SUPPLEMENTARY INFORMATION
|
|
- Shana Molly Osborne
- 5 years ago
- Views:
Transcription
1 In the format provided by the authors and unedited. SUPPLEMENTARY INFORMATION ARTICLE NUMBER: DOI: /NENERGY Photocatalytic hydrogen generation from hydriodic acid using methylammonium lead iodide in dynamic equilibrium with aqueous solution Sunghak Park 1, Woo Je Chang 2, Chan Woo Lee 1, Sangbaek Park 1, Hyo-Yong Ahn 1, and Ki Tae Nam 1,2* 1 Department of Materials Science and Engineering, Seoul National University, Seoul , Korea 2 Interdisciplinary Program for Bioengineering, Seoul National University, Seoul , Korea These authors contributed equally to this work * To whom correspondence should be addressed: Ki Tae Nam, Ph.D. Department of Materials Science and Engineering, Seoul National University, Seoul , Korea (Republic of) Tel: , Fax: nkitae@snu.ac.kr NATURE ENERGY 1
2 Supplementary Figure 1 Scanning Electron Microscope (SEM) images of MAPbI3 prepared from organic solvent before (a) and after (b-d) dipping in a saturated solution. The dipping times were 1 min (b), 10 min (c), and 30 min (d). NATURE ENERGY 2
3 Supplementary Figure 2 SEM images of the as-prepared MAPbI3 powder formed in saturated HI solution. a, Image of MAPbI3 powders with wide size distributions. b, Magnified image of one MAPbI3 powder. NATURE ENERGY 3
4 NATURE ENERGY 4
5 Supplementary Figure 3 X-ray diffraction (XRD) patterns of the precipitates with various [I - ] and [H + ] concentrations. The black, red, blue, magenta, green, royal blue, purple, and violet lines indicate log[i - ]=1, 0.5, 0, -0.2, -0.4, -0.5, -0.6 and The black dashed line indicates the peak position of the tetragonal MAPbI3 phase, the sky blue line indicates the peak position of the monohydrate phase, the blue line indicates the peak position of the dihydrate phase and the dark yellow line indicates the peak position of the PbI2 phase. The star indicates the pattern of KI. a, The ph is b, The ph is c, The ph is d, The ph is e, The ph is f, The ph is 0. g, The ph is 0.5. h, The ph is 1. NATURE ENERGY 5
6 Supplementary Figure 4 Kubelka-Munk equation applied to the absorbance spectrum of the MAPbI3 Powder. The energy is determined from the wavelength of the absorbance spectrum. The optical absorption coefficient, F(α) = A 2 / 2(1-A), is calculated where A is absorbance, h is the planck constant ( m 2 kg s -1 ), and ν is the frequency of light at a specific wavelength. The multiplying factor of P at (F(α)hν) P is confirmed as 2 due to its linear drop line, which indicates the direct band gap character of the MAPbI3 powder. By extrapolating the drop line to zero, the band gap can be determined to be 1.53 ev. NATURE ENERGY 6
7 Supplementary Figure 5 Photocatalytic HI splitting by the MAPbI3 powder in saturated solution at various conditions. a, Photocatalytic HI splitting reaction of MAPbI3 powder in a saturated solution under both light and dark conditions. b, Photocatalytic HI splitting reaction of the saturated solution in the presence and absence of MAPbI3 powder. NATURE ENERGY 7
8 Supplementary Figure 6 Electrochemical H2 evolution from an MAPbI3 electrode in a saturated solution system. a, Linear sweep voltammetry curve of an MAPbI3-loaded carbon electrode in a saturated solution system. It shows significant electrocatalytic H2 evolution activity. In contrast, an unmodified carbon electrode shows minimal H2 evolution activity in aqueous HI. The carbon electrode also shows little H2 evolution activity in a saturated solution. b, Theoretical amount of evolved H2 and measured amount of H2 after bulk electrolysis using the MAPbI3 electrode. The bulk electrolysis was conducted at -0.9 V versus saturated calomel electrode (vs. SCE), and the evolved H2 was analysed by GC. NATURE ENERGY 8
9 Supplementary Figure 7 Absorbance of the standard I3 - solution for I3 - quantification. The standard solutions containing specific amounts of I3 - were characterized by UV-Vis absorption spectroscopy. The inset displays the absorbance curve of the standard at 353 nm. The concentration of I3 - in an unknown solution could be determined by substituting the value of the absorbance at 353 nm into the I3 - standard curve at 353 nm. The slope of the standard curve was , and intercept was The R 2 value was NATURE ENERGY 9
10 Supplementary Figure 8 Absorbance of 6.06 mol L -1 HI and the HI solution with added H3PO2. Visible light could be absorbed by the 6.06 mol L -1 HI solution. In contrast, almost no visible light could be absorbed by the H3PO2 added HI solution. NATURE ENERGY 10
11 Supplementary Figure 9 Linear sweep voltammetry measurement of H3PO2 aqueous solution with different ions conditions. The applied anodic potential only oxidize I - ions into I3 - ions in the solution. Concomitant I3 - generation was visually observed by the formation of dark brown colour at Pt working electrode during the sweep. H3PO2 remains stably in the measured potential range. NATURE ENERGY 11
12 Supplementary Figure 10 XRD patterns of MAPbI3 powder before and after photocatalytic HI splitting reaction. Tetragonal MAPbI3 phase was maintained after photocatalytic HI splitting reaction NATURE ENERGY 12
13 Supplementary Figure 11 MAPbI3 powder cycling test. Each evacuation process was performed with Ar after following 5 h of photocatalytic reaction. This cycling was repeated three times. NATURE ENERGY 13
14 Supplementary Figure 12 Photocatalytic H2 evolution using various amounts of MAPbI3 powder. The rate of H2 evolution becomes sluggish at 1,000 mg of MAPbI3 due to the irregular dispersion of the powder. NATURE ENERGY 14
15 Supplementary Figure 13 Photocatalytic H2 evolution of MAPbI3 powder with different light irradiation areas at a light power of 100 mw cm -2. NATURE ENERGY 15
16 Supplementary Figure 14 XRD patterns of the MAPbI3 powder and thermally annealed MAPbI3 powder in a polar solvent atmosphere. The intensities of the annealed MAPbI3 powder show higher values than the untreated MAPbI3 powder. NATURE ENERGY 16
17 Material (Cocatalyst) Solar HI splitting efficiency (%) Experimental Condition MAPbI3 (Pt) [This work] 0.81 % Photocatalyst 100 mw cm -2 (λ > 475nm) MAPbI3 [This work] 0.44 % Photocatalyst 100 mw cm -2 (λ > 475nm) [This work] WSe % Photocatalyst 100 mw cm -2 (λ > 475nm) Silicon (Pt) 1 0.6% PEC cell 100 mw cm -2 (Full solar light) WSe 2 (Pt) 2 4.2% PEC cell 100 mw cm -2 (Full solar light) Si (PEDOT:PSS) 3 3.7% PEC cell 100 mw cm -2 (Full solar light) GaAs (Pt) 4 2.6% PV-EC system 100 mw cm -2 (Full solar light) Supplementary Table 1 Solar HI splitting efficiency table. The MAPbI3 based photocatalysis system shows an efficiency that is comparable to PEC and PV-EC type HI splitting systems. NATURE ENERGY 17
18 Material (Cocatalyst) Amount of hydrogen evolved for 1h from 1 mol of MAPbI3 (mmolh2 molmapbi3-1 h -1 ) MAPbI3 (X) 6.94 Thermally annealed MAPbI3 in DMF atmosphere (X) 13.3 Thermally annealed MAPbI3 in DMSO atmosphere (X) 22.7 Thermally annealed MAPbI3 in DMSO atmosphere (Pt) 33.4 Supplementary Table 2 Hydrogen evolution activity of the MAPbI3 photocatalyst with various treatments under a light irradiation of 100 mw cm -2. The mol to mol comparison was conducted based on the hydrogen evolved after 5 h as shown in Fig. 5a. NATURE ENERGY 18
19 Supplementary References 1 Ardo, S., Park, S.H., Warren, E.L. & Lewis, N.S. Unassisted solar-driven photoelectrosynthetic HI splitting using membrane-embedded Si microwire arrays. Energy Environ. Sci. 8, (2015). 2 McKone, J.R., Potash, R.A., DiSalvo, F.J. & Abruña, H.D. Unassisted HI photoelectrolysis using n-wse2 solar absorbers. Phys. Chem. Chem. Phys. 17, (2015). 3 Mubeen, S., Lee, J., Singh, N., Moskovits, M. & McFarland, E.W. Stabilizing inorganic photoelectrodes for efficient solar-to-chemical energy conversion. Energy Environ. Sci. 6, (2013). 4 Khaselev, O. & Turner, J.A. Photoelectrolysis of HBr and HI using a monolithic combined photoelectrochemical/photovoltaic device. Electrochem. Solid-State Lett. 2, (1999). NATURE ENERGY 19
Supplementary Figures
Supplementary Figures Supplementary Figure 1. AFM profiles of the charge transport and perovskite layers. AFM Image showing the thickness (y axis) of the layer with respect to the horizontal position of
More informationNanochannel-Assisted Perovskite Nanowires: Growth Mechanisms. to Photodetector Applications
Supplementary Information: Nanochannel-Assisted Perovskite Nanowires: Growth Mechanisms to Photodetector Applications Qitao Zhou, Jun Gyu Park, Riming Nie, Ashish Kumar Thokchom, Dogyeong Ha, Jing Pan,
More informationSupporting Information
Supporting Information Dynamic Interaction between Methylammonium Lead Iodide and TiO 2 Nanocrystals Leads to Enhanced Photocatalytic H 2 Evolution from HI Splitting Xiaomei Wang,, Hong Wang,, Hefeng Zhang,,
More informationEffect of Chloride Anions on the Synthesis and. Enhanced Catalytic Activity of Silver Nanocoral
Supporting Information Effect of Chloride Anions on the Synthesis and Enhanced Catalytic Activity of Silver Nanocoral Electrodes for CO 2 Electroreduction Polyansky* Yu-Chi Hsieh, Sanjaya D. Senanayake,
More informationSupporting Information. CdS/mesoporous ZnS core/shell particles for efficient and stable photocatalytic hydrogen evolution under visible light
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting Information CdS/mesoporous ZnS core/shell particles for efficient
More informationDual Extraction of Photogenerated Electrons and Holes from a Ferroelectric Sr 0.5 Ba 0.5 Nb 2 O 6 Semiconductor
Supporting Information Dual Extraction of Photogenerated Electrons and Holes from a Ferroelectric Sr 0.5 Ba 0.5 Nb 2 O 6 Semiconductor Dayong Fan,, Jian Zhu,, Xiuli Wang, Shengyang Wang,, Yong Liu,, Ruotian
More informationEfficient Co-Fe layered double hydroxide photocatalysts for water oxidation under visible light
Supplementary Information Efficient Co-Fe layered double hydroxide photocatalysts for water oxidation under visible light Sang Jun Kim, a Yeob Lee, a Dong Ki Lee, a Jung Woo Lee a and Jeung Ku Kang* a,b
More informationSupplementary Figure 1. A photographic image of directionally grown perovskite films on a glass substrate (size: cm).
Supplementary Figure 1. A photographic image of directionally grown perovskite films on a glass substrate (size: 1.5 4.5 cm). 1 Supplementary Figure 2. Optical microscope images of MAPbI 3 films formed
More informationN-doped Graphene Quantum Sheets on Silicon Nanowire Photocathode for Hydrogen Production
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information N-doped Graphene Quantum Sheets on Silicon
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 217 Supporting Information Experimental Section Materials. Dicyandiamide(DCDA, C 2 H 4 N 4,
More informationphoto-mineralization of 2-propanol under visible light irradiation
Electronic Supplementary Information for WO 3 modified titanate network film: highly efficient photo-mineralization of 2-propanol under visible light irradiation Experimental Preparation of STN, and WO
More informationDivision of Physics and Semiconductor Science, Dongguk University, Seoul 04620, South Korea
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary information for Self-assembled Two-dimensional Copper Oxide
More informationA novel Ag 3 AsO 4 visible-light-responsive photocatalyst: facile synthesis and exceptional photocatalytic performance
Electronic Supplementary Material (ESI) for Chemical Communications Supporting Information A novel Ag 3 AsO 4 visible-light-responsive photocatalyst: facile synthesis and exceptional photocatalytic performance
More informationSupporting Information
Supporting Information Utilization of Metal Sulfide Material of (CuGa) 1 x Zn 2x S 2 Solid Solution with Visible Light Response in Photocatalytic and Photoelectrochemical Solar Water Splitting Systems
More informationElectronic Supplementary Information. Enhanced Photocatalytic/photoelectrocatalytic Activities
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Electrospun BiVO 4 Nanobelts with Tailored Structures
More informationA novel AgIO 4 semiconductor with ultrahigh activity in photodegradation of organic dyes: insights into the photosensitization mechanism
Supporting Information for: A novel AgIO 4 semiconductor with ultrahigh activity in photodegradation of organic dyes: insights into the photosensitization mechanism Jianting Tang*, Datang Li*, Zhaoxia
More informationSupplementary Figure 1
Supplementary Figure 1 XRD patterns and TEM image of the SrNbO 3 film grown on LaAlO 3(001) substrate. The film was deposited under oxygen partial pressure of 5 10-6 Torr. (a) θ-2θ scan, where * indicates
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information MoS 2 nanosheet/mo 2 C-embedded N-doped
More informationHysteresis-free low-temperature-processed planar perovskite solar cells with 19.1% efficiency
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Supplementary Information Hysteresis-free low-temperature-processed planar
More informationSupporting Information
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 2017 Supporting Information Formation Criteria of High Efficiency Perovskite Solar
More informationSupplementary information for Organically doped palladium: a highly efficient catalyst for electroreduction of CO 2 to methanol
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2015 Supplementary information for rganically doped palladium: a highly efficient catalyst for
More informationSolar desalination coupled with water remediation and molecular hydrogen production: A novel solar water-energy nexus
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 17 Supporting Information Solar desalination coupled with water remediation and
More informationSulfur-bubble template-mediated synthesis of uniform porous g-c 3 N 4 with superior photocatalytic performance
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Sulfur-bubble template-mediated synthesis of uniform porous
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting Information Synthesis and Application of Hexagonal Perovskite BaNiO 3 with Quadrivalent
More informationUV Degradation and Recovery of Perovskite Solar Cells
Supplementary Information UV Degradation and Recovery of Perovskite Solar Cells Sang-Won Lee 1, Seongtak Kim 1, Soohyun Bae 1, Kyungjin Cho 1, Taewon Chung 1, Laura E. Mundt 2, Seunghun Lee 1,2, Sungeun
More informationPhotocathode for Water Electrolysis Applications
Supporting Information Efficient and Stable Pt/TiO 2 /CdS/Cu 2 BaSn(S,Se) 4 Photocathode for Water Electrolysis Applications Yihao Zhou 1#, Donghyeop Shin 1,2,4#, Edgard Ngaboyamahina 3#, Qiwei Han 1,2,
More informationLaser Crystallization of Organic-Inorganic Hybrid
Supporting information Laser Crystallization of Organic-Inorganic Hybrid Perovskite Solar Cells Taewoo Jeon, Hyeong Min Jin, Seung Hyun Lee, Ju Min Lee, Hyung Il Park, Mi Kyung Kim, Keon Jae Lee, Byungha
More informationand Technology, Luoyu Road 1037, Wuhan, , P. R. China. *Corresponding author. ciac - Shanghai P. R.
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry Supplementary Information For Journal of Materials Chemistry A Perovskite- @BiVO
More informationElectronic Supplementary Information (ESI )
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI ) Hollow nitrogen-doped carbon spheres as an efficient
More informationPlasma-functionalized carbon-layered separators for improved performance of
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2019 Electronic Supplementary Material (ESI) for Journal of Materials Chemistry
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Precious-metal free photoelectrochemical water splitting
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supplementary Information Integrated Cobalt Disulfide (CoS 2 ) Co-catalytic
More informationState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences,
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The oyal Society of Chemistry 16 Electronic Supplementary Information Insight into the Charge Transfer in Particulate Ta 3
More informationElectronic Supplementary Information. Three-Dimensional Carbon Foam/N-doped 2. Hybrid Nanostructures as Effective Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Three-Dimensional Carbon Foam/N-doped
More informationElectronic Supplementary Information. Crystallographic Orientation Propagation in Metal Halide Perovskite Thin Films
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Crystallographic Orientation Propagation
More informationAll-Inorganic Perovskite Solar Cells
Supporting Information for: All-Inorganic Perovskite Solar Cells Jia Liang, Caixing Wang, Yanrong Wang, Zhaoran Xu, Zhipeng Lu, Yue Ma, Hongfei Zhu, Yi Hu, Chengcan Xiao, Xu Yi, Guoyin Zhu, Hongling Lv,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information 1. Synthesis of perovskite materials CH 3 NH 3 I
More informationSupporting Information
Supporting Information Oxygen Reduction on Graphene-Carbon Nanotube Composites Doped Sequentially with Nitrogen and Sulfur Drew C. Higgins, Md Ariful Hoque, Fathy Hassan, Ja-Yeon Choi, Baejung Kim, Zhongwei
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 215 Supplementary Information CdSe quantum dots/molecular cobalt catalyst co-grafted
More informationIntensity / a.u. 2 theta / deg. MAPbI 3. 1:1 MaPbI 3-x. Cl x 3:1. Supplementary figures
Intensity / a.u. Supplementary figures 110 MAPbI 3 1:1 MaPbI 3-x Cl x 3:1 220 330 0 10 15 20 25 30 35 40 45 2 theta / deg Supplementary Fig. 1 X-ray Diffraction (XRD) patterns of MAPbI3 and MAPbI 3-x Cl
More informationElectronic Supplementary Information (ESI)
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) Synthesis of 1T-MoSe 2 ultrathin
More informationSupporting Information for. Photoactive PANI/TiO 2 /Si Composite Coatings With 3D Bio-inspired. Structures
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Supporting Information for
More informationDefect mitigation of Solution-Processed 2D WSe 2 Nano-flakes for Solar-to- Hydrogen Conversion
Supporting information for: Defect mitigation of Solution-Processed 2D WSe 2 Nano-flakes for Solar-to- Hydrogen Conversion Xiaoyun Yu, Néstor Guijarro, Melissa Johnson, and Kevin Sivula* Laboratory for
More informationSupplementary Information 1. Enhanced Solar Absorption, Visible-Light Photocatalytic and. Photoelectrochemical Properties of Aluminium-reduced
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supplementary Information to Enhanced Solar Absorption, Visible-Light Photocatalytic and Photoelectrochemical
More informationElectronic Supplementary Information (ESI) for:
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information (ESI) for: A novel photoelectrocatalytic approach for
More informationSupporting Information. Electrochemical Vapor Deposition (E-CVD) of Semiconductors from Gas. Phase with a Solid Membrane Cell
Supporting Information Electrochemical Vapor Deposition (E-CVD) of Semiconductors from Gas Phase with a Solid Membrane Cell Sung Ki Cho 1, Fu-Ren F. Fan, and Allen J. Bard * Center for Electrochemistry,
More informationTransparent and ultra-bendable all-solid-state supercapacitors without percolation problems
Electronic Supplementary Information: Transparent and ultra-bendable all-solid-state supercapacitors without percolation problems Inho Nam, Soomin Park, Gil-Pyo Kim, Junsu Park and Jongheop Yi* World Class
More informationSupplementary Information
Supplementary Information In situ ion exchange synthesis of the novel Ag/AgBr/BiOBr hybrid with highly efficient decontamination of pollutants Hefeng Cheng, Baibiao Huang*, Peng Wang, Zeyan Wang, Zaizhu
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2016 Supporting Information Single-crystalline Pd square nanoplates enclosed by {100}
More informationSupplementary Information
Supplementary Information Metal tips on pyramid-shaped PbSe/CdSe/CdS heterostructure nanocrystal photocatalysts: study of ripening and core/shell formation Whi Dong Kim, a Sooho Lee, a Chaewon Pak, a Ju
More informationHetero-crystals with Enhanced Photocatalytic Properties and Stabilities
Supporting Information for Facile Synthesis of Rhombic Dodecahedral AgX/Ag 3 PO 4 (X=Cl, Br, I) Hetero-crystals with Enhanced Photocatalytic Properties and Stabilities Yingpu Bi, Shuxin Ouyang, Junyu Cao,
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting Information Synergistic Effect of Three-dimensional Orchid-like
More informationElectronic Supplementary Information: Synthesis and Characterization of Photoelectrochemical and Photovoltaic Cu2BaSnS4 Thin Films and Solar Cells
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information: Synthesis and Characterization of
More informationSupplementary Information
Supplementary Information Supplementary Figures Supplementary Figure S1. Change in open circuit potential ( OCP) of 1% W-doped BiVO 4 photoanode upon illumination with different light intensities. Above
More informationSupplementary Material (ESI) for Chemical Communications This journal is (c) The Royal Society of Chemistry Supporting Information
Supporting Information A facile approach to the synthesis of highly electroactive Pt nanoparticles on graphene as anode catalyst for direct methanol fuel cells Yi-Ge Zhou, Jing-Jing Chen, Feng-bin Wang*,
More informationSupplementary Figure 1 Scheme image of GIXD set-up. The scheme image of slot die
Supplementary Figure 1 Scheme image of GIXD set-up. The scheme image of slot die printing system combined with grazing incidence X-ray diffraction (GIXD) set-up. 1 Supplementary Figure 2 2D GIXD images
More informationSupplementary Information
Supplementary Information Visible Photocatalytic Water Splitting and Photocatalytic Two-Electron Oxygen Formation over Cu and Fe Doped g-c 3 N 4 Zhen Li a,b, Chao Kong a,b, Gongxuan Lu a* a State Key Laboratory
More informationImproved visible-light activities of nanocrystalline CdS by coupling ultrafine NbN with lattice matching for hydrogen evolution
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 2018 Improved visible-light activities of nanocrystalline CdS by coupling ultrafine
More informationof (002) plane on the surfaces of porous N-doped carbon nanotubes for
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Growth of MoSe 2 nanosheet arrays with small size and expanded
More informationLaurea in Scienza dei Materiali Materiali Inorganici Funzionali. Hydrogen production by photocatalytic water splitting
Laurea in Scienza dei Materiali Materiali Inorganici Funzionali Hydrogen production by photocatalytic water splitting Prof. Dr. Antonella Glisenti -- Dip. Scienze Chimiche -- Università degli Studi di
More informationTwo-dimensional homologous perovskites as light absorbing materials for solar cell applications
Supporting Information for Two-dimensional homologous perovskites as light absorbing materials for solar cell applications Duyen H. Cao, Constantinos C. Stoumpos, Omar K. Farha,, Joseph T. Hupp, and Mercouri
More informationSupplementary Figure 1 Morphology and composition of the original carbon nanotube (CNT) sample. (a, b) TEM images of CNT; (c) EDS of CNT.
1 Supplementary Figure 1 Morphology and composition of the original carbon nanotube (CNT sample. (a, b TEM images of CNT; (c EDS of CNT. Cobalt is not detected in the original CNT sample (Note: The accidentally
More informationSupporting Information
Supporting Information German Edition: DOI: High Catalytic Activity of Heteropolynuclear Cyanide Complexes Containing Cobalt and Platinum Ions: Visible-Light Driven Water Oxidation** Yusuke Yamada,* Kohei
More informationLow-temperature-processed inorganic perovskite solar cells via solvent engineering with enhanced mass transport
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 1 Low-temperature-processed inorganic perovskite solar cells via solvent engineering
More informationSupplementary Information. A miniature solar device for overall water splitting consisting of. series-connected spherical silicon solar cells
Supplementary Information A miniature solar device for overall water splitting consisting of series-connected spherical silicon solar cells Yosuke Kageshima 1*, Tatsuya Shinagawa 2*, Takaaki Kuwata 3,
More informationElectronic Supplementary Information for: Evaluation of Pt, Ni, and Ni Mo Electrocatalysts for Hydrogen Evolution on Crystalline Si Electrodes
Electronic Supplementary Information for: Evaluation of Pt, Ni, and Ni Mo Electrocatalysts for Hydrogen Evolution on Crystalline Si Electrodes James R. McKone, Emily L. Warren, Matthew J. Bierman, Shannon
More informationBistriazole-p-benzoquinone and its alkali salts: electrochemical behaviour in aqueous alkaline solutions
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Bistriazole-p-benzoquinone and its alkali salts: electrochemical behaviour in aqueous
More informationEfficient Visible Light Photocatalytic CO 2 Reforming of CH 4
SUPPORTING INFORMATION Efficient Visible Light Photocatalytic CO 2 Reforming of CH 4 Bing Han, Wei Wei, Liang Chang, Peifu Cheng, and Yun Hang Hu* Department of Materials Science and Engineering, Michigan
More informationHighly Efficient Flexible Solar Cells Based on Room-Temperature
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry Please do 2018 not adjust margins Supporting Information Highly Efficient Flexible
More informationThe Current Status of Perovskite Solar Cell Research at UCLA
The Current Status of Perovskite Solar Cell Research at UCLA Lijian Zuo, Sanghoon Bae, Lei Meng, Yaowen Li, and Yang Yang* Department of Materials Science and Engineering University of California, Los
More informationSupporting Information
Supporting Information Metal to Halide Perovskite )HaP(: an Alternative Route to HaP Coating Directly from Pb (0) or Sn (0) films Yevgeny Rakita, Satyajit Gupta, David Cahen*, Gary Hodes* Department of
More informationSupplementary Information for. Immobilizing photogenerated electrons from graphitic carbon nitride for
Supplementary Information for Immobilizing photogenerated electrons from graphitic carbon nitride for an improved visible-light photocatalytic activity Han Sun, Yue Cao, Leiyu Feng *, Yinguang Chen * State
More informationElectronic Supplementary Information. Photoelectrochemical Water Splitting in an Organic Artificial Leaf
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Photoelectrochemical Water Splitting
More informationExperimental Section
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supplementary Material (ESI) for Chemical Communications Modification of Ga 2 O 3 by Ag Cr Core
More informationCdTe quantum dot sensitized hexaniobate nanoscrolls and Photoelectrochemical properties
CdTe quantum dot sensitized hexaniobate nanoscrolls and Photoelectrochemical properties Feriha Eylul Sarac a, Ceren Yilmaz,b, Funda Yagci Acar a,b,c and Ugur Unal* a,b,c a Koc University, Chemistry Department,
More informationSupporting Information. Concave Rhombic Dodecahedral Au Nanocatalyst with Multiple High-Index Facets for CO 2 Reduction
Supporting Information Concave Rhombic Dodecahedral Au Nanocatalyst with Multiple High-Index Facets for CO 2 Reduction Hye-Eun Lee 1, Ki Dong Yang 1, Sang Moon Yoon 1, Hyo-Yong Ahn 1, Yoon Young Lee 1,
More informationSupporting information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting information Selective production of hydrogen peroxide and oxidation
More informationMonolithic Cells for Solar Fuels
Electronic Supplementary Material (ESI) for Chemical Society Reviews. This journal is The Royal Society of Chemistry 2014 Monolithic Cells for Solar Fuels Jan Rongé, Tom Bosserez, David Martel, Carlo Nervi,
More informationSupplementary Information
Supplementary Information Supplementary Figure 1. Photographs show the titration experiments by dropwise adding ~5 times number of moles of (a) LiOH and LiOH+H 2 O, (b) H 2 O 2 and H 2 O 2 +LiOH, (c) Li
More informationPreparation of mixed-ion and inorganic perovskite solar cells using water and isopropanol as solvents for solar cell applications
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 217 Preparation of mixed-ion and inorganic perovskite solar cells using water and
More informationElectronic Supplementary Information
Electronic Supplementary Information High Electrocatalytic Activity of Self-standing Hollow NiCo 2 S 4 Single Crystalline Nanorod Arrays towards Sulfide Redox Shuttles in Quantum Dot-sensitized Solar Cells
More informationSchool of Advanced Materials Science & Engineering, Sungkyunkwan University, Suwon , Korea.
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary information (ESI) Highly Efficient and Bending Durable
More informationPhotosynthesis of Formate from CO 2 and Water at 1% Energy Efficiency via Copper Iron Oxide Catalysis
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Supporting Information Photosynthesis of Formate from CO 2 and Water at 1%
More information[Supplementary Information] One-Pot Synthesis and Electrocatalytic Activity of Octapodal Au-Pd Nanoparticles
[Supplementary Information] One-Pot Synthesis and Electrocatalytic Activity of Octapodal Au-Pd Nanoparticles Jong Wook Hong, Young Wook Lee, Minjung Kim, Shin Wook Kang, and Sang Woo Han * Department of
More informationSupplementary Materials for
advances.sciencemag.org/cgi/content/full/2/6/e1501764/dc1 Supplementary Materials for Efficient solar-driven water splitting by nanocone BiVO4-perovskite tandem cells Yongcai Qiu, Wei Liu, Wei Chen, Wei
More informationEfficient Hydrogen Evolution. University of Central Florida, 4000 Central Florida Blvd. Orlando, Florida, 32816,
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 MoS 2 /TiO 2 Heterostructures as Nonmetal Plasmonic Photocatalysts for Highly
More informationTailoring of Electron Collecting Oxide Nano-Particulate Layer for Flexible Perovskite Solar Cells. Gajeong-Ro, Yuseong-Gu, Daejeon , Korea
Supporting Information Tailoring of Electron Collecting Oxide Nano-Particulate Layer for Flexible Perovskite Solar Cells Seong Sik Shin 1,2,, Woon Seok Yang 1,3,, Eun Joo Yeom 1,4, Seon Joo Lee 1, Nam
More informationTransparent TiO 2 nanotube/nanowire arrays on TCO coated glass substrates: Synthesis and application to solar energy conversion
Transparent TiO 2 nanotube/nanowire arrays on TCO coated glass substrates: Synthesis and application to solar energy conversion Craig A. Grimes Department of Electrical Engineering Center for Solar Nanomaterials
More informationElectronic Supplementary Information. Fang He, Gang Chen,* Yaoguang Yu, Yansong Zhou, Yi Zheng and Sue Hao*
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information Synthesis of condensed C-PDA/g-C 3 N 4 composites with superior
More informationSupplementary Figure 1. Schematic layout of set-up for operando NMR studies.
Supplementary Figure 1. Schematic layout of set-up for operando NMR studies. Supplementary Figure 2. Correlations between different ratios of D2O/H2O and 1 H chemical shifts of HDO. The spectra were acquired
More informationBlock Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology
The 7 th Korea-U.S. Nano Forum Block Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology Dong Ha Kim Department of Chemistry and Nano Science, Ewha Womans University
More informationSupporting Information for
Supporting Information for Pb-activated Amine-assisted Photocatalytic Hydrogen Evolution Reaction on Organic-Inorganic Perovskites Lu Wang *,,, Hai Xiao, Tao Cheng, Youyong Li *,, William A. Goddard III
More informationAchieving High Electrocatalytic Efficiency on Copper: A Low-Cost Alternative to Platinum for Hydrogen Generation in Water
Supporting Information Achieving High Electrocatalytic Efficiency on Copper: A Low-Cost Alternative to Platinum for Hydrogen Generation in Water Jian Zhao, a,b,c,d Phong D. Tran,* a,c Yang Chen, a,c Joachim
More informationELECTRONIC SUPPLEMENTARY INFORMATION
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 ELECTRONIC SUPPLEMENTARY INFORMATION Oxygen-vacancy rich 3D novel hierarchical
More informationShuo Li, Qidong Zhao, Dejun Wang and Tengfeng Xie *
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Work Function Engineering Derived All-solid-state Z-scheme Semiconductor-Metal-Semiconductor
More informationShape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes
Supporting Information Shape-selective Synthesis and Facet-dependent Enhanced Electrocatalytic Activity and Durability of Monodisperse Sub-10 nm Pt-Pd Tetrahedrons and Cubes An-Xiang Yin, Xiao-Quan Min,
More informationEfficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response
Supporting information for Efficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response Jing Cao 1,*,, Congping Li 1,, Xudong
More informationElectronic Structure and Photocatalytic Activity of Wurtzite Cu Ga S Nanocrystals and their Zn substitution
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 SUPPORTING INFORMATION Electronic Structure and Photocatalytic Activity
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Engineering Cu 2 O/NiO/Cu 2 MoS 4 Hybrid Photocathode for H 2 Generation in Water Chen Yang, a,b
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Sustainable Energy & Fuels. This journal is The Royal Society of Chemistry 218 Electronic Supplementary Information Powder-based (CuGa 1-y In y ) 1-x Zn 2x S
More information