AMBIENT AIR MONITORING MONTHLY DATA REPORT

Transcription

1 MAXXAM ANALYTICS # Ave. NE, Calgary, AB T2E 6P7 maxxam.ca Toll Free Fax AMBIENT AIR MONITORING MONTHLY DATA REPORT PEACE RIVER AREA MONITORING PROGRAM COMMITTEE RENO STATION JOB #: C January 2017 Prepared for: PEACE RIVER AREA MONITORING PROGRAM COMMITTEE ST NW CALGARY, ALBERTA T2N 2J1 Attention: Karla Reesor DATE: March 03, 2017 Prepared by: Wunmi Adekanmbi, M.Sc., EPt. Project Manager, Customer Service, Air Services Reviewed by: Cheri Sinclair, B.Sc. Supervisor, Customer Service, Air Services

2 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SUMMARY In January 2016, Maxxam Analytics was contracted to manage the ambient air quality monitoring and maintenance activities at the Reno Station, near Peace River Oil Sands Area 1, Alberta. The monitoring station provides continuous meteorological measurements and air quality data for non-compliance parameters, as requested by the PRAMP Committee. All data collected this month was compliant with the requirements outlined in the Air Monitoring Directive (Alberta Environment and Parks, 2016). The operational time for all continuous ambient air analyzers, meteorological systems and data acquisition systems were above the 90% requirement. SO 2 : Three hours of downtime were recorded this month. The analyzer exhibited a biased high span response, prompting additional quality checks. TRS: Three hours of downtime were recorded this month. The analyzer exhibited a biased low response on January 2 and a biased high span response on January 19, prompting additional quality checks. The summary of results is presented on the following pages. Any deviations or modifications made to the sampling or analytical methods are outlined in Section 1.0, Discussion. On this basis, Maxxam Analytics is issuing this completed report to Peace River Area Monitoring Program Committee, Reno Station. Should you have any questions concerning the results or if we can be of further assistance, please contact us at or toll-free at JOB #: C Page 1 of 102

3 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 Monthly Continuous Data Summary Peace River Area Monitoring Program Committee Reno Station PARAMETER SO₂ (ppb) TRS (ppb) THC (ppm) CH₄ (ppm) NMHC (ppm) RELATIVE HUMIDITY (%) BAROMETRIC PRESSURE (inhg) AMBIENT TEMPERATURE ( C) STATION TEMPERATURE ( C) VECTOR WS (kph) VECTOR WD (deg) VAR-VARIOUS OBJECTIVES 1-hr 24-hr 1-hr 24-hr S SW (SW) N 11.8 DAY S OPERATIONAL TIME (%) S S EXCEEDANCES 0 0 MONTHLY AVERAGE , 20 VAR, VAR VAR VAR VAR VAR N N HOUR READING DAY HOUR 15 MAXIMUM VALUES WIND SPEED (kph) WIND DIRECTION (sector) N READING HOUR JOB #: C Page 2 of 102

4 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SOUR GAS PROCESSING INDUSTRY MONTHLY REPORT SUMMARY Reno Station Plant Name / Location Peace River Area Monitoring Program Committee Company Report Date Licence Number YEAR MONTH N/A 2017 January CONTINUOUS AMBIENT MONITORING ONE - HOUR AVERAGE PARAMETER STN No. % TIME OPERATIONAL MAXIMUM VALUES NO. READINGS > REGULATION SO₂ ppm ppm 0 TRS ppm ppm - THC ppm ppm - CH₄ ppm ppm - NMHC ppm ppm - RH % - 90 % - BP inhg inhg - Ambient TPX C C - Station TPX C C - Wind Speed kph kph Wind Direction HOUR AVERAGE NO. READINGS > MAXIMUM VALUES REGULATION FOR ALBERTA ENVIRONMENT USE ONLY - - SIGNATURE OF COMPANY REPRESENTATIVE JOB #: C Page 3 of 102

5 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 Exceedance Summary Report SO 2 1-Hour Exceedances Measured concentrations of sulphur dioxide were below the 1-hour AAAQO of 172 ppb. SO 2 24-Hour Exceedances Measured concentrations of sulphur dioxide were below the 24-hour AAAQO of 48.0 ppb. In accordance with EPEA and the Substance Release Regulation. In accordance with A Guide to Release Reporting and the Alberta Ambient Air Quality Objectives and Guidelines Summary. JOB #: C Page 4 of 102

6 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TABLE OF CONTENTS Title Page SUMMARY 1 MONTHLY CONTINUOUS DATA SUMMARY REPORT 2 SOUR GAS SUMMARY REPORT 3 EXCEEDANCE SUMMARY REPORT 4 TABLE OF CONTENTS Discussion Project Personnel Plant Monthly Required AMD Summary Calculations and Results Methods and Procedures 9 Appendix I Continuous Monitoring Data Results 12 Sulphur Dioxide 13 Total Reduced Sulphur 21 Total Hydrocarbon 29 Methane 37 Non-Methane Hydrocarbon 45 Wind Speed 53 Wind Direction 60 Relative Humidity 63 Barometric Pressure 66 Ambient Temperature 69 Station Temperature 72 Appendix II Equipment Calibration Results 75 Sulphur Dioxide 76 Total Reduced Sulphur 81 Total Hydrocarbon 86 Wind System 90 Calibrators 92 Calibration Gases 95 Appendix III Report Certification Form 99 Appendix IV Data Validation Certification Form 101 JOB #: C Page 5 of 102

7 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January Discussion This monthly report consists of continuous monitoring results for the following parameters: Sulphur Dioxide (SO ₂ ), Total Reduced Sulphur (TRS), Total Hydrocarbon (THC), Methane (CH ₄ ), Non-Methane Hydrocarbon (NMHC), Relative Humidity (RH), Barometric Pressure (BP), Ambient Temperature (AmbTPX), Station Temperature (StnTPX), Wind Speed (WS) and Wind Direction (WD). Sample filters for all continuous air monitors are changed before the calibration begins. The sample manifold is cleaned during the site visit each month. Control checks, consisting of a zero and span, are conducted daily on all continuous air monitors. In place of the air sample, zero air (from scrubbed air or gas cylinders) is used for zero checks, and a known concentration of the pollutant being analyzed is used for span checks. These checks are controlled by automatic timers and valves. The total zero span cycle is completed within an hour, the commencement of the zero span cycle is at the beginning of the hour. Multipoint calibrations are done a minimum of once a month for each continuous air monitor. An additional calibration is required under the following conditions: 1) within three days after the initial start-up and stabilization of a newly installed instrument, 2) prior to shut-down or moving of an instrument which has been working to specification, and 3) when major repair has been done on the instrument. Time during the first multi-point calibration is not considered downtime (Data is flagged as C). If more than one calibration is performed during the month, the time during the additional calibration is considered as downtime (Data is flagged as C1). Only one zero/span check is run per day. Time during the zero/span check is not considered as downtime (Data is flagged as S). If an extra zero/span check is performed, the time during the additional check is considered as downtime (Data is flagged as S1). The AMD requires each instrument and accompanying data recording system to be operational 90% of the time, at a minimum, for each monthly monitoring period. All sampling, analysis, and QA/QC for this project was performed by Maxxam Analytics and complies with the Alberta Air Monitoring Directive. Data contained in this monthly report has undergone the verification and validation based on the requirements of the AMD Chapter 6: Ambient Data Quality (August 3, 2016). The descriptions of the data verification and validation process can be found in Section 5 of this report. Instantaneous data, where applicable, is provided for reference purposes and has not undergone zero correction. Hourly/minute data have been reviewed based on daily zero/span results and multi-point calibration results. Data may be considered invalid if a zero-corrected span check in excess of +/- 10% of the span concentration (established by the previous multi-point calibration) is encountered and/or significant differences in the calibration factor occurs (greater than 10%). JOB #: C Page 6 of 102

8 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SULPHUR DIOXIDE (SO₂) The routine monthly calibration was performed on January 3. The analyzer spanned within 75% of the upper acceptance limit on January 17. An additional zero/span check, conducted on January 18, confirmed the drift. An as-found response check was completed on January 20 to assess analyzer performance; and the results met AMD, 2016 requirements. No data was discarded due this event, however, three hours of downtime were recorded due to the additional quality checks. TOTAL REDUCED SULPHUR (TRS) The analyzer spanned towards the lower acceptance limit on January 1. A repeat zero/span check was triggered on January 2 and the result was outside acceptance limits. This prompted a site visit on January 3, where a successful routine monthly calibration was performed. The analyzer spanned within 75% of the upper acceptance limit on January 19. An as-found response check was conducted on January 20 to assess analyzer performance; and the results met AMD, 2016 requirements. No data was discarded due these events, however, three hours of downtime were recorded due to the additional quality checks. TOTAL HYDROCARBONS (THC), METHANE (CH₄) and NON-METHANE HYDROCARBONS (NMHC) The routine monthly calibration was performed on January 3. The fuel gas cylinder was replaced during this visit. The channels were placed in "maintenance" mode for some minutes on January 20, while the fuel gas cylinder was being replaced. This caused the invalidation of maximum instantaneous data collected at hours 17:00 and 18:00. Hourly averages were not impacted. The canister sampler is programmed to draw in a whole air sample when the 5-minute average concentration of NMHC is above 0.30 ppm. A representative sample of ambient air is collected over a one-hour period when the canister event is triggered. No canister event was recorded this month. WIND SPEED (WS) AND WIND DIRECTION (WD) The wind system was working well throughout the month. Wind data is reported as vector wind speed and vector wind direction. Wind direction is defined as the direction from which the wind is blowing from and is measured in degrees from true north. No operational issues were identified this month. RELATIVE HUMIDITY (RH) No operational issues were identified this month. BAROMETRIC PRESSURE (BP) No operational issues were identified this month. AMBIENT TEMPERATURE (AmbTPX) No operational issues were identified this month. STATION TEMPERATURE (StnTPX) No operational issues were identified this month. JOB #: C Page 7 of 102

9 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January Project Personnel Karla Reesor was the contact for Peace River Area Monitoring Program Committee and the Maxxam field technician was Raja Ashraf. 3.0 Plant Monthly Required AMD Summary All data collected this month was compliant with the requirements outlined in the Air Monitoring Directive (Alberta Environment and Parks, 2016). The operational time for all continuous ambient air analyzers, meteorological systems and data acquisition systems were above the 90% requirement. 4.0 Calculations and Results All calculations and reporting of results follow the methods described in the AMD, JOB #: C Page 8 of 102

10 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January Methods and Procedures The following methods and procedures were used to complete the monitoring program: Maxxam AIR SOP Methane, Non-Methane Hydrocarbon Analyzer Monitoring Maxxam AIR SOP-00208: RM Young Wind Monitor Calibration Maxxam AIR SOP-00209: Ambient Sulphur Monitoring There were no deviations from the prescribed methods. The following instruments were used to perform the test program: Sulphur Dioxide - API 100A UV Flourescent Analyzer Total Reduced Sulphur - Thermo 450i UV Flourescent Analyzer Methane, Non-Methane Hydrocarbon - Thermo 55i FID Analyzer Wind System - RM Young Unit Relative Humidity - Met One Unit Barometric Pressure - Met One Unit Ambient Temperature - Met One Unit Datalogger - ESC 8832 JOB #: C Page 9 of 102

11 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 The following steps were used to complete the data verification and validation process: Level 0 Preliminary Verification Level 0 data are raw data obtained directly from the data acquisition system (DAS). Under the step of Level 0, these data undergo a certain amount of manual or automated screening and flagging. It included a) identification of periods of missing data; b) verification of time stamps against reference time; c) verification that instrument diagnostics/datalogger flags indicate normal operation; d) comparison of data to upper and lower limits; e) rate of change flagging indicating that data changed too rapidly or not at all; and f) verification that zero, span and multipoint performance checks are within specifications. This level of verification is performed on a daily basis. Level 1 Primary Validation Validation actions under the step of Level 1 include a) review of all screening flags assigned during preliminary verification; b) review of all supporting site information and documentation; c) review of operational acceptance limits for each parameter/analyzer; d) review of daily zero/span and monthly calibration results for all gaseous parameters; and e) application of any necessary adjustments to data (e.g. baseline adjustments, below zero adjustments). This level of validation is performed on a monthly basis. Level 2 Final Validation The purpose of Level 2 validation is to verify that there are no inconsistencies among related data, or among regional data measured at nearby sites. Level 3 Independent Data Review Level 3 validation is the last step of data review, and it is completed by an individual that is independent of both field operations and primary data validation. A final independent QA review and endorsement is performed during this step before data is submitted to Alberta Environment. Post-Final Validation The Post-Final Validation step serves to re-evaluate the data that errors or omissions are discovered and/or suspected after the initial submittal of data. Any data issues or patterns which were not clear on a monthly basis are highlighted during this step. This validation is performed on an annual basis. JOB #: C Page 10 of 102

12 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 Source: Air Monitoring Directive (Aug 3, 2016), Chapter 6, Ambient Data Quality; Figure 1 Data Collection and Management Process Flow Chart JOB #: C Page 11 of 102

13 APPENDIX I CONTINUOUS MONITORING DATA RESULTS JOB #: C Page 12 of 102

14 SULPHUR DIOXIDE JOB #: C Page 13 of 102

15 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SULPHUR DIOXIDE Hourly Averages (SO₂ ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C S S S S S S S S S S S S S S S S S S C1 C1 0.0 S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE OBJECTIVE LIMIT: ALBERTA ENVIRONMENT: 1-HR 172 ppb 24-HR 48 ppb C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR MONTHLY SUMMARY S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE NUMBER OF 1-HR EXCEEDANCES: 0 NUMBER OF 24-HR EXCEEDANCES: 0 24 HR AVERAGES January 2017 NUMBER OF NON-ZERO READINGS: 115 MINIMUM 1-HR AVERAGE 0.0 HOUR(S) VAR ON DAY(S) ALL MAXIMUM 1-HR AVERAGE: 0.9 HOUR(S) 8 ON DAY(S) 2 MAXIMUM 24-HR AVERAGE: 0.3 ppb ON DAY(S) VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 741 hrs MONTHLY CALIBRATION TIME: 4 hrs AMD OPERATION UPTIME: 99.6 % STANDARD DEVIATION: 0.1 MONTHLY AVERAGE: 0.0 ppb JOB #: C Page 14 of 102

16 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SULPHUR DIOXIDE Hourly Averages (SO₂ ppb) 10.0 SO₂ 1hrAve (ppb) AAAQO (172 ppb) SO₂ (ppb) AAAQO 1-Hr Averaging Period Day 0 JOB #: C Page 15 of 102

17 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SULPHUR DIOXIDE Instantaneous Maximum (SO₂ ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C C S S S S S S S S S S S S S S S S1 S S S C1 C1 1.1 S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 347 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 1.7 HOUR(S) VAR, 9 ON DAY(S) 2, 11 VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 740 hrs MONTHLY CALIBRATION TIME: 5 hrs STANDARD DEVIATION: 0.4 JOB #: C Page 16 of 102

18 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 SULPHUR DIOXIDE Instantaneous Maximum (SO₂ ppb) 10.0 SO₂ InsMax (ppb) SO₂ max (ppb) Day JOB #: C Page 17 of 102

19 Wind: PRAMP RENO TRAILER Poll.: PRAMP RENO TRAILER-SO2[ppb] Monthly: 01/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr Calm: 8.95% Valid Data: 94.62% Calm Avg: 0.08 [ppb] Direction >170.0 Total N NE E SE S SW W NW Summary JOB #: C Page 18 of 102

20 JOB #: C Page 19 of 102

21 JOB #: C Page 20 of 102

22 TOTAL REDUCED SULPHUR JOB #: C Page 21 of 102

23 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL REDUCED SULPHUR Hourly Averages (TRS ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S S C C C C C C S S S S S S S S S S S S S S S S S C1 C1 0.2 S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE HR AVERAGES January MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 604 MINIMUM 1-HR AVERAGE 0.0 HOUR(S) VAR ON DAY(S) VAR MAXIMUM 1-HR AVERAGE: 1.5 HOUR(S) 18 ON DAY(S) 17 MAXIMUM 24-HR AVERAGE: 0.6 ppb ON DAY(S) VAR-VARIOUS 18 IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 741 hrs MONTHLY CALIBRATION TIME: 6 hrs AMD OPERATION UPTIME: 99.6 % STANDARD DEVIATION: 0.2 MONTHLY AVERAGE: 0.2 ppb JOB #: C Page 22 of 102

24 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL REDUCED SULPHUR Hourly Averages (TRS ppb) 5.0 TRS 1hrAve (ppb) TRS (ppb) Day JOB #: C Page 23 of 102

25 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL REDUCED SULPHUR Instantaneous Maximum (TRS ppb) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S1 S S C C C C C C C C S S S S S S S S S S S S S S S S S C1 C1 0.2 S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 654 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 1.4 HOUR(S) 18 ON DAY(S) 17 VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 740 hrs MONTHLY CALIBRATION TIME: 8 hrs STANDARD DEVIATION: 0.3 JOB #: C Page 24 of 102

26 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL REDUCED SULPHUR Instantaneous Maximum (TRS ppb) TRS InsMax (ppb) TRS max (ppb) Day JOB #: C Page 25 of 102

27 Wind: PRAMP RENO TRAILER Poll.: PRAMP RENO TRAILER-TRS[ppb] Monthly: 01/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 8.70% Valid Data: 94.22% Calm Avg: 0.23 [ppb] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 26 of 102

28 JOB #: C Page 27 of 102

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30 TOTAL HYDROCARBON JOB #: C Page 29 of 102

31 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL HYDROCARBONS Hourly Averages (THC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C S S S S S S S S S S S S S S S S S S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 709 MINIMUM 1-HR AVERAGE 1.87 HOUR(S) VAR, VAR ON DAY(S) 14, 15 MAXIMUM 1-HR AVERAGE: 3.35 HOUR(S) 22 ON DAY(S) 25 MAXIMUM 24-HR AVERAGE: 2.24 ppm ON DAY(S) VAR-VARIOUS 25 IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 744 hrs MONTHLY CALIBRATION TIME: 4 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.18 MONTHLY AVERAGE: 2.01 ppm JOB #: C Page 30 of 102

32 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL HYDROCARBONS Hourly Averages (THC ppm) THC 1hrAve (ppm) THC (ppm) Day JOB #: C Page 31 of 102

33 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL HYDROCARBONS Instantaneous Maximum (THC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C C C S S S S S S S S S S S S S S S S S Y Y S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 705 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 5.32 HOUR(S) 1 ON DAY(S) 26 VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 742 hrs MONTHLY CALIBRATION TIME: 6 hrs STANDARD DEVIATION: 0.45 JOB #: C Page 32 of 102

34 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 TOTAL HYDROCARBONS Instantaneous Maximum (THC ppm) THC InsMax (ppm) THC max (ppm) Day JOB #: C Page 33 of 102

35 Wind: PRAMP RENO TRAILER Poll.: PRAMP RENO TRAILER-THC[ppm] Monthly: 01/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 8.79% Valid Data: 94.76% Calm Avg: 2.16 [ppm] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 34 of 102

36 JOB #: C Page 35 of 102

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38 METHANE JOB #: C Page 37 of 102

39 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 METHANE Hourly Averages (CH₄ ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C S S S S S S S S S S S S S S S S S S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 709 MINIMUM 1-HR AVERAGE 1.87 HOUR(S) VAR, VAR ON DAY(S) 14, 15 MAXIMUM 1-HR AVERAGE: 3.35 HOUR(S) 22 ON DAY(S) 25 MAXIMUM 24-HR AVERAGE: 2.24 ppm ON DAY(S) VAR-VARIOUS 25 IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 744 hrs MONTHLY CALIBRATION TIME: 4 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.18 MONTHLY AVERAGE: 2.01 ppm JOB #: C Page 38 of 102

40 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 METHANE Hourly Averages (CH₄ ppm) CH₄ 1hrAve (ppm) CH₄ (ppm) Day JOB #: C Page 39 of 102

41 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 METHANE MAX Instantaneous Maximum (CH₄ ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C C C S S S S S S S S S S S S S S S S S Y Y S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 705 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 5.31 HOUR(S) 1 ON DAY(S) 26 VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 742 hrs MONTHLY CALIBRATION TIME: 6 hrs STANDARD DEVIATION: 0.45 JOB #: C Page 40 of 102

42 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 METHANE MAX Instantaneous Maximum (CH₄ ppm) CH₄ InsMax (ppm) CH₄ max (ppm) Day JOB #: C Page 41 of 102

43 Wind: PRAMP RENO TRAILER Poll.: PRAMP RENO TRAILER-CH4[ppm] Monthly: 01/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr Calm: 8.79% Valid Data: 94.76% Calm Avg: 2.16 [ppm] Direction >10.0 Total N NE E SE S SW W NW Summary JOB #: C Page 42 of 102

44 JOB #: C Page 43 of 102

45 JOB #: C Page 44 of 102

46 NON-METHANE HYDROCARBON JOB #: C Page 45 of 102

47 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 NON-METHANE HYDROCARBONS Hourly Averages (NMHC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C S S S S S S S S S S S S S S S S S S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January 2017 MONTHLY SUMMARY NUMBER OF NON-ZERO READINGS: 4 MINIMUM 1-HR AVERAGE 0.00 HOUR(S) VAR ON DAY(S) ALL MAXIMUM 1-HR AVERAGE: 0.06 HOUR(S) 15 ON DAY(S) 17 MAXIMUM 24-HR AVERAGE: 0.01 ppm ON DAY(S) VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 744 hrs MONTHLY CALIBRATION TIME: 4 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.00 MONTHLY AVERAGE: 0.00 ppm JOB #: C Page 46 of 102

48 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 NON-METHANE HYDROCARBONS Hourly Averages (NMHC ppm) NMHC 1hrAve (ppm) NMHC (ppm) Day JOB #: C Page 47 of 102

49 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 NON-METHANE HYDROCARBONS Instantaneous Maximum (NMHC ppm) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY S S C C C C C C S S S S S S S S S S S S S S S S S Y Y S S S S S S S S S S S S HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE MONTHLY SUMMARY C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION NUMBER OF NON-ZERO READINGS: 28 S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 0.51 HOUR(S) 15 ON DAY(S) 17 VAR-VARIOUS IZS CALIBRATION TIME: 31 hrs OPERATIONAL TIME: 742 hrs MONTHLY CALIBRATION TIME: 6 hrs STANDARD DEVIATION: 0.03 JOB #: C Page 48 of 102

50 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 NON-METHANE HYDROCARBONS Instantaneous Maximum (NMHC ppm) NMHC InsMax (ppm) NMHC max (ppm) Day JOB #: C Page 49 of 102

51 Wind: PRAMP RENO TRAILER Poll.: PRAMP RENO TRAILER-NMHC[ppm] Monthly: 01/2017 Type: PollutionRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 8.79% Valid Data: 94.76% Calm Avg: 0.00 [ppm] Direction >2.0 Total N NE E SE S SW W NW Summary JOB #: C Page 50 of 102

52 JOB #: C Page 51 of 102

53 JOB #: C Page 52 of 102

54 WIND SPEED JOB #: C Page 53 of 102

55 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND SPEED Hourly Averages (WS kph) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE LAST CALIBRATION: C1 - REPEAT CALIBRATION R - RECOVERY DECLINATION : Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE HR AVERAGES January 2017 NUMBER OF NON-ZERO READINGS: 743 October 13, 2016 MAGNETIC DECLINATION 15 DEGREE EAST MONTHLY SUMMARY MINIMUM 1-HR AVERAGE 0.0 HOUR(S) 2 ON DAY(S) 8 MAXIMUM 1-HR AVERAGE: 18.3 HOUR(S) 14 ON DAY(S) 11 MAXIMUM 24-HR AVERAGE: 11.8 kph ON DAY(S) VAR-VARIOUS OPERATIONAL TIME: 744 hrs MONTHLY CALIBRATION TIME: 0 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 3.7 MONTHLY AVERAGE: 2.8 kph JOB #: C Page 54 of 102

56 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND SPEED Hourly Averages (WS kph) WS 1hrAve (kph) WS (kph) Day JOB #: C Page 55 of 102

57 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND SPEED Instantaneous Maximum (WS kph) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION MONTHLY SUMMARY S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MAXIMUM INSTANTANEOUS VALUE: 48.2 HOUR(S) 14 ON DAY(S) 11 VAR-VARIOUS OPERATIONAL TIME: 744 hrs JOB #: C Page 56 of 102

58 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND SPEED Instantaneous Maximum (WS kph) WS InsMax (kph) WS max (kph) Day JOB #: C Page 57 of 102

59 Wind: PRAMP RENO TRAILER Monitor: WSP [kph] Monthly: 01/2017 Type: WindRose Direction: Blowing From (Wind Frequency) Based On 1 Hr. Calm: 9.01% Valid Data: % Direction >39.0 Total N NE E SE S SW W NW Summary JOB #: C Page 58 of 102

60 JOB #: C Page 59 of 102

61 WIND DIRECTION JOB #: C Page 60 of 102

62 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND DIRECTION Hourly Averages (WD) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24-HOUR AVG 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 QUADRANT RDGS. DAY 1 WNW W W WNW NW WNW WNW WNW W W W W W W W W WSW WSW WSW S S S SSW SSW W 24 2 SSE ESE E ESE E E ENE NNE N NNE NE E W WSW S SSW SSW SW SSW SSW SSW SSW S S SSE 24 3 S S SSW SSW SSW SSW SSW SW SW SW SSW SSW SW WSW WSW WSW SW SSW SSW SSW SW SW SW SSW SW 24 4 SW SW SSW SW SW SSW SSW S SSE S S SSW SW SW SW WSW WSW WSW WSW WSW WSW NNW N NNE SW 24 5 NNE NNE N N N N N N N N N NNE NNE NE NE NE ENE NE NE ENE E E ESE E NE 24 6 E ESE ESE ESE ESE ESE ESE ESE ESE ESE ESE ESE ESE E E E E E E NE NNE NNW N N E 24 7 N N N N N N N N N N N N N N N N N NNE NNE N NNE NNE NNE NNE N 24 8 NNE NNE ENE ENE NE SSE SE SSE SSE SSE SSE SSE SSE SSE SE WSW WNW SW SW SW SW WSW WSW SW SW 24 9 SW WSW WSW W W W WSW W WSW WSW WSW W WNW NNW NNW WNW W WSW WSW SW WSW SW SW SW WSW SSW SSW SW W N N N N N NNW W W SW SSW SW SW WSW SW SW SW SW SW SW SW W SW WSW WSW W WSW WSW WSW W W W WNW WNW WNW NNW N N NNE NNE NNE NE NE SW S SSE WNW S SSE SSE SSE S S S S S SSE SSE S S S S S S SSW SW WSW WSW SW SW SW S WSW SW SW SSW SW SW SW SW SSW SSW SSW SSW SW SW SW SW SSW SW SSW S S S SSW SW SSW SW SW SW SW SW SW SW SW SW WSW SW SW SW SW SW WSW SW S SSW SSW SW SW WSW WSW SW WSW WSW WSW WSW WSW WSW WSW WSW WSW SW SW SW WSW WSW WSW WSW SW SW SW SW SW SW SW SW SW SW SSW SW SW SSW SSW SSW SSW S SSW SSW SSW SSW S S S S S S S S S S S SSW SSW SSW SW SW SW SSW S S S S SSW SSW S S S S S S S SE SE SE SSE SSE S SSE S S S SSE S S S S S S S S S SSE SSE S S S S S S S SSW S N NNW N NNE NNE NNE NNE NE ENE SSW NW NNE NE ESE WSW WNW N NE E S S S SSW SSW NNE SSW SSW SSW SSW SSW S S S S S S S S S S S S S SW WSW N N NNE NNE S NNE NNE NNE N N N NNE N N N N N N NNE N N N N NNE NNE N N N NNE N NNE NNE NNE NNE NNE NNE NNE NNE NNE NNE NNE NNE N N NE ENE ENE ENE NE NE NE NE ENE ENE NE ENE ENE E E ENE ENE ENE ENE ENE E ESE SE SSE SE S SSW SW SSE SSE SSW S S SSE SSE ESE S S S S S S SSW SSW SSW SSW SSW SSW SSW S S S S S S S S S S S S S S S S S S S S S S S S S S S S S SSW SSW SSE S S S S S S S S SSE S SW SW SW SW SSW SW SW SW SW WSW SW SW SW WSW SW WSW WSW WSW WSW SW WSW WSW WSW SW SW SW SW SW SW SW SW SW SW WSW SW SW WSW WSW WSW W SW SW SW WSW SW SW SSW SW SW SW SW SW SSW SSW SSW S SSW SSW SSW SW SW SW SW SW SW SW SSW S S SW SSW SW SW SW SW SW SW SW SW SW SW SW WSW WSW SSE S SW SSW SW SW WSW WSW WSW WSW SW WSW W W WNW W W WNW WNW WNW WNW W W W W W W WNW WNW WNW NNW N N N N WNW N N N NNE N NNE N NW W W W W NW NW NW NW WNW W WSW WSW W W W W NW 24 STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE LAST CALIBRATION: October 13, 2016 C1 - REPEAT CALIBRATION R - RECOVERY DECLINATION : MAGNETIC DECLINATION 15 DEGREE EAST Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE MONTHLY CALIBRATION TIME: 0 hrs OPERATIONAL TIME: 744 hrs STANDARD DEVIATION: 89 AMD OPERATION UPTIME: % MONTHLY AVERAGE: 233 (SW) JOB #: C Page 61 of 102

63 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 WIND DIRECTION Hourly Averages (WD) WD 1hrAve (deg) WD (deg) Day JOB #: C Page 62 of 102

64 RELATIVE HUMIDITY JOB #: C Page 63 of 102

65 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 RELATIVE HUMIDITY Hourly Averages (RH %) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: 43 HOUR(S) 15 ON DAY(S) 28 MAXIMUM 1-HR AVERAGE: 95 HOUR(S) VAR, VAR ON DAY(S) 19, 20 MAXIMUM 24-HR AVERAGE: 90 % ON DAY(S) VAR-VARIOUS 19 OPERATIONAL TIME: 744 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 10 MONTHLY AVERAGE: 74 % JOB #: C Page 64 of 102

66 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 RELATIVE HUMIDITY Hourly Averages (RH %) RH 1hrAve (%) RH (%) Day JOB #: C Page 65 of 102

67 BAROMETRIC PRESSURE JOB #: C Page 66 of 102

68 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 BAROMETRIC PRESSURE Hourly Averages (BP inhg) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: HOUR(S) 6 ON DAY(S) 18 MAXIMUM 1-HR AVERAGE: HOUR(S) 11 ON DAY(S) 7 MAXIMUM 24-HR AVERAGE: inhg ON DAY(S) VAR-VARIOUS OPERATIONAL TIME: 744 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.33 MONTHLY AVERAGE: inhg JOB #: C Page 67 of 102

69 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 BAROMETRIC PRESSURE Hourly Averages (BP inhg) BP 1hrAve (inhg) BP (inhg) Day JOB #: C Page 68 of 102

70 AMBIENT TEMPERATURE JOB #: C Page 69 of 102

71 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 AMBIENT TEMPERATURE Hourly Averages (AmbTPX C) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: HOUR(S) 23, 0 ON DAY(S) 11, 12 MAXIMUM 1-HR AVERAGE: 8.6 HOUR(S) 15 ON DAY(S) 28 MAXIMUM 24-HR AVERAGE: 3.7 C ON DAY(S) VAR-VARIOUS 28 OPERATIONAL TIME: 744 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 9.0 MONTHLY AVERAGE: -8.7 C JOB #: C Page 70 of 102

72 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 AMBIENT TEMPERATURE Hourly Averages (AmbTPX C) 15 AmbTPX 1hrAve ( C) AmbTPX ( C) Day JOB #: C Page 71 of 102

73 STATION TEMPERATURE JOB #: C Page 72 of 102

74 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 STATION TEMPERATURE Hourly Averages (StnTPX C) HR START (MST) 0:00 1:00 2:00 3:00 4:00 5:00 6:00 7:00 8:00 9:00 10:00 11:00 12:00 13:00 14:00 15:00 16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 DAILY DAILY 24-HR HR END (MST) 0:59 1:59 2:59 3:59 4:59 5:59 6:59 7:59 8:59 9:59 10:59 11:59 12:59 13:59 14:59 15:59 16:59 17:59 18:59 19:59 20:59 21:59 22:59 23:59 MIN. MAX. AVG. RDGS. DAY HOURLY MAX HOURLY AVG STATUS FLAG CODES C - MONTHLY CALIBRATION Q - QUALITY ASSURANCE C1 - REPEAT CALIBRATION R - RECOVERY Y - MAINTENANCE X - MACHINE MALFUNCTION S - DAILY ZERO/SPAN CHECK G - OUT FOR REPAIR S1 - REPEAT ZERO/SPAN CHECK P - POWER FAILURE 24 HR AVERAGES January 2017 MONTHLY SUMMARY MINIMUM 1-HR AVERAGE: 16.5 HOUR(S) 20 ON DAY(S) 2 MAXIMUM 1-HR AVERAGE: 22.5 HOUR(S) 8 ON DAY(S) 5 MAXIMUM 24-HR AVERAGE: 22.0 C ON DAY(S) VAR-VARIOUS 23 OPERATIONAL TIME: 744 hrs AMD OPERATION UPTIME: % STANDARD DEVIATION: 0.7 MONTHLY AVERAGE: 21.1 C JOB #: C Page 73 of 102

75 PEACE RIVER AREA MONITORING PROGRAM COMMITTEE Reno Station - January 2017 STATION TEMPERATURE Hourly Averages (StnTPX C) StnTPX 1hrAve ( C) StnTPX ( C) Day JOB #: C Page 74 of 102

76 APPENDIX II EQUIPMENT CALIBRATION RESULTS JOB #: C Page 75 of 102

77 SULPHUR DIOXIDE JOB #: C Page 76 of 102

78 API 100A Sulphur Dioxide Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: January 3, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: 21 Reno Weather Conditions: Mainly cloudy with light snow Sulphur Dioxide Calibration Purpose: routine monthly 13:29 Performed By/Reviewer: Raja Abid Trina Whitsitt 17:02 Cal Gas Expiry Date: May 23, 2019 Gas Dilution Converter Model & s/n (if applicable): n/a Analyzer: ID# or Serial Number: 841 Range ppb: 500 Last Calibration Date: December 1, 2016 As Found C.F.: Previous C.F.: New C.F.: Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: Environics 6100 High 380 Serial #: 5212 Mid 180 Cal Gas Cylinder I.D. # : LL Low 90 Cal Gas Conc. (ppm): 50.6 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high adjusted zero n/a adjusted high mid low calibrator zero n/a Average C.F.= Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= 0.17% ± 3% F.S. % change in C.F. from last cal= 1.47% ± 10% API 100A Sulphur Dioxide Analyzer Calibration indicated ppb calculated ppb SLOPE: OFFSET: HVPS: DCPS: RCELL TEMP: BOX TEMP: PMT TEMP: IZS TEMP: Converter Temp: PRES: SAMP FL: PMT: UV LAMP: LAMP RATIO: STR. LGT DRK PMT: DRK LMP: Expected Value: As found: As left: SLOPE: OFFSET: HVPS: DCPS: RCELL TEMP: BOX TEMP: PMT TEMP: IZS TEMP: 45.0 n/a Converter Temp: n/a 25.4 PRES: SAMP FL: PMT: UV LAMP: LAMP RATIO: STR. LGT DRK PMT: DRK LMP: Expected Value: Comments: The analyzer sample inlet filter was changed. JOB #: C Page 77 of 102

79 JOB #: C Page 78 of 102

80 API 100A Sulphur Dioxide Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: January 20, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: 22 Reno Weather Conditions: Mainly sunny Sulphur Dioxide Calibration Purpose: as found 16:36 Performed By/Reviewer: Raja Abid 17:23 Cal Gas Expiry Date: May 23, 2019 Gas Dilution Converter Model & s/n (if applicable): n/a Trina Whitsitt Analyzer: ID# or Serial Number: 841 Range ppb: 500 Station SO2 Analyzer Range? Last Calibration Date: January 3, 2017 As Found C.F.: ppb Previous C.F.: New C.F.: n/a Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: API 700 High 380 Serial #: 830 Mid 180 Cal Gas Cylinder I.D. # : LL Low 90 Cal Gas Conc. (ppm): 50.6 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high Average C.F.= n/a Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = n/a > or = Slope = n/a b (Intercept as % of full scale)= n/a ± 3% F.S. % change in C.F. from last cal= -0.07% ± 10% SLOPE: OFFSET: HVPS: DCPS: RCELL TEMP: BOX TEMP: PMT TEMP: IZS TEMP: Converter Temp: PRES: SAMP FL: PMT: UV LAMP: LAMP RATIO: STR. LGT DRK PMT: DRK LMP: Expected Value: As found: As left: SLOPE: n/a 44.2 OFFSET: n/a 763 HVPS: n/a 2561 DCPS: n/a 49.6 RCELL TEMP: n/a 29.3 BOX TEMP: n/a 7.1 PMT TEMP: n/a 45.2 IZS TEMP: n/a n/a Converter Temp: n/a 24.4 PRES: n/a 671 SAMP FL: n/a 59.9 PMT: n/a 2130 UV LAMP: n/a 95.3 LAMP RATIO: n/a 21.7 STR. LGT n/a 24.9 DRK PMT: n/a DRK LMP: n/a n/a Expected Value: n/a Comments: At 17:44 Channel was taken out of M mode JOB #: C Page 79 of 102

81 JOB #: C Page 80 of 102

82 TOTAL REDUCED SULPHUR JOB #: C Page 81 of 102

83 Thermo 450i Total Reduced Sulphur Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: January 3, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: 21 Reno Weather Conditions: Mainly cloudy with light snow Total Reduced Sulphur Calibration Purpose: routine monthly 10:03 Performed By/Reviewer: Raja Abid Trina Whitsitt 16:00 Cal Gas Expiry Date: December 1, 2018 Gas Dilution Converter Model & s/n (if applicable): CD NOVA-CDN 101 s/n 534 Analyzer: ID# or Serial Number: Range ppb: 100 Last Calibration Date: December 1, 2016 As Found C.F.: Previous C.F.: New C.F.: Calibrator: Standard Calibration Points for Ranges SO 2 Scrubber Check (10 mins.) Flow Meter ID's: n/a Point ppb Start/End Time 24 hr.: 11:54-12:04 Make & Model: API 700 High 78 Target Concentration (ppb): 380 Serial #: 830 Mid 38 Result (ppb): 0 Cal Gas Cylinder I.D. # : BLM Low 19 Zero Corrected Result (ppb): 0 Cal Gas Conc. (ppm): 10.3 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high adjusted zero n/a adjusted high mid low calibrator zero n/a Average C.F.= Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= 0.35% ± 3% F.S. % change in C.F. from last cal= -0.04% ± 10% Thermo 450i Total Reduced Sulphur Analyzer Calibration indicated ppb calculated ppb BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: CONVERTER TEMP: CONVERTER SET: PERM OVEN GAS: PERM OVEN HTR: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: Expected Value: Comments: The analyzer sample inlet filter was changed. As found: As left: 16.2 BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: CONVERTER TEMP: CONVERTER SET: PERM OVEN GAS: PERM OVEN HTR: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: Expected Value: 37.8 The analyzer cooling fan filter(s) were cleaned. 10:12-11:06 As Found performed to confirm the efficiency of the analyzer as there was drift in IZS. Adjusted high point interrupted by daily span check, restarted at 13:12. Concentration drop at the start of low point was due to low gas pressure, issue fixed. JOB #: C Page 82 of 102

84 JOB #: C Page 83 of 102

85 Thermo 450i Total Reduced Sulphur Analyzer Calibration Date: Company/Airshed: Location/Station Name: Parameter: Start Time 24 hr. (mst): End Time 24 hr. (mst): Calibration Method: January 20, 2017 Barometric Pressure: inhg PRAMP Station Temperature o C: 22 Reno Weather Conditions: Mainly sunny Total Reduced Sulphur Calibration Purpose: as found 16:36 Performed By/Reviewer:ip Raja Abid Trina Whitsitt 17:35 Cal Gas Expiry Date: Converter Model December 1, 2018 Gas Dilution & s/n (if applicable): CD NOVA-CDN 101 s/n 534 Analyzer: ID# or Serial Number: Range ppb: 100 Last Calibration Date: January 3, 2017 As Found C.F.: Previous C.F.: New C.F.: n/a Calibrator: Standard Calibration Points for Ranges Flow Meter ID's: n/a Point ppb Make & Model: Environics 6100 High 78 Serial #: 5212 Mid 38 Cal Gas Cylinder I.D. # : BLM Low 19 Cal Gas Conc. (ppm): 10.3 ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Concentration: Indicated Concentration: Correction Factors (C.F.): Point Diluent Cal Gas Total (ppb) (ppb) - as found zero n/a as found high Average C.F.= n/a Linear Regression/Calibration Results: LIMITS Correlation Coeffecient = n/a > or = Slope = n/a b (Intercept as % of full scale)= n/a ± 3% F.S. % change in C.F. from last cal= -1.49% ± 10% BKG: COEF: PMT: FLASH: INTERNAL: CHAMBER: CONVERTER TEMP: CONVERTER SET: PERM OVEN GAS: PERM OVEN HTR: PRESSURE: SAMPLE FLOW: LAMP INTENSITY: As found: As left: 17.1 BKG: n/a COEF: n/a PMT: n/a 929 FLASH: n/a 28.4 INTERNAL: n/a 45.1 CHAMBER: n/a 800 CONVERTER TEMP: n/a 800 CONVERTER SET: n/a PERM OVEN GAS: n/a PERM OVEN HTR: n/a PRESSURE: n/a SAMPLE FLOW: n/a 90 LAMP INTENSITY: n/a Comments: At 17:44 Channel was taken out of M mode JOB #: C Page 84 of 102

86 JOB #: C Page 85 of 102

87 TOTAL HYDROCARBON JOB #: C Page 86 of 102

88 Thermo 55i Methane/Non-Methane Analyzer Calibration remove Date: January 3, 2017 Barometric Pressure: inhg Company/Airshed: PRAMP Station Temperature o C: 22 Location/Station Name: Reno Weather Conditions: Mainly cloudy with light snow Parameter: CH 4 / NMHC / THC Calibration Purpose: routine monthly Start/End Time 24 hr. (mst): 10:03/14:02 Performed By/Reviewer: Raja Abid Trina Whitsitt Calibration Method: Gas Dilution Cal Gas Expiry Date: January 9, 2021 Analyzer: Correction Factors: ID# or Serial Number: Previous C.F.: As Found C.F.: New C.F.: Measured Flow: 1329 CH 4 = Last Calibration Date: December 1, 2016 NMHC = Range ppm: 20 CH4/20 NMHC/40 THC THC = Calibrator: Flow Meter ID's: n/a Standard Calibration Points for Analyzer Range of 20/20/40 ppm Make & Model: Environics 6100 Point CH4 NMHC THC Serial #: 5212 High Cal Gas Cylinder I.D. # : LL Mid CH4 Cylinder Conc.= =C 3H 8 Cylinder Conc. Low CH 4 as C 3H 8= =total CH 4 equivilant ALL POINTS ARE 15 MINUTES OF STABILITY AS OF SEPTEMBER 23, 2015 Calibrator Flow Rates (cc/min) Calculated Correction Factors: Calculated Calculated Indicated CH Indicated NMHC 4 Indicated Point Diluent Cal Gas Total Flow CH 4 (ppm) THC (ppm) (ppm) NMHC (ppm) THC (ppm) CH (ppm) 4 NMHC THC as found zero n/a n/a n/a as found high adjusted zero n/a n/a n/a adjusted high mid low calibrator zero n/a n/a n/a Linear Regression/Calibration Results: CH 4 NMHC THC LIMITS Average C.F.= Correlation Coeffecient = > or = Slope = b (Intercept as % of full scale)= -0.08% -0.04% -0.04% ± 3% F.S. % change in C.F. from last cal= 1.05% 0.14% 0.68% ± 10% As found: As left: Interface Board Voltages: Bias Supply: Calibration History cnt'd: NM Peak Area: n/a Temperatures: Detector Oven: Crucial Settings: Methane Start: n/a Filter: Methane End: n/a Column Oven: 75.0 Backflush: n/a Internal: 29.1 NMHV Start: n/a Cylinder Pressures/reg.: Carrier: NMHC End: n/a Fuel: Run History>1: Date: 03Jan17 Span Gas: Time: 10:08 Zero Air Generator: 45 CH 4 PK HT: 0 Internal Pressures: Carrier: 31.3 CH 4 RT: 8.0 Fuel: 41.6 CH 4 Baseline: 2035 Air: 25.9 CH 4 LOD: 57 FID Status: Status: LIT CH 4 SD: 19 Counts: CH 4 CONC: 0.00 Flame: NM PK HT: 0 Det Base: NM Peak Area: 0 Flame and Power Stats: Last Power On: 26Dec2016@17:38 NM CONC: 0.00 Flameouts: 1 NM Base Start: 2023 Det Oven at Start: NM Base End: 2025 Col Oven at Start: 74.4 NM LOD: 4 Calibration History: Time: n/a NM Start IDX: 57 Type: n/a NM End IDX: 34 Status: n/a NM Max Slope: 5.4e-01 Check/Adjust: n/a NM Min Slope: -6.96e-01 CH 4 Span Conc: n/a NM PT Count: 0 CH 4 SP Ratio: n/a Expected Values: Previous CH4: 9.44 CH 4 RT: n/a Previous NMHC CH 4 PK IDX: n/a Previous THC: CH 4 PK HT: n/a New CH4: 9.58 NM Span Conc: n/a New NMHC NM SP Ratio: n/a New THC: Comments: The analyzer sample inlet filter was changed. The analyzer cooling fan filter(s) were cleaned. No zero adjustment was required/made. As found zero values were copied to adjusted zero values for linearity calculation purposes. 10:06-10:07: Flow check performed. Calibrator lost power at 11:46 during mid p0int, restarted at 11:48. Calibarator zero was interrupted by daily span check, restarted at 13:07. JOB #: C Page 87 of 102

89 Date: Company/Airshed: Location/Station Name: January 3, 2017 Start/End Time 24 hr. (mst): 10:03/14:02 PRAMP Calibration Purpose: routine monthly Reno Calibration Method: Gas Dilution CH 4 Calibration Graph indicated ppb calculated ppb 16 NMHC Calibration Graph indicated ppb calculated ppb 35 THC Calibration Graph indicated ppb calculated ppb JOB #: C Page 88 of 102

90 JOB #: C Page 89 of 102