Aggregation States and Proton Conductivity of Nafion in Thin Films
|
|
- Gabriel Shepherd
- 5 years ago
- Views:
Transcription
1 2 nd Oct Fluoropolymer 2016 New Orleans, USA Aggregation States and Proton Conductivity of Nafion in Thin Films Department of Applied Chemistry and International Institute for Carbon-neutral Energy Research (WPI-I2CNER), Kyushu University Keiji Tanaka
2 Aggregation States and Proton Conductivity of Nafion in Thin Films Introduction Swelling Kinetics Proton Conductivity Conclusions
3 Polymer Electrolyte Fuel Cells separator H 2 polyelectrolyte ex. Nafion separator fuel electrode air electrode O 2 The device performance depends on water sorption in polyelectrolyte. To improve the cell performance, it is crucial to understand the swelling behavior of the polyelectrolyte film. Downsizing PEFC is one of the interesting developments due to portability.
4 T g / K Segmental Dynamics in Supported Thin Polystyrene (PS) Films h = 1.6 nm 2. h = 290 nm h PS SiO x layer Si substrate Film thickness / nm ACS Macro Lett. 1(11), (2012). d interfacial potential:f(d) C Φd Φd 8 vdw d long-range interaction ASiO ASiO A x x Si Φd vdw 2 12πd 12π d h 2 A: Hamaker constant
5 Aggregation States and Proton Conductivity of Nafion in Thin Films Introduction Swelling Kinetics Proton Conductivity Conclusions
6 Sample & Film Preparation Nafion Sigma Aldrich Inc. x = 5 ~ 13.5 y = 1000 SiO x Film thickness (h 0 ): 20, 47, 80 nm Nafion Silver Silver Glass (BK7) SiOx Silver Glass (BK7) SiOx Silver Glass (BK7) Glass (BK7) Deposition Spin-coating 3000 rpm, 60 s 313 K, 20 h under vacuum Deposition Nafion Silver Silver Glass (BK7) Glass (BK7)
7 Surface Morphology on silver on quartz in air 1.0 mm 1.0 mm in water 1.0 mm 1.0 mm R q : Root-mean-square roughness Nafion films were flat enough to be characterized both in air and water.
8 Surface Plasmon Resonance (SPR) p-polarized light Critical angle evanescent wave SPR Resonance angle Soft Matter 7(21), (2011).
9 SPR Curve for a Thin Nafion Film in Water Model used to fit the data Water (n = 1.33) Nafion (n = 1.35) silver BK7 parameters d i / nm Nafion 47 silver 34 d i : thickness of i th layer c 2 = h 0 : initial thickness
10 Reflectivity Time Dependence of SPR Curves s 1200 s 3600 s 6000 s s time Nafion / water h 0 = 47 nm Incident angle / deg. The resonance angle shifted to a higher angle with increasing time. The film became thicker in water with increasing time.
11 Swelling ratio Swelling Kinetics by SPR 1.5 Nafion films on silver (SPR) SiO x (SPR) RegimeⅢ 47 nm Time 10 3 / s RegimeⅡ RegimeⅠ A thin Nafion film thickened in the three steps. The swelling kinetics depended on the substrate.
12 Relation between Swelling Ratio and Hydrated Structures in Bulk bound water ionic cluster ionic channel sulfonic acid group free water water binding to sulfonic acid groups 1.05 Formation of sphere-like ionic clusters 1.26 bridge formation between clusters Yoshida et al. J. Membr. Sci. 68, 1 (1992). Laporta et al. PCCP. 1, 4619 (1999). Gebel et al. Macromolecules, 30, 7914 (1997). Gebel et al.. Polymer, 41, 5829 (2000). Schmidt-Rohr et al. Nat. Mater., 7, 75(2008). Hinatsu et al.. J. Electrochem. Soc., 141, 1493 (1994).
13 Reflectivity Reflectivity Neutron Reflectivity (NR) Soft Interface Analyzer (SOFIA) (BL-16, Japan Proton Accelerator Research Complex) neutron quartz q sample D 2 O conditions Elapsed time :15 min Wavelength (l n ) : 0.2 ~ 1.76 nm Incident angle(q) : 0.3 deg. 4 lsinq q π / q : incident angle q : scattering vector Film thickness 100 nm Film thickness 50 nm Roughness 0 nm 10 nm q / nm q / nm -1
14 NR Curves for Thin Nafion Films The shape of an NR curve strongly depended on the type of substrates.
15 Aggregation States of Nafion at Substrate Interface On silver silver Interfacial layer quartz On quartz Interfacial layers quartz D 2 O Nafion D 2 O Nafion (b/v) 10 4 / nm t = s Film thickness / nm single hydrated layer (b/v) 10 4 / nm t = s Film thickness / nm multi-lamellar hydrated layers
16 Swelling ratio Swelling Kinetics by NR 1.5 Nafion films on silver (SPR) silver (NR) 1.4 SiO x (SPR) SiO x (NR) 1.3 RegimeⅢ Time 10 3 / s RegimeⅡ RegimeⅠ
17 Plausible Swelling Model of a Thin Nafion Film in Water RegimeⅢ : : : bound water free water sulfonic acid group ionic cluster ionic channel RegimeⅡ RegimeⅠ RegimeⅠ RegimeⅡ RegimeⅢ / s dried Time swollen
18 Swelling ratio Water Diffusion Diffusion Coefficients based on Fickian model h h w h h 0, i 0, i 1 n0 8 2n 1 2 exp 2n 1 2 D i t t h 0, i 2 0, i D / cm 2 s cf. D in bulk : cm 2 s 1 RegimeⅠ(silver) RegimeⅡ(silver) RegimeⅢ(silver) 1.5 Nafion films on silver (SPR) silver (NR) 1.4 SiO x (SPR) SiO x (NR) RegimeⅢ RegimeⅡ 1.1 RegimeⅠ(SiO x ) RegimeⅡ(SiO x ) 1.0 RegimeⅢ(SiO x ) Time / s h 0 / nm : : : bound water free water sulfonic acid group RegimeⅠ RegimeⅠ RegimeⅡ RegimeⅢ dried ionic cluster Time swollen ionic channel The water sorption was restricted by the substrate interface.
19 Aggregation States and Proton Conductivity of Nafion in Thin Films Introduction Swelling Kinetics Proton Conductivity Conclusions
20 Conclusions Water sorption kinetics and proton conductivity in thin Nafion films were examined. Three-step swelling associated with structural change was observed. Hydrated layers were formed at the substrate interface. Water sorption was restricted by substrate interface. Out-of- and in-plane proton conductivity decreased and increased with decreasing thickness due to the interfacial hydrated layers, respectively.
Layer-by-Layer (LBL) Self-Assembly
Layer-by-Layer (LBL) Self-Assembly 1 Layer-by-Layer (LBL) Self-Assembly No! Layers! Onions have layers! Ogres have Layers! Onions have Layers. You get it? We both have layers. Sherk 2001 Oh, you both have
More informationINTERFACIAL STRUCTURE AND KINETIC MIXING OF Li-SPS/PC BLEND STUDIED BY NEUTRON REFLECTIVITY
Journal of Research (Science), Bahauddin Zakariya University, Multan, Pakistan. Vol.13, No.2, December 2002, pp. 167-175 ISSN 1021-1012 INTERFACIAL STRUCTURE AND KINETIC MIXING OF Li-SPS/PC BLEND STUDIED
More informationSolutions for Assignment-6
Solutions for Assignment-6 Q1. What is the aim of thin film deposition? [1] (a) To maintain surface uniformity (b) To reduce the amount (or mass) of light absorbing materials (c) To decrease the weight
More information6. Plasmon coupling between a flat gold interface and gold nanoparticles.
6. Plasmon coupling between a flat gold interface and gold nanoparticles. 6.1. Introduction In this outlook oriented chapter the applicability of the multilayered system used in chapter 4.1., for the study
More informationSolid State electrochemistry
Solid State electrochemistry edited by Peter G. Bruce Department of Chemistry, University of St Andrews, Scotland IH CAMBRIDGE ^pf UNIVERSITY PRESS 1 1.1 1.2 1.3 1.4 1.5 1.6 Preface Introduction P. G.
More informationSurface Plasmon Wave
Surface Plasmon Wave In this experiment you will learn about a surface plasmon wave. Certain metals (Au, Ag, Co, etc) exhibit a negative dielectric constant at certain regions of the electromagnetic spectrum.
More informationElectrolytes for Fuel Cells
Electrolytes for Fuel Cells Tom Zawodzinski Materials Science and Technology Division Los Alamos National Laboratory Air-Breather Fuel Cell Stack Systems Laptop Demo DCH/Enable Prototype Small Battery
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supplementary Information Visualization of equilibrium position of colloidal particles at fluid-water
More informationStudy on mechanical model of Nafion membrane
ICCM4 8-3 th July, Cambridge, England Abstract Study on mechanical model of Nafion membrane *I. Riku, K. Marui and K. Mimura Graduate School of Engineering, Osaka Prefecture niversity, -, Gakuen-cho, Naka-ku,
More informationSupplementary material for High responsivity mid-infrared graphene detectors with antenna-enhanced photo-carrier generation and collection
Supplementary material for High responsivity mid-infrared graphene detectors with antenna-enhanced photo-carrier generation and collection Yu Yao 1, Raji Shankar 1, Patrick Rauter 1, Yi Song 2, Jing Kong
More informationLow Power Phase Change Memory via Block Copolymer Self-assembly Technology
Low Power Phase Change Memory via Block Copolymer Self-assembly Technology Beom Ho Mun 1, Woon Ik Park 1, You Yin 2, Byoung Kuk You 1, Jae Jin Yun 1, Kung Ho Kim 1, Yeon Sik Jung 1*, and Keon Jae Lee 1*
More informationDielectric constant measurement of P3HT, polystyrene, and polyethylene
Dielectric constant measurement of P3HT, polystyrene, and polyethylene Supervisor: prof. dr. J.C. Hummelen Daily supervisor: Jenny Douvogianni Name: Si Chen (s2660482) 1. Introduction Dielectric constant
More informationProton channels FUEL CELLS
Page 1 FUEL CELLS Proton channels The structure of Nafion, the polymer electrolyte membrane used in some fuel cells, has been extensively debated over recent decades. Now, a newly proposed model reveals
More informationLITHIUM ION BATTERIES
LITHIUM ION BATTERIES 1 Electrodes & Jelly roll 2 3 Types of Lithium ion batteries 원형, 원통형, cylindrical 각형, prismatic 폴리머, polymer (pouch type) 4 Materials composing electrodes 5 6 Terminology-1
More informationMesoporous titanium dioxide electrolyte bulk heterojunction
Mesoporous titanium dioxide electrolyte bulk heterojunction The term "bulk heterojunction" is used to describe a heterojunction composed of two different materials acting as electron- and a hole- transporters,
More informationIn-situ ellipsometry studies of thin swollen films, a review
In-situ ellipsometry studies of thin swollen films, a review Wojciech Ogiegło, Herbert Wormeester, Klaus-Jochen Eichhorn, Matthias Wessling, Nieck E. Benes 1 Thin polymer films Why are they important?
More informationLecture 4. Conductance sensors. ChemFET. Electrochemical Impedance Spectroscopy. py Practical consideration for electrochemical biosensors.
Lecture 4 Conductance sensors. ChemFET. Electrochemical Impedance Spectroscopy. py Practical consideration for electrochemical biosensors. Conductivity I V = I R=, L - conductance L= κa/, l Λ= κ /[ C]
More informationStructure and Characterization of Polystyrene Thin Films
Structure and Characterization of Polystyrene Thin Films Jeffrey L. Ellis 1, Hans G. L. Coster 2, Terry C. Chilcott 2, David L. Tomasko 1*, Fariba Dehghani 2 1 Department of Chemical and Biomolecular Engineering,
More informationTitle. CitationThe Journal of Physical Chemistry B, 111(29): Issue Date Doc URL. Type. File Information. Effect
Title Structural Analysis of Polyelectrolyte Film Absorbin Effect Sugiyama, Masaaki; Mitsui, Takao; Sato, Takashi; Aka Author(s) Itoh, Keiji; Mori, Kazuhiro; Fukunaga, Toshiharu CitationThe Journal of
More informationAn Effect of Molecular Motion on Carrier Formation. in a Poly(3-hexylthiophene) Film
Supplementary Information An Effect of Molecular Motion on Carrier Formation in a Poly(3-hexylthiophene) Film Yudai Ogata 1, Daisuke Kawaguchi 2*, and Keiji Tanaka 1,3* 1 Department of Applied Chemistry,
More information4. CV curve of GQD on platinum electrode S9
Supporting Information Luminscent Graphene Quantum Dots (GQDs) for Organic Photovoltaic Devices Vinay Gupta*, Neeraj Chaudhary, Ritu Srivastava, Gauri Dutt Sharma, Ramil Bhardwaj, Suresh Chand National
More informationCOMPLEX FLOW OF NANOCONFINED POLYMERS
COMPLEX FLOW OF NANOCONFINED POLYMERS Connie B. Roth, Chris A. Murray and John R. Dutcher Department of Physics University of Guelph Guelph, Ontario, Canada N1G 2W1 OUTLINE instabilities in freely-standing
More informationPorous silicon as base material of MEMS-compatible fuel cell components
Porous silicon as base material of MEMS-compatible fuel cell components José Geraldo Alves Brito Neto Tokyo University of Science - Faculty of Science and Technology Department of Mechanical Engineering
More informationEnergy fluxes in plasmas for fabrication of nanostructured materials
Energy fluxes in plasmas for fabrication of nanostructured materials IEAP, Universität Kiel 2nd Graduate Summer Institute "Complex Plasmas" August 5-13, 2010 in Greifswald (Germany) AG 1 Outline Motivation
More informationDEVELOPMENT OF POLYELECTROLYTES COMPLEX MEMBRANE FOR SUPERCAPACITOR
DEVELOPMENT OF POLYELECTROLYTES COMPLEX MEMBRANE FOR SUPERCAPACITOR Pisut Wijitsettakun a, Stephan Thierry Dubas a a The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, Thailand
More informationHydrophilization of Fluoropolymers and Silicones
2017 Adhesive and Sealant Council Spring Meeting Hydrophilization of Fluoropolymers and Silicones Aknowledgements: Wei Chen Mount Holyoke College NSF, NIH, Dreyfus, ACS-RF, MHC Bryony Coupe, Mamle Quarmyne,
More informationSupporting Information
Supporting Information Electrogenerated Chemiluminescence of Single Conjugated Polymer Nanoparticles Ya-Lan Chang, Rodrigo E. Palacios, Fu-Ren F. Fan, Allen J. Bard, and Paul F. Barbara Department of Chemistry
More informationAugust 27, International ANSYS Conference Nick Reynolds, Ph.D. Director, Materials Pre-Sales, US, Accelrys
Multiscale modeling and simulation developing solutions which link the atomistic, mesoscale, and engineering scales August 27, 2008 2008 International ANSYS Conference Nick Reynolds, Ph.D. Director, Materials
More informationAdvanced Analytical Chemistry Lecture 12. Chem 4631
Advanced Analytical Chemistry Lecture 12 Chem 4631 What is a fuel cell? An electro-chemical energy conversion device A factory that takes fuel as input and produces electricity as output. O 2 (g) H 2 (g)
More informationSuppporting Information for Electrochemical Effects in Thermoelectric Polymers
Suppporting Information for Electrochemical Effects in Thermoelectric Polymers William B. Chang 1, Haiyu Fang 2, Jun Liu 3, Christopher M. Evans 2, Boris Russ 4, Bhooshan C. Popere 2, Shrayesh N. Patel
More informationStructure-Thermal Property Correlation of Aligned Silicon. Dioxide Nanorod Arrays
Supplementary Material for Structure-Thermal Property Correlation of Aligned Silicon Dioxide Nanorod Arrays S. Dynamic shadowing growth (DSG) technique Figure S depicts a schematic of the DSG setup. For
More informationA Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide. Ryan Huschka LANP Seminar February 19, 2008
A Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide Ryan Huschka LANP Seminar February 19, 2008 TiO 2 Applications White Pigment Photocatalyst Previous methods to
More informationSelf-assembled nanostructures for antireflection optical coatings
Self-assembled nanostructures for antireflection optical coatings Yang Zhao 1, Guangzhao Mao 2, and Jinsong Wang 1 1. Deaprtment of Electrical and Computer Engineering 2. Departmentof Chemical Engineering
More informationInteraction of Gold Nanoparticle with Proteins
Chapter 7 Interaction of Gold Nanoparticle with Proteins 7.1. Introduction The interfacing of nanoparticle with biomolecules such as protein is useful for applications ranging from nano-biotechnology (molecular
More informationHigh Performance, Low Operating Voltage n-type Organic Field Effect Transistor Based on Inorganic-Organic Bilayer Dielectric System
Journal of Physics: Conference Series PAPER OPEN ACCESS High Performance, Low Operating Voltage n-type Organic Field Effect Transistor Based on Inorganic-Organic Bilayer Dielectric System To cite this
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION Facile Synthesis of High Quality Graphene Nanoribbons Liying Jiao, Xinran Wang, Georgi Diankov, Hailiang Wang & Hongjie Dai* Supplementary Information 1. Photograph of graphene
More informationSynthesis of Highly Ion-Conductive Polymers for Fuel Cells (for H + and OH )
Synthesis of Highly Ion-Conductive Polymers for Fuel Cells (for H + and OH ) Chulsung Bae Department of Chemistry & Chemical Biology Rensselaer Polytechnic Institute Collaborators: Michael A. Hickner (Penn
More informationSpecific ion effects on the interaction of. hydrophobic and hydrophilic self assembled
Supporting Information Specific ion effects on the interaction of hydrophobic and hydrophilic self assembled monolayers T. Rios-Carvajal*, N. R. Pedersen, N. Bovet, S.L.S. Stipp, T. Hassenkam. Nano-Science
More informationSupporting Information for. Highly durable Pd metal catalysts for the oxygen. reduction reaction in fuel cells; Coverage of Pd metal with.
Supporting Information for Highly durable Pd metal catalysts for the oxygen reduction reaction in fuel cells; Coverage of Pd metal with silica Sakae Takenaka 1 *, Naoto Susuki 1, Hiroaki Miyamoto 1, Eishi
More information*blood and bones contain colloids. *milk is a good example of a colloidal dispersion.
Chap. 3. Colloids 3.1. Introduction - Simple definition of a colloid: a macroscopically heterogeneous system where one component has dimensions in between molecules and macroscopic particles like sand
More informationMeasure mass, thickness and structural properties of molecular layers Automated and fully integrated turn-key system
Product Information Q-Sense Omega Auto Real-time interface characterization Measure mass, thickness and structural properties of molecular layers Automated and fully integrated turn-key system 30 µl sample
More informationTunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen. reduction reaction Electronic Supplementary information (ESI)
Tunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen reduction reaction Electronic Supplementary information (ESI) Stephanie-Angelika Wohlgemuth,* a Tim-Patrick Fellinger
More informationDETERMINATION OF THE REFRACTIVE INDEX OF THE SE1211 RESIN USING AN SPR SPECTROSCOPY
Molecular and Quantum Acoustics vol. 26, (2005) 267 DETERMINATION OF THE REFRACTIVE INDEX OF THE SE1211 RESIN USING AN SPR SPECTROSCOPY Cuma TYSZKIEIWCZ, Erwin MACIAK, Paweł KARASIŃSKI, Tadeusz PUSTELNY
More informationSynthesis and Substitution Chemistry of Redox-Active
Supporting Information Synthesis and Substitution Chemistry of Redox-Active Manganese/Cobalt Oxide Nanosheets Nobuyuki Sakai, Katsutoshi Fukuda, Renzhi Ma, and Takayoshi Sasaki *, International Center
More informationSupplementary Information
Electrochemical Charging of Single Gold Nanorods Carolina Novo, Alison M. Funston, Ann K. Gooding, Paul Mulvaney* School of Chemistry & Bio21 Institute, University of Melbourne, Parkville, VIC, 3010, Australia
More informationSUPPLEMENTARY INFORMATION
doi:10.1038/nature17653 Supplementary Methods Electronic transport mechanism in H-SNO In pristine RNO, pronounced electron-phonon interaction results in polaron formation that dominates the electronic
More informationElectronic Supplementary Information for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 018 Electronic Supplementary Information for Broadband Photoresponse Based on
More informationdissolved into methanol (20 ml) to form a solution. 2-methylimidazole (263 mg) was dissolved in
Experimental section Synthesis of small-sized ZIF-8 particles (with average diameter of 50 nm): Zn(NO 3 ) 2 (258 mg) was dissolved into methanol (20 ml) to form a solution. 2-methylimidazole (263 mg) was
More informationHydrocarbon Fuel Cell Membranes Containing Perfluorosulfonic Acid Group
Hydrocarbon Fuel Cell Membranes Containing Perfluorosulfonic Acid Group Ying Chang and Chulsung Bae Department of Chemistry & Chemical Biology Rensselaer Polytechnic Institute, Troy, NY 12180 Collaborators
More informationA Novel Electroless Method for the Deposition of Single-Crystalline Platinum Nanoparticle Films On
Supplementary Information A Novel Electroless Method for the Deposition of Single-Crystalline Platinum Nanoparticle Films On an Organic Solid Matrix in the Presence of Gold Single Crystals Khaleda Banu,,,*
More informationFuel-Cell Performance of Multiply-Crosslinked Polymer Electrolyte Membranes Prepared by Two-Step Radiation Technique
Fuel-Cell Performance of Multiply-Crosslinked Polymer Electrolyte Membranes Prepared by Two-Step Radiation Technique T. Yamaki a, S. Sawada a, M. Asano a, Y. Maekawa a, M. Yoshida a, L. Gubler b, S. Alkan-Gürsel
More informationLocalized and Propagating Surface Plasmon Co-Enhanced Raman Spectroscopy Based on Evanescent Field Excitation
Supplementary Information Localized and Propagating Surface Plasmon Co-Enhanced Raman Spectroscopy Based on Evanescent Field Excitation Yu Liu, Shuping Xu, Haibo Li, Xiaoguang Jian, Weiqing Xu* State Key
More information1 EX/P4-8. Hydrogen Concentration of Co-deposited Carbon Films Produced in the Vicinity of Local Island Divertor in Large Helical Device
1 EX/P4-8 Hydrogen Concentration of Co-deposited Carbon Films Produced in the Vicinity of Local Island Divertor in Large Helical Device T. Hino 1,2), T. Hirata 1), N. Ashikawa 2), S. Masuzaki 2), Y. Yamauchi
More informationSupplementary Information for. Effect of Interface on Surface Morphology and Proton Conduction of Polymer Electrolyte Thin Films
Supplementary Information for Effect of Interface on Surface Morphology and Proton Conduction of Polymer Electrolyte Thin Films Akihiro Ohira* a,b, Seiichi. Kuroda* b, Hamdy F. M. Mohamed b,c, and Bruno
More informationThermal conductance of weak and strong interfaces
Thermal conductance of weak and strong interfaces David G. Cahill, Wen-Pin Hsieh, Mark Losego, Paul Braun, Dong-Wook Oh, Seok Kim, Eric Pop, Sanjiv Sinha, Paul Braun, and John Rogers Department of Materials
More information768 Lecture #11 of 18
Lecture #11 of 18 768 769 Q: What s in this set of lectures? A: B&F Chapter 2 main concepts: Section 2.1 : Section 2.3: Salt; Activity; Underpotential deposition Transference numbers; Liquid junction potentials
More informationMagnetoplasmonics: fundamentals and applications
Antonio García-Martín http://www.imm-cnm.csic.es/magnetoplasmonics Instituto de Microelectrónica de Madrid Consejo Superior de Investigaciones Científicas Magnetoplasmonics: fundamentals and applications
More informationSupplemental Information for
Supplemental Information for Densely arranged two-dimensional silver nanoparticle assemblies with optical uniformity over vast areas as excellent surface-enhanced Raman scattering substrates Yoshimasa
More informationExperimental Study of Nafion- and Flemion-based Ionic Polymermetal Composites (IPMCs) with Ethylene Glycol as Solvent
Experimental Study of Nafion- and Flemion-based Ionic Polymermetal Composites (IPMCs) with Ethylene Glycol as Solvent Sia Nemat-Nasser and Shahram Zamani University of California, San Diego Center of Excellence
More informationLight-Induced Atom Desorption in Alkali Vapor Cells
Fundamental Physics Using Atoms, 2010/08/09, Osaka Light-Induced Atom Desorption in Alkali Vapor Cells A. Hatakeyama (Tokyo Univ. Agr. Tech.) K. Hosumi K. Kitagami Alkali vapor cells UHV cell for laser
More informationHysteresis-free low-temperature-processed planar perovskite solar cells with 19.1% efficiency
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Supplementary Information Hysteresis-free low-temperature-processed planar
More information7.1 Electrolyte and electrolytic solution
Out-class reading: Levine, pp. 294-310 Section 10.6 solutions of electrolytes Section 10.9 ionic association pp. 512-515 Section 16.6 electrical conductivity of electrolyte solutions. Contents of solution
More informationQuasi-3D Modeling of Water Transport in Polymer Electrolyte Fuel Cells
A1432 0013-4651/2003/15011/A1432/8/$7.00 The Electrochemical Society, Inc. Quasi-3D Modeling of Water Transport in Polymer Electrolyte Fuel Cells A. A. Kulikovsky a Research Center Jülich, Institute for
More informationMicroscopic Analysis of Current and Mechanical Properties of Nafion Studied by Atomic Force Microscopy
Membranes 2012, 2, 783-803; doi:10.3390/membranes2040783 Article OPEN ACCESS membranes ISSN 2077-0375 www.mdpi.com/journal/membranes Microscopic Analysis of Current and Mechanical Properties of Nafion
More informationElectrolytic membranes : Ion conduction in nanometric channels
Electrolytic membranes : Ion conduction in nanometric channels Philippe Knauth Aix Marseille Université - CNRS Marseille, France Philippe Knauth 1 utline of the Presentation 1. Introduction 2. Synthesis
More informationFrom the excitation of surface plasmon polaritons (SPP s) by evanescent waves to SERS active sites Andreas Otto
From the excitation of surface plasmon polaritons (SPP s) by evanescent waves to SERS active sites Andreas Otto 1) History of plasmons, surface plasmon polaritons (SPP) and Ottoconfiguration 2) Roughness
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Engineering Cu 2 O/NiO/Cu 2 MoS 4 Hybrid Photocathode for H 2 Generation in Water Chen Yang, a,b
More informationSupporting Information
Supporting Information Spatial heterogeneity in lyotropic liquid crystal with hexagonal phase David P. Penaloza Jr., Koichiro Hori, Atsuomi Shundo,* and Keiji Tanaka* Department of Applied Chemistry, Kyushu
More informationPaper presentation. M S Bootha Raju Date: 28/11/09
Paper presentation M S Bootha Raju Date: 28/11/09 Photoemission Spectroscopy and Atomic Force Microscopy Investigation of Vapor-Phase Codeposited Silver/Poly(3-hexylthiophene) Composites L. Scudiero, Haoyan
More informationSeminar Series. Fabrication and Characterization of Thin Film Nickel Hydroxide Electrodes for Micro Power Applications ABSTRACT.
Fabrication and Characterization of Thin Film Nickel Hydroxide Electrodes for Micro Power Applications Hamid Falahati Micro power sources are very attractive for nano and micro scale devices, such as Point
More informationCharge and mass transfer across the metal-solution interface. E. Gileadi School of Chemistry Tel-Aviv University, ISRAEL
Charge and mass transfer across the metal-solution interface E. Gileadi School of Chemistry Tel-Aviv University, ISRAEL gileadi@post.tau.ac.il 1 Time-Resolved Kinetics The idea of different time scales
More informationGrating-coupled transmission-type surface plasmon resonance sensors based on dielectric and metallic gratings
Grating-coupled transmission-type surface plasmon resonance sensors based on dielectric and metallic gratings Kyung Min Byun, 1 Sung June Kim, 1 and Donghyun Kim 2, * 1 School of Electrical Engineering
More informationPlasmonic Hot Hole Generation by Interband Transition in Gold-Polyaniline
Supplementary Information Plasmonic Hot Hole Generation by Interband Transition in Gold-Polyaniline Tapan Barman, Amreen A. Hussain, Bikash Sharma, Arup R. Pal* Plasma Nanotech Lab, Physical Sciences Division,
More informationSurface plasmon resonance based refractive index sensor for liquids
Indian Journal of Pure & Applied Physics Vol. 43, November 005, pp. 854-858 Surface plasmon resonance based refractive index sensor for liquids Navina Mehan, Vinay Gupta, K Sreenivas & Abhai Mansingh Department
More informatione - Galvanic Cell 1. Voltage Sources 1.1 Polymer Electrolyte Membrane (PEM) Fuel Cell
Galvanic cells convert different forms of energy (chemical fuel, sunlight, mechanical pressure, etc.) into electrical energy and heat. In this lecture, we are interested in some examples of galvanic cells.
More informationElectronic Supplementary Information Organic electrochemical transistors monitoring micelle formation
Electronic Supplementary Information Organic electrochemical transistors monitoring micelle formation Giuseppe Tarabella 1, Gaurav Nanda 2, Marco Villani 1, Nicola Coppedè 1, Roberto Mosca 1, George G.
More informationmaximal photofluorescence decay time of 6 hours (purchased from Shenzhen HuiDuoSheng
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Experimental section Preparation of m-tio 2 /LPP photoanodes. TiO 2 colloid was synthesized according
More informationDevelopment of active inks for organic photovoltaics: state-of-the-art and perspectives
Development of active inks for organic photovoltaics: state-of-the-art and perspectives Jörg Ackermann Centre Interdisciplinaire de Nanoscience de Marseille (CINAM) CNRS - UPR 3118, MARSEILLE - France
More informationPingshan Wang. Jim Rui
Probing, Charging and Discharging of Single Nanopores in a Supercapacitor Pingshan Wang Electrical and Computer Engineering Department, Clemson University Jim Rui Mechanical Engineering Department Clemson
More informationSurfactant-free exfoliation of graphite in aqueous solutions
Surfactant-free exfoliation of graphite in aqueous solutions Karen B. Ricardo, Anne Sendecki, and Haitao Liu * Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, U.S.A 1. Materials
More informationSurface Sensitive X-ray Scattering
Surface Sensitive X-ray Scattering Introduction Concepts of surfaces Scattering (Born approximation) Crystal Truncation Rods The basic idea How to calculate Examples Reflectivity In Born approximation
More informationSupplementary Information for. Vibrational Spectroscopy at Electrolyte Electrode Interfaces with Graphene Gratings
Supplementary Information for Vibrational Spectroscopy at Electrolyte Electrode Interfaces with Graphene Gratings Supplementary Figure 1. Simulated from pristine graphene gratings at different Fermi energy
More informationSupplementary Information. Light Manipulation for Organic Optoelectronics Using Bio-inspired Moth's Eye. Nanostructures
Supplementary Information Light Manipulation for Organic Optoelectronics Using Bio-inspired Moth's Eye Nanostructures Lei Zhou, Qing-Dong Ou, Jing-De Chen, Su Shen, Jian-Xin Tang,* Yan-Qing Li,* and Shuit-Tong
More informationEvaluating nanogaps in Ag and Au nanoparticle clusters for SERS applications using COMSOL Multiphysics
Evaluating nanogaps in Ag and Au nanoparticle clusters for SERS applications using COMSOL Multiphysics Ramesh Asapu 1, Radu-George Ciocarlan 2, Nathalie Claes 3, Natan Blommaerts 1, Sara Bals 3, Pegie
More information3.155J/6.152J Microelectronic Processing Technology Fall Term, 2004
3.155J/6.152J Microelectronic Processing Technology Fall Term, 2004 Bob O'Handley Martin Schmidt Quiz Nov. 17, 2004 Ion implantation, diffusion [15] 1. a) Two identical p-type Si wafers (N a = 10 17 cm
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Supporting Information Graphene transfer method 1 : Monolayer graphene was pre-deposited on both
More informationJournal of Electroanalytical Chemistry
Journal of Electroanalytical Chemistry 622 (2008) 145 152 Contents lists available at ScienceDirect Journal of Electroanalytical Chemistry journal homepage: www.elsevier.com/locate/jelechem Investigation
More informationElectrochemically Exfoliated Graphene as Solution-Processable, Highly-Conductive Electrodes for Organic Electronics
Supporting Information Electrochemically Exfoliated Graphene as Solution-Processable, Highly-Conductive Electrodes for Organic Electronics Khaled Parvez, Rongjin Li, Sreenivasa Reddy Puniredd, Yenny Hernandez,
More informationWater sorption, desorption and transport in Nafion membranes
Journal of Membrane Science 301 (2007) 93 106 Water sorption, desorption and transport in Nafion membranes Paul W. Majsztrik b, M. Barclay Satterfield a, Andrew B. Bocarsly b, Jay B. Benziger a, a Department
More informationFoundations of. Colloid Science SECOND EDITION. Robert J. Hunter. School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS
Foundations of Colloid Science SECOND EDITION Robert J. Hunter School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS CONTENTS 1 NATURE OF COLLOIDAL DISPERSIONS 1.1 Introduction 1 1.2 Technological
More informationSeiichi Tagawa, Satoshi Enomoto, Akihiro Oshima
Time Resolved Spectroscopy of Nanoparticle EUV Photoresists Reactions of HfO nanoparticles with electrons and the following solubility change studied by pulse radiolysis Seiichi Tagawa, Satoshi Enomoto,
More informationStructural and Electronic properties of platinum nanoparticles studied by diffraction and absorption spectroscopy
The 4 th SUNBEAM Workshop Structural and Electronic properties of platinum nanoparticles studied by in situ x-ray x diffraction and in situ x-ray x absorption spectroscopy Hideto Imai Fundamental and Environmental
More informationINVESTIGATION of Si and SiO 2 ETCH MECHANISMS USING an INTEGRATED SURFACE KINETICS MODEL
46 th AVS International Symposium Oct. 25-29, 1999 Seattle, WA INVESTIGATION of Si and SiO 2 ETCH MECHANISMS USING an INTEGRATED SURFACE KINETICS MODEL Da Zhang* and Mark J. Kushner** *Department of Materials
More informationTunable Nanoparticle Arrays at Charged Interfaces
Tunable Nanoparticle Arrays at Charged Interfaces Supporting Material Sunita Srivastava 1, Dmytro Nykypanchuk 1, Masafumi Fukuto 2 and Oleg Gang 1* 1 Center for Functional Nanomaterials, Brookhaven National
More informationSupporting Information
Supporting Information Band Gap Tuning of CH 3 NH 3 Pb(Br 1-x Cl x ) 3 Hybrid Perovskite for Blue Electroluminescence Naresh K. Kumawat 1, Amrita Dey 1, Aravindh Kumar 2, Sreelekha P. Gopinathan 3, K.
More informationSupplementary information
Supplementary information Neutral Colour Semitransparent Microstructured Perovskite Solar Cells Giles E. Eperon, Victor M. Burlakov, Alain Goriely and Henry J. Snaith 1. Controlling dewetting to achieve
More information1. Depleted heterojunction solar cells. 2. Deposition of semiconductor layers with solution process. June 7, Yonghui Lee
1. Depleted heterojunction solar cells 2. Deposition of semiconductor layers with solution process June 7, 2016 Yonghui Lee Outline 1. Solar cells - P-N junction solar cell - Schottky barrier solar cell
More informationHigh-Performance Semiconducting Polythiophenes for Organic Thin Film. Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner
Supplementary Materials for: High-Performance Semiconducting Polythiophenes for Organic Thin Film Transistors by Beng S. Ong,* Yiliang Wu, Ping Liu and Sandra Gardner 1. Materials and Instruments. All
More informationPhotolithography 光刻 Part II: Photoresists
微纳光电子材料与器件工艺原理 Photolithography 光刻 Part II: Photoresists Xing Sheng 盛兴 Department of Electronic Engineering Tsinghua University xingsheng@tsinghua.edu.cn 1 Photolithography 光刻胶 负胶 正胶 4 Photolithography
More informationSupporting Information
Supporting Information Water uptake study of anion exchange membranes Yiwei Zheng, Uri Ash, Ravi P. Pandey, Amobi G. Ozioko, Julia Ponce-González, Michael Handl, Thomas Weissbach, John R. Varcoe, Steven
More information