Liquids, Solids and Solutions

Transcription

1 1 Liquids, Solids and Solutions This is a broad topic that will be spread out over several questions. This is section that will have lots of conceptual problems, but mathematical ones can also happen as well. Be prepared for: Metals and their bonding Ionic solids vapor pressure: How it works and how it relates to boiling point phase diagrams: Pressure vs Temperature changes of state Q=mc T Factors affecting solution formation vapor pressure of solutions (depression) and why this is changed: Raoult s law: Ideal and nonideal solutions in Raoult s law Boiling point elevation and Freezing point depression T = Kfm freezing point depression and molecular weight: we did a lab like this Calculations involving solutions: MV=moles etc. #1: In 1884 the Swedish chemist Svante Arrhenius proposed that salts dissociate into two or more separate, independent, ionic fragments when they dissolve in water. (a) Give one piece of experimental evidence that more than 1 mole of particles is formed when 1 mole of a salt dissolves in water. (b) Give one piece of experimental evidence that the particles formed when a salt dissolves in water are charged. (c) Explain why the heat of neutralization is always the same when 1 mole of any monoprotic strong acid reacts with enough strong base to form a neutral solution. (d) Explain why hydrogen chloride, HCl, dissociated when it dissolves in water but not when it dissolves in benzene.

2 2 #2 The normal boiling and freezing points of argon are 87.3 K and 84.0 K, respectively. The triple point is at 82.7 K and 0.68 atmosphere. (a) Use the data above to draw a phase diagram for argon. Label the axes and label the regions in which the solid, liquid and gas phases are stable. On the phase diagram, show the position of the normal boiling point. (b) Describe any changes that can be observed in a sample of solid argon when the temperature is increased from 40 K to 160 K at a constant pressure of 0.50 atmosphere. (c) Describe any changes that can be observed in a sample of liquid argon when the pressure is reduced from 10 atmospheres to 1 atmosphere at a constant temperature of 100 K, which is well below the critical temperature. (d) Does the liquid phase of argon have a density greater than, equal to, or less than the density of the solid phase? Explain your answer, using information given in the introduction to this question. #3 Consider three unlabeled bottles, each contain small pieces of one of the following metals. Magnesium Sodium Silver The following reagents are used for identifying the metals. Pure water A solution of 1.0 molar HCl A solution of concentrated HNO 3 (a) Which metal can be easily identified because it is much softer than the other two? Describe a chemical test that distinguishes this metal from the other two, using only one of the reagents above. Write a balanced chemical equation for the reaction that occurs. (b) One of the other two metals reacts readily with the HCl solution. Identify the metal and write the balanced chemical equation for the reaction that occurs when this metal is added to the HCl solution. Use the table of standard reduction potentials (attached) to account for the fact that this metal reacts with HCl while the other does not. (c) The one remaining metal reacts with the concentrated HNO 3 solution. Write a balanced chemical equation for the reaction that occurs. (d) The solution obtained in (c) is diluted and a few drops of 1 M HCl is added. Describe what would be observed. Write a balanced chemical equation for the reaction that occurs.

3 3 #4: The solubility of iron(ii) hydroxide, Fe(OH) 2, is gram per litre at 25 C. (a) Write a balanced equation for the solubility equilibrium. (b) Write the expression for the solubility product constant, K sp, and calculate its value. (c) Calculate the ph of a saturated solution of Fe(OH) 2 at 25 C. (d) A 50.0 millilitre sample of molar FeSO 4 solution is added to 50.0 millilitres of molar NaOH solution. Does a precipitate of Fe(OH) 2 form? Explain and show calculations to support your answer. #5: Elemental analysis of an unknown pure substance indicated that the percent composition by mass is as follows. Element Percent by Mass Carbon 49.02% Hydrogen 2.743% Chlorine 48.23% A solution that is prepared by dissolving grams of the substance in grams of benzene, C 6 H 6, has a freezing point of 1.12 C. (The normal freezing point of benzene is 5.50 C and the molal freezing point depression constant, K f, for benzene is 5.12 C/molal.) (a) Determine the empirical formula of the unknown substance. (b) Using the data gathered from the freezing point depression method, calculate the molar mass of the unknown substance. (c) Calculate the mole fraction of benzene in the solution described above. (d) The vapor pressure of pure benzene at 35 C is 150. millimeters of Hg. Calculate the vapor pressure of benzene over the solution described above at 35 C.

4 4 #6 Elemental analysis of an unknown pure substance indicated that the percent composition by mass is as follows: Element Percent by Mass Carbon 49.02% Hydrogen 2.743% Chlorine 48.23% A solution is prepared by dissolving grams of the substance in grams of benzene, C 6 H 6, has a freezing point of 1.12 o C. (The normal freezing point of benzene is 5.50 o C and the molal freezing-point depression constant, K f, for benzene is 5.12 o C/molal). (a) (b) (c) (d) Determine the empirical formula of the unknown substance. Using the data gathered from the freezing-point depression method, calculate the molar mass of the unknown substance. Calculate the mole fraction of benzene in the solution described above. The vapor pressure of pure benzene at 35 o C is 150. Mm Hg. Calculate the vapor pressure of benzene over the solution described above at 35 o C. #7: The normal boiling and freezing points of argon are 87.3 K and 84.0 K, respectively. The triple point is at 82.7 K and 0.68 atm. (a) (b) (c) (d) Use the data above to draw a phase diagram for argon. Label the axes and label the regions in which the solid, liquid and gas phases are stable. On the phase diagram, show the position of the normal boiling point. Describe any changes that can be observed in a sample of solid argon when the temperature is increased from 40 K to 160 K at a constant pressure of 0.50 atmosphere. Describe any changes that can be observed in a sample of a liquid argon when the pressure is reduced from 10 atmospheres to 1 atmosphere at a constant temperature of 100 K, which is well below the critical temperature. Does the liquid phase of argon have a density greater than, equal to, or less than the density of the solid phase? Explain your answer using information given in the introduction to this question.

5 5 #8: The phase diagram for a pure substance is shown above. Use this diagram and your knowledge about changes of phase to answer the following questions. (a) What does point V represent? What characteristics are specific to the system only at point V?. (b) What does each point on the curve between V and W represent? (c) Describe the changes that the system undergoes as the temperature slowly increases from X to Y to Z at 1.0 atmosphere. (d) In a solid-liquid mixture of this substance, will the solid float or sink? Explain.