr. Md. Zahurul Haq Professor Department of Mechanical Engineering Bangladesh University of Engineering & Technology (BUET) Dhaka-1000,
More informationUnit D-2: List of Subjects
ES312 Energy Transfer Fundamentals Unit D: The Second Law of Thermodynamics ROAD MAP... D-1: From First to Second Law D-2: Second Law of Thermodynamics Unit D-2: List of Subjects Second Law of Thermodynamics
More information12 The Laws of Thermodynamics
June 14, 1998 12 The Laws of Thermodynamics Using Thermal Energy to do Work Understanding the laws of thermodynamics allows us to use thermal energy in a practical way. The first law of thermodynamics
More informationEngineering Thermodynamics. Chapter 5. The Second Law of Thermodynamics
5.1 Introduction Chapter 5 The Second aw of Thermodynamics The second law of thermodynamics states that processes occur in a certain direction, not in just any direction. Physical processes in nature can
More informationThermodynamic system is classified into the following three systems. (ii) Closed System It exchanges only energy (not matter) with surroundings.
1 P a g e The branch of physics which deals with the study of transformation of heat energy into other forms of energy and vice-versa. A thermodynamical system is said to be in thermal equilibrium when
More informationThermodynamics: An Engineering Approach Seventh Edition Yunus A. Cengel, Michael A. Boles McGraw-Hill, Chapter 7 ENTROPY
Thermodynamics: An Engineering Approach Seventh Edition Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2011 Chapter 7 ENTROPY Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction
More information1. INTRODUCTION TO REFRIGERATION AND AIR CONDITION
CHAPTER ONE 1. INTRODUCTION TO REFRIGERATION AND AIR CONDITION Refrigeration may be defined as the process of reducing and maintaining a temperature of a space or material below that of the surroundings.
More informationLecture 21: Introducing the Second Law, Irreversibilities
ME 200 Thermodynamics I Spring 2016 Lecture 21: Introducing the Second Law, Irreversibilities Yong Li Shanghai Jiao Tong University Institute of Refrigeration and Cryogenics 800 Dong Chuan Road Shanghai,
More informationChapter 12. The Laws of Thermodynamics
Chapter 12 The Laws of Thermodynamics First Law of Thermodynamics The First Law of Thermodynamics tells us that the internal energy of a system can be increased by Adding energy to the system Doing work
More informationENTROPY. Chapter 7. Mehmet Kanoglu. Thermodynamics: An Engineering Approach, 6 th Edition. Yunus A. Cengel, Michael A. Boles.
Thermodynamics: An Engineering Approach, 6 th Edition Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2008 Chapter 7 ENTROPY Mehmet Kanoglu Copyright The McGraw-Hill Companies, Inc. Permission required
More informationExamples. Fire Piston (demo) Example (Comparison of processes)
Examples Fire Piston (demo) Fire Piston istory http://en.wikipedia.org/wiki/fire_piston Example 19.68 (Comparison of processes) Fire piston calculations http://complex.gmu.edu/www-phys/phys262/soln/fire_piston.pdf
More informationSpring_#7. Thermodynamics. Youngsuk Nam.
Spring_#7 Thermodynamics Youngsuk Nam ysnam1@khu.ac.kr You can t connect the dots looking forward; you can only connect them looking backwards. So you have to trust that the dots will somehow connect in
More informationThermodynamics: An Engineering Approach Seventh Edition in SI Units Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2011.
Thermodynamics: An Engineering Approach Seventh Edition in SI Units Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2011 Chapter 7 ENTROPY Mehmet Kanoglu University of Gaziantep Copyright The McGraw-Hill
More informationSECOND LAW OF THERMODYNAMICS
SECOND LAW OF THERMODYNAMICS 2 ND Law of Thermodynamics Puts a limitation on the conversion of some forms of energy Determines the scope of an energy conversion and if an energy conversion is possible
More informationIrreversible Processes
Irreversible Processes Examples: Block sliding on table comes to rest due to friction: KE converted to heat. Heat flows from hot object to cold object. Air flows into an evacuated chamber. Reverse process
More informationPY2005: Thermodynamics
ome Multivariate Calculus Y2005: hermodynamics Notes by Chris Blair hese notes cover the enior Freshman course given by Dr. Graham Cross in Michaelmas erm 2007, except for lecture 12 on phase changes.
More informationSpring_#8. Thermodynamics. Youngsuk Nam
Spring_#8 Thermodynamics Youngsuk Nam ysnam1@khu.ac.krac kr Ch.7: Entropy Apply the second law of thermodynamics to processes. Define a new property called entropy to quantify the secondlaw effects. Establish
More informationLecture 9. Heat engines. Pre-reading: 20.2
Lecture 9 Heat engines Pre-reading: 20.2 Review Second law when all systems taking part in a process are included, the entropy remains constant or increases. No process is possible in which the total entropy
More informationCARNOT CYCLE = T = S ( U,V )
hermodynamics CANO CYCE Do not trouble students with history In 1824, Sadi Carnot (1796-1832) published a short book, eflections on the Motive Power of Fire (he book is now free online You should try it
More information= for reversible < for irreversible
CAPER 6 Entropy Copyright he McGraw-ill Companies, Inc. Permission required for reproduction or display. he Clausius Inequality: 0 his inequality is valid for all cycles, reversible or irreversible Cycle
More informationBasic Thermodynamics. Prof. S. K. Som. Department of Mechanical Engineering. Indian Institute of Technology, Kharagpur.
Basic Thermodynamics Prof. S. K. Som Department of Mechanical Engineering Indian Institute of Technology, Kharagpur Lecture - 06 Second Law and its Corollaries I Good afternoon, I welcome you all to this
More informationApplied Thermodynamics. Gas Power Cycles
Applied Thermodynamics Gas Power Cycles By: Mohd Yusof Taib Faculty of Mechanical Engineering myusof@ump.edu.my Chapter Description Aims To identify and recognized ideal thermodynamics cycle. To analyze
More informationCHEM Introduction to Thermodynamics Fall Entropy and the Second Law of Thermodynamics
CHEM2011.03 Introduction to Thermodynamics Fall 2003 Entropy and the Second Law of Thermodynamics Introduction It is a matter of everyday observation that things tend to change in a certain direction.
More informationSecond Law of Thermodynamics -
Second Law of Thermodynamics - REVIEW ENTROPY EXAMPLE Dr. Garrick 1/19/09 First Law of Thermodynamics you can t win! First Law of Thermodynamics: Energy cannot be Created or Destroyed the total energy
More informationChapter 19. Heat Engines
Chapter 19 Heat Engines Thermo Processes Eint = Q+ W Adiabatic No heat exchanged Q = 0 and E int = W Isobaric Constant pressure W = P (V f V i ) and E int = Q + W Isochoric Constant Volume W = 0 and E
More informationChapter 1: FUNDAMENTAL CONCEPTS OF THERMODYNAMICS AND VARIOUS THERMODYMIC PROCESSES
Chapter 1: FUNDAMENTAL CONCEPTS OF THERMODYNAMICS AND VARIOUS THERMODYMIC PROCESSES Thermodynamics is that branch of science which deals with energy transfer A system may be closed, open or isolated system
More informationHeat What is heat? Work = 2. PdV 1
eat What is heat? eat (Q) is the flow or transfer of energy from one system to another Often referred to as heat flow or heat transfer Requires that one system must be at a higher temperature than the
More informationCHAPTER 7 ENTROPY. Copyright Hany A. Al-Ansary and S. I. Abdel-Khalik (2014) 1
CHAPTER 7 ENTROPY S. I. Abdel-Khalik (2014) 1 ENTROPY The Clausius Inequality The Clausius inequality states that for for all cycles, reversible or irreversible, engines or refrigerators: For internally-reversible
More informationEntropy and the Second Law of Thermodynamics
Entropy and the Second Law of Thermodynamics Reading Problems 7-1 7-3 7-88, 7-131, 7-135 7-6 7-10 8-24, 8-44, 8-46, 8-60, 8-73, 8-99, 8-128, 8-132, 8-1 8-10, 8-13 8-135, 8-148, 8-152, 8-166, 8-168, 8-189
More information1. Second Law of Thermodynamics
1. Second Law of hermodynamics he first law describes how the state of a system changes in response to work it performs and heat absorbed. he second law deals with direction of thermodynamic processes
More informationDepartment of Mechanical Engineering ME 322 Mechanical Engineering Thermodynamics. Introduction to 2 nd Law and Entropy.
Department of Mechanical Engineering ME 322 Mechanical Engineering hermodynamics Introduction to 2 nd aw and Entropy ecture 18 Example Consider an adiabatic compressor steadily moving R125, P2 2 430 psia
More informationSOLUTION: Consider the system to be the refrigerator (shown in the following schematic), which operates over a cycle in normal operation.
Soln_21 An ordinary household refrigerator operating in steady state receives electrical work while discharging net energy by heat transfer to its surroundings (e.g., the kitchen). a. Is this a violation
More informationChapter 12 Thermodynamics
Chapter 12 Thermodynamics 12.1 Thermodynamic Systems, States, and Processes System: definite quantity of matter with real or imaginary boundaries If heat transfer is impossible, the system is thermally
More informationWhere F1 is the force and dl1 is the infinitesimal displacement, but F1 = p1a1
In order to force the fluid to flow across the boundary of the system against a pressure p1, work is done on the boundary of the system. The amount of work done is dw = - F1.dl1, Where F1 is the force
More informationT s change via collisions at boundary (not mechanical interaction)
Lecture 14 Interaction of 2 systems at different temperatures Irreversible processes: 2nd Law of Thermodynamics Chapter 19: Heat Engines and Refrigerators Thermal interactions T s change via collisions
More informationChapter 12. The Laws of Thermodynamics. First Law of Thermodynamics
Chapter 12 The Laws of Thermodynamics First Law of Thermodynamics The First Law of Thermodynamics tells us that the internal energy of a system can be increased by Adding energy to the system Doing work
More informationChapter 16 Thermodynamics
Nicholas J. Giordano www.cengage.com/physics/giordano Chapter 16 Thermodynamics Thermodynamics Introduction Another area of physics is thermodynamics Continues with the principle of conservation of energy
More informationThermodynamic entropy
1 1.1 Thermodynamics and entropy The existence of entropy follows inevitably from the first and second laws of thermodynamics. However, our purpose is not to reproduce this deduction, but rather to focus
More informationChapter 16 The Second Law of Thermodynamics
Chapter 16 The Second Law of Thermodynamics To examine the directions of thermodynamic processes. To study heat engines. To understand internal combustion engines and refrigerators. To learn and apply
More informationLecture 26. Second law of thermodynamics. Heat engines and refrigerators.
ecture 26 Second law of thermodynamics. Heat engines and refrigerators. The Second aw of Thermodynamics Introduction The absence of the process illustrated above indicates that conservation of energy is
More informationTHERMODYNAMICS NOTES. These notes give a brief overview of engineering thermodynamics. They are based on the thermodynamics text by Black & Hartley.
THERMODYNAMICS NOTES These notes give a brief overview of engineering thermodynamics. They are based on the thermodynamics text by Black & Hartley. Topics covered include: concepts; properties; conservation
More informationChapter 6. Using Entropy
Chapter 6 Using Entropy Learning Outcomes Demonstrate understanding of key concepts related to entropy and the second law... including entropy transfer, entropy production, and the increase in entropy
More informationThe Limits of Efficiency. The Limits of Efficiency. The Limits of Efficiency
The Limits of Efficiency If a perfectly reversible heat engine is used to operate a perfectly reversible refrigerator, the two devices exactly cancel each other. 2017 Pearson Education, Inc. Slide 20-1
More information2. Describe the second law in terms of adiabatic and reversible processes.
Lecture #3 1 Lecture 3 Objectives: Students will be able to: 1. Describe the first law in terms of heat and work interactions.. Describe the second law in terms of adiabatic and reversible processes. 3.
More informationThermodynamic Systems, States, and Processes
Thermodynamics Thermodynamic Systems, States, and Processes A thermodynamic system is described by an equation of state, such as the ideal gas law. The location of the state can be plotted on a p V diagram,
More informationLecture Notes Set 4c: Heat engines and the Carnot cycle
ecture Notes Set 4c: eat engines and the Carnot cycle Introduction to heat engines In the following sections the fundamental operating principles of the ideal heat engine, the Carnot engine, will be discussed.
More informationConsequences of Second Law of Thermodynamics. Entropy. Clausius Inequity
onsequences of Second Law of hermodynamics Dr. Md. Zahurul Haq Professor Department of Mechanical Engineering Bangladesh University of Engineering & echnology BUE Dhaka-000, Bangladesh zahurul@me.buet.ac.bd
More informationAljalal-Phys March 2004-Ch21-page 1. Chapter 21. Entropy and the Second Law of Thermodynamics
Aljalal-Phys.102-27 March 2004-Ch21-page 1 Chapter 21 Entropy and the Second Law of hermodynamics Aljalal-Phys.102-27 March 2004-Ch21-page 2 21-1 Some One-Way Processes Egg Ok Irreversible process Egg
More informationHeat Engines and the Second Law of Thermodynamics
Heat Engines and the Second Law of hermodynamics here are three equivalent forms of the second law of thermodynamics; will state all three, discuss: I. (Kelvin-Planck) It is impossible to construct an
More informationPhysics 150. Thermodynamics. Chapter 15
Physics 150 Thermodynamics Chapter 15 The First Law of Thermodynamics Let s consider an ideal gas confined in a chamber with a moveable piston If we press the piston è the gas in the chamber compresses
More information1. Second Law of Thermodynamics
1. Second Law of hermodynamics he first law describes how the state of a system changes in response to work it performs and heat absorbed. However, the first law cannot explain certain facts about thermal
More informationChemistry 163B Refrigerators and Generalization of Ideal Gas Carnot (four steps to exactitude) E&R pp 86-91, Raff pp.
statements of the Second Law of hermodynamics Chemistry 163B Refrigerators and Generalization of Ideal Gas Carnot (four steps to exactitude) E&R pp 86-91, 109-111 Raff pp. 159-164 1. Macroscopic properties
More informationThermodynamics Second Law Heat Engines
Thermodynamics Second Law Heat Engines Lana Sheridan De Anza College May 10, 2018 Last time entropy (microscopic perspective) Overview heat engines heat pumps Carnot engines Heat Engines Steam engines
More informationLecture 2 Entropy and Second Law
Lecture 2 Entropy and Second Law Etymology: Entropy, entropie in German. En from energy and trope turning toward Turning to energy Motivation for a Second Law!! First law allows us to calculate the energy
More informationHeat Machines (Chapters 18.6, 19)
eat Machines (hapters 8.6, 9) eat machines eat engines eat pumps The Second Law of thermodynamics Entropy Ideal heat engines arnot cycle Other cycles: Brayton, Otto, Diesel eat Machines Description The
More informationAdiabatic Expansion (DQ = 0)
Adiabatic Expansion (DQ = 0) Occurs if: change is made sufficiently quickly and/or with good thermal isolation. Governing formula: PV g = constant where g = C P /C V Adiabat P Isotherms V Because PV/T
More informationMAE 320 HW 7B. 1e. For an isolated system, please circle the parameter which will change with time. (a) Total energy;
MAE 320 HW 7B his comprehensive homework is due Monday, December 5 th, 206. Each problem is worth the points indicated. Copying of the solution from another is not acceptable. Multi-choice, multi-answer
More informationConsequences of Second Law of Thermodynamics. Entropy. Clausius Inequity
onsequences of Second Law of hermodynamics Dr. Md. Zahurul Haq Professor Department of Mechanical Engineering Bangladesh University of Engineering & echnology BUE Dhaka-000, Bangladesh zahurul@me.buet.ac.bd
More informationV. The Second Law of Thermodynamics. V. The Second Law of Thermodynamics
P V. he Second aw of hermodynamics E. he Carnot Cycle. he reversible heat engine (a piston cylinder device) that operates on a cycle between heat reservoirs at and, as shown below on a P-v diagram, is
More informationw = -nrt hot ln(v 2 /V 1 ) nrt cold ln(v 1 /V 2 )[sincev/v 4 3 = V 1 /V 2 ]
Chemistry 433 Lecture 9 Entropy and the Second Law NC State University Spontaneity of Chemical Reactions One might be tempted based on the results of thermochemistry to predict that all exothermic reactions
More informationChapter 2 Thermodynamics
Chapter 2 Thermodynamics 2.1 Introduction The First Law of Thermodynamics is a statement of the existence of a property called Energy which is a state function that is independent of the path and, in the
More informationPhysics 207 Lecture 27. Lecture 26. Chapters 18, entropy and second law of thermodynamics Chapter 19, heat engines and refrigerators
Goals: Lecture 26 Chapters 18, entropy and second law of thermodynamics Chapter 19, heat engines and refrigerators Reading assignment for Wednesday: Chapter 20. Physics 207: Lecture 27, Pg 1 Entropy A
More informationChemistry 163B Winter 2013 Clausius Inequality and ΔS ideal gas
Chemistry 163B q rev, Clausius Inequality and calculating ΔS for ideal gas,, changes (HW#5) Challenged enmanship Notes 1 statements of the Second Law of hermodynamics 1. Macroscopic properties of an isolated
More informationSurvey of Thermodynamic Processes and First and Second Laws
Survey of Thermodynamic Processes and First and Second Laws Please select only one of the five choices, (a)-(e) for each of the 33 questions. All temperatures T are absolute temperatures. All experiments
More informationThermodynamics II. Week 9
hermodynamics II Week 9 Example Oxygen gas in a piston cylinder at 300K, 00 kpa with volume o. m 3 is compressed in a reversible adiabatic process to a final temperature of 700K. Find the final pressure
More informationLaws of Thermodynamics
Laws of Thermodynamics The Three Laws of Thermodynamics - The first lawof thermodynamics, also called conservation of energy. We can use this knowledge to determine the amount of energy in a system, the
More informationChapter 19. Heat Engines
Chapter 19 Heat Engines QuickCheck 19.11 The efficiency of this Carnot heat engine is A. Less than 0.5. B. 0.5. C. Between 0.5 and 1.0. D. 2.0. E. Can t say without knowing Q H. 2013 Pearson Education,
More informationClassification following properties of the system in Intensive and Extensive
Unit I Classification following properties of the system in Intensive and Extensive Extensive : mass, weight, volume, potential energy, Kinetic energy, Internal energy, entropy, exergy, energy, magnetization
More informationc Dr. Md. Zahurul Haq (BUET) Entropy ME 203 (2017) 2 / 27 T037
onsequences of Second Law of hermodynamics Dr. Md. Zahurul Haq Professor Department of Mechanical Engineering Bangladesh University of Engineering & echnology BUE Dhaka-000, Bangladesh zahurul@me.buet.ac.bd
More informationReversible Processes. Furthermore, there must be no friction (i.e. mechanical energy loss) or turbulence i.e. it must be infinitely slow.
Reversible Processes A reversible thermodynamic process is one in which the universe (i.e. the system and its surroundings) can be returned to their initial conditions. Because heat only flows spontaneously
More information第 1 頁, 共 6 頁 Chap20 1. Test Bank, Question 5 Which of the following is NOT a state variable? Work Internal energy Entropy Temperature Pressure 2. Test Bank, Question 18 Let denote the change in entropy
More informationClassical thermodynamics
Classical thermodynamics More about irreversibility chap. 6 Isentropic expansion of an ideal gas Sudden expansion of a gas into vacuum cf Kittel and Kroemer end of Cyclic engines cf Kittel and Kroemer
More information(1)5. Which of the following equations is always valid for a fixed mass system undergoing an irreversible or reversible process:
Last Name First Name ME 300 Engineering Thermodynamics Exam #2 Spring 2008 March 28, 2008 Form A Note : (i) (ii) (iii) (iv) Closed book, closed notes; one 8.5 x 11 sheet allowed. 60 points total; 60 minutes;
More informationMinimum Bias Events at ATLAS
Camille Bélanger-Champagne McGill University Lehman College City University of New York Thermodynamics Charged Particle and Statistical Correlations Mechanics in Minimum Bias Events at ATLAS Thermodynamics
More informationChapter 20 Entropy and the 2nd Law of Thermodynamics
Chapter 20 Entropy and the 2nd Law of Thermodynamics A one-way processes are processes that can occur only in a certain sequence and never in the reverse sequence, like time. these one-way processes are
More informationMore Thermodynamics. Specific Specific Heats of a Gas Equipartition of Energy Reversible and Irreversible Processes
More Thermodynamics Specific Specific Heats of a Gas Equipartition of Energy Reversible and Irreversible Processes Carnot Cycle Efficiency of Engines Entropy More Thermodynamics 1 Specific Heat of Gases
More information