Polymer Chemistry - Synthesis, Characterisation and Applications
|
|
- Derick Short
- 5 years ago
- Views:
Transcription
1 Polymer Chemistry - Synthesis, Characterisation and Applications
2 Lectures every Thursday, 16:15 18:00 Small PC Lecture Hall Exceptions: (before Easter) asic Infos: Contact Dr. Jens Gaitzsch PC uilding, Room 4.06 Written Exam in the end, Graded Exam (tbc): , 10:00 am, Large PC lecture Hall
3 Outline 1. Introduction, Classifications, Overview, Terminology 2. Polymer Synthesis Polycondensation/Polyaddition Ring Opening (Metathesis) Polymerisation Radical Polymerisation Ionic polymerisation 3. Hyperbranched Polymers and Dendrimers 4. lock-copolymers 5. Polymer Networks
4 Polymer Chemistry - The asics
5 History of polymers Aims of this part: Classes and types of polymers Synthetic origin of polymers Nomenclature of polymers raun, Chedron, Rehann, Ritter, Voit Polymer Synthesis: Theory and Practice, Springer, 5 th Edition, Sections Lechner, Gehkre, Nordmeier, Makromolekulare Chemie, Springer, 5 th Edition, Section 2.1
6 Polymers are everywhere Starch Cotton DNA PET ottles Polystyrene Expanding Foam (Polyurethane)
7 Definition of a Polymer Polymers are Macromolecules Molecules with > 1000 atoms with (mainly) covalent bonds in between uilt from repeating units (monomers) Monomer Oligomer Polymer = uilding lock of the Polymer = up to 10 repeating / M < 1000 g/mol = more than 10 repeating units, M >> 1000 g/mol These definitions are NOT rock solid but do vary for each system Ethylene (Monomer) Paraffin Wax (Oligomer) Polyethylene (PE, Polymer)
8 History of Polymers Used for a very long time: Natural polymers are used since a long time (some since the stone age) Sometimes modified for better use: : skin (leather), hair (wool), cellulose (paper), resins, natural rubber Also: designed use of special resins: e.g. asphalt (Egypt), laquers (China) and rubber balls (Maya) Through the middle ages no significant development Industrial revolution made basis for new man-made materials Actual research started in 20th century
9 History of Polymers 1st industrial Polymers: 1901 Röhm: polyacrylic acid esters 1906 Hoffmann: polyisoprene 1907 akeland: akelit (phenol-formaldehyde-resin); typical black! 1915 ayer: polydimethylbutadiene 1920 Hermann Staudinger: Macromolecules for the first time considered, not micelles or associates! Many opposite opinions at that time: Molecules with molar masses > 5000 g/mol do not exist! He should clean his stuff! Schmierenchemie! (= dirty chemistry)! critical remarks by Wieland and Fischer, both Nobel laureates, 1902 and 1927) 1940 Controversial discussion stops Compare work of Flory and Stockmeyer 1970 Prestigious Hermann Staudinger Preis gets started in Germany. Given every 2 years at max. (Reveived by Wolfgang Meier in 2006) H. Staudinger, noble laureate 1953
10 History of Polymers Important steps for industrial polymers 1928 Röhm: Plexiglas (PMMA) 1930 ASF: polystyrene, polyacrylonitrile 1934 PVC 1937 IG Farben: UNA (first synthetic rubber) DuPont: Nylon-6,6 ayer: polyurethanes via isocyanates 1938/39 ASF: Nylon-6 = Perlon 1945/46 ICI/Hoechst: Terylen/Trevira PET 1946 DuPont: Teflon (polytetrafluorethylene) 1952/53 ZIEGLER-catalysts TiCl 4 + Al(C 2 H 5 ) 3 polymerization of ethylene at ambient pressure Natta: used ZIEGLER-catalysts for polyolefine synthesis stereoselective (= isotactic) polypropylene! Ziegler-Natta-polymerization for preparation of tactic polymers 1957 General Electric and ayer: polycarbonate 1962 DuPont: polyimide and polyphenylene 1970 PET/PT (poly(butylene terephthalate)) SS (stryrene-butadiene-styrene) block copolymers (Kraton) 1975 Kevlar (aromatic polyamide, bullet proof west, aerospace)
11 Classes of Polymers - by Origin Natural Polymers Synthetic Polymers Synthesised in in animals/plants/etc. Controlled synthesis by the means of specialised enzymes Defined branching and folding Only biodegradble polymers ased Sugars, Amino acids or nucleobases Can be modified for specific uses Synthesised in laboratories/industry Catalysts sometimes used, but uncontrolled synthesis also common ranching and Folding at random Many non-degradable polymers ased on styrenes, (meth)acrylates, alcohols, esters - all bifunctional molecules can be polymerised
12 Classes of Polymers - by Origin Natural Polymers Synthetic Polymers For DNA/ Proteins: Highly Defined Molecular Structure, so one substance refers to: One Structure One Molecular Weight Defined branching & folding Defined primary sequence Holds Information Holds recognition centres Can be translated into other polymers Most Synthetic Polymers: Defined repeating molecular Structure, meaning: One Substance Mostly one repeating unit Only average Molecular Weight Seldomly defined secondary structure Do not hold information Also possible: Modified natural polymers (Cellulose acetate, vulcanised rubber)
13 Classes of Polymers - by Chemical ond Polyester PET (bottles), PLA, PCL as biodegradble polymers Polyamide Nylon, Pept(o)ides, Kevlar, Nomex (mech. strong if R =H) Polyurethane Expansion Foam, Ski boots thermoplastic elastomers Polyenes Poly(meth)- acrylates, Styrenes, Polydienes (Mass Polymers) Polycarbonates Often semicrystalline Used for CDs/DVDs Polyoxazolines PMOxa PEtOz And so on (quasi- Polyamides) Polyether PEG Poly/THF And similar Polythioether & Polysulfone Synthetically not very important Silicone Hybrid Organic/ Inorganic Polymer R = Me PDMS (most prominent)
14 Classes of Polymers - by Architecture Thermoplasts Polymers Many Single Chains Not interconnected Can Melt Can be reshaped in heat Duroplasts (Duromers) All one Molecule Strong and Tight Network Cannot Melt Cannot be reshaped All one Molecule Elastomers Loosely interconnected Network Cannot Melt Can regain shape after deformation
15 Synthetic Polymers Synthetic Polymers are derived from resources like mineral oil or methane gas 46,3 Million tons of plastic were demanded Europe in % of the European demand of plastic goes to Germany (2 nd with 14% Italy, then France with 10%) Used in construction, packaging, automobiles, electronics, etc. Plastic-Reusage: 26% get recycled, 38% to landfill, 36 % energy recovery Plastic is a resource thought is on the rise across Europe.
16 Polymeric Terms Tacticity important for polymers with side chains at stereocentres Atactic No specific arrangement Isotactic All on the same side Syndiotactic Always alternating Has great influence on the processability of the polymer Synthesis of tacticity-defined polymers is demanding & important Atactic Polypropylene is a wax used as additive Isotactic Polypropylene is used for shopping baskets
17 Polymeric Terms Upon heating, the polymer chains can increasingly easily with 2 Transitions Glass Transition Temperature, T g Determines the transition between a glassy amorphous state (below T g ) and an elastic state (above T g ) T g can be tuned by plastifiers Prominent T g s: PE: -133 C, PDMS: -123 C PEG: -133 C PP: 0 C (atactic) / 25 C (isotactic) PS: 100 C PMMA: 105 C (atactic, Plexiglas) PC: 150 C (PA-based)
18 Polymeric Terms Upon heating, the polymer chains can increasingly easily with 2 Transitions Crystallisation Temperature, T c chains are mobile enough to take order not for all polymers, just semicrystalline ones. T g and T c can be the same! Melting Temperature, T m - Determines the transition between an elastic OR semicrystalline state (below T m ) and a Polymer melt (above T m ) Thermoplasts only Thermal reshaping is possible Decomposition Temperature (T d ) present for all polymers Elastomers, Duromers go from T g directly to T d
19 Polymeric Terms Terminology on polymer architecture linear branched star network Dendritic = Dendrimers Hyperbranched Polymers Polymer where the branches continue to have branches Hyperbranched polymer: Unordered branches, also terminating units present Dendrimers: Continous branching, highly ordered. Terminating units ONLY on the outside
20 Terminology overall structure Polymeric Terms worm like rigid rod Coil (amorph) highly crystalline beta-sheet structure partial crystalline liquid crystalline orientation of dipols Dependent on: Polymer-Polymer interactions Polymer-Solvent interactions Physical state of the polymer
21 Terminology on polymer sequences Polymeric Terms Homopolymer n = ( ) n Monomer A n = Copolymer ( ) n Monomer alternating random block structure (long monomer sequences) graft copolymers star copolymers
22 Molecular Weight Types of Molecular Weight Number Average: As a consequence: Weight Average: Dispersity is a measure for the grade of distribution: Đ with Đ M n i M n M w 1.3 (1.4) being narrowly distributed i n M i n i i M w M M i w n i n M i n M i 2 i i An example: 1x6, 2x7, 1x8, 1x9 In most cases, the number average is given How to asses the molecular weight and its distribution?
23 Molecular Weight Titration of End Groups (e.g. counting them) - gives you number of chains M = m n An example: m = 5 g of PET (pictured) n (acid) = mol (1 mmol) M = 5 g mol = 5000 g mol In repeating units (a) M(repeat) = 192 g mol Rings are not counted!!! Molecular weight is overestimated a = M (Polymer) M(repeat) = = 26
24 EVM r.esp Assessment by NMR Molecular Weight Polymer peaks are broad, no peak splitting present Molecular weight? PDPA Homopolymer 0.7 Normalized Intensity Chemical Shift (ppm)
25 JGU65-3.esp Molecular weight accessible! Molecular Weight 0.8 PEG lock of known length 0.7 Normalized Intensity Chemical Shift (ppm)
26 Molecular Weight GPC = Gel Permeation Chromatography also SEC (Size Exclusion Chromatography) = Chromatography by Size, calibration required!
27 Molecular Weight Resulting GPC Trace Distribution of Molecular Weight 1 Peak = Monomodal 2 Peaks - imodal >3 peaks = multimodal Retention Time (min) Retention Time (min) A narrow, monomodal distribution is aimed for - typical for controlled polymerisation types (Controlled Radical P., Ring-Opening P.) The broader, the more uncontrolled (Free Radical P., Polyaddition/ Polycondensation) i/multimodal distribution account as dirty polymers
28 Molecular Weight Other methods to access molecular weight Light Scattering Absolute method, no calibration required Has to be calculated to infinite dilution and no angle (Zimm-Plot) Delivers only M w (if connected to GPC also M n ) Viscosimetry: Relative method, multiple factors need to be determined Delivers M h the Mark-Houwink coefficient a a = 0 for rigid spheres, 0.5 for non-expanded coils, 1.0 for expanded coils, 2.0 for rigid rods Mass spectrometry Mostly MALDI-TOF MS used No specific calibration required Makes single chains visible direct calculation of M n and M w Mass (Da)
29 Summary Polymers or Macromolecules are: Molecules with > 1000 atoms with (mainly) covalent bonds in between uilt from repeating units (monomers) Polymers have a: Defined repeating molecular Structure, meaning: One Substance, mostly one repeating unit, only average molecular weight Polymers can be classified into: Natural Polymers vs. Synthetic polymers Thermoplasts vs. Duromers vs. Elastomers Polyesters vs. Polyamides vs. Polyvinylenes vs. Polycarbonates... Polymers have a tacticity (atactic vs. Isotactic vs. syndiotactic) Thermal transitions of polymers are characterised by: Glass Transition Crystallisation Melting Decomposition We owe him a lot
TOPIC 7. Polymeric materials
Universidad Carlos III de Madrid www.uc3m.es MATERIALS SCIENCE AND ENGINEERING TOPIC 7. Polymeric materials 1. Introduction Definition General characteristics Historic introduction Polymers: Examples 2.
More informationChapter 13 - Polymers Introduction
Chapter 13 - Polymers Introduction I. Nomenclature A. Polymer/Macromolecule polymer - nonmetallic material consisting of large molecules composed of many repeating units - from Greek: poly (many) and meros
More informationLecture No. (1) Introduction of Polymers
Lecture No. (1) Introduction of Polymers Polymer Structure Polymers are found in nature as proteins, cellulose, silk or synthesized like polyethylene, polystyrene and nylon. Some natural polymers can also
More informationPolymers in Modified Asphalt Robert Q. Kluttz KRATON Polymers
Polymers in Modified Asphalt Robert Q. Kluttz KRATON Polymers Polymers in Modified Asphalt Types of Polymers Compatibility of Polymers Effects of Polymers Analysis of polymers Recovery of PMA What Is a
More informationPolypropylene. Monomer. mer
Polymer Polymer: Maromolecule built-up by the linking together of a large no. of small molecules Ex. Nucleic acid, paper, bakelite,pvc Monomer: The small molecule which combine with each other Mer: The
More information2. Amorphous or Crystalline Structurally, polymers in the solid state may be amorphous or crystalline. When polymers are cooled from the molten state
2. Amorphous or Crystalline Structurally, polymers in the solid state may be amorphous or crystalline. When polymers are cooled from the molten state or concentrated from the solution, molecules are often
More information1.1 Basic Polymer Chemistry. 1.2 Polymer Nomenclature. 1.3 Polymer Synthesis. 1.4 Chain Growth Polymerization. Polymer =
1.1 Basic Polymer hemistry Polymers are the largest class of soft materials: over 100 billion pounds of polymers made in US each year lassification systems 1.2 Polymer Nomenclature Polymer = Monomer =
More informationMaterials of Engineering ENGR 151 POLYMER STRUCTURES
Materials of Engineering ENGR 151 POLYMER STRUCTURES LEARNING OBJECTIVES Understand different molecular and crystal structures of polymers What are the general structural and chemical characteristics of
More informationPolymer Chemistry - Ring-Opening-Polymerisation (ROP)
Polymer Chemistry - Ring-Opening-Polymerisation (ROP) Aims of this part: General Mechanism Polyesters from Ring-Opening Polymerisation Formation of Nylon 6 (and similar) Polymerisation of N-Carboxy-Anhydrids
More informationPOLYMER SCIENCE : lecture 1. Dr. Hanaa J. Alshimary Second class Poly. Eng. Dep. Introduction of Polymers Polymer poly mer Monomer Polymerization
Introduction of Polymers Polymer - The word polymer is the Greek word : poly means many and mer means unit or parts, A Polymer is a large molecule that comprises repeating structural units joined by the
More informationPolymers and Composite Materials
Polymers and omposite Materials Shibu G. Pillai hemical Engineering Department shibu.pillai@nirmauni.ac.in ontents lassification of Polymers Types of polymerization Elastomers/ Rubber Advanced Polymeric
More informationChapter 11. Polymer Structures. Natural vs man-made
. Polymer Structures Polymers: materials consisting of long molecules - the word polymer comes from the Greek Polys = many Meros = parts Macromolecules (long size of the chains) many parts - typically,
More informationMATERIALS SCIENCE POLYMERS
POLYMERS 1) Types of Polymer (a) Plastic Possibly the largest number of different polymeric materials come under the plastic classification. Polyethylene, polypropylene, polyvinyl chloride, polystyrene,
More informationnot to be republished NCERT Unit I. Multiple Choice Questions (Type-I) 1. Which of the following polymers of glucose is stored by animals?
I. Multiple Choice Questions (Type-I) 1. Which of the following polymers of glucose is stored by animals? Cellulose Amylose Amylopectin Glycogen 2. Which of the following is not a semisynthetic polymer?
More informationCOMPOSITE MATERIALS. Asst. Prof. Dr. Ayşe KALEMTAŞ
COMPOSITE MATERIALS Office ours: Tuesday, 16:30-17:30 akalemtas@mu.edu.tr, akalemtas@gmail.com Phone: +90 252 211 19 17 Metallurgical and Materials Engineering Department ISSUES TO ADDRESS Polymers Applications
More informationThermoplastic. Condensation. Homopolymer. Polymer POLYMERS. Synthetic. Natural. Addition. Copolymer. Polymer. Thermosetting
Thermoplastic Homopolymer Condensation Polymer Natural POLYMERS Synthetic Addition Polymer Copolymer Thermosetting Polymers are very large covalent molecular substances containing tens of thousands of
More informationCH 2 = CH - CH =CH 2
MULTIPLE CHOICE QUESTIONS 1. Styrene is almost a unique monomer, in that it can be polymerized by practically all methods of chain polymerization. A. Free radical B. Anionic C. Cationic D. Co-ordination
More informationChapter : 15. POLYMERS. Level-1:Questions
1) What are polymers? Chapter : 15. POLYMERS Level-1:Questions A: These are referred to as Macromolecules which are formed by joining of repeating structural units on a large scale. 2) Give two examples
More informationTop concepts Chapter : Polymers 1. Polymers are high molecular mass substance consisting of large number of repeating structural units. As polymers are single, giant molecules i.e. big size molecules,
More informationDownloaded from Unit - 15 POLYMERS. Points to Remember
Unit - 15 POLYMERS Points to Remember 1. Polymers are defined as high molecular mass macromolecules which consist of repeating structural units derived from the appropriate monomers. 2. In presence of
More informationSCH4U Synthesis and Polymers. Synthesis Reactions and Addition and Condensation Polymers
SCH4U Synthesis and Polymers Synthesis Reactions and Addition and Condensation Polymers ADDITION POLYMERS ADDITION POLYMERS A + A + A + A A A A A monomers polymer + + + ethylene (ethene) polyethylene
More informationPolymer Chemistry. Radical Polymerisation
Polymer Chemistry Radical Polymerisation Aims of this part: Monomers for Radical Polymerisation Free Radical Polymerisation PS and PMMA and their applications Controlled Radical Polymerisation Emulsion
More informationPaul Rempp and Edward W. Merrill. Polymer Synthesis. 2nd, revised Edition. Hüthig & Wepf Verlag Basel Heidelberg New York
Paul Rempp and Edward W. Merrill Polymer Synthesis 2nd, revised Edition Hüthig & Wepf Verlag Basel Heidelberg New York Table of Contents Part I: Polymerization Reactions Chapter 1: General Considerations
More informationCombustion and thermal degradation of polymers
Polymers and biomaterials - laboratory Combustion and thermal degradation of polymers Theoretical background dr Hanna Wilczura-Wachnik University of Warsaw Faculty of Chemistry Chemical Technology Division
More information(c) Dr. Payal B. Joshi
Polymer (Greek: poly=many; mer=part) Made up of large molecules characterized by repeating units called monomers held together by covalent bonds Functionality To act as monomer, it must have at least two
More informationPolymers. Steep Slope = 3/5 : Self-Avoiding Walk (Polymer Solution) Shallow Slope = 1/2 : Gaussian Random Walk (Polymer Melt)
Polymers 1 Polymers Steep Slope = 3/5 : Self-Avoiding Walk (Polymer Solution) Shallow Slope = 1/2 : Gaussian Random Walk (Polymer Melt) 2 If we consider a series of chains = 0 Except when i = j, and
More informationIntroduction to Polymerization Processes
Introduction to Polymerization Processes Reference: Aspen Polymers: Unit Operations and Reaction Models, Aspen Technology, Inc., 2013. 1- Polymer Definition A polymer is a macromolecule made up of many
More informationPrinciples of Polymer Chemistry
Principles of Polymer Chemistry A. Ravve Consultant in Polymer Chemistry Lincolnwood, Illinois PLENUM PRESS NEW YORK AND LONDON Contents 1. Introduction 1.1. Definitions 1 1.2. Nomenclature of Polymers
More informationMATERIALS SCIENCE TEST Part 1: Structure & Synthesis Topics
Fairfax Science Olympiad Tryouts 2018 Name: _ Score: /75 MATERIALS SCIENCE TEST Part 1: Structure & Synthesis Topics In questions 1-6, draw a diagram of the named functional group. Use R to denote the
More information(Refer Slide Time: 00:58)
Nature and Properties of Materials Professor Bishak Bhattacharya Department of Mechanical Engineering Indian Institute of Technology Kanpur Lecture 18 Effect and Glass Transition Temperature In the last
More informationPolymers are high molecular mass macromolecules composed of repeating structural
Question 15.1: Explain the terms polymer and monomer. Polymers are high molecular mass macromolecules composed of repeating structural units derived from monomers. Polymers have a high molecular mass (10
More informationPHYSICS OF SOLID POLYMERS
PYSIS OF SOLID POLYMERS Professor Goran Ungar WU E, Department of hemical and Biological Engineering Recommended texts: G. Strobl, The Physics of Polymers, Springer 996 (emphasis on physics) U. Gedde,
More informationLecture 25 POLYMERS. April 19, Chemistry 328N
Lecture 25 POLYMERS Wallace Carothers April 19, 2016 Paul Flory Wallace Hume Carothers 1896-1937 Carothers at Dupont 1.Commercializion of Nylon https://www.chemheritage.org/ Nylon was first used for fishing
More informationPOLYMER STRUCTURES ISSUES TO ADDRESS...
POLYMER STRUTURES ISSUES TO ADDRESS... What are the basic microstructural features? ow are polymer properties effected by molecular weight? ow do polymeric crystals accommodate the polymer chain? Melting
More informationPolymeric Materials. Sunan Tiptipakorn, D.Eng.
Polymeric Materials Sunan Tiptipakorn, D.Eng. Department of Chemistry, Faculty of Liberal Arts and Science, Kasetsart University, Kamphaen Saen Campus, Nakorn Phathom, 73140 Thailand. Introduction Material
More informationPOLYMER CHEMISTRY Lecture/Lession Plan -2
Chapter 6 POLYMER CHEMISTRY Lecture/Lession Plan -2 POLYMER CHEMISTRY 6.0.1 Classification on the basis of tactility On the basis of orientation of functional group or side groups throughout the long backbone
More informationIntroduction to Synthetic Methods in Step-Growth Polymers 1.1 INTRODUCTION Historical Perspective Some of the earliest useful polymeric
Synthetics Polymers Introduction to Synthetic Methods in Step-Growth Polymers 1.1 INTRODUCTION 1.1.1 Historical Perspective Some of the earliest useful polymeric materials, the Bakelite resins formed from
More informationThe functionality of a monomer is the number of binding sites that is/are present in that monomer.
Question 15.1: Explain the terms polymer and monomer. Polymers are high molecular mass macromolecules composed of repeating structural units derived from monomers. Polymers have a high molecular mass (10
More informationIntroduction to Engineering Materials ENGR2000 Chapter 14: Polymer Structures. Dr. Coates
Introduction to Engineering Materials ENGR2000 Chapter 14: Polymer Structures Dr. Coates 14.1 Introduction Naturally occurring polymers Wood, rubber, cotton, wool, leather, silk Synthetic polymers Plastics,
More informationMacromolecular chemistry S112003
Supporting material for students registered to subject: Macromolecular chemistry S112003 Teacher: Jan Merna, Department of Polymers, Institute of Chemical Technology,Prague Lecture authored by Jan Merna
More informationPOLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS
POLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS THIRD EDITION J.M.G. COWIE Heriot-Watt University Scotland,UK VALERIA ARRIGHI Heriot-Watt University Scotland,UK Contents Preface The Authors xv xvii
More informationA polymer is a very large molecule that is built from monomers. A monomer is one of the repeating units that make up a polymer.
1.8 Polymers The General Structure of Polymers A polymer is a very large molecule that is built from monomers. A monomer is one of the repeating units that make up a polymer. Many biological molecules,
More informationNote: Brief explanation should be no more than 2 sentences.
Her \Hmher UNIVERSITY OF TORONTO FACULTY OF APPLIED SCIENCE AND ENGINEERING FINAL EXAMINATION, April 26, 2017 DURATION: 2 and /2 hrs MSE245 - HiS - Second Year - MSE Organic Material Chemistry & Processing
More informationDr. M. Medraj Mech. Eng. Dept. - Concordia University MECH 221 lecture 19/2
Polymers Outline Introduction Molecular Structure and Configurations Polymer s synthesis Molecular weight of polymers Crystallinity You may think of polymers as being a relatively modern invention however
More informationMSE 383, Unit 1-4. Joshua U. Otaigbe Iowa State University Materials Science & Engineering Dept.
Polymer Classifications Mole. Wt. MSE 383, Unit 1-4 Joshua U. Otaigbe Iowa State University Materials Science & Engineering Dept. Introduction Recall polymer (macromolecular) definition Covalent linkages
More informationUnit - 15 POLYMERS Points to Remember 1. Polymers are defined as high molecular mass macromolecules which consist of repeating structural units derived from the appropriate monomers. 2. In presence of
More informationLecture 26 Classification
Lecture 26 Classification April 24, 2018 Industrial Influence: Trade Names PVC poly (vinylidene chloride) Saran wrap PVC poly (vinyl chloride) Pipe and records PET poly (ethylene teraphthalate) Coke bottles,
More informationFinal Exam Introduction to Polymers (each part, a,b,c,, is worth 2.2 points)
168 Final Exam Introduction to Polymers (each part, a,b,c,, is worth 2.2 points) 1) Polymers are different than low-molecular weight oligomers. For example an oligomeric polyethylene is wax, oligomeric
More informationAppendix A: The Names of Polymers and Polymeric Materials
Appendix A: The Names of Polymers and Polymeric Materials Every newcomer to the study of polymers is inevitably troubled by the profusion of names for individual polymer materials. Some of the difficulties
More informationSS Vorlesung Polymermaterialien Polymerisationsmethoden
Professur Polymerchemie SS 2017 Vorlesung Prof. Michael Sommer 1 www.tu-chemnitz.de Content Free radical polymerization (PS, PMMA) Controlled radical polymerization Ionic polymerization (cationic, anionic)
More informationEffect of crystallinity on properties. Melting temperature. Melting temperature. Melting temperature. Why?
Effect of crystallinity on properties The morphology of most polymers is semi-crystalline. That is, they form mixtures of small crystals and amorphous material and melt over a range of temperature instead
More informationAn Introduction to Polymer Physics
An Introduction to Polymer Physics David I. Bower Formerly at the University of Leeds (CAMBRIDGE UNIVERSITY PRESS Preface Acknowledgements xii xv 1 Introduction 1 1.1 Polymers and the scope of the book
More informationExperiment 5. Synthetic Polymers.
Experiment 5. Synthetic Polymers. References: Brown & Foote, Chapters 24 INTRODUCTION: A polymer (Greek: polys + meros = many parts) is a giant or macromolecule made up of repeating structural units. The
More informationP O L Y M E R S. The Academic Support Daytona State College (Science 106, Page 1 of 25
P O L Y M E R S The Academic Support Center @ Daytona State College (Science 106, Page 1 of 25 POLYMERS Polymers are large, long-chain molecules. found in nature, including cellulose in plants, starches
More informationLecture 8 Polymers and Gels
Lecture 8 Polymers and Gels Variety of polymeric materials Polymer molecule made by repeating of covalently joint units. Living polymers (not considered in this lecture) long-chain objects connected by
More informationElectronic materials and components-polymer types
Introduction Electronic materials and components-polymer types Polymer science is a broad field that includes many types of materials which incorporate long chain structures with many repeated units. One
More informationPresentation shared files at:
Forrest Schultz, PhD Wisconsin State Science Olympiad Director Director, 2016 Science Olympiad National Tournament Chemistry National Rules Committee Professor, Department of Chemistry and Physics University
More informationChemistry Class 12 th NCERT Solutions
This e-book is prepared by the CBSE board exam experts of jagranjosh.com, an online educational portal of Dainik Jagran. The purpose of providing solutions for CBSE class 12 th Science and Mathematics
More informationPolymers Reactions and Polymers Production (3 rd cycle)
MEQ, MQ, DEQuim, DQuim 2 nd semester 2017/2018, IST-UL Science and Technology of Polymers (2 nd cycle) Polymers Reactions and Polymers Production (3 rd cycle) Lecture 1 Block 1 Fundamentals of Macromolecular
More informationOlle Inganäs: Polymers structure and dynamics. Polymer physics
Polymer physics Polymers are macromolecules formed by many identical monomers, connected through covalent bonds, to make a linear chain of mers a polymer. The length of the chain specifies the weight of
More informationChapter 14: Polymer Structures
Chapter 14: Polymer Structures ISSUES TO ADDRESS... What are the general structural and chemical characteristics of polymer molecules? What are some of the common polymeric materials, and how do they differ
More informationPolymers on the Crime Scene
Polymers on the Crime Scene Valerio Causin Polymers on the Crime Scene Forensic Analysis of Polymeric Trace Evidence Valerio Causin Università di Padova Padova, Italy ISBN 978-3-319-15493-0 DOI 10.1007/978-3-319-15494-7
More informationPOLYMERS: MACROMOLECULES
C21 11/08/2013 16:8:37 Page 311 CHAPTER 21 POLYMERS: MACROMOLECULES SOLUTIONS TO REVIEW QUESTIONS 1. An addition polymer is one that is produced by the successive addition of repeating monomer molecules.
More informationSUBJECT: Polymer Chemistry. STAFF NAME: DrA.Vijayabalan and S.Immanuel. UNIT-I (Part-A)
SUBJECT: Polymer Chemistry SUB.CODE: ECH618 STAFF NAME: DrA.Vijayabalan and S.Immanuel UNIT-I (Part-A) 1. Polymers are obtained by which of the following polymerization reaction. (a) Addition (c) Both
More informationNMR Spectroscopy of Polymers
r NMR Spectroscopy of Polymers Edited by ROGER N. IBBETT Courtaulds Research and Technology Coventry BLACKIE ACADEMIC & PROFESSIONAL An Imprint of Chapman & Hall London Glasgow New York Tokyo Melbourne
More informationChapter 5: Structures of Polymers
hapter 5: Structures of Polymers ISSUES TO ADDRESS... What are the general structural and chemical characteristics of polymer molecules? What are some of the common polymeric materials, and how do they
More informationPacking of Atoms in Solids [5]
Packing of Atoms in Solids [5] Non dense, random packing Energy typical neighbor bond length typical neighbor bond energy r Dense, ordered packing Energy typical neighbor bond length typical neighbor bond
More informationChemistry Notes. Daniel P
Chemistry Notes Daniel P Contents 1 Introduction 3 2 Production of Materials 4 2.1 Ethylene and its Uses...................................... 4 1. Chemical Equations...................................
More informationThe rate of oxygen consumption from a cone calorimeter as an original criterion of evaluation of the fire risk for the Resin Kit polymers
European Journal of Environmental and Safety Sciences 2014 2(2): 23-27 ISSN 1339-472X European Science and Research Institute (Original Research Paper) The rate of oxygen consumption from a cone calorimeter
More informationCan you imagine a world without plastics? Plastic soft drink containers,
21 Polymer Parts R EA D I N G Can you imagine a world without plastics? Plastic soft drink containers, bags, pens, DVDs, and computer and television parts are just a few things made of plastics that would
More informationPOLYMER CHEMISTRY. An Introduction. Malcolm P. Stevens University of Hartford SECOND EDITION
POLYMER CHEMISTRY An Introduction SECOND EDITION Malcolm P. Stevens University of Hartford New York Oxford OXFORD UNIVERSITY PRESS 1990 Contents PART I POLYMER STRUCTURE AND PROPERTIES 1. Basic principles,
More informationSample file. *Learn Basic Information About Polymers *Make a Polymer Ball *Make Slime *Make Floam
S C I E N C E C H E M I S T R Y This Enrichment4You e-guide provides a brief overview of polymers with an emphasis on playful or toy based polymers. In this e-guide you will: PLAYFUL POLYMERS *Learn Basic
More informationChapter 5. Ionic Polymerization. Anionic.
Chapter 5. Ionic Polymerization. Anionic. Anionic Polymerization Dr. Houston S. Brown Lecturer of Chemistry UH-Downtown brownhs@uhd.edu What you should know: What is anionic polymerization? What is MWD,
More informationJBA 2018 Chemistry Exam 2. Name: Score: /100 = /80
JBA 2018 hemistry Exam 2 ame: Score: /100 = /80 Multiple choice questions are worth two points each. 1. onstitutional isomers are compounds that have a. the same chemical formulas and molecular structures
More informationExam III, March 27, 2012, 100 pts Polymer Chemistry, CHEM 466, Spring 2012 Texas A&M University, College Station, TX, USA
On my honor, as an Aggie, I have neither given nor received unauthorized aid on this academic work. Exam III, March 27, 2012, 100 pts Polymer Chemistry, CHEM 466, Spring 2012 Texas A&M University, College
More informationPeriodic table with the elements associated with commercial polymers in color.
Polymers 1. What are polymers 2. Polymerization 3. Structure features of polymers 4. Thermoplastic polymers and thermosetting polymers 5. Additives 6. Polymer crystals 7. Mechanical properties of polymers
More informationIndex. Cationic polymerization alkene monomer, 286
Index A Acrylonitrile-butadiene-styrene (ABS) plastics, 44, 179 Active material, 76 Additive lubricant, 85, 287 odorant, 85 pigment, 85 plasticizer, 85 Anionic co, 236, 237, 259, 296, 297 Anionic carbonyl
More informationPAPER No. 6: PHYSICAL CHEMISTRY-II (Statistical
Subject Chemistry Paper No and Title Module No and Title Module Tag 6, PHYSICAL -II (Statistical 32, Concept of Number average and Mass average molecular weights CHE_P6_M32 TABLE OF CONTENTS 1. Learning
More informationTitle: Cesa-extend a User Friendly Technology to Enhance Reprocessing and Recycling of Condensation Plastics
GPEC 24 Paper Abstract #52: Title: Cesa-extend a User Friendly Technology to Enhance Reprocessing and Recycling of Condensation Plastics Author(s): V. Karayan, Clariant Masterbatches, and M. Villalobos,
More information1 P a g e h t t p s : / / w w w. c i e n o t e s. c o m / Chemistry (A-level)
1 P a g e h t t p s : / / w w w. c i e n o t e s. c o m / Electrophoresis (Chapter 27): Chemistry (A-level) Electrophoresis: the separation of charged particles by their different rates of movement in
More informationThe vibrational spectroscopy of polymers
D. I. BOWER Reader in Polymer Spectroscopy Interdisciplinary Research Centre in Polymer Science & Technology Department of Physics, University of Leeds W.F. MADDAMS Senior Visiting Fellow Department of
More informationLecture 8. Polymers and Gels
Lecture 8 Polymers and Gels Variety of polymeric materials Polymer molecule made by repeating of covalently joint units. Many of physical properties of polymers have universal characteristic related to
More informationContents. Principles: Theory and Practice
Contents Part I Principles: Theory and Practice 1 Physical Principles of Scanning Probe Microscopy Imaging... 3 1.1 Introduction... 3 1.2 The Physical Principles of Atomic Force Microscopy... 4 1.2.1 Forces
More informationComparison of Polymer Separation by Size Exclusion Chromatography and Asymmetric Flow Field Flow Fractionation
Comparison of Polymer Separation by Size Exclusion Chromatography and Asymmetric Flow Field Flow Fractionation Stepan Podzimek, 1 Christoph Johann 2 1 SYNPO / University of Pardubice, Czech Republic, stepan.podzimek@synpo.cz
More informationPOLYMER CHEMISTRY AN INTRODUCTION. Malcolm P. Stevens. University of Hartford. New York Oxford OXFORD UNIVERSITY PRESS
T H I R D E D I T I O N POLYMER CHEMISTRY AN INTRODUCTION Malcolm P. Stevens University of Hartford New York Oxford OXFORD UNIVERSITY PRESS 1999 CONTENTS Preface, PART I xvii POLYMER STRUCTURE AND PROPERTIES
More informationThis name hints at how polymers are made
Chapter- I Many + Parts This name hints at how polymers are made POLYMERS (the whole train) are made out of MONOMERS (individual cars of the train) joined together. repeat unit H H H H H H C C C C C
More informationHow to use GPC/SEC for compositional analysis
How to use GPC/SEC for compositional analysis Determining the relative concentration of two components in a polymer sample MOLECULAR SIZE MOLECULAR STRUCTURE MOLECULAR WEIGHT Introduction Over the last
More informationLiquid Crystal. Liquid Crystal. Liquid Crystal Polymers. Liquid Crystal. Orientation of molecules in the mesophase
Liquid Crystal - Liquid crystals (LCs) are a state of matter that have properties between those of a conventional liquid and those of a solid crystal. (Fourth state of matter) Liquid Crystal Orientation
More informationUnit title: Polymer Chemistry
Unit title: Polymer Chemistry Unit code: L/601/0415 QCF level: 5 Credit value: 15 Aim This unit enables learners to gain an understanding of aspects of the structure, reaction mechanisms and polymer preparations.
More informationHydrocarbon Molecules Polymer Molecules The Chemistry of Polymer Molecules
CHAPTER 14 POLYMER STRUCTURES PROBLEM SOLUTIONS Hydrocarbon Molecules Polymer Molecules The Chemistry of Polymer Molecules 14.1 On the basis of the structures presented in this chapter, sketch repeat unit
More informationIII. Molecular Structure Chapter Molecular Size Size & Shape
III. Molecular Structure Chapter 3. 3. Molecular Size Size & Shape Molecular Structure (1)Molecular Size & Shape Size : molecular weight molecular weight distribution Shape : branching (2) Molecular Flexibility
More informationYou are advised to spend an equal amount of time on each question.
UNIVERSITY OF EAST ANGLIA School of Chemistry Main Series UG Examination 2015 16 MATERIALS AND POLYMER CHEMISTRY CHE-5350Y Time allowed: 2 hours Answer THREE questions. You are advised to spend an equal
More informationGPC - Gel Permeation Chromatography. aka Size Exclusion Chromatography- SEC
GPC - Gel Permeation Chromatography aka Size Exclusion Chromatography- SEC Wendy Gavin Biomolecular Characterization Laboratory Version 1 May 2016 1 Table of Contents 1. GPC Introduction. Page 3 2. How
More informationGPC/SEC An essential tool for polymer analysis
GPC/SEC An essential tool for polymer analysis Ben MacCreath, PhD Product Manager GPC/SEC Instrumentation 26 th March 2013 Introduction to Polymers Where are they found? Polyolefins Engineering Polymers
More informationPS 712 Advanced Polymer Analysis
PS 712 Advanced Polymer Analysis Course outline Prof. Peter Mallon (Course Convener) 1 Aim of this course: Polymer Science 712 Advanced Polymer Analysis 2012 Prof. Peter Mallon (Course Convener) Office:
More informationCatalysis & Sustainable Processes
Catalysis & Sustainable Processes The Polymers Story 8 lectures http://www.kcpc.usyd.edu.au/cem3113.html username: chem3 password: carbon12 Lecturer: Associate Professor Sébastien Perrier s.perrier@chem.usyd.edu.au;
More informationLecture 4 Chapter 13 - Polymers. Functional Groups Condensation Rxns Free Radical Rxns
Lecture 4 Chapter 13 - Polymers Functional Groups Condensation Rxns Free Radical Rxns Chemistry the whole year on one page Last semester Basic atomic theory Stoichiometry, balancing reactions Thermodynamics
More informationOption C: Chemistry in industry and technology
Option C: Chemistry in industry and technology As one of the most important roles of chemistry is to make forms of matter that have never existed before, it plays a central role in any material revolution.
More informationChemical Reaction: another name for a chemical change; a change in which 1 or more substances are converted into new substances
Chemical Reaction: another name for a chemical change; a change in which 1 or more substances are converted into new substances A + B à AB AB à A + B Absorb or release Energy CHEMICAL REACTION No change
More information(1) (2) (3) (4) Quantity
Chapter 39 In primary form (1) (2) (3) (4) 39.01 Polymers of ethylene, in primary forms. 3901.10 000 - Polyethylene having a specific gravity of less than 0.94 kg 20 12 5 0 0 0 3901.20 000 - Polyethylene
More information