Overview and industry links

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1 Department of Chemistry Overview and industry links 19th March 2018

2 REF 2014 Chemistry : 6= in UK Cambridge 62.7 FTE staff Liverpool 34 Oxford 83.9 Bristol 58.6 Durham 40.8 Imperial 54.9 UCL 62 Warwick 34.8 Cardiff 23 UEA 19.6 Medium size / high quality

3 Department profile Ca. 500 UG students Ca. 160 PhD Students Ca. 70 postdoctoral researchers /fellows 42 academic staff (8 teaching only) 36 support staff Ca. 40 PG taught students on range of MSc programmes

4 Research organised into four thematic clusters Chemical biology Natural product biosynthesis Industrial biotechnology Drug discovery Biocatalysis Polymers and materials Synthesis / applications of polymer and colloid materials Mechanisms of polymer formation Polymer therapeutics Solid state: photovoltaic and magnetic materials

5 Synthesis and catalysis Synthetic methodology Organometallic chemistry Supramolecular chemistry Medicinal chemistry Homogeneous / heterogeneous catalysis Measurement and modelling Molecular assembly at interfaces Electroanalytical chemistry Scanning probe microscopy NMR and mass spectrometry Computational modelling of materials

6 Wide range of interactions with industry High proportion of our funding is from industry leading amongst peer group (ca. 1M p.a.) HESA data for % market share of industry funding (11/12 15/16)

7 Examples of types of interaction CDTs (Analytical sciences; Polymers; Diamond science and technology) require 50% industrial funding of PhD projects Polymer club: consortium which links Warwick Polymer Chemistry to global industries with an interest in polymer science Wide range of individual partnerships (see later) Facilities access: 800K of income from industry access to facilities such mid-2014

8 Spin-out companies Dave Haddleton: Medherant (medherant.co.uk) Transdermal drug delivery using adhesive polymer patches with constant rate of drug release

9 Peter Scott: Interface polymers (interfacepolymers.com) Polarfins are a new range of polymer additives that modify the properties of the world s most commonly used plastics polyethylene and polypropylene making them easier to mix, glue, paint and coat.

10 3 Royal Society Industry Fellows Julie Macpherson: diamondbased electrochemical sensors for applications in healthcare, analysis, environment and security (with ElementSix) Richard Walton: functional inorganic metal oxide materials for hetergeneous catalysis, and electronic properties (with JM) Peter Scott: Interface polymers spinout company

11 Current examples of industry co-sponsored CDT projects: Exploiting very-fast MAS NMR: Enabling New Applications to Pharmaceutical Chemistry and Life Sciences Applications of Electrochemistry in Pharmaceutical Research and Development Detailed structural analysis of agrichemicals using advanced mass spectrometry methods. Photons to heat; how chemical filters deal with UV radiation Analysis of Atomic Order and Disorder in Mixed-Metal Oxide Materials relevat to Heter0geneous Catalysis Petroleomics: Crude and Heavy Fuel Oil Fingerprinting and Asphaltenes Brown / Lewandowski Macpherson O Connor Stavros Walton Barrow Bruker Pfizer Syngenta Lubrizol JM Lubrizol

12 Example 1: Matt Gibson cryopreservation with GE Healthcare Use of low-cost synthetic polymers which prevent / control ice growth Allow cells and tissue samples to be frozen / stored at low temps with less damage

13 Example 2: Martin Wills enantioselective reduction catalyst Commercialised / sold by JM and used in patented work by others

14 Example 3: Giovanni Costantini corrosion inhibitors (with Lubrizol) What is the adsorption configuration of corrosion inhibitors on various metallic surfaces? And what is their chemical state? High-resolution STM and XPS studies on films of corrosion inhibitors

15 Simulation Outputs Example 4: Scott Haberson accelerating catalyst design using reaction-path data-mining (with JM) Modelling the large number of relevant chemical reactions in a catalytic system, provides new directions in nanoparticle catalyst design. Catalysis for exhaust gas processing Path-constrained molecular dynamics Quantum chemistry Kinetic modelling Common exhaust gases CO NOx Pt/Pd/Rh nanoparticles Reaction network + Mechanisms Thermodynamics + Rates (TST) Rate laws + Product selectivity N2 NH3 O2 ktst ΔG Reaction-path data-mining Reactivity/selectivity descriptors Feature extraction Cu-promoted zeolites Reaction-network visualisation

16 Example 5: Ann Dixon structural biology projects with Mologic Ltd. Structures and ligandbinding properties of proteins by NMR, CD, fluorescence, DLS Expertise in protein and ligand design; cloning; mutagenesis; bacterial expression / purification

17 Summary I could go on and on Take-home message: proven outstanding research quality leading amongst our peers in industry income proven success in translation / exploitation Industry-funded projects in all areas (computation, drug discovery, polymers, catalysis, electrochemistry ) Outstanding analytical facilities through out RTPs

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