Q1. Which one of the following is least likely to occur in the reaction between methane and chlorine?
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1 Q1. Which one of the following is least likely to occur in the reaction between methane and chlorine? A B C D C 4 + Cl C 3 + Cl C 3 + Cl C 3 Cl + C 3 + Cl 2 C 3 Cl + Cl C 3 Cl + Cl C 2 Cl + Cl (Total 1 mark) Q2. An alkane contains 30 hydrogen atoms per molecule. Its empirical formula is A C 6 15 B C 7 15 C C D C (Total 1 mark) Q3. (a) Butane, C 4 10, is a hydrocarbon which is used as a fuel. Explain what is meant by the term hydrocarbon. Explain what is meant by the term fuel. (iii) Write an equation for the complete combustion of butane. (iv) Write an equation for the incomplete combustion of butane to produce carbon monoxide and water. (v) Under what conditions would you expect incomplete combustion to occur? (5) Page 1 of 26
2 (b) Three different carbocations are formed by breaking C C bonds in separate molecules of butane during catalytic cracking. One of these structures is shown below. Give the structures of the other two carbocations. Structure 1 Structure 2 Structure 3 (c) Ethane can be cracked in the presence of a catalyst to produce ethene and hydrogen. Write an equation for this reaction. Give a suitable catalyst for this reaction. (iii) State one reason why cracking is important. (3) (Total 10 marks) Q4. The percentage by mass of carbon is 83.3% in A B C D propane. butane. pentane. hexane. (Total 1 mark) Page 2 of 26
3 Q5. Tetradecane (C ) is an alkane found in crude oil. When tetradecane is heated to a high temperature, one molecule of tetradecane decomposes to form one molecule of hexane and three more molecules. Which of the following could represent this reaction? A C C C C 2 4 B C C C C 2 4 C C C C 3 6 D C C C C 3 6 (Total 1 mark) Q6. Which one of the following types of reaction mechanism is not involved in the above sequence? C 3 C 2 C 3 (C 3 ) 2 CCl (C 3 ) 2 CCN (C 3 ) 2 CC 2 NCOC 3 (C 3 ) 2 CC 2 N 2 A B C D free-radical substitution nucleophilic substitution elimination nucleophilic addition-elimination (Total 1 mark) Q7. The fractions obtained from petroleum contain saturated hydrocarbons that belong to the homologous series of alkanes. (a) Any homologous series can be represented by a general formula. State two other characteristics of homologous series. Characteristic 1... Characteristic 2... Name the process which is used to obtain the fractions from petroleum. Page 3 of 26
4 (iii) State what is meant by the term saturated, as applied to hydrocarbons. (4) (b) Decane has the molecular formula C State what is meant by the term molecular formula. Give the molecular formula of the alkane which contains 14 carbon atoms. (iii) Write an equation for the incomplete combustion of decane, C 10 22, to produce carbon and water only. (3) (c) When petrol is burned in an internal combustion engine, some nitrogen monoxide, NO, is formed. This pollutant is removed from the exhaust gases by means of a reaction in a catalytic converter. Write an equation for the reaction between nitrogen and oxygen to form nitrogen monoxide. Identify a catalyst used in a catalytic converter. (iii) Write an equation to show how nitrogen monoxide is removed from the exhaust gases as they pass through a catalytic converter. (3) (Total 10 marks) Page 4 of 26
5 Q8. (a) exane (C 6 14 ) is a hydrocarbon which is a component of LPG (liquid petroleum gas), used as a fuel for heating. When burning fuels in boilers it is important to ensure complete combustion. Give two reasons why boilers are designed to ensure complete combustion. Reason 1... Reason 2... Write an equation for the incomplete combustion of hexane. (iii) Suggest how an engineer or a chemist could demonstrate that the combustion of hexane in a faulty boiler was incomplete. (5) (b) Branched chain alkanes are often preferred as fuels. Draw the structure of two branched chain isomers of hexane and name the first isomer. Isomer 1 Isomer 2 Name of isomer 1... (3) (c) exane can be cracked in the presence of a catalyst to produce another hydrocarbon, Z, and methane. Draw a possible structure for Z. Page 5 of 26
6 Give a suitable catalyst for this reaction. (iii) Suggest why the product Z has more commercial value than hexane. (3) (d) The overall equation for the production of dichloromethane from methane and chlorine is shown below. C 4 + 2Cl 2 C 2 Cl 2 + 2Cl Calculate the % atom economy for the formation of C 2 Cl 2 in this reaction. Give one reason why this atom economy of less than 100% is an important consideration for the commercial success of this process and predict how a chemical company would maximise profits from this process. (3) (Total 14 marks) Q9. The reaction of bromine with ethane is similar to that of chlorine with ethane. Three steps in the bromination of ethane are shown below. Step 1 Br 2 2Br Step 2 Br + C 3 C 3 C 3 C 2 + Br Step 3 C 3 C 2 + Br2 C 3 C 2 Br + Br Page 6 of 26
7 (a) Name this type of mechanism. Suggest an essential condition for this reaction. (iii) Steps 2 and 3 are of the same type. Name this type of step. (iv) In this mechanism, another type of step occurs in which free-radicals combine. Name this type of step. Write an equation to illustrate this step. Type of step... Equation... (5) (b) Further substitution in the reaction of bromine with ethane produces a mixture of liquid organic compounds. Name a technique which could be used to separate the different compounds in this mixture. Write an equation for the reaction between bromine and ethane which produces hexabromoethane, C 2 Br 6, by this substitution reaction. (c) The compound 1,2-dibromo-1,1,2,2-tetrafluoroethane is used in some fire extinguishers. Draw the structure of this compound. (d) alothane is used as an anaesthetic and has the following structure. Give the systematic name of halothane. Page 7 of 26
8 Calculate the M r of halothane. (iii) Calculate the percentage by mass of fluorine in halothane. (3) (Total 11 marks) Q10. exane (C 6 14 ) is a member of the homologous series of alkanes. (a) Name the raw material from which hexane is obtained... Name the process used to obtain hexane from this raw material... (b) C 6 14 has structural isomers. Deduce the number of structural isomers with molecular formula C 6 14 Write the number in this box. (Space for working) State one type of structural isomerism shown by the isomers of C (c) One molecule of an alkane X can be cracked to form one molecule of hexane and two molecules of propene. Deduce the molecular formula of X..... Page 8 of 26
9 State the type of cracking that produces a high percentage of alkenes. State the conditions needed for this type of cracking. Type of cracking... Conditions..... (iii) Explain the main economic reason why alkanes are cracked..... (d) exane can react with chlorine under certain conditions as shown in the following equation. C Cl 2 C 6 13 Cl + Cl Both the products are hazardous. The organic product would be labelled flammable'. Suggest the most suitable hazard warning for the other product... Calculate the percentage atom economy for the formation of C 6 13 Cl (M r = 120.5) in this reaction..... (e) A different chlorinated compound is shown below. Name this compound and state its empirical formula. Name... Empirical formula... (Total 12 marks) Page 9 of 26
10 Q11. Alkanes are saturated hydrocarbons which can be obtained from crude oil. Pentane is an example of an alkane. A molecule of pentane contains five carbon atoms. (a) State the meaning of the term saturated and of the term hydrocarbon as applied to alkanes. Saturated... ydrocarbon... Give the general formula for the alkanes. (b) Pentane burns completely in oxygen. Write an equation for this reaction. State how the products of this reaction may affect the environment. (c) Give the name of a solid pollutant which may form when pentane burns incompletely in air.... (d) One molecule of C 9 20 can be cracked to form one molecule of pentane and one other product. Write an equation for this cracking reaction. Suggest a type of compound that can be manufactured from the other product of this cracking reaction. Page 10 of 26
11 (iii) State why a high temperature is needed for cracking reactions to occur. (e) Pentane can react to form the following haloalkane Q. Name Q. State the type of structural isomerism shown by Q and the haloalkane shown below. (Total 11 marks) Q12. (a) The reaction of bromine with propane is similar to that of chlorine with methane. Three steps in the mechanism for the bromination of propane to form 1-bromopropane are shown below. Step 1 Br 2 2Br Step 2 Br + C 3 C 2 C 3 C 3 C 2 C 2 + Br Step 3 C 3 C 2 C 2 + Br 2 C 3 C 2 C 2 Br + Br Name the type of mechanism in this reaction. Page 11 of 26
12 Give an essential condition for Step 1 to occur. (iii) Name the type of step illustrated by Steps 2 and 3. (iv) In this mechanism, a different type of step occurs in which free radicals combine. Name this type of step. Write an equation to show how hexane could be formed from two free radicals in the mechanism of this reaction. Type of step... Equation... (v) Write an overall equation for the reaction between bromine and propane by the same mechanism to produce octabromopropane (C 3 Br 8 ). (b) Bromine reacts with alkenes, even though bromine is a non-polar molecule. Explain why bromine molecules react with the double bonds in alkenes. Name the type of mechanism involved in this reaction. (iii) Draw the structure of the compound with M r = formed when penta-1,4-diene ( 2 C CC 2 C C 2 ) reacts with an excess of bromine. Page 12 of 26
13 (c) Two products are formed when propene reacts with hydrogen bromide. Draw the structure of the intermediate that leads to the formation of the major product in the reaction of propene with hydrogen bromide. Give the name of this type of intermediate. Structure of intermediate Type of intermediate... (Total 12 marks) Q13. Pentane is a member of the alkane homologous series. (a) Give the general formula for the homologous series of alkanes.... (b) One of the structural isomers of pentane is 2,2-dimethylpropane. Draw the displayed formula of 2,2-dimethylpropane. State the type of structural isomerism shown.... Page 13 of 26
14 (c) A molecule of hydrocarbon Y can be thermally cracked to form one molecule of pentane and two molecules of ethene only. Deduce the molecular formula of Y. State why high temperatures are necessary for cracking reactions to occur. Give one reason why thermal cracking reactions are carried out in industry (Extra space) (3) (d) Write an equation for the incomplete combustion of pentane to form a solid pollutant. Suggest why this solid pollutant is an environmental problem (Extra space) Page 14 of 26
15 (e) Pentane can react with chlorine as shown in the following equation. C Cl 2 C 5 11 Cl + Cl Calculate the percentage atom economy for the formation of C 5 11 Cl Deduce how many straight-chain isomers of C 5 11 Cl could be formed (Extra space) (3) (f) Consider the following compound. Name this compound. Deduce the empirical formula of this compound (Total 13 marks) Page 15 of 26
16 Q14. Alkanes are used as fuels. A student burned some octane (C 8 18 ) in air and found that the combustion was incomplete. (a) Write an equation for the incomplete combustion of octane to produce carbon monoxide as the only carbon-containing product... Suggest one reason why the combustion was incomplete..... (b) Catalytic converters are used to remove the toxic gases NO and CO that are produced when alkane fuels are burned in petrol engines. Write an equation for a reaction between these two toxic gases that occurs in a catalytic converter when these gases are removed... Identify a metal used as a catalyst in a catalytic converter. Suggest one reason, other than cost, why the catalyst is coated on a ceramic honeycomb. Metal... Reason..... (c) If a sample of fuel for a power station is contaminated with an organic sulfur compound, a toxic gas is formed by complete combustion of this sulfur compound. State one environmental problem that can be caused by the release of this gas..... Page 16 of 26
17 Identify one substance that could be used to remove this gas. Suggest one reason, other than cost, why this substance is used. Substance... Reason why used..... (Total 8 marks) Q15. Chlorine can be used to make chlorinated alkanes such as dichloromethane. (a) Write an equation for each of the following steps in the mechanism for the reaction of chloromethane (C 3 Cl) with chlorine to form dichloromethane (C 2 Cl 2 ). Initiation step... First propagation step... Second propagation step... The termination step that forms a compound with empirical formula C 2 Cl.... (4) (b) When chlorinated alkanes enter the upper atmosphere, carbon-chlorine bonds are broken. This process produces a reactive intermediate that catalyses the decomposition of ozone. The overall equation for this decomposition is 2O 3 3O 2 Name the type of reactive intermediate that acts as a catalyst in this reaction... Write two equations to show how this intermediate is involved as a catalyst in them decomposition of ozone. Equation 1... Equation 2... (Total 7 marks) Page 17 of 26
18 Q16. Compound X is shown below. It is a member of a homologous series of hydrocarbons. (a) Deduce the general formula of the homologous series that contains X... Name a process used to obtain a sample of X from a mixture containing other members of the same homologous series... (b) There are several isomers of X. Give the IUPAC name of the position isomer of X... Draw the structure of a functional group isomer of X. (c) At high temperatures, one molecule of C can be converted into two molecules of X and one molecule of another compound. Write an equation for this reaction... State the name of the process used to obtain a high yield of X from C Give one reason why this process is used in industry. Name... Reason..... Page 18 of 26
19 (iii) State why high temperatures are needed for this process..... (d) Compound X can be converted into compound Y. Compound Y is shown below. Suggest the formula of a reagent that could be added to X in order to convert it into Y... Give one use of Y... (iii) Write an equation to show the reaction of Y in a limited supply of air to produce a solid and water only... (iv) When a sample of Y, contaminated with C 3 S, is burned completely in air, a toxic gas is formed. Identify this toxic gas and suggest a compound that could be used to remove the toxic gas from the products of combustion. Toxic gas... Compound used to remove toxic gas..... (v) Suggest the name of the process that occurs when the toxic gas in part (d)(iv) is removed... Page 19 of 26
20 (e) Explain why the boiling points of X and Y are similar (Total 16 marks) Q17. Some oil-fired heaters use paraffin as a fuel. One of the compounds in paraffin is the straight-chain alkane, dodecane (C ). (a) Give the name of the substance from which paraffin is obtained. State the name of the process used to obtain paraffin from this substance. Substance... Process... (b) The combustion of dodecane produces several products. Write an equation for the incomplete combustion of dodecane to produce gaseous products only.... (c) Oxides of nitrogen are also produced during the combustion of paraffin in air. Explain how these oxides of nitrogen are formed Write an equation to show how nitrogen monoxide in the air is converted into nitrogen dioxide... Page 20 of 26
21 (iii) Nitric acid (NO 3 ) contributes to acidity in rainwater. Deduce an equation to show how nitrogen dioxide reacts with oxygen and water to form nitric acid... (d) Dodecane (C ) can be cracked to form other compounds. Give the general formula for the homologous series that contains dodecane... Write an equation for the cracking of one molecule of dodecane into equal amounts of two different molecules each containing the same number of carbon atoms. State the empirical formula of the straight-chain alkane that is formed. Name the catalyst used in this reaction. Equation... Empirical formula of alkane... Catalyst..... (3) (iii) Explain why the melting point of dodecane is higher than the melting point of the straight-chain alkane produced by cracking dodecane (e) Give the IUPAC name for the following compound and state the type of structural isomerism shown by this compound and dodecane. IUPAC name... Type of structural isomerism... Page 21 of 26
22 (f) Dodecane can be converted into halododecanes. Deduce the formula of a substance that could be reacted with dodecane to produce 1- chlorododecane and hydrogen chloride only.... (Total 16 marks) Q18. Trifluoromethane (CF 3 ) can be used to make the refrigerant chlorotrifluoromethane (CClF 3 ). (a) Chlorotrifluoromethane is formed when trifluoromethane reacts with chlorine. CF 3 + Cl 2 CClF 3 + Cl The reaction is a free-radical substitution reaction similar to the reaction of methane with chlorine. Write an equation for each of the following steps in the mechanism for the reaction of CF 3 with Cl 2 Initiation step.. First propagation step.. Second propagation step.. Termination step to form hexafluoroethane.. (4) Give one essential condition for this reaction... (b) In some refrigeration systems, CF 3 has replaced CClF 3 because of concerns about ozone depletion. Identify the species formed from CClF 3 that is responsible for the catalytic decomposition of ozone in the upper atmosphere... Page 22 of 26
23 Write an overall equation to represent the decomposition of ozone into oxygen... (Total 7 marks) Q19. Sulfur dioxide (SO 2 ) is produced when some fossil fuels are burned. Which of the following statements is true? A B C D Sulfur dioxide can be removed from waste gases in a power station by an acid-base reaction with calcium oxide. Sulfur dioxide is insoluble in water. Sulfur dioxide is a basic oxide. Sulfur dioxide is an ionic compound. (Total 1 mark) Q20. Which molecule is not produced when ethane reacts with bromine in the presence of ultraviolet light? A C 2 4 Br 2 B Br C 2 D C 4 10 (Total 1 mark) Page 23 of 26
24 Q21. There are many uses of halogenated organic compounds despite environmental concerns. (a) Bromotrifluoromethane is used in fire extinguishers in aircraft. Bromotrifluoromethane is formed when trifluoromethane reacts with bromine. CF 3 + Br 2 CBrF 3 + Br The reaction is a free-radical substitution reaction similar to the reaction of methane with chlorine. Write an equation for each of the following steps in the mechanism for the reaction of CF 3 with Br 2 Initiation step.. First propagation step.. Second propagation step.. A termination step.. (4) State one condition necessary for the initiation of this reaction... (b) Bromine-containing and chlorine-containing organic compounds may have a role in the decomposition of ozone in the upper atmosphere. Draw an appropriate displayed formula in the space provided to complete the following equation to show how CBrF 3 may produce bromine atoms in the upper atmosphere. CBrF 3 + Br... In the upper atmosphere, it is more likely for CBrF 3 to produce bromine atoms than it is for CClF 3 to produce chlorine atoms. Suggest one reason for this Page 24 of 26
25 (iii) Bromine atoms have a similar role to chlorine atoms in the decomposition of ozone. The overall equation for the decomposition of ozone is 2O 3 3O 2 Write two equations to show how bromine atoms (Br ) act as a catalyst in the decomposition of ozone. Explain how these two decomposition equations show that bromine atoms behave as a catalyst. Equation 1.. Equation 2.. Explanation (3) (Total 10 marks) Page 25 of 26
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