Analysis. Priority LC GC. Zebron PAH Accurately quantitate EU and EPA PAHs in less than 28 minutes

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1 Priority Analysis LC GC Core-Shell Technology GC Columns Kinetex PAH Expanded resolution with chemical selectivity specifically for PAHs Increased throughput and sensitivity with core-shell technology for HPLC/UHPLC Zebron PAH Accurately quantitate EU and EPA PAHs in less than minutes Excellent separation for critical PAH isomers

2 FASTER, BETTER RE Kinetex Core-Shell Technology The Chosen Core-Shell Brand Kinetex Core-Shell Technology delivers dramatic improvements in efficiency over conventional fully porous media which can be leveraged to increase resolution, greatly improve productivity, reduce solvent consumption, and decrease costs. Whether you are running HPLC or UHPLC methods, the Kinetex core-shell family can deliver shockingly improved performance over the current column you are using. Solid Core Porous Shell Finely Tuned, Unique Core-Shell Manufacturing Process Phenomenex designs, manufactures, and sells its very own silica and organo-silica core-shell particles. Using silica sol-gel processing techniques that incorporate nano-structuring technology, a durable, homogeneous porous shell is grown on a solid silica core to create a core-shell particle. The combination of a consistent, solid high density core along with proprietary column packing technologies ensures optimum bed structure and high column performance. LC Typical Core-Shell Performance Gains! mau Kinetex Core-Shell Fully Porous You can unleash the power of Kinetex Core-Shell Technology columns to achieve faster and better results just not possible on conventional fully porous materials. No matter what type of system you have or type of analysis you are performing, there is a Kinetex solution for you. 1 App ID min 1 Phenomenex, Inc. All rights reserved. Phenomenex l WEB:

3 ESULTS DRIVEN BY: Zebron Gas Chromatography Technology Continued Innovation with GC Expertise Our inventive GC scientists have + years of experience, and many helped create keystone phases at J&W Scientific before joining the Phenomenex team. Zebron s track record of innovation is the only to be recognized with R&D 1 Awards and Readers Choice awards! This tradition of GC innovation continues even into 1 with the release of the ZB-, ZB-, ZB-FAME and ZB-PAH. NE W ZB-FAME Faster results and improved separation of cis/trans FAME isomers GC Birth of Zebron GC Columns 199 ZB-WAXplus 1 % water stable MS Phases Low bleed, sensitive performance Inferno Phases Stable up to C ZB-MultiResidue Phases Targeted selectivity for pesticide screening ZB-1XT SimDist Robust simulated distillation 9 ZB-Drug-1 For drugs of abuse ZB-Bioethanol min results 1 1 ZB-PAH Accurate PAH analysis from food and environmental samples ZB-CLPesticides Phases Versatility for pesticides by GC/ECD 1 ZB-SemiVolatiles Supreme inertness for environmental SVOCs, PBDEs, and PAHs 1 1 ZB-MSplus Versatile, inert performance for industrial and food applications More Than Just A Column When you choose Zebron, you get more than just high quality GC products. Choosing Zebron means you get access to a wide variety of tools, resources, and personalized support to help make your GC work easier, faster, and simply better. TRY MIS E H SE C N PHA ATIO V I T C DEA CA SILI D E FUS Phenomenex l WEB:

4 Designed for PAH Analysis by HPLC/UHPLC Innovative Polymerically Bonded C1 Core-Shell PAH Column! Si Si O Si Si O Polycyclic aromatic hydrocarbons (PAHs) are a hazardous set of compounds that come from a variety of materials and processes. With the need to accurately identify toxic forms of these compounds quickly in the environmental, fuel, food industries, we specifically developed the first core-shell based LC product for PAH analysis. Now high resolution PAH separations can be attained under fast run times on both HPLC or UHPLC instrumentation. O O PAH QC tested for PAHs (EPA 1) Enhanced resolution and performance for PAH analysis Controlled pore size processing and a proprietary polymerically bonded stationary phase were developed to ensure excellent resolution between priority polycyclic aromatic hydrocarbons (PAHs). Combined with core-shell particle technology, incredibly high efficiency and sensitivity at comfortable LC pressures is very achievable. Have either an HPLC or UHPLC? No worries! The Kinetex PAH.µm core-shell particle size and format has been chosen to provide optimal performance on both HPLC and UHPLC instrumentation. Learn More Online Find more methods and applications online at Phenomenex l WEB:

5 EPA and EU Core-Shell Technology LC Application Examples EPA 1 PAH Analysis mau min App ID 1 Column: Kinetex. µm PAH Dimensions: 1 x. mm Part No.: D--E Mobile Phase: A: Water B: Acetonitrile Gradient: Time (min) % B Flow Rate: 1. ml/min Backpressure: 1 Bar Temperature: C Detection: 9 nm Sample: 1. Naphthalene. Acenaphthylene. Acenaphthene. Fluorene. Phenanthrene. Anthracene. Fluoranthene. Pyrene 9. Benzo[a]anthracene 1. Chrysene. Benzo[b]fluoranthene 1. Benzo[k]fluoranthene 1. Benzo[a]pyrene 1. Dibenzo[a,h]anthracene 1. Benzo[ghi]perylene 1. Indeno[1,,-cd]pyrene EPA 1 PAH Analysis 1 mau min App ID 1 Column: Kinetex. µm PAH Dimensions: 1 x. mm Part No.: D--E Mobile Phase: A: Water B: Acetonitrile Gradient: Time (min) % B Flow Rate: 1. ml/min Backpressure: 1 Bar Temperature: C Detection: 9 nm Sample: 1. Naphthalene 1. Pyrene. Acenaphthylene. 1-Methylnaphthalene. -Methylnaphthalene. Acenaphthene. Fluorene. Phenanthrene. Anthracene 9. Fluoranthene. Benzo[a]anthracene 1. Chrysene 1. Benzo[b]fluoranthene 1. Benzo[k]fluoranthene 1. Benzo[a]pyrene 1. Dibenzo[a,h]anthracene 1. Benzo[ghi]perylene 1. Indeno[1,,-cd]pyrene EU 1+1 PAH Analysis mau min App ID 1 Column: Kinetex. µm PAH Dimensions: 1 x. mm Part No.: D--E Mobile Phase: A: Water B: Acetonitrile Gradient: Time (min) % B Flow Rate: 1. ml/min Backpressure: 1 Bar Temperature: C Detection: 9 nm Sample: 1. Benzo[c]fluorene. Cyclopenta[cd]pyrene. Benzo[a]anthracene. Chrysene. -Methylchrysene. Benzo[j]fluoranthene. Benzo[b]fluoranthene. Benzo[k]fluoranthene 9. Benzo[a]pyrene 1. Dibenzo[a,l]pyrene. Dibenz[a,h]anthracene 1. Benzo[ghi]perylene 1. Indeno[1,,-cd]pyrene 1. Dibenzo[a,e]pyrene 1. Dibenzo[a,i]pyrene 1. Dibenzo[a,h]pyrene Phenomenex l WEB:

6 Designed for PAH Analysis by GC Zebron ZB-PAH columns are manufactured and tested to provide the most optimal performance for EU-regulated polycyclic aromatic hydrocarbons (PAHs). The columns are individually tested with an application-specific QC test probe mixture and deliver excellent resolution of critical PAH isomers, such as benzo[b,j,k]fluoranthene. Cross-Linked Bonding Reinforces stationary phase with incorporation of ladders into polymer backbone Very low bleed propietary stationary phase is applied to the deactivated surface Low Bleed Stationary Phase Deactivated Surface Durable Polyimide Coating With exceptional thermal stability and low column bleed at elevated temperatures, ZB-PAH columns bring the added benefit of good column lifetime alongside a consistent column inertness that promotes accurate baseline resolution for critical isomer pairs. Fit for Purpose Testing ZB-PAH columns are verified with tight industry QC specifications for column bleed, sensitivity, and performance to provide you utmost confidence in qualitative and quantitative results for the analysis of PAHs. QC tested for PAHs Exceptional thermal stability and low column bleed Remarkably Inert! Easy Liner Selection Our GC liner finder tool makes liner selection a breeze. You can even search by application, injection type, GC system, or your current liner part number. Phenomenex l WEB:

7 EPA and EU GC Columns GC Application Examples EU 1+1 PAH Analysis Separation of Key PAHs App ID 1 Column: Zebron ZB-PAH Dimension: meter x.1 mm x.1 µm Part No.: FD-G- Injection: C,. µl Carrier Gas: 1mL/min (constant flow) Oven Program: C for. min to C/min to C/min to C/min to C/min to 1 C/ min for. min Detector: C; - amu Sample: 1. Benzo[c]fluorene. Benz[a]anthracene. Cyclopenta[c,d]pyrene. Chrysene. -Methylchrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[j]fluoranthene 9. Benz[a]pyrene 1. Indeno[1,,-cd]pyrene. Dibenzo[a,h]anthracene 1. Benzo[g,h,i]perylene 1. Dibenzo[a,l]pyrene 1. Dibenzo[a,e]pyrene 1. Dibenzo[a,i]pyrene 1. Dibenzo[a,lh]pyrene Expanded EU 1+1 and EPA 1 PAH Analysis min App ID 9 Column: Zebron ZB-PAH Dimension: meter x.1 mm x.1 µm Part No.: FD-G- Injection: C,. µl Carrier Gas: 1. ml/min (constant flow) Oven Program: C for. min to 1 C/min to C/ min for min to C/min for min to C/min for min Detector: C; - amu Sample: 1. Naphthalene. Acenaphthylene. Acenaphthene. Fluorene. Phenanthrene. Anthracene. Flouranthene. Pyrene 9. Benzo[c]fluorene 1. Benzo[a]anthracene. Cyclopenta[c,d]pyrene 1. Chrysene 1. N-Methylchrysene 1. Benzo[b]fluoranthene 1. Benzo[k]fluoranthene 1. Benzo[j]fluoranthene 1. Benzo[a]pyrene 1. Indeno[1,,-cd]pyrene 19. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene 1. Dibenzo[a,l]pyrene. Dibenzo[a,e]pyrene. Dibenzo[a,i]pyrene. Dibenzo[a,h]pyrene GC-MS Analysis of PAHs in Rubber and Plastic min App ID Column: Zebron ZB-PAH Dimension: meter x.1 mm x.1 µm Part No.: FD-G- Injection: 9 C, 1 µl Carrier Gas: cm/sec (constant flow) Oven Program: 1 C for 1. min to C/min for. min to C/min to C/min Detector: C; - amu Sample: 1. Naphthalene-d. Naphthalene. -Methylnaphthalene. 1-Methylnaphthalene. Acenaphthylene. Acenaphthylene-d1. Acenaphthene. Fluorene 9. Phenanthrene-d1 1. Phenanthrene. Anthracene 1. Fluoranthene 1. Pyrene 1. p-terphenyl-d1 1. Benzo[a]anthracene 1. Chrysene-d1 1. Chrysene 1. Benzo[b]fluoranthene 19. Benzo[k]fluoranthene. Benzo[j]fluoranthene 1. Benzo[e]pyrene. Benzo[a]pyrene. Perylene-d1. Indeno[1,,-cd]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene Phenomenex l WEB:

8 Easily improve your sensitivity and recovery before analysis! With the widest range of sample preparation solutions from Phenomenex you can clean up any matrix before testing for PAHs! roq Type: QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) Description: Quick and efficient process to extract multi-residue target analytes from food samples while removing unwanted interferences such as organic acids, lipids, pigments, sugars, and more. Each kit contain centrifuge tubes, pre-weighed salts in convenient single-use packets, and pre-weighed and packed SPE centrifuge tubes. Strata Silica SPE Type: Solid Phase Extraction Description: Reversed phase, normal phase, or ion-exchange based media that allows for direct retention and elution of compounds of interest, with wash steps to remove unwanted interferences. Available in tubes (ranging from 1 ml to ml) and 9-well plate formats. Strata PAH is available for clean up of water samples. Solid Phase Extraction Strata-X Polymeric SPE Type: Solid Phase Extraction Description: Unique, combined reverse phase and ion-exchange polymeric media developed to cover a diverse spectrum of analytes and simplify the method development process for fast and efficient sample preparation. Available in tubes (ranging from 1 ml to ml) and standard and microelution 9-well plate formats. Polymeric SPE

9 Ordering Information Kinetex SecurityGuard ULTRA. μm Minibore Columns (mm) Cartridges (mm) Phase x.1 1 x.1 1 x.1 /pk PAH B--AN D--AN F--AN AJ-9 for.1 mm ID SecurityGuard ULTRA. μm MidBore (mm) Cartridges (mm) Phase 1 x. /pk PAH D--Y AJ-9 for. mm ID SecurityGuard ULTRA. μm Analytical Columns (mm) Cartridges (mm) Phase 1 x. 1 x. x. /pk PAH D--E F--E G--E AJ-9 for. mm ID *SecurityGuard ULTRA Cartridges require holder, Part No.: AJ-9 Zebron Phase ID (mm) df (µm) Length (m) Part No. ZB-PAH.1.1 FD-G- ZB-PAH.. HG-G- ZB-PAH.. KG-G- Sample Preparation Find part numbers, phases and sizes for our sample preparation solutions through the following links: roq QuEChERS: Strata Silica SPE Strata-X Polymeric SPE If Phenomenex LC and GC columns in this brochure do not provide at least equivalent separations to a competing column of the same phase, particle size, and dimensions, return the Phenomenex column with comparative data within days for a FULL REFUND. 9

10 Find more methods and applications online at Priority Analysis Australia t: +1 ()-9- f: +1 ()-9- Austria t: + ()1-19- f: + () anfrage@phenomenex.com Belgium t: + () 1 (French) t: + () (Dutch) f: +1 ()-9 beinfo@phenomenex.com Canada t: +1 () -1 f: +1 (1) - info@phenomenex.com China t: f: + () -1 phen@agela.com Denmark t: + f: + 1 nordicinfo@phenomenex.com Finland t: + ()9 9 f: + 1 nordicinfo@phenomenex.com France t: + () f: + ()1 9 1 franceinfo@phenomenex.com Germany t: +9 ()1-- f: +9 ()1-- anfrage@phenomenex.com India t: +91 ()-1 f: +91 ()-1 indiainfo@phenomenex.com Ireland t: + ()1 f: eireinfo@phenomenex.com Luxembourg t: +1 ()-1 f: +1 ()-9 nlinfo@phenomenex.com Mexico t: 1--- f: tecnicomx@phenomenex.com The Netherlands t: +1 ()-1 f: +1 ()-9 nlinfo@phenomenex.com New Zealand t: + ()9-91 f: + ()9-9 nzinfo@phenomenex.com Norway t: + 1 f: + 1 nordicinfo@phenomenex.com Puerto Rico t: +1 () 1-HPLC f: +1 (1) - info@phenomenex.com Spain t: f: espinfo@phenomenex.com Sweden t: + () 9 f: + 1 nordicinfo@phenomenex.com United Kingdom t: + ()1-1 f: + ()1-19 ukinfo@phenomenex.com USA t: +1 (1) 1- f: +1 (1) - info@phenomenex.com All other countries Corporate Office USA t: +1 (1) 1- f: +1 (1) - info@phenomenex.com Italy t: +9 1 f: +9 1 italiainfo@phenomenex.com Phenomenex products are available worldwide. For the distributor in your country, contact Phenomenex USA, International Department at international@phenomenex.com BR1_W Terms and Conditions Subject to Phenomenex Standard Terms & Conditions, which may be viewed at Trademarks Kinetex and Strata are registered trademarks and Zebron, Inferno, MultiResidue, WAXplus, MSplus, roq and SecurityGuard are trademarks of Phenomenex. Strata-X is patented by Phenomenex. U.S. Patent No.,9,1, 1 Phenomenex, Inc. All rights reserved.

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