Lipidic Protic Ionic Liquid Crystals

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1 SUPPORTING INFORMATION Lipidic Protic Ionic Liquid Crystals Guilherme J. Maximo, Ricardo J. B. N. Santos, José A. Lopes-da-Silva, Mariana C. Costa, Antonio J. A. Meirelles and João A. P. Coutinho* Laboratory of Extraction, Applied Thermodynamics and Equilibrium, School of Food Engineering, University of Campinas, , Campinas, São Paulo, Brazil. CICECO, Chemistry Department, University of Aveiro, , Aveiro, Portugal. QOPNA, Chemistry Department, University of Aveiro, , Aveiro, Portugal. School of Applied Sciences, University of Campinas, , Limeira, São Paulo, Brazil. PAGES: 6 FIGURES: 1 TABLES: 4 S1

2 SUPPORTING INFORMATION H eut / kj mol x fatty acid Figure S1. Tammann plots of the eutectic transitions H eut in the ethanolamine-rich region (x = 0.0 to 0.5 fatty acid molar fraction) and in the fatty acid-rich region (x = 0.5 to 1.0 fatty acid molar fraction) of the (+) oleic acid + monoethanolamine, ( ) oleic acid + diethanolamine, ( ) stearic acid + monoethanolamine and ( ) stearic acid + diethanolamine systems. Solid lines are linear fitting of the data (R 2 > 0.95 considering that y = 0.0 at the pure compounds concentration). Dashed lines are supposed plots close to pure component concentration. ( ) Diethanolamine and ( ) monoethanolamine melting enthalpy for analysis purpose. S2

3 Table S1. Experimental solid-liquid equilibrium data for oleic acid + ethanolamine systems for molar fraction x, temperature T and pressure p = kpa. oleic acid (1) + monoethanolamine (2) oleic acid (1) + diethanolamine (2) x 1 T eut / K T 1 / K T m / K T LCm / K x 1 T eut / K T 1 / K T 2 / K T m / K T LCm / K T eut is the temperature of the eutectic transition, T 1 and T 2 are the temperatures of the other invariant transitions, T m is the melting temperature (liquidus line) and T LCm is the melting of the liquid crystal. Uncertainties for molar fraction and pressure are ± and ± 0.5 kpa, respectively. Uncertainty for temperatures T eut, T 1, T 2, T m is ± 0.4 K and for temperature T LCm is ± 1.0 K. S3

4 Table S2. Experimental solid-liquid equilibrium data for stearic acid + ethanolamine systems for mole fraction x, temperature T and pressure p = kpa. stearic acid (1) + monoethanolamine (2) stearic acid (1) + diethanolamine (2) x 1 T eut / K T m / K T LCm / K x 1 T eut / K T 1 / K T m / K T LCm / K T eut is the temperature of the eutectic transition, T 1 is the temperature of the other invariant transitions, T m is the melting temperature (liquidus line) and T LCm is the melting of the liquid crystal. Uncertainties for molar fraction and pressure are ± and ± 0.5 kpa, respectively. Uncertainty for temperatures T eut, T 1, T 2, T m is ± 0.4 K and for temperature T LCm is ± 1.0 K. S4

5 Table S3. Rheological models parameters related to shear stress / shear rate curves fitted to flow experimental data for the monoethanolammonium oleate T / K σ 0 / Pa K n R 2 model Bingham plastic Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Vocadlo Newtonian Newtonian Newtonian K V for Vocadlo model, η for Bingham plastic model and η for Newtonian model. n V for Vocadlo model. S5

6 Table S4. Rheological models parameters related to shear stress / shear rate curves fitted to flow experimental data for the diethanolammonium oleate T / K σ 0 / Pa K n R 2 model H-B H-B H-B Shear thinning Shear thinning Shear thinning Shear thinning Newtonian Newtonian Newtonian Newtonian Newtonian Newtonian Newtonian Newtonian K for shear-thinning model, K H for H-B model and η for Newtonian model. n for shear-thinning model and n H for H-B model. S6

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